CN1279145C - Device for preparing coal gas by using fluffy biomass raw material - Google Patents
Device for preparing coal gas by using fluffy biomass raw material Download PDFInfo
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- CN1279145C CN1279145C CN200410041865.9A CN200410041865A CN1279145C CN 1279145 C CN1279145 C CN 1279145C CN 200410041865 A CN200410041865 A CN 200410041865A CN 1279145 C CN1279145 C CN 1279145C
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- 239000003034 coal gas Substances 0.000 title claims abstract description 77
- 239000002028 Biomass Substances 0.000 title claims abstract description 47
- 239000002994 raw material Substances 0.000 title claims abstract description 19
- 238000005406 washing Methods 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000003960 organic solvent Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims description 48
- 239000011343 solid material Substances 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 3
- 238000002309 gasification Methods 0.000 abstract description 33
- 239000011269 tar Substances 0.000 abstract description 22
- 238000000746 purification Methods 0.000 abstract description 20
- 238000006243 chemical reaction Methods 0.000 abstract description 11
- 238000000926 separation method Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000002893 slag Substances 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 9
- 239000002904 solvent Substances 0.000 description 7
- 230000005611 electricity Effects 0.000 description 5
- 239000010902 straw Substances 0.000 description 5
- 238000005336 cracking Methods 0.000 description 4
- 239000000295 fuel oil Substances 0.000 description 4
- 239000010763 heavy fuel oil Substances 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 4
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 238000006479 redox reaction Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000010903 husk Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 244000046109 Sorghum vulgare var. nervosum Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
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- Industrial Gases (AREA)
Abstract
The invention discloses a process and a device for preparing coal gas by using fluffy biomass raw materials. The process comprises the steps of raw material pretreatment, raw material gasification, separation and slag discharge, coal gas purification and coal gas conveying; the device comprises a raw material pretreatment system, a coal gas generation system, a coal gas purification system and a coal gas conveying and storing system. The built-in fast fluidized bed gasification furnace adopted by the invention has the characteristics of high production strength, high gasification efficiency, low coal gas tar content, good operation stability and the like. The gasification reaction is completed at a pneumatic conveying speed, the built-in separator realizes the rapid circulation of the biomass raw material in the gasification furnace, the gas purification adopts a method combining water washing and organic solvent washing, and the method has the characteristics of high tar removal rate, small variation fluctuation of tar content in the gas and the like. The process and the equipment can continuously gasify the fluffy biomass raw material, and the coal gas generated by gasification can be used as the gas source of a gas generator and can also supply gas to surrounding resident users through a pipe network.
Description
Technical field
The present invention relates to biomass material and prepare coal gas craft and equipment, particularly relate to and utilize the fluff type biomass material to prepare coal gas craft, the invention still further relates to the device of this technology.
Background technology
The generalized biomass are meant the hydrocarbon polymer that is produced by photosynthesis.Pressing the quality of biomass material divides, biomass material can be divided into compact-type and fluff type two big classes: the compact-type biomass material mainly comprises agricultural crop straws such as forest zone logging residue, Chinese sorghum, corn, cotton, and the fluff type biomass material mainly comprises farming stalks such as straw, wheat straw, rice husk.China is large agricultural country, and farm crop are based on wheat, paddy rice, so the fluff type biomass material accounts for suitable vast scale in China's biomass resource.
How developing fluff type biomass resource (straw, wheat straw, rice husk, wood chip etc.) effectively and rationally is the key subjects that we face.Domestic gasifying biomass generally adopts the downdraft vapourizing furnace, and this type of furnace is relatively good to compact-type biomass material gasification result, and not ideal enough for fluff type biomass material result of use.For pulverulent materials such as wood chip, wood powders the report that adopts the external circulation fluidized bed vapourizing furnace is arranged, but have defectives such as furnace type structure complexity, poor stability.Wet process is generally adopted in the purification of coal gas, and scavenging process produces a large amount of tar sewage that contain, and causes second environmental pollution.
Summary of the invention
But the object of the present invention is to provide a kind of efficient height, cost low, pollute less continuous gasification fluff type biomass material and prepare coal gas craft.
Another object of the present invention provides the isolated plant of above-mentioned technology.
The objective of the invention is to realize by following measure:
A kind of fluff type biomass material that utilizes prepares coal gas craft, may further comprise the steps:
(1) pre-treatment of raw material: the fluff type biomass material is through pulverizing or be chopped into the fragment of 3-10mm;
(2) gasification of raw material: send into vapourizing furnace through pretreated biomass material fragment, biomass material generates coal gas with gasifying medium generation part redox reaction in vapourizing furnace, gasification reaction carries out in 600 ℃～1000 ℃ temperature ranges, and making the abundant cracking of tar, temperature controlling realizes by the add-on of regulating gasifying medium amount and raw material;
(3) separate, slag tap: the coal gas of high temperature that contains ash content and a small amount of tar of being drawn by vapourizing furnace enters tripping device, and lime-ash adopts the wet method mode of slagging tap that the lime-ash after moistening is discharged gasification system after separating, and the coal gas behind the separation lime-ash enters purification system;
(4) gas purification: the coal gas after the separation is lowered the temperature by washing, can remove ash content and part tar in the coal gas simultaneously; Residual a small amount of tar adopts the organic solvent washing method to remove in the coal gas behind the water washing cleaning; Solvent after using in the purification system recycles after reclaiming;
(5) transmission ﹠ distribution of coal gas: send into gas chamber by the coal gas of purification system output and store standby or as the source of the gas of gas electricity generator, also can pass through the peritropous resident's air feed of pipe network.
The described fluff type biomass material that utilizes prepares coal gas craft, and wherein gasifying medium is an air, and unit is Nm
3Gasification air amount and unit be that the ratio of volume and weight of the raw material add-on of kg is controlled at 1.05～1.15: 1, fluidizing gas velocity is 1.4～2.5m/s.
The described fluff type biomass material that utilizes prepares coal gas craft, and wherein the used organic solvent of gas purification can be heavy oil or heavy fuel oil (HFO), and the solvent cycle amount is 3～5m
3/ h.
A kind of device that utilizes the fluff type biomass material to prepare coal gas comprises raw materials pretreatment system, gas generating system, gas cleaning system, coal gas conveying storage system.
The described device that utilizes the fluff type biomass material to prepare coal gas, wherein gas generating system adopts built-in fast fluidized bed vapourizing furnace.
The described device that utilizes the fluff type biomass material to prepare coal gas, be provided with integral separator in the wherein built-in fast fluidized bed vapourizing furnace, the dipleg of integral separator has adopted the flutter valve sealed structure that contains one or more mobile wings, the sealing structure only allows solid materials dirty and do not allow gas to scurry into, and the mobile wing of flutter valve can be according to the buildup situation automatic open close in the dipleg.
The described device that utilizes the fluff type biomass material to prepare coal gas, wherein integral separator links to each other with the coal gas fairlead of sufficient length in the vapourizing furnace, and coal gas fairlead process vapourizing furnace is drawn vapourizing furnace behind the high-temperature zone.
The described device that utilizes the fluff type biomass material to prepare coal gas, wherein gas cleaning system is made of water washing device and organic solvent washing device.
The described device that utilizes the fluff type biomass material to prepare coal gas, wherein the water washing device is made of bubble tower, one or several washing tower.
The described device that utilizes the fluff type biomass material to prepare coal gas, wherein the organic solvent washing device is made of Venturi meter.
Processing step key of the present invention is the gasification of biomass material and the purification of coal gas, and the key equipment of gasification is built-in fast fluidized bed vapourizing furnace.
Advantage of the present invention:
(1) the built-in fast fluidized bed gasification furnace structure of the present invention's employing is simple, and the body of heater overall cost is cheap, easy construction, body of heater long service life; Closed circulation stage purification technology is adopted in gas purification in the technology, and the micro-tar in the coal gas after washing adopts solvent method to remove, and solvent recycles after recycling, the purification efficiency height, and production cost is low.
(2) integral separator is realized the Rapid Cycle of fluff type biomass material in the vapourizing furnace, biomass gasification reaction is finished under high gas speed 1.4～2.5m/s (greater than the raw material particle velocity) condition, gasification furnace heat transfer, mass transfer velocity is fast, unit gasification space production intensity is big, and the vapourizing furnace operational stability is good; The dipleg of integral separator has adopted single-blade or multiple wing valve seal structure, and the sealing structure only allows solid materials dirty and do not allow gas to scurry into, and the valve wing can guarantee the separating effect of integral separator according to the buildup situation automatic open close in the dipleg; The solid materials of the not gasification that integral separator is collected returns the vapourizing furnace bottom by dipleg to be continued to participate in reaction, has reduced vapourizing furnace and has flown the charcoal amount, and the charcoal transformation efficiency of biomass material has improved the utilization ratio of biomass greater than 95%.The 5-10 that the built-in fast fluidized bed vapourizing furnace production intensity that the present invention adopts is common fluidized-bed gasification furnace doubly, carbon content is less than 20% in the lime-ash, the material carbon transformation efficiency is greater than 95%, the caloric power of gas that produces greater than 5800kJ/Nm
3
(3) because temperature is too high, be easy to slagging scorification, temperature is low excessively, be difficult for effecting reaction, the gas quality of preparation is poor, one aspect of the present invention is by regulating the feed rate control gasification reaction temperature of gasification air amount and raw material, on the other hand the vapourizing furnace main body is adopted metallic substance and non-metallic material structure combining, be that steel construction is adopted on top, the bottom adopts non-metallic refractory to construct, and makes this vapourizing furnace gasification zone wide, and the gasification reaction temperature is even, the furnace heat transfer mass transfer velocity is fast, can effectively prevent the slagging scorification problem that causes because of local superheating.
(4) coal gas of vapourizing furnace generation adopts the fairlead of certain-length to draw vapourizing furnace behind the vapourizing furnace high-temperature zone, coal gas has enough residence time to make the tar in the coal gas obtain abundant cracking in fairlead, the coal-tar middle oil content of vapourizing furnace outlet coal gas is low, and the main flammable composition in the coal gas is: CO, H
2, CH
4, C
mH
nDeng.The method that gas purification adopts washing and organic solvent washing to combine is undertaken by bubble tower-first washing tower-second washing tower-4 grades of purification process of organic solvent washing device (Venturi meter); Solvent method is removed micro-tar technology and is had characteristics such as running cost is low, tar clearance height, and the coal-tar middle oil content of the coal gas after the purification is less than 30mg/Nm
3, can satisfy the requirement of gas electricity generator requirement or pipe-line transportation fully.
(5) coal gas that produced of the present invention gasification can be used as the source of the gas of gas electricity generator; also can pass through the peritropous resident's air feed of pipe network; it is the effective way that solves the superfluous problem of a large amount of fluff type biomass materials in rural area; applying of this technology for promoting rural area renewable biomass reasonable resources utilization; the protection environment; improve the rural energy supply, the quality of life that improves the peasant has huge social and economic benefit.
Description of drawings
Fig. 1 is a process flow sheet of the present invention.
Fig. 2 be the present invention adopt contain the vertical built-in fast fluidized bed gasification furnace structure synoptic diagram that draws formula coal gas fairlead down.
Fig. 3 is the double-vane valve seal structural representation that the present invention adopts.
Fig. 4 be the present invention adopt contain the built-in fast fluidized bed gasification furnace structure synoptic diagram that draws formula coal gas fairlead under the spiral.
Fig. 5 is the single-blade valve seal structural representation that the present invention adopts.
Embodiment
In conjunction with the accompanying drawings specific embodiments of the present invention is further described:
In conjunction with the accompanying drawings 1,2,3, technology of the present invention is: the fluff type biomass material is ground into the particle of 8-10mm with shredding unit, adds material bin 2 by promoting spiral 1, sent into the bottom of built-in fast fluidized bed vapourizing furnace 4 again by screw feeder 3; Air is sent in the stove from inlet mouth 27, controls the gasification reaction temperature at 800 ℃～900 ℃ by the feed rate of regulating gasification air amount and raw material, and the ratio of control gasification air amount (Nm3) and raw material add-on (kg) is 1.15.Fluidizing gas velocity is 2.5m/s in the vapourizing furnace, and biomass material is boiling state in vapourizing furnace and the part redox reaction takes place gasifying medium (air), produces coal gas.Entrained solids material and cindery coal gas enter built-in cyclonic separator 20, the solid materials that captures through cyclonic separator 20 returns the vapourizing furnace bottom by the double-vane valve seal structure 22 of dipleg 21 to be continued reaction (double-vane valve seal structure 22 is connected dipleg 21 lower ends by fin 26 by hinge 24, the inner conical device 25 in addition in dipleg 21 lower ends, lime-ash after the separation and solid materials fall into dipleg 21, solid materials runs up to certain altitude in dipleg, the pressure that material produces fin during greater than the restoring force of fin self fin open automatically, material flows out thus, in dipleg material more after a little while, fin 26 is returned to sealed state under the own wt effect).The coal gas that vapourizing furnace produces contains impurity such as part lime-ash draws through coal gas fairlead 23 that (coal gas fairlead 23 adopts and draws formula under vertical, draw behind the high-temperature zone of vapourizing furnace 4 from built-in cyclonic separator 20, coal gas fairlead 23 keeps certain length in vapourizing furnace, make tar under high temperature action, carry out abundant cracking), send into external cyclone water-separator 5, isolated lime-ash enters ash bin 6, lime-ash in the ash bin is discharged continuously by spiral tapping machine 7 after moistening, the coal gas of high temperature that is come out by cyclonic separator 5 is introduced into bubble tower 8, utilize the water in the bubble tower to remove part of ash and tar in the coal gas, enter first washing tower 9 again, second washing tower 10 continues the washing cooling, remove tar and dust, enter organic solvent washing device (Venturi meter) 12 at last and further go out micro-tar in the coal gas by heavy oil.Heavy oil enters storage tank 13 after separating, the heavy oil of recovery is sent into washing system by pump 11 and recycled, solvent cycle amount 5m
3/ h, the tar content in the coal gas after the purification is less than 30mg/Nm
3Coal gas after the purification is sent into gas chamber 16 by roots blower 14 after water seal 15, the coal gas in the gas chamber can be used as the source of the gas of gas electricity generator 17, also can be by pipe network to resident's 18 air feed.
In conjunction with the accompanying drawings 1,4,5, technology of the present invention is: the fluff type biomass material is ground into the particle of 3-5mm with shredding unit, adds material bin 2 by promoting spiral 1, sent into the bottom of built-in fast fluidized bed vapourizing furnace 4 again by screw feeder 3; Air is sent in the stove from inlet mouth 27, controls the gasification reaction temperature at 700 ℃～800 ℃ by the feed rate of regulating gasification air amount and raw material, and the ratio of control gasification air amount (Nm3) and raw material add-on (kg) is 1.05.Fluidizing gas velocity is 1.4m/s in the vapourizing furnace, and biomass material is boiling state in vapourizing furnace and the part redox reaction takes place gasifying medium (air), produces coal gas.Entrained solids material and cindery coal gas enter built-in cyclonic separator 20, the solid materials that captures through cyclonic separator 20 returns the vapourizing furnace bottom by the single-blade valve seal structure 22 of dipleg 21 to be continued reaction (single-blade valve seal structure 22 is connected dipleg 21 lower ends by fin 26 by hinge 24, the inner conical device 25 in addition in dipleg 21 lower ends, lime-ash after the separation and solid materials fall into dipleg 21, solid materials runs up to certain altitude in dipleg, the pressure that material produces fin 26 is during greater than the restoring force of fin self, fin is opened automatically, material flows out thus, in dipleg material more after a little while, fin 26 is returned to sealed state under the own wt effect).The coal gas that vapourizing furnace produces contains impurity such as part lime-ash draws through coal gas fairlead 23 that (coal gas fairlead 23 adopts and draws formula under the spirals, behind the high temperature of built-in cyclonic separator 20, draw via vapourizing furnace 4, coal gas fairlead 23 keeps certain length in vapourizing furnace, make tar under high temperature action, carry out abundant cracking), send into external cyclone water-separator 5, isolated lime-ash enters ash bin 6, lime-ash in the ash bin is discharged continuously by spiral tapping machine 7 after moistening, the coal gas of high temperature that is come out by cyclonic separator 5 is introduced into bubble tower 8, utilize the water in the bubble tower to remove part of ash and tar in the coal gas, enter first washing tower 9 again, second washing tower 10 continues the washing cooling, remove tar and dust, enter organic solvent washing device (Venturi meter) 12 at last and further go out micro-tar in the coal gas by the 180# heavy fuel oil (HFO).Heavy fuel oil (HFO) enters storage tank 13 after separating, the heavy fuel oil (HFO) of recovery is sent into washing system by pump 11 and recycled, solvent cycle amount 3m
3/ h, the tar content in the coal gas after the purification is less than 27mg/Nm
3Coal gas after the purification is sent into gas chamber 16 by roots blower 14 after water seal 15, the coal gas in the gas chamber can be used as gas electricity generator 17, also can be by pipe network to resident's 18 air feed.
Claims (4)
1, a kind of device that utilizes the fluff type biomass material to prepare coal gas, this device comprises raw materials pretreatment system, gas generating system, gas cleaning system, coal gas conveying storage system, wherein gas generating system adopts built-in fast fluidized bed vapourizing furnace, it is characterized in that being provided with built-in cyclonic separator in the built-in fast fluidized bed vapourizing furnace; The dipleg of built-in cyclonic separator has adopted the flutter valve sealed structure that contains one or more mobile wings, the sealing structure only allow solid materials by and do not allow gas to scurry into, the movable wing of flutter valve can be according to the buildup situation automatic open close in the dipleg.
2, the device that utilizes the fluff type biomass material to prepare coal gas according to claim 1 is characterized in that built-in cyclonic separator links to each other with the coal gas fairlead of sufficient length in the vapourizing furnace, and coal gas fairlead process vapourizing furnace is drawn vapourizing furnace behind the high-temperature zone.
3, the device that utilizes the fluff type biomass material to prepare coal gas according to claim 1 is characterized in that gas cleaning system is combined with the organic solvent washing device by the water washing device to form.
4, the device that utilizes the fluff type biomass material to prepare coal gas according to claim 3 is characterized in that the organic solvent washing device is made of Venturi meter.
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| Application Number | Priority Date | Filing Date | Title |
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| CN200410041865.9A CN1279145C (en) | 2004-09-03 | 2004-09-03 | Device for preparing coal gas by using fluffy biomass raw material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200410041865.9A CN1279145C (en) | 2004-09-03 | 2004-09-03 | Device for preparing coal gas by using fluffy biomass raw material |
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| CN1279145C true CN1279145C (en) | 2006-10-11 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101319752B (en) * | 2007-06-06 | 2010-06-02 | 曾自旺 | Biomass gasification centralized safety and early warning air supplying system |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102653687A (en) * | 2011-03-03 | 2012-09-05 | 天津大明恒运再生能源利用科技有限公司 | Process for preparing high-purity combustible gas by utilizing biomass fuel |
| CN102260538B (en) * | 2011-06-24 | 2013-04-17 | 华中科技大学 | Method and device for air-floatation flow-state high-temperature heat-transfer gasification of biomass |
| CN105299622A (en) * | 2014-05-27 | 2016-02-03 | 上海毅知实业有限公司 | Method for combusting biomass synthetic fuel |
| CN104449793A (en) * | 2014-12-11 | 2015-03-25 | 广州迪森热能技术股份有限公司 | Biomass liquefaction system |
| CN106701197A (en) * | 2016-12-27 | 2017-05-24 | 广东国能中林实业有限公司 | Tar removal structure of biomass gasifying furnace and application method of tar removal structure |
| CN108676580B (en) * | 2018-06-28 | 2023-09-12 | 内蒙古科技大学 | High Wen Jiaohu type double-fixed bed gasification furnace and process method thereof |
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2004
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101319752B (en) * | 2007-06-06 | 2010-06-02 | 曾自旺 | Biomass gasification centralized safety and early warning air supplying system |
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