CN104449793A - Biomass liquefaction system - Google Patents

Biomass liquefaction system Download PDF

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Publication number
CN104449793A
CN104449793A CN201410764533.7A CN201410764533A CN104449793A CN 104449793 A CN104449793 A CN 104449793A CN 201410764533 A CN201410764533 A CN 201410764533A CN 104449793 A CN104449793 A CN 104449793A
Authority
CN
China
Prior art keywords
gas
bed reactor
communicated
solid separator
fluidized bed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410764533.7A
Other languages
Chinese (zh)
Inventor
常厚春
马革
杨红斌
孙国家
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU DISEN BIOLOGICAL ENERGY CO Ltd
Guangzhou Devotion Thermal Technology Co Ltd
Original Assignee
SUZHOU DISEN BIOLOGICAL ENERGY CO Ltd
Guangzhou Devotion Thermal Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU DISEN BIOLOGICAL ENERGY CO Ltd, Guangzhou Devotion Thermal Technology Co Ltd filed Critical SUZHOU DISEN BIOLOGICAL ENERGY CO Ltd
Priority to CN201410764533.7A priority Critical patent/CN104449793A/en
Publication of CN104449793A publication Critical patent/CN104449793A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The invention discloses a biomass liquefaction system, which comprises a drying oven, a fluidized bed reactor, a gas-solid separator and a two-stage spray tower, wherein a discharge outlet of the drying oven is communicated with a feed inlet of the fluidized bed reactor, a cracking gas outlet of the fluidized bed reactor is communicated with a cracking gas inlet of the gas-solid separator, a cracking gas outlet of the gas-solid separator is communicated with a cracking gas inlet of the two-stage spray tower, and a non-condensable gas outlet of the two-stage spray tower is communicated with a hearth of the drying oven; and the bottom of the fluidized bed reactor is communicated with an air blower with the output air velocity of 600-800m<3>/h and pressure of 2-4kpa. The air blower is used for supplying low-velocity air for the bottom of the fluidized bed reactor, a biomass fuel is at a gently rolling state and has slow gasification reaction, the yield of cracking gas can be increased, the carbon yield can be reduced and the cracking gas contains extremely low heat carriers, an auxiliary reactor is omitted, and the system running safety can be improved.

Description

Biomass liquefaction system
Technical field
The invention belongs to liquefaction technology field, specifically relate to a kind of system utilizing biomass fuel liquefaction to prepare ecological oil.
Background technology
The main process of ecological oil preparation technology is: biomass material reacts and produces splitting gas in ebullated bed reactor, the charcoal contained in gas and thermal barrier are separated through the gas solid separation step of separator by splitting gas, clean splitting gas through condensing tower cooling step formed ecological oil, and not condensated gas it directly need be diffused all burnt or recycle supply stoving oven burning produce heat energy to dry biomass material.
The gasification reaction system of prior art adopts circulating fluidized bed as main reactor, belong to Quick-gasifying reaction, the output of splitting gas is lower, and due to the combined amount of the charcoal that contains in gas and thermal barrier more, therefore, the subsequent step of gas-solid separator also needs to increase auxiliary reactor, utilize charcoal and thermal barrier Thorough combustion Posterior circle to be inputed to circulating fluid bed reactor, the composition structure of whole system is seemed, and redundancy is complicated, recycle charcoal comes, to thermal barrier additional heat, to add system cloud gray model risk.Condensated gas is not in constantly recycle process, requires higher to the stopping property of system and oxygen level.
Summary of the invention
In order to solve prior art Problems existing, the invention provides that a kind of ecological oil output is high, the biomass liquefaction system of system simplification, safety.
In order to realize above object, the technical scheme that the present invention takes is: a kind of biomass liquefaction system, comprises the stoving oven of drying biomass material, twin-stage spray column that the ebullated bed reactor producing splitting gas, the gas-solid separator isolating splitting gas and solids, condensation splitting gas become ecological oil; The discharge port of stoving oven is communicated with the opening for feed of ebullated bed reactor, the splitting gas entrance of the splitting gas outlet gas-solid separator of ebullated bed reactor, the splitting gas entrance of the splitting gas outlet twin-stage spray column of gas-solid separator, the burner hearth of the not condensated gas outlet stoving oven of twin-stage spray column; It is 600 ~ 800m that the bottom of described ebullated bed reactor is communicated with an output wind speed 3/ h and pressure is the gas blower of 2 ~ 4kpa.
Compared with prior art, the advantage of liquefaction system of the present invention is: by being communicated with a gas blower at ebullated bed reactor, and gas blower provides wind speed to be 600 ~ 800m bottom boiling reactor 3/ h and pressure is the low velocity wind of 2 ~ 4kpa, the biomass fuel of ebullated bed reactor inside produces mild tumbling state, anti-raw gasification reaction at a slow speed simultaneously, improve splitting gas output, reduce carbon yield and containing the thermal barrier of very low amounts in splitting gas, save auxiliary reactor, improve system cloud gray model security.
Accompanying drawing explanation
Fig. 1 is the structural representation of biomass liquefaction system.
Embodiment
As shown in Figure 1, biomass liquefaction system comprises stoving oven, ebullated bed reactor, gas-solid separator, twin-stage spray column and gas blower.
Stoving oven exports dried biomass fuel and inputs ebullated bed reactor by pipeline, the gas that ebullated bed reactor scission reaction produces inputs gas-solid separator by tracheae, the gas of gas-solid separator is by tracheae input twin-stage spray column, and the gas of twin-stage spray column inputs the burner hearth of stoving oven by tracheae.
The principle of work of biomass liquefaction system is: thermal barrier (sand) is present in the medium as heating in ebullated bed reactor.Stoving oven inputs ebullated bed reactor after being dried by biomass wet feed material, and now, it is 600 ~ 800m that ebullated bed reactor sends into wind speed from bottom by gas blower 3/ h and pressure are that the air of 2 ~ 4kpa participates in incomplete combustion reaction, biomass fuel produces mild tumbling state, anti-raw gasification reaction at a slow speed simultaneously, after scission reaction, produce splitting gas enter gas-solid separator, the clean splitting gas separated enters twin-stage spray column, condensated gas in splitting gas is condensed into as ecological oil, not condensated gas then circulation and stress input to stoving oven burning.The a small amount of charcoal contained in the splitting gas that ebullated bed reactor produces stores after gas-solid separator is separated with powder thermal barrier mixture.

Claims (1)

1. a biomass liquefaction system, comprises the stoving oven of drying biomass material, twin-stage spray column that the ebullated bed reactor producing splitting gas, the gas-solid separator isolating splitting gas and solids, condensation splitting gas become ecological oil;
The discharge port of stoving oven is communicated with the opening for feed of ebullated bed reactor, the splitting gas entrance of the splitting gas outlet gas-solid separator of ebullated bed reactor, the splitting gas entrance of the splitting gas outlet twin-stage spray column of gas-solid separator, the burner hearth of the not condensated gas outlet stoving oven of twin-stage spray column;
It is characterized in that: it is 600 ~ 800m that the bottom of described ebullated bed reactor is communicated with an output wind speed 3/ h and pressure is the gas blower of 2 ~ 4kpa.
CN201410764533.7A 2014-12-11 2014-12-11 Biomass liquefaction system Pending CN104449793A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410764533.7A CN104449793A (en) 2014-12-11 2014-12-11 Biomass liquefaction system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410764533.7A CN104449793A (en) 2014-12-11 2014-12-11 Biomass liquefaction system

Publications (1)

Publication Number Publication Date
CN104449793A true CN104449793A (en) 2015-03-25

Family

ID=52896556

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410764533.7A Pending CN104449793A (en) 2014-12-11 2014-12-11 Biomass liquefaction system

Country Status (1)

Country Link
CN (1) CN104449793A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108949203A (en) * 2018-06-08 2018-12-07 嘉禾聚能(天津)科技有限公司 A kind of biomass pyrolysis system of solid thermal carriers circulation
CN109628160A (en) * 2019-01-30 2019-04-16 中国科学院广州能源研究所 A kind of high humidity biomass gasification method and system

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1603388A (en) * 2004-09-03 2005-04-06 南京工业大学 Process and device for preparing coal gas by using fluffy biomass raw material
CN101848979A (en) * 2007-07-20 2010-09-29 芬欧汇川集团 Method and apparatus for producing liquid biofuel from solid biomass
CN102108301A (en) * 2009-12-24 2011-06-29 中国石油化工股份有限公司 Method for producing high-yield tar by pyrolyzing coal
CN103313783A (en) * 2010-11-16 2013-09-18 科伊奥股份有限公司 Two-stage reactor and process for conversion of solid biomass meterial
US20130239479A1 (en) * 2010-11-01 2013-09-19 Shiqiu Gao Apparatus and Method for Multistage Hierachical Pyrolysis and Gasification of Solid Fuels
CN203715567U (en) * 2014-01-16 2014-07-16 华北电力大学 Rolling type biomass pyrolysis poly-generation device

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1603388A (en) * 2004-09-03 2005-04-06 南京工业大学 Process and device for preparing coal gas by using fluffy biomass raw material
CN101848979A (en) * 2007-07-20 2010-09-29 芬欧汇川集团 Method and apparatus for producing liquid biofuel from solid biomass
CN102108301A (en) * 2009-12-24 2011-06-29 中国石油化工股份有限公司 Method for producing high-yield tar by pyrolyzing coal
US20130239479A1 (en) * 2010-11-01 2013-09-19 Shiqiu Gao Apparatus and Method for Multistage Hierachical Pyrolysis and Gasification of Solid Fuels
CN103313783A (en) * 2010-11-16 2013-09-18 科伊奥股份有限公司 Two-stage reactor and process for conversion of solid biomass meterial
CN203715567U (en) * 2014-01-16 2014-07-16 华北电力大学 Rolling type biomass pyrolysis poly-generation device

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
牛晓庆等: "《固体废物处理与处置》", 31 December 2013, article "热解原理及影响因素", pages: 142 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108949203A (en) * 2018-06-08 2018-12-07 嘉禾聚能(天津)科技有限公司 A kind of biomass pyrolysis system of solid thermal carriers circulation
CN109628160A (en) * 2019-01-30 2019-04-16 中国科学院广州能源研究所 A kind of high humidity biomass gasification method and system
CN109628160B (en) * 2019-01-30 2024-08-06 中国科学院广州能源研究所 High-humidity biomass gasification method and system

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Application publication date: 20150325