CN1269863C - 含有缩二脲的聚异氰酸酯的制备及其作为涂料的交联剂的用途 - Google Patents

含有缩二脲的聚异氰酸酯的制备及其作为涂料的交联剂的用途 Download PDF

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Publication number
CN1269863C
CN1269863C CNB028185757A CN02818575A CN1269863C CN 1269863 C CN1269863 C CN 1269863C CN B028185757 A CNB028185757 A CN B028185757A CN 02818575 A CN02818575 A CN 02818575A CN 1269863 C CN1269863 C CN 1269863C
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CN
China
Prior art keywords
polyisocyanate
groups
adduct
biuret
isocyanurate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB028185757A
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English (en)
Chinese (zh)
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CN1582309A (zh
Inventor
杰尔姆·T.·亚当斯
罗伯特·J.·巴尔索蒂
劳拉·A.·卢因
莱因哈德·哈尔普艾普
迪特尔·马杰
迈伦·W.·谢弗
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Bayer AG
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Bayer AG
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Publication date
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Publication of CN1582309A publication Critical patent/CN1582309A/zh
Application granted granted Critical
Publication of CN1269863C publication Critical patent/CN1269863C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
    • C08G18/022—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB028185757A 2001-09-21 2002-09-20 含有缩二脲的聚异氰酸酯的制备及其作为涂料的交联剂的用途 Expired - Fee Related CN1269863C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US32408401P 2001-09-21 2001-09-21
US60/324,084 2001-09-21

Publications (2)

Publication Number Publication Date
CN1582309A CN1582309A (zh) 2005-02-16
CN1269863C true CN1269863C (zh) 2006-08-16

Family

ID=23261994

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB028185757A Expired - Fee Related CN1269863C (zh) 2001-09-21 2002-09-20 含有缩二脲的聚异氰酸酯的制备及其作为涂料的交联剂的用途

Country Status (13)

Country Link
US (2) US20030109664A1 (cg-RX-API-DMAC10.html)
EP (1) EP1446435B1 (cg-RX-API-DMAC10.html)
JP (1) JP2005504137A (cg-RX-API-DMAC10.html)
KR (1) KR20040039380A (cg-RX-API-DMAC10.html)
CN (1) CN1269863C (cg-RX-API-DMAC10.html)
AT (1) ATE290030T1 (cg-RX-API-DMAC10.html)
BR (1) BR0212992A (cg-RX-API-DMAC10.html)
CA (1) CA2457802C (cg-RX-API-DMAC10.html)
DE (1) DE60203137D1 (cg-RX-API-DMAC10.html)
ES (1) ES2236565T3 (cg-RX-API-DMAC10.html)
MX (1) MXPA04002650A (cg-RX-API-DMAC10.html)
TW (1) TW593393B (cg-RX-API-DMAC10.html)
WO (1) WO2003025040A1 (cg-RX-API-DMAC10.html)

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ES2288553T3 (es) * 2001-06-15 2008-01-16 Huntsman Petrochemical Corporation Extensores de cadena amina sinergicos en elastomeros en pulverizacion de poliurea.
DE10322911A1 (de) * 2003-05-21 2004-12-16 Bayer Materialscience Ag Verfestigungsstabile blockierte Polyisocyanate
US20050038204A1 (en) * 2003-08-14 2005-02-17 Walters David N. Increased pot-life urethane coatings
DE10348380A1 (de) * 2003-10-17 2005-06-02 Bayer Materialscience Ag Mit sekundären Aminen blockierte Polyisocyanate mit Biuretstruktur
US8653220B2 (en) * 2004-09-01 2014-02-18 Ppg Industries Ohio, Inc. Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same
US7371807B2 (en) * 2004-10-21 2008-05-13 Bayer Materialscience Llc Blocked biuretized isocyanates
US20060089480A1 (en) * 2004-10-21 2006-04-27 Roesler Richard R Biuretized isocyanates and blocked biuretized isocyanates
US20060089481A1 (en) * 2004-10-21 2006-04-27 Roesler Richard R Blocked biuretized isocyanates
JP5183025B2 (ja) * 2005-12-22 2013-04-17 旭化成ケミカルズ株式会社 ポリイソシアネート組成物の製造方法
US20070269661A1 (en) * 2006-05-16 2007-11-22 Graham William F Ultraproductive coating composition using a chemically mixed isocyanate system
CA2652660A1 (en) * 2006-05-16 2007-11-29 E.I. Du Pont De Nemours And Company Highly productive coating composition for automotive refinishing
GB2456696B (en) * 2006-10-23 2012-05-02 Kansai Paint Co Ltd Aqueous two-package type clear coating composition
US20100305294A1 (en) * 2007-11-28 2010-12-02 Mitsui Chemicals, Inc. Polyurethane resin composition for reaction injection molding and molded article
DE102009038463A1 (de) * 2009-08-21 2011-02-24 Bayer Materialscience Ag Verfahren zur Herstellung von Polyisocyanaten mit Biuretstruktur
KR101102730B1 (ko) * 2010-03-22 2012-01-05 임성훈 줄 홀더
CN102617827B (zh) * 2011-01-27 2013-10-30 襄阳精信汇明化工有限责任公司 一种固化剂改性1，6-己二异氰酸酯缩二脲及其制备方法
CN102702476B (zh) * 2012-06-07 2013-12-25 华南理工大学 一种六亚甲基二异氰酸酯缩二脲的制备方法
JP5948164B2 (ja) * 2012-06-28 2016-07-06 Ｂａｓｆジャパン株式会社 複層塗膜形成方法
JP5688571B2 (ja) * 2013-02-04 2015-03-25 日本ペイント株式会社 複層塗膜形成方法
ES2692995T3 (es) * 2014-06-06 2018-12-07 Akzo Nobel Coatings International B.V. Revestimientos que pueden ser decapados selectivamente para substratos metálicos y de plástico
KR101493269B1 (ko) * 2014-09-17 2015-02-16 애경화학 주식회사 저장성이 향상된 뷰렛 그룹 함유 알리파틱 폴리이소시아네이트의 제조방법
EP3309189B1 (en) 2015-06-12 2026-03-04 Mitsui Chemicals, Inc. Polyisocyanate composition, polyurethane resin, two-liquid curable polyurethane composition, and coating material
EP3309185B1 (en) * 2015-06-12 2020-01-29 Mitsui Chemicals, Inc. Polyisocyanate composition, polyurethane resin and two-component curable polyurethane composition
WO2016199795A1 (ja) 2015-06-12 2016-12-15 三井化学株式会社 ポリイソシアネート組成物、ポリウレタン樹脂、二液硬化型ポリウレタン組成物、コーティング材料および接着材料
US10689481B2 (en) 2015-06-12 2020-06-23 Mitsui Chemicals, Inc. Polyisocyanate composition, polyurethane resin, two-component curable polyurethane composition, and coating material
US10400112B2 (en) * 2017-06-22 2019-09-03 Covestro Llc Powder coating compositions with a polymeric aromatic product of an aromatic isocyanate manufacturing process
EP3421516A1 (de) * 2017-06-28 2019-01-02 Covestro Deutschland AG Gefärbte kunststoffe basierend auf vernetzten polyisocyanaten
WO2020057933A1 (en) * 2018-09-18 2020-03-26 Byk-Chemie Gmbh An amine functional compound having a urethane group
ES3059952T3 (en) 2019-03-18 2026-03-24 Allnex Netherlands Bv Non-aqueous crosslinkable composition
CN110790895B (zh) * 2019-11-08 2021-09-07 万华化学集团股份有限公司 一种脂肪族多异氰酸酯组合物、其制备方法及涂料组合物
CN113930142B (zh) * 2020-06-29 2024-06-11 科思创德国股份有限公司 一种双组分涂料组合物
CN116444764B (zh) * 2022-01-07 2026-07-10 万华化学（宁波）有限公司 一种低粘度的高官能度缩二脲多异氰酸酯组合物及其制备方法

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Also Published As

Publication number Publication date
DE60203137D1 (de) 2005-04-07
BR0212992A (pt) 2004-09-21
CN1582309A (zh) 2005-02-16
TW593393B (en) 2004-06-21
EP1446435B1 (en) 2005-03-02
MXPA04002650A (es) 2004-07-08
CA2457802A1 (en) 2003-03-27
US20050033008A1 (en) 2005-02-10
CA2457802C (en) 2010-11-16
ATE290030T1 (de) 2005-03-15
WO2003025040A1 (en) 2003-03-27
US20030109664A1 (en) 2003-06-12
EP1446435A1 (en) 2004-08-18
ES2236565T3 (es) 2005-07-16
WO2003025040A8 (en) 2004-03-11
JP2005504137A (ja) 2005-02-10
KR20040039380A (ko) 2004-05-10

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Termination date: 20110920