CN1266788C - 一种具有锌阳极的碱性二次电化学发电机 - Google Patents
一种具有锌阳极的碱性二次电化学发电机 Download PDFInfo
- Publication number
- CN1266788C CN1266788C CNB028193407A CN02819340A CN1266788C CN 1266788 C CN1266788 C CN 1266788C CN B028193407 A CNB028193407 A CN B028193407A CN 02819340 A CN02819340 A CN 02819340A CN 1266788 C CN1266788 C CN 1266788C
- Authority
- CN
- China
- Prior art keywords
- zinc
- zinc anode
- secondary electrochemical
- electrochemical generators
- alkaline secondary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011701 zinc Substances 0.000 title claims abstract description 137
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 133
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 131
- 239000000654 additive Substances 0.000 claims abstract description 53
- 239000003792 electrolyte Substances 0.000 claims abstract description 53
- 230000000996 additive effect Effects 0.000 claims abstract description 51
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 12
- 229910052788 barium Inorganic materials 0.000 claims abstract description 11
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 11
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 10
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 10
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 10
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 8
- 229910052701 rubidium Inorganic materials 0.000 claims abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 82
- 239000011787 zinc oxide Substances 0.000 claims description 39
- 239000011149 active material Substances 0.000 claims description 36
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 33
- 229910010293 ceramic material Inorganic materials 0.000 claims description 32
- 150000001875 compounds Chemical class 0.000 claims description 24
- -1 alkali metal titanate Chemical class 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 239000006183 anode active material Substances 0.000 claims description 12
- 239000011575 calcium Substances 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 11
- 239000012141 concentrate Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 9
- 239000010936 titanium Substances 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 150000001399 aluminium compounds Chemical class 0.000 claims description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 7
- 150000004767 nitrides Chemical class 0.000 claims description 7
- 229910052797 bismuth Inorganic materials 0.000 claims description 6
- 230000004044 response Effects 0.000 claims description 6
- 229910017083 AlN Inorganic materials 0.000 claims description 4
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 claims description 4
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 3
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 150000004645 aluminates Chemical class 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims 8
- 239000000919 ceramic Substances 0.000 abstract description 4
- 239000012670 alkaline solution Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 33
- 238000003860 storage Methods 0.000 description 31
- 230000004087 circulation Effects 0.000 description 27
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 24
- 230000008569 process Effects 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 6
- 239000010405 anode material Substances 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 230000035784 germination Effects 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 150000005837 radical ions Chemical group 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 241000555268 Dendroides Species 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 239000006262 metallic foam Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 229920013683 Celanese Polymers 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 235000012241 calcium silicate Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- BSWGGJHLVUUXTL-UHFFFAOYSA-N silver zinc Chemical compound [Zn].[Ag] BSWGGJHLVUUXTL-UHFFFAOYSA-N 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- KRVQALMTMXRXDE-UHFFFAOYSA-M Br[Zn] Chemical compound Br[Zn] KRVQALMTMXRXDE-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- ZXYNGLRGFYLTQZ-UHFFFAOYSA-M [Zn]Cl Chemical compound [Zn]Cl ZXYNGLRGFYLTQZ-UHFFFAOYSA-M 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910000052 cadmium hydride Inorganic materials 0.000 description 1
- JEZHBSJTXKKFMV-UHFFFAOYSA-N calcium nickel Chemical compound [Ca].[Ni] JEZHBSJTXKKFMV-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000001976 improved effect Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- GROMGGTZECPEKN-UHFFFAOYSA-N sodium metatitanate Chemical compound [Na+].[Na+].[O-][Ti](=O)O[Ti](=O)O[Ti]([O-])=O GROMGGTZECPEKN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 210000000352 storage cell Anatomy 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YJVLWFXZVBOFRZ-UHFFFAOYSA-N titanium zinc Chemical compound [Ti].[Zn] YJVLWFXZVBOFRZ-UHFFFAOYSA-N 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/244—Zinc electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/26—Selection of materials as electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
Description
活性材料金属锌氮化钛(2)钛酸钙铝酸钙氧化铋氢氧化镍增塑剂悬浮剂 | 阳极A1 | 阳极A2 | 阳极A3 |
ZnO粉末5%(1)18%(3)--5%(1)5%(1)P.T.F.E.(4)水 | ZnO粉末5%(1)15%(3)2.5%(3)2%(3)5%(1)5%(1)P.T.F.E.(4)水 | ZnO粉末5%(1)10%(3)1.25%3%(3)5%(1)5%(1)P.T.F.E.(4)水 | |
支撑体:交联泡沫(5)(初始厚度2mm) | Cu+Pb,45PPI550g/m2 | Cu+Pb,45PPI550g/m2 | Cu,45PPI400g/m2 |
Claims (31)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR01/10488 | 2001-08-03 | ||
FR0110488A FR2828335B1 (fr) | 2001-08-03 | 2001-08-03 | Anode de zinc pour generateurs electrochimiques secondaires alcalins |
FR0204379A FR2828336B1 (fr) | 2001-08-03 | 2002-04-05 | Generateurs electrochimiques secondaires alcalins a anode de zinc |
FR02/04379 | 2002-04-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1561553A CN1561553A (zh) | 2005-01-05 |
CN1266788C true CN1266788C (zh) | 2006-07-26 |
Family
ID=26213131
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB028193407A Expired - Lifetime CN1266788C (zh) | 2001-08-03 | 2002-08-05 | 一种具有锌阳极的碱性二次电化学发电机 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7300721B2 (zh) |
EP (1) | EP1412994B1 (zh) |
JP (1) | JP4374247B2 (zh) |
CN (1) | CN1266788C (zh) |
AU (1) | AU2002321709A1 (zh) |
CA (1) | CA2456214C (zh) |
DK (1) | DK1412994T5 (zh) |
ES (1) | ES2421507T3 (zh) |
FR (1) | FR2828336B1 (zh) |
HK (1) | HK1061923A1 (zh) |
WO (1) | WO2003015197A2 (zh) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8003258B2 (en) * | 2006-01-19 | 2011-08-23 | The Gillette Company | Alkaline cell with improved anode |
JP2011187226A (ja) * | 2010-03-05 | 2011-09-22 | Sumitomo Electric Ind Ltd | 電池用負極前駆体材料の製造方法、電池用負極前駆体材料、及び電池 |
TW201222938A (en) | 2010-04-06 | 2012-06-01 | Sumitomo Electric Industries | Method for producing separator, method for manufacturing molten salt battery, separator, and molten salt battery |
EP2687622B1 (de) * | 2012-07-18 | 2018-05-23 | VARTA Microbattery GmbH | Zink-zellen mit verbesserter anodenzusammensetzung |
FR3034412B1 (fr) | 2015-04-03 | 2018-10-05 | Easyl | Procede de fabrication de cristaux de zincate de calcium, ainsi que ses utilisations |
WO2019093125A1 (ja) * | 2017-11-08 | 2019-05-16 | シャープ株式会社 | 電池用負極、電池および電池の製造方法 |
FR3091042A1 (fr) * | 2018-12-21 | 2020-06-26 | Electricite De France | Procédé de fabrication d’une électrode de zinc par voie aqueuse |
US11450847B2 (en) * | 2019-01-23 | 2022-09-20 | Energizer Brands, Llc | Alkaline electrochemical cells comprising increased zinc oxide levels |
FR3099851B1 (fr) | 2019-08-09 | 2021-07-16 | Sunergy | générateurs ELECTROCHIMIQUES secondaires ALCALINS À anode de zinc |
JP7316309B2 (ja) | 2021-02-26 | 2023-07-27 | 本田技研工業株式会社 | 二酸化炭素処理装置、二酸化炭素処理方法及び炭素化合物の製造方法 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USB730525I5 (zh) * | 1958-04-24 | |||
US3476601A (en) * | 1964-06-29 | 1969-11-04 | Mc Donnell Douglas Corp | Battery including inorganic fibrous material |
US4041221A (en) * | 1976-07-27 | 1977-08-09 | Yardney Electric Corporation | Zinc electrodes and methods of making same |
US4332871A (en) * | 1980-09-15 | 1982-06-01 | Energy Research Corporation | Zinc electrode with cement additive |
JPH06283194A (ja) * | 1993-03-29 | 1994-10-07 | Yuasa Corp | 密閉形アルカリ亜鉛蓄電池 |
DE19546333A1 (de) * | 1994-12-17 | 1996-06-20 | Grillo Werke Ag | Zellen auf Basis von Zink-Alkali-Mangan und Verfahren zur Herstellung derselben |
JP2000133302A (ja) * | 1998-10-29 | 2000-05-12 | Sanyo Electric Co Ltd | アルカリ蓄電池 |
FR2788887B1 (fr) * | 1999-01-27 | 2001-04-20 | Conseil Et De Prospective Scie | Generateurs electrochimiques secondaires alcalins a anode de zinc |
JP2003502825A (ja) * | 1999-06-23 | 2003-01-21 | エヴァレディー バッテリー カンパニー インコーポレイテッド | 電気化学電池用の性能強化添加剤 |
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2002
- 2002-04-05 FR FR0204379A patent/FR2828336B1/fr not_active Expired - Fee Related
- 2002-08-05 CN CNB028193407A patent/CN1266788C/zh not_active Expired - Lifetime
- 2002-08-05 AU AU2002321709A patent/AU2002321709A1/en not_active Abandoned
- 2002-08-05 EP EP02755435A patent/EP1412994B1/fr not_active Expired - Lifetime
- 2002-08-05 ES ES02755435T patent/ES2421507T3/es not_active Expired - Lifetime
- 2002-08-05 CA CA2456214A patent/CA2456214C/fr not_active Expired - Lifetime
- 2002-08-05 JP JP2003520017A patent/JP4374247B2/ja not_active Expired - Fee Related
- 2002-08-05 WO PCT/IB2002/003155 patent/WO2003015197A2/fr active Application Filing
- 2002-08-05 DK DK02755435.1T patent/DK1412994T5/en active
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2004
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Also Published As
Publication number | Publication date |
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WO2003015197A3 (fr) | 2003-10-23 |
US7300721B2 (en) | 2007-11-27 |
FR2828336A1 (fr) | 2003-02-07 |
DK1412994T5 (en) | 2017-02-06 |
CA2456214A1 (fr) | 2003-02-20 |
HK1061923A1 (en) | 2004-10-08 |
DK1412994T3 (da) | 2013-06-10 |
WO2003015197A2 (fr) | 2003-02-20 |
JP4374247B2 (ja) | 2009-12-02 |
EP1412994B1 (fr) | 2013-03-13 |
ES2421507T3 (es) | 2013-09-03 |
FR2828336B1 (fr) | 2006-07-07 |
CA2456214C (fr) | 2011-04-19 |
AU2002321709A1 (en) | 2003-02-24 |
JP2004538609A (ja) | 2004-12-24 |
EP1412994A2 (fr) | 2004-04-28 |
CN1561553A (zh) | 2005-01-05 |
US20040166412A1 (en) | 2004-08-26 |
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