CN1256876C - Bactericide composition containing SYP-Zo48 - Google Patents
Bactericide composition containing SYP-Zo48 Download PDFInfo
- Publication number
- CN1256876C CN1256876C CN 200310104923 CN200310104923A CN1256876C CN 1256876 C CN1256876 C CN 1256876C CN 200310104923 CN200310104923 CN 200310104923 CN 200310104923 A CN200310104923 A CN 200310104923A CN 1256876 C CN1256876 C CN 1256876C
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- bactericidal
- agent
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a composition containing bacteria-din oxazole and triazole bactericide, and the weight part ratio of the two active components is 1: 100 to 100: 1. The composition comprises at least two kinds of carriers, wherein at least one carrier is a surface active agent. The composition can be made into formulations, such as emulsifiable solution, a suspending agent, (water) emulsion, wettable powder, a (water dispersing) granular formulation, etc., and is used for preventing and curing plant diseases caused by ascomycete, basidiomycete and adelomycete.
Description
Technical field
The invention belongs to the disinfectant use in agriculture field.
Background technology
SYP-Zo48 is the outstanding bactericide of plurality of plant diseases such as control cereal, paddy rice, fruit, vegetables and economic crops, its bactericidal activity height, have prevention and therapeutic action and good interior suction conductivity is arranged, the plurality of plant diseases that is caused by sac fungi, basidiomycetes and imperfect fungus is had good control efficiency.Having now found that has higher activity to graw mold of tomato, gray mold of cucumber, cladosporium leaf and fruit mould of tomato, alternaria leaf spot of apple, scab of cucumber, root rotof flax, fruit white rot of grape, brown spot of grape, the cercospora brown spot of peanut, and especially the gray mold to crops such as vegetables, fruit trees has special efficacy.This compound is open in CN1280767A, is the isoxazole class heterocyclic substituted compound that a class has novel chemical constitution.
Summary of the invention
For fear of the resistance of using the single agent of SYP-Zo48 to bring take place, degradation problem under the drug effect, the present invention proposes a kind of bactericidal composition, preparation of compositions and application that contains SYP-Zo48 and two kinds of active components of triazole type.
First kind of active component of composition that the present invention proposes is SYP-Zo48, chemical name: 5-(4-chlorphenyl)-2,3-dimethyl-3-(3-pyridine radicals) isoxazoline, structural formula is as follows:
Second kind of active component of composition that the present invention proposes is selected from following any one triazole bactericidal agent:
Triazolone (English common name: triadimefon): 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazole-1-yl)-butanone
Molecular formula: C
14H
16ClN
3O
2Molecular weight: 293.8
Difenoconazole (English common name: difenoconazole): suitable, anti--3-chloro-4-[4-methyl-2-(1H-1,2,4-triazol-1-yl methyl)-1,3-dioxin-pentane-2-yl] phenyl-4-chlorphenyl ether
Molecular formula: C
19H
17Cl
2N
3O
3Molecular weight: 406.3
Alkene azoles alcohol (English common name diniconazole): β-[(2,4 dichloro benzene base)-methene]-α-(1, the 1-dimethyl ethyl)-1H-1,2, the 4-triazole ethanol
Molecular formula: C
15H
17Cl
2N
3O molecular weight: 326.2
Nitrile bacterium azoles (English common name: myclobutanil), the own nitrile of 2-(4-chlorphenyl)-2-(1H-1,2,4-triazole-1-methyl)
Molecular formula: C
15H
17ClN
4Molecular weight: 286.8
Propiconazole (English common name: propiconazloe): 1-[2-(2,4 dichloro benzene base)-4-propyl group-1,3-dioxolanes-2-methyl]-1-hydrogen-1,2, the 4-triazole
Molecular formula: C
15H
17Cl
2N
3O
2Molecular weight: 342.2
Triadimenol (English common name: triadimenol): (1RS, 2RS; 1RS, 2SR)-1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazole-1-butyl)-2-alcohol
Molecular formula: C
14H
18ClN
3O
2Molecular weight: 295.8
Tebuconazole (English common name: tebuconazole): (RS)-1-(4-chlorphenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-yl methyl) penta-3-alcohol
Molecular formula: C
16H
22ClN
3O molecular weight: 307.8
Own azoles alcohol (English common name: hexaconazole): (RS)-2-(2,4 dichloro benzene base)-1-(1H-1,2,4-triazol-1-yl)-oneself-2-alcohol
Molecular formula: C
14H
17Cl
2N
3O molecular weight: 314.2
Epoxy bacterium azoles (English common name: Epoxiconazole): (2RS, 3SR)-1-[3-(2-chlorphenyl)-2,3-epoxy-2-(4-fluorophenyl) propyl group]-1-hydrogen-1,2, the 4-triazole
Molecular formula: C
17H
13ClFN
3O molecular weight: 329.8
Have now found that the use that is mixed of SYP-Zo48 and triazole bactericidal agent has very obvious synergistic effect, have significance to improve, and can enlarge fungicidal spectrum, delay the drug-fast generation of pathogen the control efficiency of corps diseases.The disinfecting composition that the present invention proposes contains SYP-Zo48 and any one or two or more triazole type bactericidal active constituent.Because two class medicaments possess different structure types and different mechanism of action, the two composite can the pathogen pesticide resistance produces and development delaying to a greater extent, thereby reached main purpose of the present invention.
In the bactericidal composition of the present invention, the ratio of weight and number of SYP-Zo48 and two kinds of active components of triazole bactericidal agent is 1: 100 to 100: 1.Better suited ratio is 1: 20 to 20: 1.
Active component is 0.5% to 95% of a gross weight in the bactericidal composition of the present invention.The amount that contains active component in the bactericidal composition of the present invention depends on the amount of application when every kind of component is used separately, also depends on the ratio of a kind of component and another kind of component and the degree of synergistic effect.
Contain at least two kinds of carriers in the bactericidal composition of the present invention, carrier can be solid or liquid, and the carrier that is generally used for preparing bactericidal composition all can use.At least a carrier is a surfactant in the composition of the present invention, for example can be emulsifier, dispersant or wetting agent etc.Surfactant all has commercially available, and its selection is known in those skilled in the art, for example, and lauryl sodium sulfate, Teepol, neopelex, polyoxyethylene fatty acid fat, polyoxyethylene aliphatic alcohol ether or polyoxyethylene fatty amine etc.
The present composition can be mixed with missible oil, suspending agent, (water) emulsion, wetting powder, (aqueous dispersion) granule etc., and these preparations can be prepared by method in common.
The composition that the present invention describes can be the finished product preparation form to be provided, and promptly each material mixes in the composition: but the composition of composition also can provide directly mixing in bucket (jar) before using with independent preparation.Concentrate of the present invention mixes the concentration that obtains required active substance usually with water.
Composition of the present invention can be used for preventing and treating the disease that is caused various plants by sac fungi, basidiomycetes and imperfect fungus, as cereal, wheat, paddy rice, grape, strawberry, cucumber, custard squash, capsicum, pimento, eggplant, tomato, Kidney bean, cowpea, leek, lettuce, Chinese cabbage, sunflower, lichee, tobacco, rubber and some flowers, traditional Chinese medicine, lawn etc.The place of using of bactericidal composition of the present invention is farmland, orchard or warehouse etc.
Composition of the present invention also can with other compound with weeding, desinsection or bactericidal property particularly protective fungicide mix use, can also mix use with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
The present invention comprises that also a kind of scene kills the method for fungi, before or after crop is susceptible, uses composition of the present invention to the place of crop and plant growth or storage.Can use by common method, as cast, injection, spraying.Amount of application of the present invention is with weather condition or crop state variation.The duration of protective effect is usually relevant with the content of individualized compound in the composition, also relevant with extraneous factor, weather for example, but by using suitable formulation can slow down climatic influences.
Composition of the present invention has three advantages: the one, and composition shows fabulous synergistic effect in certain ratio range, mixed composition has obviously improved bactericidal effect than its single agent, thereby reduced using dosage, when reducing peasant's drug cost, reduced influence degree.The 2nd, enlarged fungicidal spectrum, a kind of medicament can be prevented and treated the various crop disease simultaneously, and a kind of dispenser means extremely easily and effectively are provided.Has the well double effect of controlling for simultaneous disease on the various plants, as graw mold of tomato, leaf mold, early blight, gray mold of cucumber, scab, powdery mildew, alternaria leaf spot of apple, scab, wheat powdery mildew, rust, banded sclerotial blight, head blight, fruit white rot of grape, brown spot etc.The 3rd, the application of said composition, the resistance that can delay single agent takes place and development.
Embodiment
The present invention is elaborated with following instantiation, so that advantage of the present invention is more obvious, but the present invention is limited to these examples absolutely not.Be percetage by weight in the prescription of all preparations; The treatment dosage of biologically-active moiety is effective content.
Preparation of compositions and biologically active example
1, the preparation of missible oil
By the prescription requirement, add solvent, former medicine, emulsifier respectively, mix, use the hot bath heating for dissolving in case of necessity, promptly obtain transparence missible oil.As example 1～3 prescription.
Example 1 (20% missible oil)
SYP-Zo48 15%, Difenoconazole 5%, farming breast 500
#10%, agricultural newborn OX-653 3%, methyl alcohol 10%, dimethylbenzene complements to 100%.
Example 2 (45% missible oil)
SYP-Zo48 2.5%, triazolone 42.5%, Nongru-700
#10%, agricultural newborn 0X-638 5%, cyclohexanone 10%, toluene complements to 100%.
Example 3 (50% missible oil)
SYP-Zo48 40%, epoxy bacterium azoles 10%, farming breast 1600
#15%, agricultural newborn 500# 5%, isopropyl alcohol 10%, dimethylbenzene complements to 100%.
2, the preparation of wetting powder
By the prescription requirement, former medicine, various auxiliary agent and filler etc. are fully mixed, after ultrafine crusher is pulverized, promptly obtain converted products.As example 4～7 prescriptions
Example 4 (15% wetting powder)
SYP-Zo48 5%, alkene azoles alcohol 10%, lauryl sodium sulfate 5%, carboxymethyl cellulose 3%, sodium lignin sulfonate 12%, precipitated calcium carbonate complements to 100%.
Example 5 (25% wetting powder)
SYP-Zo48 5%, Triadimenol 20%, neopelex 2%, white carbon black 10%, calcium lignosulfonate 10%, diatomite complements to 100%.
Example 6 (45% wetting powder)
SYP-Zo48 36%, nitrile bacterium azoles 9%, dispersing agent MF 8%, sodium lignin sulfonate 5%, lauryl sodium sulfate 3%, precipitated calcium carbonate complements to 100%.
Example 7 (50% wetting powder)
SYP-Zo48 45%, Difenoconazole 15%, neopelex 5%, white carbon black 10%, sodium methylene bis-naphthalene sulfonate 10%, attapulgite complements to 100%.
3, the preparation of aqueous emulsion
Former medicine, solvent, emulsifier added with co-emulsifier be in the same place, make and be dissolved into even oil phase.Water, antifreeze etc. is mixed, becomes the homogeneous water.Under high-speed stirred, water is joined oil phase or oil phase is joined water, form the aqueous emulsion of favorable dispersibility.As example 8～11 prescriptions.
Example 8 (10% aqueous emulsion)
SYP-Zo48 2.5%, Tebuconazole 7.5%, polyvinyl alcohol 0.5%, agricultural newborn 0201B 6%, dimethyl formamide 8%, dimethylbenzene 20%, ethylene glycol 5%, water complements to 100%.
Example 9 (15% aqueous emulsion)
SYP-Zo48 10%, propiconazole 5%, polyvinyl alcohol 0.9%, Nonyl pheno (10) ether 8.5%, agricultural newborn 600#5%, oxolane 20%, glycerine 5%, water complements to 100%.
Example 10 (20% aqueous emulsion)
SYP-Zo48 19%, own azoles alcohol 1%, polyvinyl alcohol 0.9%, aliphatic alcohol polyethenoxy (15) ether 12%, Nongru-700 # 8%, dimethyl sulfoxide (DMSO) 20%, urea 10%, water complements to 100%.
Example 11 (25% aqueous emulsion)
SYP-Zo48 12.5%, nitrile bacterium azoles 12.5%, polyethylene glycol 5%, alkylaryl polyoxyethylene poly-oxygen propylene aether 10%, agricultural newborn 0203B 15%, cyclohexanone 15%, ethylene glycol 5%, water complements to 100%.
4, the preparation of water-dispersible granules
Former medicine and powder carrier, wetting spreader-sticker and binding agent etc. are mixed pulverizing, after adding water again and mediating, add in the comminutor that the certain specification screen cloth is housed and carry out granulation.And then drying, screening (pressing the screen cloth scope) promptly get granular product.As example 12～14 prescriptions.
Example 12 (45% water-dispersible granules)
SYP-Zo48 30%, nitrile bacterium azoles 15%, dispersing agent MF 12%, polyvinylpyrrolidone 5%, soluble starch 15%, urea 10%, talcum powder complements to 100%.
Example 13 (50% water-dispersible granules)
SYP-Zo48 25%, epoxy bacterium azoles 25%, sodium methylene bis-naphthalene sulfonate 10%, methylene benzyl naphthalene sodium sulfonate 5%, sodium sulphate 15%, soluble starch complements to 100%.
Example 14 (60% water-dispersible granules)
SYP-Zo48 55%, Tebuconazole 5%, sodium methylene bis-naphthalene sulfonate 10%, cellulose sodium sulfate 15%, Boratex 15%, kaolin complements to 100%.
5, the preparation of suspending agent
By the prescription requirement, be medium with water, former medicine, dispersant, suspending agent and antifreezing agent etc. are added in the sand milling still, carry out porphyrize, make suspending agent.As example 15～prescription.
Example 15 (15% suspending agent)
SYP-Zo48 2.5%, nitrile bacterium azoles 12.5%, sodium methylene bis-naphthalene sulfonate 5.5%, white carbon black 2%, aluminium-magnesium silicate 0.5%, ethylene glycol 4%, aliphatic alcohol polyethenoxy (15) ether 5%, silicone a little, water complements to 100%.
Example 16 (20% suspending agent)
SYP-Zo48 10%, Tebuconazole 10%, calcium lignosulfonate 5%, white carbon black 5%, ethylene glycol 8%, polyvinylpyrrolidone 5%, farming breast 22014%, silicone a little, water complements to 100%.
Example 17 (30% suspending agent)
SYP-Zo48 5%, Difenoconazole 25%, Zhong Ji phenol polyethenoxy (10) ether 10%, sodium methylene bis-naphthalene sulfonate 2.5%, bentonite 5.0%, farming breast 16013%, glycerine 4%, silicone a little, water complements to 100%.
6. biologically active exsomatizes
Stripped biological activity determination all adopts toxic dielectric method, promptly adds quantitative reagent agent (test dose is by active ingredient) in the PDA medium respectively, and inoculation test pathogen in cooling back is cultivated under 25 ℃ of dark conditions.When treating that the blank colony diameter grows to 40～50 millimeters, measure the colony growth diameter of different disposal respectively, calculate bacteriostasis rate and EC that each is handled
50Value.Result of the test: the stripped biologically active of mixture has obvious synergistic effect apparently higher than two single agent of contrast, sees example 18～21 for details.
Example 18 scabs of cucumber (Cladosporium cucumerinum)
Example 19 alternaria leaf spot of apple (Alternaria alternata f.sp.mali)
Example 20 root rotof flaxes (Bipolaris sorokiniana)
Example 21 pears scab (Venturia pirina)
7. greenhouse pot culture biologically active
The potted plant determination method of seedling is adopted in test, and trial crops is in greenhouse pot culture to 2～3 leaf phases.Carrying out foliar spray by design dosage on the crop sprayer handles, inoculation test pathogen after 24 hours after the chemicals treatment, the cultivation of all preserving moisture in the controlled environment chamber of postvaccinal test material, carry out result's investigation when the blank of not dispenser is fully fallen ill, disease classification, preventive effect computational methods are all with reference to State Standard of the People's Republic of China " pesticide field efficacy medicine test criterion ".The bactericidal composition of result of the test SYP-Zo48 and triazole type is to having very excellent control efficiency for the examination target, and the potted plant biologically active of mixture all has obvious synergistic effect apparently higher than the single agent of contrast, and the result sees example 22～25 for details.
Example 22 wheat powdery mildews (Blumeria, graminis)
Example 23 powderys mildew of cucumber (Erysiphe cucurbitacearum)
Example 24 scabs of cucumber (Cladpsporium cucumerinum)
Embodiment 25 cladosporium leaf and fruit mould of tomato (Fulvia fulva)
8. sub-district, field control efficiency
Carry out the agricultural production routinely of the cultivation management of trial crops under the test field condition.The reagent agent that field efficacy is measured is all established 3 dosage, establishes the blank of not dispenser, 4 repetitions.Test is not fallen ill in the field or the their early stage dispenser, and spraying equipment is a knapsack hand sprayer.Natural occurrence is carried out result's investigation when the blank of not dispenser is fully fallen ill.Disease classification, preventive effect computational methods are all carried out State Standard of the People's Republic of China's " pesticide field efficacy medicine test criterion ".The bactericidal composition of result of the test SYP-Zo48 and triazole type has very excellent preventive and therapeutic effect to preventing and treating disease, and the field efficacy of mixture all has obvious synergistic effect apparently higher than the single agent of contrast, and the result sees example 26～35 for details.
Example 26 graw mold of tomato (Botrytis cinerea)
| Handle medicament | Treatment dosage and control efficiency | ||
| Example 7 (but 35% wet-milling) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 100.00％ | 100％ | 89.77％ | |
| 25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 100.00％ | 100％ | 92.05％ | |
| 10% Difenoconazole aqueous dispersion | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 87.65％ | 65.78％ | 45.18％ | |
Example 27 cercospora brown spot of peanut Cercospora arachidicola)
| Handle medicament | Treatment dosage and control efficiency | ||
| Example 9 (15% aqueous emulsion) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 89.46％ | 82.35％ | 67.38％ | |
| 25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 80.45％ | 74.25％ | 61.87％ | |
| 25% propiconazole emulsifiable concentrate | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 92.24％ | 78.27％ | 70.52％ | |
Example 28 wheat powdery mildews (Blumeria graminis)
| Handle medicament | Treatment dosage and control efficiency | ||
| Example 2 (45% missible oil) | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 94.27％ | 84.52％ | 68.32％ | |
| 25% SYP-Zo48 missible oil | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 82.45％ | 67.05％ | 50.22％ | |
| But 15% triazolone wet-milling | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 96.48％ | 80.24％ | 64.82％ | |
Example 29 stripes rust of wheat (Puccinia striiformis)
| Handle medicament | Treatment dosage and control efficiency | ||
| Example 2 (45% missible oil) | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 84.64％ | 78.62％ | 57.24％ | |
| 25% SYP-Zo48 missible oil | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 71.49％ | 60.13％ | 33.51％ | |
| But 15% triazolone wet-milling | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 86.81％ | 76.49％ | 60.08％ | |
Example 30 pears scab (Venturia pirina)
| Handle medicament | Treatment dosage and control efficiency | ||
| Example 12 (45% water dispersible granular) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 90.54％ | 84.76％ | 71.51％ | |
| 25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 88.64％ | 79.56％ | 54.87％ | |
| 12.5% nitrile bacterium azoles missible oil | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 91.46％ | 81.20％ | 60.00％ | |
Example 31 browns spot of grape (Phaeoramularia dissiliens)
| Handle medicament | Treatment dosage and control efficiency | ||
| Example 10 (20% aqueous emulsion) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 94.34％ | 88.75％ | 69.37％ | |
| 25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 94.00％ | 86.89％ | 70.17％ | |
| But 20% own azoles alcohol wet-milling | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 93.65％ | 90.24％ | 78.46％ | |
Example 32 cladosporium leaf and fruit mould of tomato (Fulvia fulva)
| Handle medicament | Treatment dosage and control efficiency | ||
| Example 15 (15% suspending agent) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 98.27％ | 90.14％ | 82.54％ | |
| 25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 95.25％ | 92.44％ | 80.14％ | |
| 12.5% nitrile bacterium azoles missible oil | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 95.01％ | 89.65％ | 76.74％ | |
Example 33 rice blasts (Pyricularia grisea)
| Handle medicament | Treatment dosage and control efficiency | ||
| Example 17 (30% suspending agent) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 86.24％ | 77.69％ | 57.21％ | |
| 25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 80.45％ | 71.24％ | 50.33％ | |
| 12% Difenoconazole water dispersible granular | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 80.52％ | 69.78％ | 55.57％ | |
Example 34 alternaria leaf spot of apple (Alternaria alternata f.sp.mali)
| Handle medicament | Treatment dosage and control efficiency | ||
| Example 16 (20% suspending agent) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 92.78％ | 85.31％ | 64.11％ | |
| 25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
| 89.47％ | 82.20％ | 58.97％ | |
| But 25% Tebuconazole wet-milling | 200g.ai/ha | 100g.ai/ha | 50g.ai/ha |
| 87.24％ | 80.31％ | 60.04％ | |
Claims (5)
1, a kind of bactericidal composition contains SYP-Zo48 and triazole bactericidal agent, and the ratio of weight and number of two kinds of active components is 1: 20 to 20: 1; Active component weight percentage in the composition is 10-60%; Described triazole bactericidal agent is selected from: triazolone, Difenoconazole, alkene azoles alcohol, nitrile bacterium azoles, Tebuconazole, own azoles alcohol, propiconazole or epoxy bacterium azoles.
2, bactericidal composition according to claim 1 is characterized in that: contain at least two kinds of carriers in the composition, wherein at least a is surfactant.
3, bactericidal composition according to claim 1 is characterized in that: said composition can be mixed with missible oil, suspending agent, aqueous emulsion, wetting powder or water dispersion granule.
4, the described bactericidal composition of claim 1 is used to prevent and treat the purposes of the plant disease that is caused by sac fungi, basidiomycetes and imperfect fungus.
5, the method for fungi is killed at a kind of scene, before or after crop is susceptible, uses claim 1 or 2 described bactericidal compositions to the place of crop and plant growth or storage.
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| CN 200310104923 CN1256876C (en) | 2003-10-24 | 2003-10-24 | Bactericide composition containing SYP-Zo48 |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007090624A2 (en) * | 2006-02-09 | 2007-08-16 | Syngenta Participations Ag | A method of protecting a plant propagation material, a plant, and/or plant organs |
| CN104012545A (en) * | 2013-06-29 | 2014-09-03 | 海利尔药业集团股份有限公司 | Bactericidal composition containing SYP-Z048 and prothioconazole |
| CN103314955B (en) * | 2013-07-17 | 2015-06-17 | 中国中化股份有限公司 | Water emulsion composition containing SYP-Z048 bactericide |
| CN105309450A (en) * | 2014-06-17 | 2016-02-10 | 沈阳中化农药化工研发有限公司 | Fungicidal composition having double active components and application thereof |
| CN104186495B (en) * | 2014-08-20 | 2016-05-04 | 青岛农业大学 | A kind of SYP-Zo48-Osthole suspended emulsion and preparation method thereof |
| CN104823985B (en) * | 2015-05-07 | 2016-07-06 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing pyridine bacterium azoles and application thereof |
| CN106172436A (en) * | 2016-07-05 | 2016-12-07 | 广东中迅农科股份有限公司 | A kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles |
| CN109769837A (en) * | 2019-03-01 | 2019-05-21 | 贵州大学 | A kind of pesticide synergistic combination preventing and treating fruits and vegetables gray mold |
| CN110050797A (en) * | 2019-06-06 | 2019-07-26 | 江西鑫邦科技有限责任公司 | A kind of composition pesticide of brassinolide-containing class compound and oxazole class, triazole bactericidal agent |
| CN112823630B (en) * | 2019-11-21 | 2021-11-23 | 沈阳中化农药化工研发有限公司 | Seed treatment agent for sterilization |
| CN110800752A (en) * | 2019-11-22 | 2020-02-18 | 湖南省水稻研究所 | Environment-friendly pesticide for rice and application thereof |
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