CN1265708C - Bactericide composition of SYP-Zo48 and thiocarbamate - Google Patents
Bactericide composition of SYP-Zo48 and thiocarbamate Download PDFInfo
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- CN1265708C CN1265708C CN 200310104924 CN200310104924A CN1265708C CN 1265708 C CN1265708 C CN 1265708C CN 200310104924 CN200310104924 CN 200310104924 CN 200310104924 A CN200310104924 A CN 200310104924A CN 1265708 C CN1265708 C CN 1265708C
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- 239000000203 mixture Substances 0.000 title claims abstract description 46
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 21
- 239000003899 bactericide agent Substances 0.000 title claims abstract description 10
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 15
- 201000010099 disease Diseases 0.000 claims abstract description 13
- 239000000375 suspending agent Substances 0.000 claims abstract description 12
- 239000000969 carrier Substances 0.000 claims abstract description 4
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- 239000005802 Mancozeb Substances 0.000 claims description 15
- 239000005823 Propineb Substances 0.000 claims description 11
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 claims description 11
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 9
- 238000009736 wetting Methods 0.000 claims description 9
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims description 7
- FROZIYRKKUFAOC-UHFFFAOYSA-N amobam Chemical compound N.N.SC(=S)NCCNC(S)=S FROZIYRKKUFAOC-UHFFFAOYSA-N 0.000 claims description 6
- 241000233866 Fungi Species 0.000 claims description 5
- 239000011717 all-trans-retinol Substances 0.000 claims description 5
- 235000019169 all-trans-retinol Nutrition 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 claims description 5
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- 238000000034 method Methods 0.000 claims description 5
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- 238000003860 storage Methods 0.000 claims description 2
- 241000235349 Ascomycota Species 0.000 abstract description 3
- 241000221198 Basidiomycota Species 0.000 abstract description 3
- 238000009472 formulation Methods 0.000 abstract description 3
- 230000002070 germicidal effect Effects 0.000 abstract 2
- 150000003560 thiocarbamic acids Chemical class 0.000 abstract 2
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- 239000003814 drug Substances 0.000 description 29
- 238000001238 wet grinding Methods 0.000 description 21
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- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 4
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- 229910052708 sodium Inorganic materials 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 4
- 241000123650 Botrytis cinerea Species 0.000 description 3
- JISVRKSRAKIYPZ-UHFFFAOYSA-N C=O.C1(=CC=CC2=CC=CC=C12)S(=O)(=O)OCOS(=O)(=O)C1=CC=CC2=CC=CC=C12.[Na] Chemical compound C=O.C1(=CC=CC2=CC=CC=C12)S(=O)(=O)OCOS(=O)(=O)C1=CC=CC2=CC=CC=C12.[Na] JISVRKSRAKIYPZ-UHFFFAOYSA-N 0.000 description 3
- 241001157813 Cercospora Species 0.000 description 3
- 241000222290 Cladosporium Species 0.000 description 3
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- 241000209140 Triticum Species 0.000 description 3
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- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 229910052625 palygorskite Inorganic materials 0.000 description 3
- 244000052769 pathogen Species 0.000 description 3
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- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 3
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 3
- 208000031968 Cadaver Diseases 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 241000222291 Passalora fulva Species 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
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- 229920005551 calcium lignosulfonate Polymers 0.000 description 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 2
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- 239000010452 phosphate Substances 0.000 description 2
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- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
- 229960002447 thiram Drugs 0.000 description 2
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- WEQPBCSPRXFQQS-UHFFFAOYSA-N 4,5-dihydro-1,2-oxazole Chemical compound C1CC=NO1 WEQPBCSPRXFQQS-UHFFFAOYSA-N 0.000 description 1
- PZVKSFBOPQYWGM-UHFFFAOYSA-N 4,5-dihydro-1,3-oxazole;pyridine Chemical class C1CN=CO1.C1=CC=NC=C1 PZVKSFBOPQYWGM-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
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- 239000005995 Aluminium silicate Substances 0.000 description 1
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- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- TZRSCXSDYYMKQN-UHFFFAOYSA-N dimethylcarbamodithioic acid;zinc Chemical compound [Zn].CN(C)C(S)=S TZRSCXSDYYMKQN-UHFFFAOYSA-N 0.000 description 1
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Handle medicament | Treatment dosage and bacteriostasis rate | EC 50 | ||||
Example 5 (but 70% wet-milling) | 1.6μg/ml | 0.8μg/ml | 0.4μg/ml | 0.2μg/ml | 0.1μg/ml | 0.186 |
85.67% | 72.29% | 61.14% | 51.49% | 40.61% | ||
25% SYP-Zo48 missible oil | 1.6μg/ml | 0.8μg/ml | 0.4μg/ml | 0.2μg/ml | 0.1μg/ml | 0.19 |
89.28% | 73.49% | 60.13% | 53.17% | 39.29% | ||
But 70% tmtd wet-milling | 3.2μg/ml | 1.6μg/ml | 0.8μg/ml | 0.4μg/ml | 0.2μg/ml | 1.83 |
60.33% | 49.67% | 31.59% | 20.09% | 9.48% |
Handle medicament | Treatment dosage and bacteriostasis rate | EC 50 | ||||
Example 7 (15% aqueous emulsion) | 2μg/ml | 1μg/ml | 0.5μg/ml | 0.25μg/ml | 0.13μg/ml | 0.83 |
75.46% | 52.73% | 34.49% | 21.21% | 10.91% | ||
25% SYP-Zo48 missible oil | 2μg/ml | 1μg/ml | 0.5μg/ml | 0.25μg/ml | 0.13μg/ml | 0.84 |
72.42% | 55.15% | 32.42% | 26.36% | 10.91% | ||
But 70% mancozeb wet-milling | 2μg/ml | 1μg/ml | 0.5μg/ml | 0.25μg/ml | 0.13μg/ml | 1.12 |
64.85% | 45.76% | 29.70% | 16.34% | 15.76% |
Handle medicament | Treatment dosage and bacteriostasis rate | EC 50 | ||||
Example 13 (15% aqueous dispersion) | 8μg/ml | 4μg/ml | 2μg/ml | 1μg/ml | 0.5μg/ml | 1.35 |
81.29% | 72.34% | 59.74% | 41.67% | 30.85% | ||
25% SYP-Zo48 missible oil | 8μg/ml | 4μg/ml | 2μg/ml | 1μg/ml | 0.5μg/ml | 0.66 |
83.54% | 77.84% | 67.72% | 53.80% | 46.84% | ||
But 70% tmtd wet-milling | 32μg/ml | 16μg/ml | 8μg/ml | 4μg/ml | 2μg/ml | 3.30 |
66.46% | 44.94% | 23.42% | 17.72% | 13.92% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 2 (but 25% wet-milling) | 200μg/ml | 100μg/ml | 50μg/ml |
95.00% | 89.36% | 72.12% | |
25% SYP-Zo48 missible oil | 200μg/ml | 100μg/ml | 50μg/ml |
96.34% | 92.75% | 74.37% | |
But 70% Propineb wet-milling | 800μg/ml | 400μg/ml | 200μg/ml |
83.75% | 69.37% | 40.67% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 3 (but 45% wet-milling) | 200μg/ml | 100μg/ml | 50μg/ml |
100.00% | 91.34% | 62.78% | |
25% SYP-Zo48 missible oil | 200μg/ml | 100μg/ml | 50μg/ml |
100.00% | 94.25% | 66.54% | |
But 70% zineb wet-milling | 800μg/ml | 400μg/ml | 200μg/ml |
96.75% | 72.21% | 22.22% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 15 (30% suspending agent) | 200μg/ml | 100μg/ml | 50μg/ml |
100.00% | 100.00% | 78.65% | |
25% SYP-Zo48 missible oil | 200μg/ml | 100μg/ml | 50μg/ml |
100.00% | 100.00% | 80.25% | |
But 70% Propineb wet-milling | 800μg/ml | 400μg/ml | 200μg/ml |
100.00% | 83.42% | 54.18% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 9 (30% aqueous emulsion) | 200μg/ml | 100μg/ml | 50μg/ml |
100.00% | 97.00% | 84.64% | |
25% SYP-Zo48 missible oil | 200μg/ml | 100μg/ml | 50μg/ml |
100.00% | 100.00% | 90.74% | |
But 70% tmtd wet-milling | 800μg/ml | 400μg/ml | 200μg/ml |
90.28% | 73.57% | 31.66% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 6 (10% aqueous emulsion) | 400μg/ml | 200μg/ml | 100μg/ml |
100.00% | 94.15% | 86.37% | |
25% SYP-Zo48 missible oil | 400μg/ml | 200μg/ml | 100μg/ml |
100.00% | 92.18% | 84.71% | |
50% ambam aqua | 400μg/ml | 200μg/ml | 100μg/ml |
100.00% | 90.21% | 71.45% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 10 (35% aqueous emulsion) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
100.00% | 98.07% | 80.65% | |
25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
100.00% | 97.77% | 80.64% | |
But 50% maneb wet-milling | 1200g.ai/ha | 800g.ai/ha | 400g.ai/ha |
65.25% | 43.22% | 40.56% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 16 (40% suspending agent) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
100.00% | 89.54% | 74.33% | |
25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
100.00% | 95.78% | 82.35% | |
But 70% mancozeb wet-milling | 1200g.ai/ha | 800g.ai/ha | 400g.ai/ha |
73.65% | 60.21% | 23.78% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 12 (40% aqueous dispersion) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
90.21% | 87.38% | 79.62% | |
25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
93.45% | 88.23% | 78.95% | |
But 70% mancozeb wet-milling | 1200g.ai/ha | 800g.ai/ha | 400g.ai/ha |
87.69% | 85.24% | 70.30% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 14 (60% aqueous dispersion) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
83.52% | 74.56% | 60.89% | |
25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
85.55% | 76.32% | 67.01% | |
But 70% Propineb wet-milling | 1200g.ai/ha | 800g.ai/ha | 400g.ai/ha |
82.32% | 71.59% | 56.28% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 8 (25% aqueous emulsion) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
82.35% | 73.28% | 63.58% | |
25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
84.28% | 77.82% | 60.14% | |
But 70% Propineb wet-milling | 1200g.ai/ha | 800g.ai/ha | 400g.ai/ha |
80.35% | 73.64% | 51.49% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 1 (but 20% wet-milling) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
81.89% | 73.37% | 50.32% | |
25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
94.36% | 86.67% | 77.85% | |
But 70% mancozeb wet-milling | 1200g.ai/ha | 800g.ai/ha | 400g.ai/ha |
79.87% | 68.69% | 48.32% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 4 (but 50% wet-milling) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
90.07% | 83.33% | 64.60% | |
25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
87.24% | 79.38% | 58.45% | |
But 70% mancozeb wet-milling | 1200g.ai/ha | 800g.ai/ha | 400g.ai/ha |
82.67% | 75.16% | 55.64% |
Handle medicament | Treatment dosage and control efficiency | ||
Example 17 (45% suspending agent) | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
92.09% | 81.56% | 74.26% | |
25% SYP-Zo48 missible oil | 400g.ai/ha | 200g.ai/ha | 100g.ai/ha |
94.67% | 84.89% | 76.49% | |
But 70% mancozeb wet-milling | 1200g.ai/ha | 800g.ai/ha | 400g.ai/ha |
73.36% | 60.59% | 41.48% | |
But 50% ziram wet-milling | 1200g.ai/ha | 800g.ai/ha | 400g.ai/ha |
95.65% | 85.23% | 79.54% |
Claims (5)
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WO2007090624A2 (en) * | 2006-02-09 | 2007-08-16 | Syngenta Participations Ag | A method of protecting a plant propagation material, a plant, and/or plant organs |
CN104012545A (en) * | 2013-06-29 | 2014-09-03 | 海利尔药业集团股份有限公司 | Bactericidal composition containing SYP-Z048 and prothioconazole |
CN103314955B (en) * | 2013-07-17 | 2015-06-17 | 中国中化股份有限公司 | Water emulsion composition containing SYP-Z048 bactericide |
CN103947660A (en) * | 2014-03-27 | 2014-07-30 | 姚卫平 | Sterilization composition containing propineb and SYP-Z048 |
CN105309450A (en) * | 2014-06-17 | 2016-02-10 | 沈阳中化农药化工研发有限公司 | Fungicidal composition having double active components and application thereof |
AU2015291490B2 (en) * | 2014-07-14 | 2018-11-01 | Clariant (Chile) Ltda. | Stable aqueous composition of neutral collectors and their use in mineral beneficiation processes |
CN106852332A (en) * | 2015-12-08 | 2017-06-16 | 中化农化有限公司 | Bactericidal composition containing SYP-Z048 |
CN106922655B (en) * | 2015-12-29 | 2020-10-09 | 沈阳中化农药化工研发有限公司 | Bactericidal composition containing stabilizer |
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