CN112823630B - Seed treatment agent for sterilization - Google Patents
Seed treatment agent for sterilization Download PDFInfo
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- CN112823630B CN112823630B CN201911148941.9A CN201911148941A CN112823630B CN 112823630 B CN112823630 B CN 112823630B CN 201911148941 A CN201911148941 A CN 201911148941A CN 112823630 B CN112823630 B CN 112823630B
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- polyoxyethylene ether
- pyrisoxazole
- sterilization
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/26—Oxidation products of dithiocarbamic acid derivatives, e.g. thiuram sulfides
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of pesticides, and relates to a seed treatment agent with a bactericide as an active component and application thereof. The seed treatment agent comprises an active ingredient, a carrier and at least one auxiliary agent; wherein the active ingredient is pyridinconazole or a mixture of pyridinconazole and one or more of tebuconazole, triadimefon, difenoconazole, carbendazim and thiram; the active component accounts for 0.9-90% of the weight of the treating agent. The active component of the seed treating agent for sterilization is a single pyrisoxazole agent or a binary complex formed by compounding the pyrisoxazole agent with other bactericides, the obtained seed treating agent has remarkable advantages in the aspect of preparation technical application performance, particularly under the low-temperature adverse environment condition of compounding with triazole bactericides, the seed treating agent mainly has excellent safety, and particularly under the adverse low-temperature environment condition, the germination potential and the germination rate of coated seeds are not influenced.
Description
Technical Field
The invention belongs to the technical field of pesticides, and relates to a seed treatment agent with a bactericide as an active component and application thereof.
Background
Pyridiniconazole (also called Pyridiniconazole) also called SYP-Z048 has strong bactericidal activity against plant pathogenic bacteria. The pyrisoxazole belongs to sterol synthesis inhibitor bactericides, has a unique action mechanism and broad-spectrum bactericidal activity, has protection and treatment effects, has good systemic property, can be absorbed by roots and leaves and stems, and can effectively control the occurrence and harm of diseases. The pyrisoxazole has broad-spectrum bactericidal activity and has outstanding prevention effect on diseases such as gray mold, powdery mildew and the like.
Currently, the technology of pyrisoxazole used as a seed treatment agent in the prior art is still in the blank stage. The compound is used as a domestic creative compound, and the pyrisoxazole per se has certain toxicity on seed coating, and particularly under the adverse low-temperature condition when the compound is compounded with triazole compounds, the germination rate of the coated seeds is the biggest problem at present.
Meanwhile, the safety research of the coated seeds is more in the industry, and because of the special use technology of the seed treatment agent, under the condition that the seeds are wrapped with high-concentration chemical pesticides in the germination stage, how to protect the seeds from being influenced and the seeds can germinate and grow is a key research problem in the seed treatment technology. The technical scheme adopted by the invention solves the safety problem of the coated seeds, and the known technical report is not found.
Disclosure of Invention
The invention aims to provide a seed treatment agent taking a bactericide as an active component and application thereof.
In order to achieve the purpose, the invention adopts the technical scheme that:
a seed treatment agent for sterilization, the seed treatment agent comprises an active ingredient, a carrier and at least one auxiliary agent; wherein the active ingredient is pyrisoxazole; or mixing pyrisoxazole with one or more of tebuconazole, triadimefon, difenoconazole, carbendazim and thiram; the active component accounts for 0.9-90% of the weight of the treating agent, preferably 10-70%.
The seed treatment agent preparation comprises a seed treatment dry powder agent, a seed treatment dispersible powder agent, a seed treatment liquid agent, a seed treatment emulsion or a seed treatment suspending agent.
The auxiliary agent comprises one or more of an anionic surfactant, a nonionic surfactant, an anionic and non-compound surfactant and a high molecular surfactant.
The anionic surfactant is one or more of sulfonate, sulfate, carboxylate, phosphate, succinate and lignosulfonate;
the nonionic surfactant is one or more of fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, fatty amine polyoxyethylene ether, fatty acid polyoxyethylene ether, acid alcohol ester and polyoxyethylene ether thereof, fatty amide and polyoxyethylene ether thereof, castor oil polyoxyethylene ether, alkanolamide and polyoxyethylene ether thereof, block copolymer, alkyl sodium naphthalene sulfonate fatty alcohol polyoxyethylene ether, sorbitan fatty acid ester polyoxyethylene ether, styrene maleic anhydride copolymer, phenylethylphenol polyoxyethylene polyoxypropylene ether and formaldehyde condensate;
the negative non-ionic compound surfactant is a mixture of one or more anionic surfactants and one or more non-ionic surfactants;
the polymer surfactant is polyvinyl alcohol or chitosan.
The auxiliary agents of the seed treatment dry powder, the seed treatment dispersible powder, the seed treatment liquid, the seed treatment emulsion and the seed treatment suspending agent also comprise wax substances, wherein the wax substances are beeswax, and the addition amount of the beeswax accounts for 0.1-5wt% of the treatment agent.
The carrier comprises a natural or synthetic solid substance;
if the system needs to improve the stability, a substance with a thickening function can be added, and the thickening agent can be one or more of xanthan gum, gelatin, gum arabic, polyvinyl acetate, polyvinylpyrrolidone, magnesium aluminum silicate, polyvinyl alcohol, polyethylene glycol, phenolic resin, shellac, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose and sodium alginate, so that the stability of the preparation can be improved to a certain extent.
When bubbles appear in the system, the bubbles can be eliminated by using a defoaming agent, wherein the defoaming agent can be one or more of SAG1522, silicones, C8-10 fatty alcohols, phosphates, C10-20 saturated fatty acids (such as capric acid) and amides or the like.
The system can also be added with antiseptic substances such as one or more of sodium benzoate, Kathon (2-methyl-4-isothiazoline-3-ketone and (B) 5-chloro-2-methyl-4-isothiazoline-3-ketone), potassium sorbate, sodium dehydroacetate, etc.
The color-alert agent may include dyes, pigments (including toners and pastes), and the like.
Under various conditions of selecting different auxiliary agents, the active components of the invention are ensured to be uniformly distributed and exert the active action, and the specific preparation method of the prior preparation is as follows:
the seed treatment dry powder is prepared by mixing raw pesticide, an auxiliary agent and a carrier and performing air flow crushing.
The dispersible powder for seed treatment is prepared by mixing raw medicines, an auxiliary agent and a carrier and crushing. Generally, the active ingredient is 0.5-80%, the auxiliary agents such as pH regulator, wetting dispersant, disintegrant and adhesive are 5-20%, and the rest is inert carrier.
The seed treatment suspending agent is prepared by adding functional additives such as active components, wetting dispersant and the like into a sand mill for sand milling until the particle size is qualified, and adding a color warning agent and a film forming substance. Generally, the liquid detergent comprises 2-60% of active ingredients, 6-20% of wetting dispersant, 2-15% of color warning agent, 1-15% of film forming substances and the balance of water.
The seed treatment liquid is prepared by dissolving active components in solvent, and adding surfactant, color warning agent and film forming substance.
The seed treatment emulsion is prepared by dissolving active components in solvent, adding surfactant, color warning agent and film forming material, and adding water to balance.
The preparation can be used in low temperature region, and optionally comprises antifreeze agent. Preservatives may also be added as needed to prevent spoilage during storage of the formulation.
The coating safety test of the seed treatment agent was carried out according to the crop seed test protocol-germination test of GB/T3543.4-1995.
The application of the seed treating agent for sterilization in preventing and treating plant diseases is provided.
The technical scheme of the invention can also be used for coating crops with high added values such as corn, wheat, soybean, rice, peanut, cotton, tobacco, potato, vegetable and the like.
The seed treatment agent product of the technical scheme of the invention can achieve the drug effect of the active ingredients and has bactericidal activity.
The invention has the advantages that:
the active component of the seed treating agent for sterilization is a single pyrisoxazole agent or a binary complex formed by compounding the pyrisoxazole agent with other bactericides, the obtained seed treating agent has remarkable advantages in the aspect of preparation technical application performance, particularly under the low-temperature adverse environment condition of compounding with triazole bactericides, the seed treating agent mainly has excellent safety, and particularly under the adverse low-temperature environment condition, the germination potential and the germination rate of coated seeds are not influenced.
The beewax used in the treating agent is a fatty substance, can provide certain nutrition for young seeds in an adverse environment, enhances the autoimmunity of the seeds in a low-temperature resistant environment, improves the safety of the seeds by adding the beewax, and further solves the safety problem of the coated seeds.
The composition of the bactericide related to the invention can be compounded with other bactericides such as fludioxonil, azoxystrobin, pyraclostrobin and thifluzamide or insecticides to obtain the seed treatment agent.
Detailed Description
The following specific examples are intended to illustrate the invention in further detail, but the invention is by no means limited to these examples, and methods known to those skilled in the art are included within the scope of the invention. The percentages and parts in the formula are by weight. In the examples, the active ingredients are prepared according to the record of the prior art (the content is 98%) and added after being folded into a hundred, the proportion of each component is weight percent, and other raw materials are all commercial products.
Formulation examples of formulations
Example 1.25% Pyrisoxazole seed treatment liquor
According to the formula requirements, 25% of pyrisoxazole, YUS-1105%, Atlox 49147%, 0.1% of rose essence and 200# of solvent oil are complemented to obtain the 25% pyrisoxazole seed treatment liquid agent.
Example 2-1.30% Pyridiniconazole seed treatment suspension
According to the formula requirements, 30% of pyrisoxazole, SK-20TX 2%, SP-270015%, RED 1316%, 0.5% of magnesium aluminum silicate and 0.5% of white carbon black are added with water to 100%, the materials are subjected to high-shear treatment and crushing, then the materials are transferred to a sand mill for sand milling, the particle size of the sand milled materials is detected by a particle size distribution instrument, and after the particle size reaches the standard, the particles are filtered to obtain the 30% pyrisoxazole seed treatment suspending agent.
Example 2-2.30% Pyridiniconazole seed treatment suspension
According to the formula requirements, 30% of pyrisoxazole, 30% of SK-20TX 2%, SP-270015%, RED 1316%, 0.5% of magnesium aluminum silicate, 0.5% of beeswax and 0.5% of white carbon black are added with water to make up to 100%, the materials are subjected to high-shear treatment and crushed, then transferred to a sand mill for sand milling, the particle size of the sand milled materials is detected by a particle size distribution instrument, and after the particle size reaches the standard, the particles are filtered to obtain the 30% pyrisoxazole seed treatment suspending agent.
Example 3.50% Pyrisoxazole seed treatment Dry powder
According to the formula requirements, 50% of pyrisoxazole, 6% of sodium lignosulfonate, 0.4% of rose essence, 3% of white carbon black and the balance of light calcium carbonate are supplemented to 100%, and after air flow crushing, 50% of pyrisoxazole seed treatment dry powder can be obtained.
Example 4-1.20% Pyridiniconazole ■ Difenoconazole seed treatment suspension (17+3)
According to the formula requirements, the pyrisoxazole is 17%, the difenoconazole is 3%, the SP-SC 32%, the SP-270015%, the RED 1314%, the magnesium aluminum silicate is 0.5%, the white carbon black is 0.5%, and the water is supplemented to 100%, the materials are subjected to high-shear treatment and crushed, then transferred to a sand mill for sand milling, the particle size of the sand milled materials is detected by a particle size distribution instrument, and after the particle size reaches the standard, the filtering is carried out, so that the 20% pyrisoxazole ■ difenoconazole seed treatment suspending agent can be obtained.
Example 4-2.20% Pyridiniconazole oxazole ■ Difenoconazole seed treatment suspension (17+3)
According to the formula requirements, the pyrisoxazole suspension is prepared by the steps of adding 17% of pyrisoxazole, 3% of difenoconazole, SP-SC 32%, SP-270015%, RED 1314%, 0.5% of magnesium aluminum silicate, 1% of beeswax and 0.5% of white carbon black in water to 100%, carrying out high-shear treatment on the materials, crushing the materials, then transferring the materials to a sand mill for sand milling, detecting the particle size of the sand milled materials by a particle size distribution instrument, and filtering the materials after the particle size reaches the standard to obtain the 20% pyrisoxazole ■ difenoconazole seed treatment suspension.
Example 5-1.20% Pyridiniconazole ■ triazolone seed treatment emulsion (15+5)
According to the formula requirements, the pyridinconazole ■ difenoconazole seed treatment suspending agent is prepared by the steps of adding 15% of pyridinconazole, 5% of difenoconazole, 5% of SP-SC 32%, TENSILOX AMS 3034%, RED 1314%, 0.5% of magnesium aluminum silicate and 0.5% of white carbon black into water until the water content is up to 100%, carrying out high-shear treatment on the materials, crushing the materials, then transferring the materials into a sand mill for sand milling, detecting the particle size of the sand milled materials by using a particle size distribution instrument, and filtering the materials after the particle size reaches the standard.
Example 5-2.20% Pyridiniconazole ■ triazolone seed treatment emulsion (15+5)
According to the formula requirement, the pyrisoxazole is 15%, the difenoconazole is 5%, the SP-SC 32%, the TENSILOX AMS 3034%, the RED 1314%, the magnesium aluminum silicate is 0.5%, the beeswax is 1%, the white carbon black is 0.5%, the water is supplemented to 100%, the materials are subjected to high-shear treatment and crushing, then the materials are transferred to a sand mill for sand milling, the particle size of the sand milled materials is detected by a particle size distribution instrument, and after the particle size reaches the standard, the filtering is carried out, so that the 20% pyrisoxazole ■ triazolone seed treatment suspending agent can be obtained.
Example 6-1.25% Pyridiniconazole ■ Tebuconazole seed treatment suspension (19+6)
According to the formula requirements, 19% of pyrisoxazole, 6% of tebuconazole, 49132% of Atlox, SK-33SC 4%, RED 1314%, 0.5% of magnesium aluminum silicate and 0.5% of white carbon black are added with water to make up to 100%, the materials are subjected to high-shear treatment and crushed, then transferred to a sand mill for sand milling, the particle size of the sand milled materials is detected by a particle size distribution instrument, and after the particle size reaches the standard, the filtration is carried out, so that the 25% pyrisoxazole ■ tebuconazole seed treatment suspending agent can be obtained.
Example 6-2.25% Pyridinium oxazole ■ Tebuconazole seed treatment suspension (19+6)
According to the formula requirement, 19% of pyrisoxazole, 6% of tebuconazole, 49132% of Atlox, SK-33SC 4%, RED 1314%, 0.5% of magnesium aluminum silicate, 5% of beeswax and 0.5% of white carbon black are added to 100% of water, the materials are subjected to high-shear treatment and crushing, then the materials are transferred to a sand mill for sand milling, the particle size of the sand milled materials is detected by a particle size distribution instrument, and after the particle size reaches the standard, the particles are filtered to obtain the 25% pyrisoxazole ■ tebuconazole seed treatment suspending agent.
Example 7.40% Pyridiniconazole ■ carbendazim seed treatment suspension (30+10)
According to the formula requirements, 30% of pyrisoxazole, 10% of carbendazim, SP-SC 34%, TENSILOX 3032%, RED 1316%, 0.6% of magnesium aluminum silicate and 0.6% of white carbon black are added with water to make up to 100%, the materials are subjected to high-shear treatment and crushed, then transferred to a sand mill for sand milling, the particle size of the sand milled materials is detected by a particle size distribution instrument, and after the particle size reaches the standard, the particles are filtered to obtain the 30% pyrisoxazole ■ carbendazim seed treatment suspending agent.
Example 8.40% Pyridiniconazole ■ Thiram seed treatment suspension (20+20)
According to the formula requirements, 20% of pyrisoxazole, 20% of thiram, SK-242%, Atlox 49137%, RED 1316%, magnesium aluminum silicate 0.5% and white carbon black 0.5% are added with water to 100%, the materials are subjected to high-shear treatment and crushed, then transferred to a sand mill for sand milling, the particle size of the sand milled materials is detected by a particle size distribution instrument, and after the particle size reaches the standard, the particles are filtered to obtain the 40% pyrisoxazole ■ thiram seed treatment suspending agent.
Seed safety test
The seed treatment agent in the above examples was coated on corn seeds, and the following properties were measured after coating.
For the safety of obtaining two kinds of seed treatment agents, the invention adopts GB/T3543.4-1995 crop seed test regulation-germination test to complete. Wherein, the germination means that the seedlings appear and grow to a certain stage in a laboratory, and the main structure of the seedlings shows whether the seedlings can grow further to be normal plants under the appropriate conditions in the field. The germination vigor is the tendency of germination, observed on day 4 according to the relevant standards, and the germination rate is the percentage of the number of normal seedlings grown under the specified conditions and time to the number of seeds to be tested.
The experiment used sand as the germinating bed. The sand grains have uniform size, the diameter of 0.05-0.80mm, and the seeds are nontoxic and sterile. Washing and high-temperature sterilization are carried out before use. The sand bed adopts a sand-in-sand mode, namely seeds are sown on a layer of flat wet sand, and loose sand with the thickness of 10-20mm is covered according to the size of the seeds.
The germination apparatus is a germination box: under illumination, controlling the temperature within the range of 10-40 ℃;
germination vigor and germination rate were measured at 20 ℃ low temperature, day and night, according to the germination conditions specified in the standard.
The germination vigor is the percentage of the number of seedlings in the total number after 4 days of planting;
the germination rate is the percentage of the number of seedlings in the total number 7 days after planting.
TABLE 1 safety data for examples and comparative examples
It is also a well-known technical problem in the art that when the pyrisoxazole is compounded with the triazole compound in the above examples 4-1, 5-1 and 6-1, the germination potential and germination rate of the coated seeds are obviously inhibited under adverse environment, especially under low temperature conditions, i.e. the triazole compound inhibits the germination of the seeds under low temperature conditions. From the above data, it can be seen that, especially in the case of the problem of low-temperature germination rate of triazole compounds, the addition of beeswax has a more remarkable unexpected effect, and the germination vigor and germination rate of the coated seeds are remarkably improved.
As can be seen from Table 1, the seed treatment agent added with beeswax substance has outstanding and unobvious effects on the coating germination potential and germination rate.
Claims (5)
1. A seed treatment agent for sterilization, characterized in that: the seed treatment agent comprises an active ingredient, a carrier and at least one auxiliary agent; wherein the active ingredients are pyrisoxazole, pyrisoxazole and tebuconazole, pyrisoxazole and difenoconazole; the active ingredient accounts for 0.9 to 90 percent of the weight of the treating agent;
the auxiliary agent also comprises beeswax; wherein the addition amount of beeswax is 0.1-5wt% of the treatment agent.
2. The seed treatment agent for sterilization as set forth in claim 1, characterized in that: the seed treatment agent preparation comprises a seed treatment dry powder agent, a seed treatment dispersible powder agent, a seed treatment liquid agent, a seed treatment emulsion or a seed treatment suspending agent.
3. The seed treatment agent for sterilization as set forth in claim 1, characterized in that: the auxiliary agent comprises one or more of an anionic surfactant, a nonionic surfactant, an anionic and non-compound surfactant and a high molecular surfactant.
4. The seed treatment for sterilization as set forth in claim 3, characterized in that: the anionic surfactant is one or more of sulfonate, sulfate, carboxylate, phosphate and succinate;
the nonionic surfactant is one or more of fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, fatty amine polyoxyethylene ether, fatty acid polyoxyethylene ether, acid alcohol ester and polyoxyethylene ether thereof, fatty amide and polyoxyethylene ether thereof, castor oil polyoxyethylene ether, alkanolamide and polyoxyethylene ether thereof, sodium alkyl naphthalene sulfonate fatty alcohol polyoxyethylene ether, sorbitan fatty acid ester polyoxyethylene ether, styrene maleic anhydride copolymer, phenethyl phenol polyoxyethylene polyoxypropylene ether and formaldehyde condensate;
the negative non-ionic compound surfactant is a mixture of one or more anionic surfactants and one or more non-ionic surfactants;
the polymer surfactant is polyvinyl alcohol or chitosan.
5. The use of the seed treatment agent for sterilization according to claim 1, characterized in that: the seed treating agent for sterilization is applied to prevention and treatment of plant diseases.
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| CN106852332A (en) * | 2015-12-08 | 2017-06-16 | 中化农化有限公司 | Bactericidal composition containing SYP-Z048 |
| CN106922655A (en) * | 2015-12-29 | 2017-07-07 | 沈阳中化农药化工研发有限公司 | A kind of bactericidal composition containing stabilizer |
| CN106717297A (en) * | 2016-11-28 | 2017-05-31 | 安徽华安种业有限责任公司 | A kind of coating paddy seeds method |
| CN108419804A (en) * | 2017-02-13 | 2018-08-21 | 中化作物保护品有限公司 | A kind of bactericidal composition and its application |
| CN108684399A (en) * | 2018-06-07 | 2018-10-23 | 芜湖县能胜农业科技有限公司 | A kind of implantation methods of green pepper prevention decayed fruit phenomenon |
| CN109769837A (en) * | 2019-03-01 | 2019-05-21 | 贵州大学 | A kind of pesticide synergistic combination preventing and treating fruits and vegetables gray mold |
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