CN110432277A - A kind of insecticidal and bactericidal composition for seed treatment - Google Patents

A kind of insecticidal and bactericidal composition for seed treatment Download PDF

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Publication number
CN110432277A
CN110432277A CN201910725501.9A CN201910725501A CN110432277A CN 110432277 A CN110432277 A CN 110432277A CN 201910725501 A CN201910725501 A CN 201910725501A CN 110432277 A CN110432277 A CN 110432277A
Authority
CN
China
Prior art keywords
seed
insecticidal
prothioconazoles
fludioxonil
clothianidin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910725501.9A
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Chinese (zh)
Inventor
张志伟
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Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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Application filed by Guangdong Zhongxun Agri Science Corp filed Critical Guangdong Zhongxun Agri Science Corp
Publication of CN110432277A publication Critical patent/CN110432277A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of insecticidal and bactericidal compositions for seed treatment, effective component is made of prothioconazoles, fludioxonil, clothianidin, the mass ratio of prothioconazoles, fludioxonil, clothianidin in the composition is respectively as follows: 1-30%, 0.1-10%, 1-55%, remaining is nonactive additive.Great number of indoor and outdoor experiments show that after being compounded is sowed after insecticidal and bactericidal composition Dressing provided by the invention, the germination percentage that can significantly improve crop seeds, the generation for mitigating crops seedling stage diseases and pests, the yield for increasing crops.

Description

A kind of insecticidal and bactericidal composition for seed treatment
Technical field
The present invention relates to composition pesticide and its application fields, specifically with prothioconazoles, fludioxonil and clothianidin For the ternary complex of effective active composition compounding, it is mainly used in the seed Dressing of crops.
Background technique
Prothioconazoles (Prothioconazole): prothioconazoles are New-type wide-spectrum triazole thioketone demethylation inhibitors Fungicide.It is mainly used for preventing and treating a variety of on wheat, barley, rape, peanut, rice, legume crop, beet and field vegetables etc. Disease.Almost to all wheat diseases have fine control efficiency, as on wheat and barley powdery mildew, banded sclerotial blight, leaf spot, Rust, net blotch, moire disease etc.;The soil-borne disease that rape and peanut can also be prevented and treated, such as sclerotiniose, southern blight and main leaf Disease, such as gray mold, black spot, brown spot, balck shank and rust.
Fludioxonil (Fludioxonil): for non-interior suction benzene pyroles contact killing type fungicide, pass through inhibition glucose phosphorylated Related transfer, and inhibit the growth of fungal mycelium, germ death is eventually led to, the mechanism of action is unique, with existing fungicide No interactions resistance.High-efficiency broad spectrum passes caused by many pathogens such as sac fungus, basidiomycetes, Fungi Imperfecti kinds and soil-borne disease has Extraordinary preventive effect.
Clothianidin (Clothianidin): belonging to second generation nicotinic insecticide, and the mechanism of action is to act on insect nerve NAChR outstanding afterwards.Mainly there is preferable control efficiency to the sucking pest on crops.
In modern agricultural production, due to the surface of the seed or inside is carried disease germs, pest is caused harm in fungus in soil or soil, kind After planting usually there is sick seedling in son, lacks nest, phenomenon of being short of seedling caused by weak seedling and insect pest etc., causes greatly to damage to agricultural production It loses.Seed chemicals treatment can not only prevent and treat crops soil biography, seed-borne disease and subterranean pest-insect, but also to plant seedling on crop field The pest and disease damage that phase occurs also has good prevention effect.
The present inventor is effective active composition ternary built formula in further investigation prothioconazoles, fludioxonil and clothianidin In the process, surprisingly the ternary recompounded composite of prothioconazoles, fludioxonil and clothianidin is to crop seeds, especially It is that can significantly improve the germination percentage of rice paddy seed after rice paddy seed Dressing, mitigate the hair of the pest and disease damages such as bakanae disease, thrips Raw, increase rice yield.
Summary of the invention
The present invention is intended to provide a kind of insecticidal and bactericidal composition for seed treatment, the insecticidal and bactericidal composition can be used for After crop seeds Dressing, especially rice paddy seed Dressing, the germination percentage of rice paddy seed can be significantly improved, mitigates and dislikes The generation of the pest and disease damages such as seedling diseases, thrips increases rice yield.
Technical solution of the present invention: to achieve the above object, the present invention provides a kind of pesticide-germicide for seed treatment Composition, effective component are made of prothioconazoles, fludioxonil, clothianidin, and prothioconazoles, fludioxonil, clothianidin are in the composition Mass ratio be respectively as follows: 1-30%, 0.1-10%, 1-55%, other components are nonactive additive, mainly include The common pesticidal preparations additive such as wetting dispersing agent, film forming agent, colorant, thickener, antifreezing agent, preservative, defoaming agent.
In order to promote wetting and dispersing between particles of active components to prevent it from agglomerating, composition pesticide of the present invention is also wrapped Wetting dispersing agent is included, the wetting dispersing agent is preferably fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether, polyoxyethylene rouge Fat acid, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fatty acid polyglycol ethylene glycol, dodecyl benzene sulfonic acid Salt, polyoxyethylene groups phenol formaldehyde condensate, polyoxyethylene poly-oxygen propylene aether block copolymer, naphthalene or alkyl naphthalene formaldehyde condensation product sulphur Hydrochlorate, aliphatic alcohol polyoxyethylene sulfonate, alkyl phenol polyoxyethylene ether sulfonate, lignin and its derivative sulfonate, rouge Fat acid ethane additive product phosphate, alkyl phenol polyoxyethylene ether phosphate, APES formaldehyde condensation products sulfat One or more of mixing.
It is not easily to fall off and disperse in order to guarantee that limited farm chemical ingredients concentration acts on seed and root, reduce pesticide Diffusion in the environment and to non-target contact, the suspension seed-coating agent also needs to include film forming agent.The film forming agent was both Guarantee institute's ventilative, good water permeability, normal seed germination growth at clothing film, guarantees that institute is insoluble in water at clothing film again, in clothing film Active constituent energy slow release, efficiency time are long.According to film forming agent of the present invention be preferably Arabic gum, animal glue, pectin, Xanthan gum, ethyl cellulose, sodium carboxymethylcellulose, hydroxypropyl cellulose, sodium alginate, polyvinyl alcohol, gathers methylcellulose The mixing of one or more of ethylene glycol, polyvinylpyrrolidone, polyacrylamide, Sodium Polyacrylate.
The also known as alert toner of colorant, can be improved suspension seed-coating agent using safe, wherein the colorant is preferably alkali The mixing of one or more of property rhodamine toner, aqueous rhodo, acid scarlet.
Suspension seed-coating agent of the present invention further includes thickener, to improve the viscosity of decentralized medium, reduces the sedimentation of particle Speed, to improve the stability of preparation.Preferably, the tackifier is xanthan gum, Arabic gum, methylcellulose, carboxylic first Base cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, sodium acrylate, sodium alginate, polyvinyl alcohol, polyvinylpyrrolidone, The mixing of one or more of polyacrylamide, Sodium Polyacrylate, aluminium-magnesium silicate, bentonite.
In order to improve seed coat agent low-temperature storage stability, suspension seed-coating agent of the present invention also added antifreezing agent. The antifreezing agent is one of ethylene glycol, propylene glycol, glycerine, hexylene glycol, urea, ammonium sulfate, sodium chloride, calcium chloride or several The mixing of kind.
Defoaming agent of the present invention is machine silicone, C8-10Fatty alcohol, C10-20Saturated fatty acid and its esters in One or more of mixing;
The preservative is benzoic acid, benzaldehyde, sodium benzoate, Potassium Benzoate, sorbic acid, sodium salicylate, 2- hydroxyl connection Benzene, parahydroxyben-zaldehyde 1, the mixing of one or more of 2-[4-morpholinodithio quinoline -3- ketone.
Suspension seed-coating agent of the present invention the preparation method comprises the following steps: by prothioconazoles, fludioxonil, clothianidin pass through air-flow powder It is broken, after wetting dispersing agent, film forming agent, colorant, thickener, antifreezing agent, preservative, defoaming agent and distilled water are completely dissolved, press Ratio puts into sand mill and grinds 2 times, until the grain fineness of suspension reaches D50It is 2-3 μm, D908 μm of < to get product.In During practical medication, the present invention can a situation arises determines the suitable dosage of the suspension seed-coating agent according to local controlling object, Usual formulation rate is that the mass ratio of seed coat agent and seed is 1: 50-100.
Suspension seed-coating agent prepared by the present invention is vivid red, flowable suspension, and low temperature, heat storage stability close Lattice, heat storage resolution ratio is less than 5%, and suspensibility is greater than 90%, and wet screening test 98% passes through 45 μm of standard screens, grain fineness D50For 2- 3μm。
Compared with the prior art, the advantages of the present invention are as follows: composition pesticide provided by the invention mixes crop seeds The production that the germination percentage of crop seeds can be significantly improved after kind processing, mitigate the generation of pest and disease damage on crops, increase crops Amount.
Specific embodiment
To better understand the essence of the present invention, below with reference to embodiment, the content of the present invention will be further explained, But limitation of the present invention cannot be considered as, the following description is only for the purpose of explaining the present invention, for without departing from spirit of that invention and principle Modification, replacement or the improvement made, fall within the scope of the claimed invention.
One: 70% prothioconazoles fludioxonil clothianidin seed treatment suspending agent of embodiment
The content of following substance is weight percentage: prothioconazoles 20%, fludioxonil 5%, clothianidin 45%, ten Dialkyl benzene sulfonate 5%, polyacrylamide 8%, xanthan gum 1.5%, aqueous rhodo 2%, sorbic acid 0.5%, glycerine 2.5%, deionized water complements to 100%.70% is made after above-mentioned each material is mixed ground and/or high speed shear in proportion Prothioconazoles fludioxonil clothianidin seed treatment suspending agent.
Two: 55% prothioconazoles fludioxonil clothianidin seed treatment suspending agent of embodiment
The content of following substance is weight percentage: prothioconazoles 15%, fludioxonil 5%, clothianidin 35%, rouge Fat alcohol polyethenoxy ether sulphonate 7%, polyurethane-modified cellulose nitrate 10%, Arabic gum 1.5%, azarin 2%, sodium salicylate 0.3%, ethylene glycol 2%, deionized water complement to 100%.Above-mentioned each material is mixed into ground and/or high speed shear in proportion 55% prothioconazoles fludioxonil clothianidin seed treatment suspending agent is made afterwards.
Three: 40% prothioconazoles fludioxonil clothianidin seed treatment suspending agent of embodiment
The content of following substance is weight percentage: prothioconazoles 10%, fludioxonil 5%, clothianidin 25%, alkane Base phenol polyethenoxy ether sulfonate 10%, polyethylene glycol-gelatin-gum arabic condensation product 8%, sodium acrylate 1.5%, brilliant blue 2%, sorbic acid 0.2%, sodium chloride 3%, deionized water complements to 100%.By above-mentioned each material mix in proportion it is ground and/ Or 40% prothioconazoles fludioxonil clothianidin seed treatment suspending agent is made after high speed shear.
Example IV: Field information test
Seed pelleting processing: health rice paddy seed full, of uniform size is selected, is poured into through diluting prepared seed coat agent It stirs in medical fluid, can be sowed after drying in the shade.
1 rice paddy seed seed dressing and coating field test results of table
As can be seen from Table 1, rice paddy seed is after insecticidal and bactericidal composition Dressing provided by the invention, rice paddy seed Emergence rate, per mu yield are handled obviously higher than each single dose and blank control, to rice safety;Simultaneously to the evil seedling of rice seedling The pest and disease damages such as disease, thrips also have good control efficiency, and preventive effect is up to 85% or more.
As it can be seen that it is provided by the invention for a kind of insecticidal and bactericidal composition for seed treatment, it can be obvious after Dressing The germination percentage for improving crop seeds, the generation for mitigating crops seedling stage diseases and pests, the yield for increasing crops, are made in agricultural It is widely applied in production.

Claims (3)

1. a kind of insecticidal and bactericidal composition for seed treatment, it is characterised in that: effective component by prothioconazoles, fludioxonil, Clothianidin composition, the mass ratio of prothioconazoles, fludioxonil, clothianidin in the composition be respectively as follows: 1-30%, 0.1-10%, 1-55%, remaining is nonactive additive.
2. a kind of insecticidal and bactericidal composition for seed treatment according to claim 1, it is characterised in that: the desinsection The dosage form of bactericidal composition is seed treatment suspending agent.
3. a kind of insecticidal and bactericidal composition for seed treatment according to claim 1, it is characterised in that: the seed For rice paddy seed.
CN201910725501.9A 2019-05-09 2019-08-07 A kind of insecticidal and bactericidal composition for seed treatment Pending CN110432277A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2019103827521 2019-05-09
CN201910382752 2019-05-09

Publications (1)

Publication Number Publication Date
CN110432277A true CN110432277A (en) 2019-11-12

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112970765A (en) * 2021-02-22 2021-06-18 安徽润农腾辉生物科技有限公司 Ternary compound seed dressing agent for preventing and treating plant diseases and insect pests
CN113057172A (en) * 2021-02-22 2021-07-02 安徽润农腾辉生物科技有限公司 Ternary compound seed dressing agent containing prothioconazole and fludioxonil

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112970765A (en) * 2021-02-22 2021-06-18 安徽润农腾辉生物科技有限公司 Ternary compound seed dressing agent for preventing and treating plant diseases and insect pests
CN113057172A (en) * 2021-02-22 2021-07-02 安徽润农腾辉生物科技有限公司 Ternary compound seed dressing agent containing prothioconazole and fludioxonil

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Application publication date: 20191112