CN106172436A - A kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles - Google Patents
A kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles Download PDFInfo
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- CN106172436A CN106172436A CN201610525503.XA CN201610525503A CN106172436A CN 106172436 A CN106172436 A CN 106172436A CN 201610525503 A CN201610525503 A CN 201610525503A CN 106172436 A CN106172436 A CN 106172436A
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- cyano
- amino
- bacterium azoles
- phenylancryic acetate
- pyridine bacterium
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
Abstract
The invention discloses a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the compositions of pyridine bacterium azoles, effective ingredient is 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles, the weight ratio of 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles is 1:10~10:1, and 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles weight summation percentage by weight in the composition are 1%~80%.According to reality application needs, bactericidal composition of the present invention can be prepared as the one in aqueous emulsion, microemulsion, suspending agent, wettable powder, water dispersible granules, is used for preventing and treating wheat scab, powdery mildew.
Description
Technical field
The present invention relates to a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles, be with 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium
Azoles is effective ingredient, is used for preventing and treating wheat scab, powdery mildew.
Background technology
The resistance problem of agricultural disease is a global problem, the emphasis class that always agricultural science and technology worker pays close attention to
Topic.Along with the continuity year in year out of disease chemical prevention, the increase of Pesticide use amount and not scientifical use pesticide, pathogenic bacteria
Resistance is day by day serious, and the pathogenic bacteria kind producing resistance is on the increase.Meanwhile, the use pesticide of high intensity, cause agricultural product pesticide
Residual exceeds standard, environmental pollution and peasant's drug cost increase etc., is unfavorable for agricultural sustainable development.Therefore, research and development efficiently,
Low toxicity, the bactericide agricultural chemicals of environmental protection have positive effect to agricultural sustainable development.
2-cyano-3-amino-3-phenylancryic acetate, is cyanoacrylate antibacterial, has protection and therapeutical effect;2-cyano-3-amino-3-phenylancryic acetate is to gibberella saubinetii
Disease has the highest activity.
Pyridine bacterium azoles, is that sterol synthesizes inhibition antibacterial, can efficiently control leaf not disease on the ground by root application
Generation and harm, it is also possible to be used for spraying;Pyridine bacterium azoles has the bactericidal activity of wide spectrum, has protection and therapeutical effect simultaneously
And good interior absorption, gray mold, the powdery mildew excellent effect to various crop.
Powdery mildew, head blight are the frequent fungal diseases mixing generation after Semen Tritici aestivi heading, are on wheat planting produces
One of Major Diseases.Head blight is mainly caused by fusarium infection, and powdery mildew is infected by ascomycetes and causes.The present composition
Antibacterial can use after Semen Tritici aestivi is eared, and prevents and treats wheat scab and powdery mildew simultaneously, reaches the effect of saving of work and time.
The mixture of different pesticide species, is the common methods of preventing and treating agricultural pest.Screened by formulation of pesticide, filter out
Reasonably formula, can be effectively improved actual prevention effect, reduces dosage, reduces cost, delays the drug-fast generation of pest and disease damage,
It it is the important means of agricultural synthesis improvement.The recipe determination of 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles has been carried out deeply grinding by the present inventor
Study carefully, find that 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles carry out mixture and have obvious potentiation to make multiple fungus in certain mixed ratio scope
With, after further study, complete the present invention.
2-cyano-3-amino-3-phenylancryic acetate and the compositions of pyridine bacterium azoles and application there is no report at present.
Summary of the invention
Present invention solves the technical problem that be to provide a kind of efficiently, low toxicity and the lasting period long, can effectively prevent and treat agricultural fungus
Sexually transmitted disease (STD) evil a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles.
For solving the problems referred to above, the technical solution adopted in the present invention is: a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with pyridine bacterium azoles
Bactericidal composition, effective ingredient is 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles, and the weight ratio of 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles is 1:10~10:
1,2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles weight summation percentage by weight in the composition are 1%~80%, and remaining is the most permissible
Accept and allow the auxiliary agent used.
Bactericidal composition of the present invention can be configured to aqueous emulsion, microemulsion according to well known to a person skilled in the art method, hang
One in floating agent, wettable powder, water dispersible granules, is used for preventing and treating wheat scab, powdery mildew.
Bactericidal composition of the present invention is possibly together with the auxiliary agent needed for preparation pesticidal preparations, and auxiliary agent is solvent, emulsifying agent, moistening
The mixing of one or more in agent, stabilizer, dispersant, thickening agent, pH adjusting agent, defoamer, antifreezing agent, packing agent etc.,
It is known substance, is various auxiliary agents conventional in pesticidal preparations, can be varied from according to different situations, there is no limit especially
Fixed.
Bactericidal composition of the present invention, is used for preventing and treating wheat scab, powdery mildew.
The bactericidal composition that the present invention provides, generally uses spray method to use, it is also possible to use as required agriculturally
Other of application use technology.
Compositions described in the invention, can provide with finished product preparation form, and i.e. in compositions, each material is the most blended, group
The composition of compound can also provide by unit dose form, directly mixes in bucket or tank, be then diluted to desired concn before using.
The bactericidal composition that the present invention provides has the advantages that:
1, the bactericidal composition that the present invention provides, shows obvious potentiation or summation action in certain ratio range,
The prevention effect of pathogenic bacteria is significantly improved by compositions than single dose, reduces the using dosage of pesticide, decreases times for spraying,
Reduce drug cost, decrease the pesticide adverse effect to ecological environment.
2, the bactericidal composition that the present invention provides, two kinds of active ingredient mechanism of action are not quite identical, can overcome long-term
Single use easily produces the shortcoming of resistance, extends the service life of medicament, and the comprehensive control to pathogenic bacteria resistance has important meaning
Justice.
3, the bactericidal composition that the present invention provides, drug effect plays rapidly, and the lasting period is long, and use cost is low, easy to use, saves
Shi Shengli, its popularization and application have huge economic benefit and social benefit.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage more short and sweet, present invention specific examples below
Illustrate, but the present invention is only limitted to absolutely not these embodiments.The following stated is only the preferable embodiment of the present invention, is used only for
The present invention is described, it is impossible to be interpreted as limiting the scope of the present invention.It should be pointed out that, it is all in the spirit and principles in the present invention
Within any amendment, equivalent and the improvement etc. made, should be included within the scope of the present invention.Therefore, this
The protection domain of bright patent should be as the criterion with claims.
Content described in embodiment is all weight percentage.
Embodiment 1:33% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azole suspending agent
Concrete operation step is: first mixed by other auxiliary agent, and in cutter, shear-mixed is uniform, is subsequently adding cyanogen alkene bacterium
Ester and pyridine bacterium azoles, grind 2-3h in ball crusher, make a diameter all at below 5mm, can be prepared by 33% 2-cyano-3-amino-3-phenylancryic acetate pyridine
Bacterium azole suspending agent.
Embodiment 2:15% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles aqueous emulsion
Concrete operation step is: first 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles, trimethylbenzene, Sorbitan fatty acid ester are blended in one
Rise, dissolve and become uniform oil phase.Again part water and other auxiliary agents are mixed, dissolve and become uniform aqueous phase.Then
While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly adds water to reach phase inversion point, carry out high speed shear afterwards,
And add remaining water, shear about 30min, can be prepared by 15% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles aqueous emulsion.
Embodiment 3:12% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles microemulsion
Concrete operation step is: first 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles fatty acid methyl ester is completely dissolved, then adds
Other auxiliary agent, mix homogeneously, it is eventually adding water, after being sufficiently stirred for, can be prepared by 12% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles microemulsion.
Embodiment 4:30% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles wettable powder
Concrete operation step is: be sufficiently stirred for, 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles, other auxiliary agent through air-flow in stirred tank
Mix homogeneously after pulverizer pulverizing, can be prepared by 30% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles wettable powder.
Embodiment 5:60% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles water dispersible granules
Concrete operation step is: will have 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles, other auxiliary agent mix homogeneously, and use ultra micro comminution by gas stream
Machine is pulverized, and adds in fluidized-bed granulation dryer and carry out pelletize, be dried, after screening, can be prepared by 60% cyanogen alkene bacterium after mediating
Ester pyridine bacterium azoles water dispersible granules.
Embodiment 6:12% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azole suspending agent
Concrete operation step is: first mixed by other auxiliary agent, and in cutter, shear-mixed is uniform, is subsequently adding cyanogen alkene bacterium
Ester and pyridine bacterium azoles, grind 2-3h in ball crusher, make a diameter all at below 5mm, can be prepared by 12% 2-cyano-3-amino-3-phenylancryic acetate pyridine
Bacterium azole suspending agent.
Embodiment 7:44% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles wettable powder
Concrete operation step is: be sufficiently stirred for, 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles, other auxiliary agent through air-flow in stirred tank
Mix homogeneously after pulverizer pulverizing, can be prepared by 44% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles wettable powder.
Embodiment 8: synergy bioassay test
Wheat powdery mildew test uses wheat nebulization dispenser (having water membrane to be advisable with blade surface), in 2015
On April 13, in carries out spraying treatment, and medicinal sprayer tool uses hand sprayer (liquid capacity about 2.0L), sprays medicine one every 10 days
Secondary, spray 2 times continuously.
Investigation method:
0 grade: without scab;
1 grade: lesion area accounts for less than the 5% of whole leaf area;
3 grades: lesion area accounts for the 6%-15% of whole leaf area;
5 grades: lesion area accounts for the 16%-25% of whole leaf area;
7 grades: lesion area accounts for the 26%-50% of whole leaf area;
9 grades: lesion area accounts for more than the 50% of whole leaf area.
According to survey data, calculate disease index and the prevention effect of each process.
Disease index is pressed formula and is calculated, result of calculation reservation 2 significant digits:
When carrying out drug combination toxicity test, this test uses Wadley method to calculate the coefficient of synergism (SR) of mixture, evaluates
The synergy type of mixture.
Wadley method: evaluate the potentiation of pharmacy mix according to coefficient of synergism (SR), i.e. SR < 0.5 is antagonism,
0.5≤SR≤1.5 are summation action, and SR > 1.5 is synergistic function.Coefficient of synergism (SR) presses formula (1), (2) calculate:
In formula:
X1--mixture EC50Theoretical value, unit is milligrams per liter (mg/L);
PA--the percentage composition of A in mixture, unit is percentage rate (%);
PB--the percentage composition of B in mixture, unit is percentage rate (%);
The EC of A in A--mixture50Value, unit is milligrams per liter (mg/L);
The EC of B in B--mixture50Value, unit is milligrams per liter (mg/L).
In formula:
The coefficient of synergism of SR--mixture;
The EC of X1--mixture50Theoretical value, unit is milligrams per liter (mg/L);
The EC of X2--mixture50Measured value, unit is milligrams per liter (mg/L).
Table 1,2-cyano-3-amino-3-phenylancryic acetate and the pyridine bacterium azoles synergy measurement result to wheat powdery mildew pathogenic bacteria
The test of wheat scab surveys standard method NY/T1156.2-2006 with reference to raw, uses pastille medium therapy: take each
The medicinal liquid 6mL of single dose and mixture series concentration, adds in the PDA culture medium of the 54mL being cooled to 45 DEG C, makes required the denseest
The pastille culture medium flat plate of degree.Then produce 6mm diameter mycelia block from the object bacteria colony edge cultivated 7 days, move to each series
In pastille culture medium, mycelia faces down, and each process repeats for 4 times.It is disposed, is placed in the constant temperature biochemical cultivation case of 25 ± 1 DEG C
Middle cultivation.
Taking out culture medium flat plate after 3 days, measure each process colony diameter by decussation method, the mycelia calculating each process is raw
Long suppression ratio.Logarithm value according to drug concentration (mg/L) is independent variable x, with the probit value of corrected mortality for dependent variable y, point
Do not set up virulence regression equation formula, use DPS computed in software single dose and the EC of each proportioning mixture50And mixture co-toxicity coefficient.Altogether
Poison coefficient (CTC) >=120 shows as potentiation;Co-toxicity coefficient (CTC)≤80 shows as antagonism;80 < co-toxicity coefficients
(CTC) < 120 shows as summation action.Actual measurement toxicity index (ATI)=(standard agent EC50/ reagent agent EC50)×100。
Theoretical toxicity index (TTI)=(percentage composition of A in the toxicity index × mixture of A)+(in the toxicity index × mixture of B the hundred of B
Divide content).Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] × 100.
Table 2,2-cyano-3-amino-3-phenylancryic acetate and the pyridine bacterium azoles indoor joint toxicity measuring result to wheat scab pathogenic bacteria
By Tables 1 and 2 it can be seen that 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles are compounding in the weight ratio of 1:10-10:1, right
Wheat powdery mildew, head blight show as potentiation.
Embodiment 9: preventing and treating wheat powdery mildew, the field test of head blight
Test site is positioned at Zhengzhou City Henan Province, uses nebulization.Use 25% 2-cyano-3-amino-3-phenylancryic acetate suspending agent, 25% pyridine bacterium
Azoles cream is as comparison medicament, and test sets 9 chemicals treatment altogether, and each process repeats for 4 times, investigates Semen Tritici aestivi diseased plant before dispenser
Number, respectively investigates a prevention effect, records diseased plant number, calculate prevention effect, result of the test such as table 3 and table for after dispenser 7 days, 15 days
Shown in 4.
Table 3,2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles combination preventing and treating wheat powdery mildew field test results
Table 4,2-cyano-3-amino-3-phenylancryic acetate and the combination of pyridine bacterium azoles prevent and treat wheat scab field test results
By table 3 and table 4 it can be seen that the effect of bactericidal composition of the present invention preventing and treating is better than the process of each comparison single dose, explanation
2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles compound and can improve prevention effect, reduce the using dosage of pesticide, decrease pesticide to environment
Impact, reduces drug cost.
Present composition antibacterial can use after Semen Tritici aestivi is eared, and prevents and treats wheat scab and powdery mildew simultaneously, reaches
To the effect of saving of work and time, actual production has the strongest practice significance.
Claims (8)
1. one kind contain 2-cyano-3-amino-3-phenylancryic acetate and the bactericidal composition of pyridine bacterium azoles, it is characterised in that: effective ingredient be 2-cyano-3-amino-3-phenylancryic acetate and
Pyridine bacterium azoles, the weight ratio of 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles is 1:10~10:1.
It is the most according to claim 1 a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles, it is characterised in that: cyanogen
The weight ratio of alkene bacterium ester and pyridine bacterium azoles is 10:1.
It is the most according to claim 1 a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles, it is characterised in that: cyanogen
Alkene bacterium ester and pyridine bacterium azoles weight summation percentage by weight in the composition are 1%~80%.
The most according to claim 1 and 2 a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles, its feature exists
In: 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles weight summation percentage by weight in the composition are 33%.
It is the most according to claim 1 a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles, it is characterised in that:
The preparation of described bactericidal composition becomes the one of aqueous emulsion, microemulsion, wettable powder, water dispersible granules.
It is the most according to claim 1 a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles, it is characterised in that:
Described bactericidal composition is prepared as suspending agent.
It is the most according to claim 6 a kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyridine bacterium azoles, it is characterised in that: institute
Stating bactericidal composition weight ratio is: 2-cyano-3-amino-3-phenylancryic acetate 30%, pyridine bacterium azoles 3%, alkylnaphthalene sulfonate 5%, sodium lignin sulfonate
7%, propylene glycol 5%, xanthan gum 3%, methanol 3%, potassium hydroxide 0.1%, water surplus, obtain 33% 2-cyano-3-amino-3-phenylancryic acetate pyridine bacterium azoles
Suspending agent.
8. a kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and pyridine bacterium azoles described in claim 1 is at preventing and treating gibberella saubinetii
Sick, the application of powdery mildew.
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Citations (3)
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2016
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CN1608467A (en) * | 2003-10-24 | 2005-04-27 | 沈阳化工研究院 | Bactericide composition containing SYP-Zo48 |
CN1559210A (en) * | 2004-02-18 | 2005-01-05 | 江苏省农药研究所有限公司 | 2-cyano-3-amino-3-ethyl phenylacrylate used for prevention and control of plant disease and elimination of pests |
CN105815324A (en) * | 2015-01-09 | 2016-08-03 | 中化农化有限公司 | Bactericidal composition containing SYP-Z048 and JS399-19 |
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