CN1240127A - Spirulina shampoo and productive method thereof - Google Patents
Spirulina shampoo and productive method thereof Download PDFInfo
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- CN1240127A CN1240127A CN 99102699 CN99102699A CN1240127A CN 1240127 A CN1240127 A CN 1240127A CN 99102699 CN99102699 CN 99102699 CN 99102699 A CN99102699 A CN 99102699A CN 1240127 A CN1240127 A CN 1240127A
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- spirulina
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Abstract
The spirulina shampoo contains not only the surfactant, preservative and water, but also the spirulia extract obtained by processing natural spirulia. The spirulia extract is added to the shampoo according to a certain proportion, so the shampoo possesses the function of protecting hair, supplementing nutrients to hair, promoting the metabolism of hair. It possesses a certain health-care effect for hair, and no irritation to skin and eyes.
Description
The present invention relates to a kind of production method that contains the shampoo and this shampoo of natural algae spirulina.
Spirulina (Spirulina) is a kind of in numerous aquatic microalgae, belong to the Cyanophyta Oscillariaceae, it contains rich in protein, aminoacid, unsaturated fatty acid, vitamin and trace element, remove as nutritional enrichment additives and add food, feedstuff or bait China and foreign countries to, some developed countries have begun with its medicine as diseases such as treatment anemia, coronary heart disease, hepatopathy, obesities, also have some open source literature introductions to make skin protection cosmetics, article of everyday use such as fat-reducing soap etc. in recent years, but the shampoo that contains spirulina still belong to blank in China with spirulina.
It is abundant to the purpose of this invention is to provide a kind of effective nutrition, can nurse one's health the production method of the spirulina shampoo and this shampoo of hair conditioning, safety non-toxic well.
Shampoo of the present invention also is added with spirulina except that containing compositions such as surfactant that common shampoo has, antiseptic, water.According to selling point, at different hair qualitys, give shampoo painted, give certain denseness, fragrance, make shampoo have the antipruritic function of anti-dandruff etc. to shampoo, also can some other additives of corresponding interpolation, as materials such as conditioner, coloring agent, thickening agent, solubilizing agent, odorant, anti-dandruff and itching-relieving agents, its composition and weight percentage are as follows:
Spirulina (in dry powder) 0.2～15%
Surfactant 5～60%
Antiseptic 0.01～10%
Other additive 0.1～30%
Water surplus
Described surfactant is selected for use from the surfactant that meets the existing hygienic standards for cosmetics of China.Spirulina can match with all surfactants, but the inventor experiment showed, that the effect that is used with the following table surface-active agent is better: alkyl quaternary ammonium salts such as C
14Acylamino-propyl-dimethyl 2,3-dihydroxypropyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride; Imidazolidine derivatives such as coconut oil imidazoline dicarboxylic acid derivatives; Alkanolamide class such as fatty acid distribution of coconut oil diglycollic amide; Amine-oxides class such as dihydroxy ethyl coco group amine-oxides; Ether sulfate such as dodecyl polyethenoxy ether sodium sulfate, polyoxyethylene lauryl ether sodium sulfate; Alkyl sodium sulfate and derivant thereof such as sodium lauryl sulphate, alkyl sulfate diethanolamine, alkyl sulfate triethanolamine; Betanin derivative such as lauroyl amido CAB.And wherein best betanin derivative, alkyl sulfate diethanolamine (or triethanolamine), sodium lauryl sulphate, sodium alkylether sulphate arranged.
Described conditioner is the hair care additive that hair is had affinity, and it can improve the cardability of hair, neutralization or minimizing electrostatic charge, outward appearance, feel, richness and the gloss of raising hair.The conditioner that the present invention uses is selected for use from the conditioner that meets the existing hygienic standards for cosmetics of China, and commonly used at present has: fats compound, as modified wool fat; Polyalcohols is as Polyethylene Glycol; Type siloxane is as polydimethylsiloxane; Hydrolyzed protein; Plant extract; Aminoacid; Vitamin; And some have cationic surfactant, cationic polymer of opsonic action etc.The present invention uses spirulina to make conditioner, generally no longer adds other conditioner.
Described odorant can be selected for use from the natural perfume material that meets the existing hygienic standards for cosmetics of China or compound essence, as Oleum Caryophylli, Oleum menthae, Oleum Rosae Rugosae, Oleum lavandula angustifolia, myrcene etc.
Described antiseptic is chosen from the antiseptic that meets the existing hygienic standards for cosmetics of China, and commonly used at present has: sorbic acid, potassium sorbate, sorbitol, benzoic acid, sodium benzoate, Nipagin ester, formaldehyde, propionate etc.
Described thickening agent is selected for use from the inorganic salt that meets the existing hygienic standards for cosmetics of China, high molecular polymer, natural gum, and commonly used at present has: NaCl, KCl, Na
3PO
4, Na
2SO
4, cellulose derivative such as CMC, natural gum such as karaya etc.The present invention selects NaCl and CMC for use, and cost is low, and is effective.
Described coloring agent is selected for use from the coloring agent that meets the existing hygienic standards for cosmetics of China.
Described anti-dandruff and itching-relieving agent is selected for use from the anti-dandruff and itching-relieving agent that meets the existing hygienic standards for cosmetics of China, and at present commonly used have ZPT, climbazole, salicylic acid and derivant thereof, allantoin, a selenium sulfide etc.The inventor's experiment shows that the compatibility of ZPT and climbazole and spirulina is better.
Described solubilizing agent is selected for use from the solubilizing agent that meets the existing hygienic standards for cosmetics of China.Commonly used at present has: butanols, isopropyl alcohol, terpineol, propylene glycol etc.The present invention generally selects propylene glycol for use.
The spirulina dry contains vitamin E 500-700mg for every kilogram, VITAMIN B15 5mg, and B243mg, carotene 2-4g, nicotinic acid 118mg also contains protein 60～70% in addition.Spirulina is a kind of prokaryote, cell wall mainly is made of crude protein and half fiber, because organellas such as its Cytoplasm, gland plastochondria are differentiation fully not, therefore it and human body skin and the hair compatibility are splendid, human body can just can directly absorb its most of nutrition through digestion, also can produce certain hair conditioning nursing efficacy in the shampoo so the present invention directly adds spirulina without processing during shampoo in preparation.But the inventor experiment showed, one or more Combined Treatment of selecting for use in the following processing method after effect improve greatly.
One. physical treatment method physical treatment method is to utilize physical process that the cell of spirulina is broken, and cellular content is flowed out, and fully contacts with hair during hair washing, improves the conditioning nursing effect of spirulina.Through inventor's research and test, the proper physical processing method has following several: apply mechanical external force 1..Finger is used spirulina such as pounding and is smash, abrasive method processing.2. cryogenics repeatedly.With spirulina under 0～-40 ℃ temperature through 2～10 times freezing repeatedly, each 2-10 hour, thaw to room temperature after each freezing, its cell is being broken in the freezing and course of defrosting repeatedly.3. ultrasonic Treatment technology.Utilize hyperacoustic acoustic wave energy that spirulina cells is broken.4. high pressure blasting technique.Principle is similar to puffed rice.With the abundant moistening of spirulina water, moisture content 45～60% is advisable, and puts in the high-pressure bottle, and air pressure is risen to 0.3～1Mpa earlier, and behind the pressurize certain hour, release pressure is to normal pressure suddenly.After contained air pressurized becomes compressed air in the spirulina,, spirulina cells is broken through producing huge energy in the decompression process suddenly.
Two. chemical treatment method 1. acid-hydrolysis methods.(concentration 3～8mol/L) hydrolysis spirulina under 80-100 ℃ of condition promptly can be used for preparing shampoo after neutralization, the filtration with mineral acid concentrated solutions such as phosphoric acid, sulphuric acid or hydrochloric acid.2. enzyme hydrolysis method.Be used to prepare shampoo with adding after protease (as carase, bromelain, ficoin, trypsin, the pepsin etc.) hydrolysis, the condition that hydrolysising condition is indicated in accordance with the operation instruction of used enzyme preparation.3. alkali hydrolysis method.NaOH aqueous solution hydrolysis spirulina under 80～100 ℃ of conditions with 3-8mol/L.
Shampoo of the present invention is compared with other shampoo, has following substantive distinguishing features and progress: rich in protein, vitamin, lipid material and polysaccharose substance can be from many aspects nursed and are kept healthy skin of head and hair in the spirulina.Spirulina through physical method or chemical method processing, good with human body skin with the blending of sending out, tack and impregnability are strong, be easy to by Skin Cell and absorption of Rhizoma Imperatae cell and assimilation, be skin and the additional nutrient of hair, and the activity of the interior plurality of enzymes of participation human body, the metabolism of promotion skin and hair has desirable reparation, nursing role to hair.In addition, experiment showed, that spirulina can effectively reduce the stimulation of shampoo to eyes.During hair washing, the flushing water that contains shampoo flows in the eyes almost imperceptible stimulation.The low irritant shampoo is the object of giving priority to of shampoo always, generally with special surfactant preparation.And the surfactant that the present invention adopts common shampoo to use can reduce its zest behind the interpolation spirulina greatly, and can compare favourably with shampoo for baby.
Below be example of the invention process:
Embodiment one, and is fully moistening the spirulina powder water, or uses and do not passed through the spirulina wet feed of dried, directly combines following shampoo:
An amount of Sodium Benzoate 0.5 citric acid of composition weight (gram) ethoxylated dodecyl alcohol sodium sulphate (28%) 50 fatty acid distribution of coconut oil diglycollic amide 5 distearyl dimethyl benzyl ammonium chloride 0.5 water, 42.5 spirulinas (in dry powder) 1 essence 0.1 pigment is transferred PH to 6-7
Method for making: after preceding four kinds of compositions mixing, transfer PH to 6～7, add in advance fully moistening spirulina, essence, pigment and sodium benzoate then, stir, promptly get product with citric acid.
Embodiment two, and is earlier that spirulina powder is moistening with an amount of water, makes moisture content 50～70%, spends the night, and places-15 ℃ freezing 8 hours of refrigerating chamber, is warming up to room temperature again and thaws, and 5 times repeatedly, combines following shampoo then:
Composition weight (gram) ethoxylated dodecyl alcohol sodium sulphate (28%) 25 coconut oil diethanol amide 2.5 ethylene glycol monostearates, 2.5 spirulinas (in dry powder) 2 sodium chloride 1～5 essence 0.6 Cobastab50.5 sorbitol 0.1 water 62.5
Method for making: earlier first three is planted composition and add in the entry, be warming up to 60-80, stir into the uniform liquid that does not have the no piece of group, under stirring at a slow speed, make it be cooled to room temperature then, add essence, sorbitol, vitamin B again
5And spirulina, regulate viscosity with NaCl, mix homogeneously promptly obtains product.
Embodiment three, with spirulina powder water furnishing thin pulp, grind with fiberizer, combine following shampoo then:
Composition weight (gram) sodium lauryl tri(oxyethyl) sulfate 15 polyoxyethylene king alkylphenol ether ammonium sulfate 10 coco group dimethyl betaine 5CMC 2～6 spirulinas (in dry powder) 10 essence 0.15 potassium sorbate 0.1 climbazole 1.5 water 55
Compound method is similar to embodiment two, replaces NaCl to regulate viscosity with CMC.
Embodiment four, and the 1kg spirulina powder adds the HCl solution of 15L 3mol/L, spends the night, and take back stream, band stirs and to boil 5 hours, transfer PH to neutral with the NaOH concentrated solution after being cooled to room temperature, filter, and are concentrated into 5L.Measure 10ml (being equivalent to 3.6g NaCl, the 2g spirulina powder) and be mixed with following shampoo:
Composition weight (gram) dodecyltriethanolamine sulfate 40 ethoxylation acetylated lanolins 2 spirulina hydrolyzate 10mlCMC 2～51,2-propane diols 2 essence 0.8 sorbierite 0.3 water 40
Method for making: compound method is similar to embodiment two, replaces NaCl to regulate denseness with CMC.
Embodiment five, and the 5g spirulina powder adds 75ml water, transfer PH to 8-9 with NaOH solution, add the 0.5g papain, place 12 hours under the room temperature.Stirred once every 2 hours, and guarantee PH8～9, be warming up to then 60～80 ℃ ten minutes enzyme-deactivating.Above enzyme hydrolyzate is directly used in the following shampoo of preparation:
Composition weight (gram) alkyl ether sulfuric acid diethanolamine salt 18 Empigens 2 spirulina enzyme hydrolyzate 75mlCMC 2～6 essence 1 Sodium Benzoate 0.5
Method for making: first three is planted the composition mixing and is heated to 60～80 ℃, stir into the uniform liquid that does not have the no piece of group, be cooled to room temperature, add essence and sodium benzoate, mix homogeneously is regulated denseness with CMC then.
Embodiment six, and the prior water of spirulina is moistening, make moisture content about 50%, spend the night, and put into the pressure vessel that air relief valve is arranged at the bottom, and air pressure is risen to 0.4MPa, and the air relief valve release pressure is used in pressurize after 30 minutes, spirulina is fiercely sprayed from air relief valve.Collect ejecta, combine following shampoo:
Composition weight (gram) coconut sodium alkyl sulfate 23 odium stearate 9.0ZPT 2.0 dimethyl silicone polymer silicone oil 2.5 water 48.2CMC 1-6 spirulinas (in dry powder) 12 Sodium Benzoates 0.5 essence 0.8 pigment is an amount of
Method for making: the first five is planted composition mix, and be warming up to 60～75 ℃, stir into the uniform liquid that does not have the no piece of group, add spirulina, essence, sodium benzoate, pigment after being cooled to room temperature, regulate denseness, stir, get product with CMC.
Embodiment seven, and 5 gram spirulinas prior waters are moistening, make moisture content 40～70%, after with ultrasonic Treatment 30 minutes cell being broken, add 75ml water, transfer PH8～9 with NaOH, add bromelain 0.5 gram, room temperature placement 12 hours.Stirred once every 2 hours, and guarantee PH8～9.At last hydrolyzed solution is heated to 60～80 ℃ enzyme-deactivating.Above hydrolyzed solution can be used for preparing following shampoo.
Composition weight (gram) sodium alkyl sulfate 1 lauryl triethanolamine sodium sulphate 15 cocinic acid isopropanol amides 4 spirulina hydrolyzate 75ml potassium sorbate 0.2CMC 3-5 essence 0.5
Method for making: preceding 4 kinds of compositions are stirred into uniform liquid under 60～70 ℃, are cooled to and add potassium sorbate, essence after the room temperature, stir, regulate denseness with CMC, product.
Embodiment eight, and the 5g spirulina powder after the processing of high pressure blasting procedure,,, filters and gets solution 100ml approximately with 4mol/L HCl neutralization in 80～100 ℃ of following hydrolysis 8 hours with 4mol/L NaOH aqueous solution 50ml, is used to prepare following shampoo.
Composition weight (g) NaLS 50 dihydroxy ethyl coco group amine oxides 10 spirulina hydrolyzate 100ml methyl p-hydroxybenzoates 0.3 essence 0.5CMC 5-10
Method for making: preceding four kinds of compositions are stirred into uniform liquid under 60～70 ℃, be cooled to room temperature after, add essence, regulate denseness with CMC, stir finished product.
Shampoo that the present invention prepares conditioning property is good, and skin, eyes are had no stimulation, and washes submissive, the easy combing of back hair, does not twine, glossy, hair is had nursing, repair, the moistening static that do not rise of hair.
The spirulina that the present invention adds, no matter be directly to add or handle or chemical method is handled through physical method, all other component with shampoo has the good compatibility, product stability is good.
Claims (6)
1. a shampoo contains surfactant, antiseptic, water and other additive, it is characterized in that it also is added with spirulina, and its composition and weight content are as follows:
Spirulina 0.2-15%
Surfactant 5-60%
Antiseptic 0.01-10%
Other additive 0.1-30%
Water surplus
Described spirulina is undressed dry powder, perhaps the spirulina of crossing through one or more Combined Treatment in physical treatment method, the chemical treatment method.
2. shampoo according to claim 1 is characterized in that surfactant selects for use from alkyl doped quaternary ammonium salt, imidazolidine derivatives, alkanolamide class, oxidation amine, ether sulfate, alkyl sodium sulfate and derivant thereof, betanin derivative.
3. shampoo according to claim 1 is characterized in that antiseptic selects for use from sorbic acid, potassium sorbate, sorbitol, benzoic acid, sodium benzoate, formaldehyde, propionate, Nipagin ester.
4. shampoo according to claim 1 is characterized in that other additive comprises conditioner, coloring agent, odorant, anti-dandruff and itching-relieving agent, solubilizing agent, thickening agent, and these additives are by the interpolation that needs of actual prescription.
5. the production method of a shampoo as claimed in claim 1 is characterized in that the physical treatment method is the method for smashing of pounding, polishing, Deep Cooling Method, ultrasonic Treatment method and high pressure blasting procedure repeatedly.
6. a shampoo production method as claimed in claim 1 is characterized in that chemical treatment method is mineral acid hydrolysis method, protease hydrolysis method and alkali hydrolysis method; The mineral acid hydrolysis method refers to be used alone or as a mixture HCl, the H that concentration is 3-8mol/L
2SO
4, H
3PO
4Aqueous solution is the hydrolysis spirulina under 80-100 ℃ of condition, obtains can be used for preparing the hydrolyzed solution of shampoo after alkali neutralization, filtration; The protease hydrolysis method refers to one or more associating hydrolysis spirulinas in the protease such as carase, bromelain, trypsin, pepsin, ficoin, the condition that hydrolysising condition is indicated in accordance with the operation instruction of used enzyme preparation; Alkali hydrolysis method refers to the NaOH aqueous hydrolysis spirulina with 3-8mol/L.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99102699 CN1240127A (en) | 1999-04-20 | 1999-04-20 | Spirulina shampoo and productive method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99102699 CN1240127A (en) | 1999-04-20 | 1999-04-20 | Spirulina shampoo and productive method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN1240127A true CN1240127A (en) | 2000-01-05 |
Family
ID=5270940
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99102699 Pending CN1240127A (en) | 1999-04-20 | 1999-04-20 | Spirulina shampoo and productive method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100457083C (en) * | 2006-09-15 | 2009-02-04 | 峰胜集团有限公司 | Scurf-eliminating shampoo composition containing blue-green alga extract |
| CN104434753A (en) * | 2014-11-13 | 2015-03-25 | 安徽创业机电设备有限公司 | Natural nutritional shampoo and preparation method thereof |
| IT201700056332A1 (en) * | 2017-05-24 | 2018-11-24 | Elena Catalina Bistreanu | Composition based on colloidal silver and its use to reinvigorate and thicken the hair and to favor its growth |
-
1999
- 1999-04-20 CN CN 99102699 patent/CN1240127A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100457083C (en) * | 2006-09-15 | 2009-02-04 | 峰胜集团有限公司 | Scurf-eliminating shampoo composition containing blue-green alga extract |
| CN104434753A (en) * | 2014-11-13 | 2015-03-25 | 安徽创业机电设备有限公司 | Natural nutritional shampoo and preparation method thereof |
| IT201700056332A1 (en) * | 2017-05-24 | 2018-11-24 | Elena Catalina Bistreanu | Composition based on colloidal silver and its use to reinvigorate and thicken the hair and to favor its growth |
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