CN1232009A - Humic acid full-nutrient organic composite pesticide fertilizer and preparation method thereof - Google Patents

Humic acid full-nutrient organic composite pesticide fertilizer and preparation method thereof Download PDF

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Publication number
CN1232009A
CN1232009A CN 99105953 CN99105953A CN1232009A CN 1232009 A CN1232009 A CN 1232009A CN 99105953 CN99105953 CN 99105953 CN 99105953 A CN99105953 A CN 99105953A CN 1232009 A CN1232009 A CN 1232009A
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Prior art keywords
fertilizer
humic acid
soil
organic composite
organic
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CN 99105953
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Chinese (zh)
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李刚
罗都强
何军
张兴
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Northwest Agricultural University Non Pollution Pesticide Research Service Center
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Northwest Agricultural University Non Pollution Pesticide Research Service Center
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Priority to CN 99105953 priority Critical patent/CN1232009A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G1/00Mixtures of fertilisers belonging individually to different subclasses of C05

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The invention relates to an organic compound pesticide fertilizer and a preparation method thereof. The invention relates to a humic acid total-nutrient organic compound fertilizer which is prepared by adding crushed crop straws (wheat and corn) into clay and soil beneficial strains for fermentation and retting, airing, mixing with humic acid, pesticide, nitrogen, phosphorus and potassium fertilizers and trace fertilizers such as zinc, iron, manganese, boron, magnesium, molybdenum, copper, calcium and the like, crushing and granulating. After the fertilizer is applied, soil organic matters can be obviously increased, the physical properties of soil are improved, the loss of soil moisture and nutrients is reduced, the nutrient absorption rate of crops is improved, and meanwhile, the fertilizer can play a role in preventing and treating soil diseases and insect pests. The invention has simple manufacturing process and low cost, and is suitable for popularization and application.

Description

A kind of all nutrient humic acid compound pesticide fertilizer and method for making thereof
The present invention relates to a kind of all nutrient humic acid compound pesticide fertilizer and method for making thereof.
With improving constantly of agricultural modernization level, not only requiring has competent chemical fertilizer, and a large amount of high-quality fertilizer and enough little fertilizer also will be arranged.The production of chemical fertilizer is because the attention and the support of country, disparities between supply and demand are alleviated substantially, and the supply of fertilizer is not enough far away, the soil organism descends year by year, meanwhile, the agricultural crop straw that is rich in organic nutrient substance is in a large number but burnt or is discarded, and this has not only seriously limited Agricultural Development, also make simultaneously the ample resources waste, and caused environmental pollution.For addressing this problem, domestic scholars has been done big quantity research, and has a plurality of technology to patent.Liu Jianhuas etc. have applied for " a kind of multi-element and multi-effect compound fertilizer " patent, and publication number is CN1072167A, and it is mainly formed by the sesame residues that becomes thoroughly decomposed, gain weight powder, micronutrient element and furans are red; Liu Jincheng etc. have applied for " efficient composite organic fertilizer " patent, and publication number is CN1095054A, and it is made up of animal dung, cake fertilizer or oil meal, bone meal, inorganic fertilizer, trace element, humic acids and agricultural rare-earth; Kuang Yongcheng etc. have applied for " compound full price fertilizer series product and complete producing technology " patent, publication number is CN1110674A, and its compound full price fertilizer is made up of materials such as trace element, humic acid substance, rare earth class material, enzymatic material, active carrier, plant growth hormones, disease-resistant bacterium; Dou Guanyi has applied for " " Sheng-tai-le " and manufacture method thereof " patent, and publication number is CN1106265A, its product by earthworm and (or) the wormcast carrier forms; Sun Keyong etc. have applied for " multi-functional complete intensified organic compound fertilizer and method for making thereof " patent, publication number is CN1137505A, its composite fertilizer comprises organic conversion product that becomes thoroughly decomposed, humic-acid kind derivative, the organic biological of short living class, the organic biological of antibiosis class, and contains nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, molydbenum fertilizer, zinc fertilizer etc.Above-mentioned technology all has defective in various degree, thereby all can not batch production implement.Retrieval shows, utilizes crop material as the still unmanned so far report of the technology of compoiste fertilizer raw material.
The objective of the invention is to make compoiste fertilizer as raw material with crop material, make the plant nutrient substance in the agricultural crop straw become the quick-acting nutrient by the late effect property nutrient, for soil increases organic, to solve the supplementary question of the soil organism, change soil physical property, improve the preserve moisture and fertility ability, reduce loss of chemical fertilizer, thereby reduce fertilizer amount and pollution by chemical fertilizer; In composite fertilizer, add simultaneously sterilant and (or) sterilant, thereby reach a fertile multi-purpose purpose.
All nutrient humic acid compound pesticide fertilizer of the present invention comprises following component (weight percent):
Humic acid substance 10~30%
Crop material is organic to become thoroughly decomposed fertile 30~60%
Azophoska 25~30%
Little fertile 5-10%
Agricultural chemicals 0.5~2%.
Humic acid substance of the present invention is humic acids and monovalence thereof or divalent salts such as Sodium salts humic acids, calcium humate, humic acids magnesium, potassium humate, ammonium humate.
The organic fertilizer that becomes thoroughly decomposed of crop material of the present invention is the fertilizer that becomes thoroughly decomposed that wheat stalk or maize straw form through the system of macerating.
Agricultural chemicals of the present invention is one or more in the sterilant such as one or more and/or fast Poly, triadimefon, thiram, the fenaminosulf in the sterilants such as furans pellet, phosfolan_methyl, isofenphos_methyl.
Nitrogenous fertilizer in the azophoska of the present invention is one or more among urea, carbon ammonium, two ammoniums; Phosphate fertilizer is calcium superphosphate; Potash fertilizer is Repone K.N wherein, P, K three's ratio is 6~8: 1~3: 2~5.
Trace element of the present invention is made up of zinc sulfate 20~25%, ferrous sulfate 5~10%, manganous sulfate 10~15%, magnesium nitrate 10~15%, ammonium molybdate 0.5~1%, copper sulfate 2~5%, nitrocalcite 15~20%, boric acid 25~30%.
Manufacture method of the present invention comprises the steps:
A. wheat stalk or maize straw are broken into the fragment of 5-10cm through meal, mix by 1: 0.1~0.4: 0.005~0.01 with clay and beneficial microorganism fermented bacterium then, and add suitable quantity of water and make water content reach 15-30% to macerate system fertilizer airing, drying that the system of will macerating is then become thoroughly decomposed;
B. the organic fertilizer that becomes thoroughly decomposed of steps A gained is placed the machine of being mixed, add humic acid substance, agricultural chemicals, azophoska and little fertilizer again, fully stir, mix;
C. step B gained mixture is placed tablets press, granulation.Wherein macerating the system temperature in the steps A is 20-35 ℃, and macerating the system time is 10-30 days.
The fertile comprehensive nutrition of all nutrient humic acid compound pesticide of the present invention, the characteristics that both kept chemical fertilizer quick-acting have common farm organic fertilizer to have the characteristics of long-lasting again, can reach and improve the soil, optimize crop growth environment, strengthen the effect of the preserve moisture and fertility performance of soil.What is more important is because the present invention is to be that main raw material is made fertilizer with the crop material, both reached straw-returning, made full use of the purpose of waste resource, significantly increased the soil organism again; All nutrient humic acid compound pesticide simultaneously of the present invention fertile since add sterilant and (or) sterilant, both can prevent and treat the harm of the sick worm of soil, also can control the crop growth period disease and pest to the causing harm of crop, reach a fertile purpose of using more.
Below further the present invention is elaborated by indefiniteness embodiment.
Embodiment 1: the organic fertile preparation of becoming thoroughly decomposed of wheat or maize straw
Take by weighing corn or wheat stalk 600kg, be crushed to 5~10cm fragment, add water 200kg, add clay 100kg, the inoculation beneficial microorganism mixes the back stack retting, macerates ripe back cold and shines to water content 15%, obtains organic fertilizer that becomes thoroughly decomposed.The data that provide by table 1 take by weighing the amount of each component, through mixing, promptly getting organic composite medicine fertilizer of the present invention after the granulation.
Table 1 organic composite medicine fertilizer
Figure A9910595300071
Experimental example 1 organic composite medicine fertilizer improves soil physico-chemical property and the manure trial report.
Shaanxi Province Academy of Agricultural Sciences clay fertilizer by the proportioning of I in the table 1 organic composite medicine fertilizer of the present invention has been carried out the land for growing field crops in Yang Ling Da Zhai township, Shaanxi and Shangxian county, Shangluo City and has used research, the result shows, organic composite medicine fertilizer of the present invention is to improving soil physico-chemical property, improve soil organic matter content, there is significant effect aspects such as increase crop yield.During test, select representational wheat paddock piece in the experiment area, area is 3 mu, and secondary uses this organic composite medicine fertilizer fraction of the year of one, base fertilizer uses 100kg for every mu, the inferior 60kg of the every mu of mu that topdresses after the wheat harvesting, takes out the wherein content of each effective ingredient of soil samples and detecting, and the thousand seed weight of investigation wheat, grain number per spike, mu spike number and per mu yield are to determine the volume increase situation to wheat.Experiment is handled and is respectively: organic composite medicine fertilizer of the present invention; Urea; The contrast of not applying fertilizer; Amount by each component in the organic composite medicine fertilizer is used respectively.
Table 2 organic composite medicine fertilizer is to the improvement of soil physico-chemical property
Yang Ling Da Zhai township 1997
Handle Organic (%) Full nitrogen (%) Full phosphorus (%) Full potassium (%) Alkali-hydrolyzable nitrogen (%) Rapid available phosphorus (%) Replacement amount (%)
Organic composite medicine fertilizer 4.25 6.50 ??4.15 ?15.97 112 45 ?41.30
Urea 2.35 6.35 ??3.14 ?13.47 108 42 ?30.50
The contrast of not applying fertilizer 2.25 4.15 ??3.04 ?13.52 98 43 ?27.30
Use respectively 4.30 6.48 ??4.13 ?15.68 111 43 ?40.97
Table 3 organic composite medicine fertilizer is to the * that improves of soil physico-chemical property
Shangxian county, Shanglou 1998
Handle Organic (%) Full nitrogen (%) Full phosphorus (%) Full potassium (%) Alkali-hydrolyzable nitrogen (%) Rapid available phosphorus (%) Replacement amount (%)
Organic composite medicine fertilizer ????2.79 ????1.58 ????0.10 ????3.23 ????98.7 ????27 ????27.20
Urea ????1.67 ????1.32 ????0.070 ????2.22 ????89 ????22 ????20.36
The contrast of not applying fertilizer ????1.54 ????0.12 ????0.052 ????2.12 ????73 ????21 ????19.76
Use respectively ????2.69 ????1.49 ????0.11 ????3.20 ????97.9 ????26 ????26.97
*: extracting soil sample is the arable layer soil sample
Table 4 organic composite medicine fertilizer is to the influence of wheat yield
Yang Ling Da Zhai township 1997
Handle The heavy g of dry granular Grain number per spike Mu spike number (ten thousand) Per mu yield (kg) Stimulation ratio (%)
Organic composite medicine fertilizer 39.2 30 ?36.8 ?432.8 ?21.95
Use respectively 39.0 30 ?36.7 ?430.6 ?21.3
Urea 38?5 28 ?35.0 ?377.3 ?6.31
The contrast of not applying fertilizer 38.1 27 ?34.5 ?354.9 ?-
*: wheat breed is for laying down for a short time No. 6
Table 5 organic composite medicine fertilizer is to the * that influences of wheat yield
Shangxian county, Shanglou 1998
Handle Thousand seed weight g Grain number per spike Mu spike number (ten thousand) Per mu yield (kg) Stimulation ratio (%)
Organic composite medicine fertilizer 38.2 29 34.6 383.3 21.03
Use respectively 38.1 29 34.4 380.1 20.0
Urea 37.5 27 33.7 341.2 7.74
The contrast of not applying fertilizer 36.2 27 32.4 316.7 -
*: wheat breed is for laying down for a short time No. 6
Experimental example 2 organic composite medicine fertilizers are to the prevention effect of soil-borne disease and subterranean pest-insect
Academy of Agricultural Sciences Institute of Plant Protection, Shaanxi Province answers the township to do field experiment research to the prevention effect of tobacco compoiste fertilizer of the present invention to underground insect and soil-borne disease greatly in the Wugong County.Select the medium plot that degree takes place, three repetitions of every processing, the every repetition 66.7m of laying particular stress on of subterranean pest-insect and wheat smut 2, respectively at the 120kg/ mu that applies fertilizer to the subsoil before the sowing, seedling stage spraying fertilizer 60kg/ mu.Experiment is treated to: organic composite medicine fertilizer of the present invention, urea, and the contrast medicament is furans pellet, thiram, medicament adopt to mix soil and handles, uses respectively by each group component in the organic composite medicine fertilizer, and fertilizer treatment not.The investigation of subterranean pest-insect was carried out in 2-3 month in spring, divided 5 samplings, shoveling area 1m during investigation in the experimental plot 2, dark 20cm, sieve soil is checked the wherein total quantity of subterranean pest-insect such as grub, wireworm.Wheat smut is before the harvesting of 5-6 month wheat, and by 5 point samplings, area 1m takes a sample at the test treatment zone 2, investigation smut is at total strain number of every sampling point, and subterranean pest-insect and dust-brand diseased plant number and check plot comparison with the treatment zone investigation draw preventive effect.Experimental result sees Table 6,7.
Table 6 organic composite medicine fertilizer is to the preventive effect of underground insect
Shaanxi acrobatic skill 1998
Handle Repeat Total borer population Preventive effect %
??Ⅰ ???Ⅱ ???Ⅲ
Organic composite medicine fertilizer 3 1 1 5 94.4
Use respectively 2 1 2 5 94.4
Urea 34 27 30 91 -
The furans pellet 3 1 2 5 93.3
The contrast of not applying fertilizer 35 28 26 89 -
Table 7 organic composite medicine fertilizer is to the preventive effect of wheat smut
Shaanxi acrobatic skill 1998
Handle Repeat Total borer population Preventive effect %
??Ⅰ ???Ⅱ ???Ⅲ
Organic composite medicine fertilizer 6 7 3 16 95.9
Use respectively 5 8 6 19 95.2
Urea 120 109 115 344 -
Thiram 8 7 4 19 95.2
The contrast of not applying fertilizer 125 140 130 395 -

Claims (6)

1. all nutrient humic acid compound pesticide fertilizer is characterized in that this composite fertilizer comprises following substances (weight percent):
Humic acid substance: 10~30%
Organic fertilizer that becomes thoroughly decomposed: 30~60%
Agricultural chemicals: 0.5~2%
Azophoska: 25~30%
Little fertilizer: 5~10%
2. organic composite medicine as claimed in claim 1 is characterized in that humic acid substance wherein is one or more among Sodium salts humic acids, calcium humate, humic acids magnesium, potassium humate, the ammonium humate.
3. organic composite medicine fertilizer as claimed in claim 1 is characterized in that agricultural chemicals is one or more and/or fast Poly, triadimefon, thiram, among the fenaminosulf one or more among furans pellet, phosfolan_methyl, the isofenphos_methyl.
4. organic composite medicine fertilizer as claimed in claim 1 is characterized in that nitrogenous fertilizer is one or more among urea, carbon ammonium, two ammoniums; Phosphate fertilizer is calcium superphosphate; Potash fertilizer is that Repone K N, P, K three's ratio is 6~8: 1~3: 2~5.
5. organic composite medicine fertilizer as claimed in claim 1, it is characterized in that trace element by zinc sulfate 20~25%, ferrous sulfate 5~10%, manganous sulfate 10~15%, magnesium nitrate 10~15%, ammonium molybdate 0.5~1%, copper sulfate 2~5%, nitrocalcite 15~20%, boric acid 25~30% are formed.
6. the manufacture method of an all nutrient humic acid compound pesticide fertilizer comprises steps such as stalk stack retting, drying, mixing, granulation, it is characterized in that stalk the ratio of each component is stalk when macerating system: clay: microorganism=1: 0.1~0.4: 0.005~0.01; And add suitable quantity of water, make water content reach 15-30%; Macerating the system temperature is 20~35 ℃, and macerating the system time is 10~30 days.
CN 99105953 1999-04-23 1999-04-23 Humic acid full-nutrient organic composite pesticide fertilizer and preparation method thereof Pending CN1232009A (en)

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100423645C (en) * 2005-07-05 2008-10-08 吴新忠 Foliage fertilizer capable of make rabbit, mouse (poultry) keep away while smelling and animal expelling agent
CN100441548C (en) * 2006-10-17 2008-12-10 王利民 Organic potash fertilizer
CN102584487A (en) * 2012-02-03 2012-07-18 官会林 Special fertilizer for high-quality and high-yield green cherry culture in fresh water and sea water source areas
CN102598911A (en) * 2012-03-29 2012-07-25 常熟市佳盛农业科技发展有限公司 Method for remedying heavy metal polluted mining soil
CN102643135A (en) * 2012-03-28 2012-08-22 常熟市滨江农业科技有限公司 Fertilizer rich in organic phosphorus and preparation method thereof
CN102649651A (en) * 2012-03-28 2012-08-29 常熟市滨江农业科技有限公司 Fertilizer rich in organic potassium and preparation method thereof
CN102701818A (en) * 2012-05-14 2012-10-03 东营三明林业发展股份有限公司 Multifunctional conditioning agent for salt pine and alkali pine
CN102875259A (en) * 2012-10-01 2013-01-16 杨天奇 Organic ecological soil conditioner and preparation method thereof
CN103242068A (en) * 2013-05-15 2013-08-14 乐农同创(北京)科技有限公司 Preparation method of organic fertilizer
CN103396212A (en) * 2013-07-23 2013-11-20 苏州仁成生物科技有限公司 Potassium-rich traditional Chinese medicine fertilizer and preparation method thereof
CN103964941A (en) * 2014-04-09 2014-08-06 嘉峪关市凯瑞特农业科技有限责任公司 Multifunctional medical fertilizer for eggplants and preparation method thereof
CN104193551A (en) * 2014-08-20 2014-12-10 山西省农业科学院小麦研究所 Special fertilizer for wheat and preparation method and application of special fertilizer
CN104262039A (en) * 2014-09-15 2015-01-07 武汉中农国际贸易有限公司 Insect-controllable controlled-release fertilizer special for sugarcanes and preparation method thereof
CN104342162A (en) * 2014-10-27 2015-02-11 苏州禾正宏新材料科技有限公司 High-alkalinity soil conditioner
CN104342163A (en) * 2014-10-27 2015-02-11 苏州禾正宏新材料科技有限公司 High-salinity soil conditioner
CN105820018A (en) * 2016-06-06 2016-08-03 佛山市聚成生化技术研发有限公司 Biological soil conditioner
CN106866264A (en) * 2017-03-21 2017-06-20 嘉禾大地园艺有限公司 A kind of deadwood powder organic fertilizer and preparation method thereof
CN110015929A (en) * 2019-04-22 2019-07-16 金昌田丰源化工有限公司 A kind of humic acid calcareous fertilisers and preparation method thereof

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100423645C (en) * 2005-07-05 2008-10-08 吴新忠 Foliage fertilizer capable of make rabbit, mouse (poultry) keep away while smelling and animal expelling agent
CN100441548C (en) * 2006-10-17 2008-12-10 王利民 Organic potash fertilizer
CN102584487A (en) * 2012-02-03 2012-07-18 官会林 Special fertilizer for high-quality and high-yield green cherry culture in fresh water and sea water source areas
CN102643135A (en) * 2012-03-28 2012-08-22 常熟市滨江农业科技有限公司 Fertilizer rich in organic phosphorus and preparation method thereof
CN102649651A (en) * 2012-03-28 2012-08-29 常熟市滨江农业科技有限公司 Fertilizer rich in organic potassium and preparation method thereof
CN102598911A (en) * 2012-03-29 2012-07-25 常熟市佳盛农业科技发展有限公司 Method for remedying heavy metal polluted mining soil
CN102701818A (en) * 2012-05-14 2012-10-03 东营三明林业发展股份有限公司 Multifunctional conditioning agent for salt pine and alkali pine
CN102875259B (en) * 2012-10-01 2016-01-06 杨天奇 Organic ecological soil conditioner and preparation method thereof
CN102875259A (en) * 2012-10-01 2013-01-16 杨天奇 Organic ecological soil conditioner and preparation method thereof
CN103242068A (en) * 2013-05-15 2013-08-14 乐农同创(北京)科技有限公司 Preparation method of organic fertilizer
CN103242068B (en) * 2013-05-15 2014-09-24 乐农同创(北京)科技有限公司 Preparation method of organic fertilizer
CN103396212A (en) * 2013-07-23 2013-11-20 苏州仁成生物科技有限公司 Potassium-rich traditional Chinese medicine fertilizer and preparation method thereof
CN103964941A (en) * 2014-04-09 2014-08-06 嘉峪关市凯瑞特农业科技有限责任公司 Multifunctional medical fertilizer for eggplants and preparation method thereof
CN104193551A (en) * 2014-08-20 2014-12-10 山西省农业科学院小麦研究所 Special fertilizer for wheat and preparation method and application of special fertilizer
CN104262039A (en) * 2014-09-15 2015-01-07 武汉中农国际贸易有限公司 Insect-controllable controlled-release fertilizer special for sugarcanes and preparation method thereof
CN104262039B (en) * 2014-09-15 2016-08-24 武汉中农国际贸易有限公司 Control worm controlled release sugarcane special-purpose fertilizer and preparation method thereof
CN104342162A (en) * 2014-10-27 2015-02-11 苏州禾正宏新材料科技有限公司 High-alkalinity soil conditioner
CN104342163A (en) * 2014-10-27 2015-02-11 苏州禾正宏新材料科技有限公司 High-salinity soil conditioner
CN105820018A (en) * 2016-06-06 2016-08-03 佛山市聚成生化技术研发有限公司 Biological soil conditioner
CN106866264A (en) * 2017-03-21 2017-06-20 嘉禾大地园艺有限公司 A kind of deadwood powder organic fertilizer and preparation method thereof
CN110015929A (en) * 2019-04-22 2019-07-16 金昌田丰源化工有限公司 A kind of humic acid calcareous fertilisers and preparation method thereof

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