CN1208172C - Method for manufacturing ceramic bricks possessing transparent or semitransparent colour spots or color lamps - Google Patents
Method for manufacturing ceramic bricks possessing transparent or semitransparent colour spots or color lamps Download PDFInfo
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- CN1208172C CN1208172C CN 03139877 CN03139877A CN1208172C CN 1208172 C CN1208172 C CN 1208172C CN 03139877 CN03139877 CN 03139877 CN 03139877 A CN03139877 A CN 03139877A CN 1208172 C CN1208172 C CN 1208172C
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- milkiness
- powder
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- porcelain tiles
- mixed powder
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Abstract
The present invention discloses a manufacturing method of porcelain tiles with transparent or semitransparent color spots or color blocks, which comprises: preparing powder from existing raw materials for producing porcelain tiles, preparing shaping material from the mixture of two or more kinds of powder, and then manufacturing out porcelain tiles with two or more color spots or color blocks on the front side from the forming material. The manufacturing method is characterized in that the forming material is mixed with milking components and includes miropowder and mixed powder. In the miropowder or mixed powder forming color spots or color blocks larger than 2.5mm on the front side of the porcelain tiles, at least one kind has a milking component content smaller than 0.5%, and at least another kind has a milking component content in a difference value of 0.3% to 8% with the former kind. The forming material can also be mixture of powders, base material or pigment. The porcelain tiles with the simple process method have the advantages of low cost, good surface quality, high abradability and texture similar to that of natural rock.
Description
Technical field
The present invention relates to a kind of manufacture method of Imitation Rock Porcelain Tiles, relate in particular to a kind of manufacture method that presents the Imitation Rock Porcelain Tiles of translucent texture.
Background technology
At present, in the manufacture process of Imitation Rock Porcelain Tiles, its material that is shaped has and adopts micro mist and mixed powder, promptly various spraying powders is mixed to obtain mixed powder, mixed powder is ground obtain micro mist again; The material that is shaped has the employing powders mixture, is about to the mixing of mixed powder and particle and obtains powders mixture; Also be useful on shaping material-base-material and the flower material of producing multitube cloth brick, base-material is meant to produce and uses more a kind of material in the cloth brick that the flower material is meant with respect to base-material and uses comparatively few a kind of material; Base-material and flower material can be mixed powders, also can be powders mixtures.Be difficult to occur transparent or semitransparent texture in the above-mentioned Imitation Rock Porcelain Tiles; And many lithotomes all have a kind of transparent or semitransparent texture, and perhaps some color lump or color spot have transparent or semitransparent texture in the monoblock stone material.People wish that Imitation Rock Porcelain Tiles also can present the transparent or semitransparent texture of similar lithotome for a long time; People have adopted with glass or frit and have made the Imitation Rock Porcelain Tiles surface that the method for transparent or semitransparent texture be arranged as raw material at present, the concrete making of the method that glass that this employing itself is transparent or frit are made raw material is mixing in glass or the frit particle adding ceramic powder, according to common technology, obtain containing the polished bricks of transparent particles through moulding, after burning till, polishing.Also handlebar glass or frit be deposited in through in the adobe of biscuiting and adobe together, according to common technology, through burn till, behind the polishing process, making the upper strata is devitrified glass, lower floor be ceramic polished bricks.Or glass made flat board, make glass ceramics (or being devitrified glass) through Overheating Treatment again.As application number be 00109796, the applying date is that July 10, denomination of invention in 2000 are a kind of patent of production technology of crystal-like relief brick, it is to adopt conventional wall floor tile production method to cooperate conventional dry glazing technology, utilize the direct heap of particle of water white transparency frit or colored transparent frit or milkiness frit and combination mutually thereof to fill in the wall floor tile semi-finished product adobe that is printed on different pattern, pattern, go into the kiln once-firing.The common trait of these methods is that to select for use itself be that transparent or semitransparent glass or frit makes Imitation Rock Porcelain Tiles present transparent or semitransparent texture.The shortcoming of said method is:
(1) cost height; Complex process;
(2) product surface is permitted great hole, and is second-rate;
(3) intersection of glass or clear frit and pottery is easy to generate defectives such as hair check or hole;
(4) abrasion resistance of product is relatively poor, is unfit to do floor tile and uses.
Summary of the invention
The object of the present invention is to provide the manufacture method of the Imitation Rock Porcelain Tiles that a kind of cost is low, technology is simple, surface quality is high, wear-resisting with the transparent or semitransparent texture in the lithotome.
In order to achieve the above object, the present invention adopts following scheme to realize: it be utilize in powder, add opacifiers make be shaped expect into porcelain after, the printing opacity of adjacent color lump or color spot is different with colour generation, causes a kind of color spot or color lump to present transparent or semitransparent texture for people's vision.In same Imitation Rock Porcelain Tiles, use at least two kinds of powders, present at least two kinds of color lumps or color spot, when the milkiness component content difference of each several part in the material that is shaped acquires a certain degree, and by controlling the wherein milkiness component content of some part, light transmittance differs when acquiring a certain degree after making it become porcelain, and this transparent or semitransparent texture will present.
Manufacture method of the present invention comprises following content:
A kind of manufacture method with Imitation Rock Porcelain Tiles of transparent or semitransparent color spot or color lump, it comprises adopts the existing employed feedstock production powder of production Imitation Rock Porcelain Tiles, powder with two or more prepares the shaping material that is used to be shaped again, and then produce the front with the material that is shaped and present two or more the color spot or the production method of the Imitation Rock Porcelain Tiles of color lump, contain the milkiness composition in the described shaping material, the material that is shaped is micro mist and mixed powder, in the positive micro mist or mixed powder that forms greater than the color spot of 2.5mm or color lump of Imitation Rock Porcelain Tiles, have a kind of micro mist or mixed powder at least, its milkiness component content is less than 0.5%, at least also have another kind of micro mist, the difference of the milkiness component content of its milkiness component content and above-mentioned micro mist or mixed powder is 0.3%~8%.Contain P in the milkiness composition
2O
5When the milkiness composition is TiO
2, SnO
2, ZrO
2, ZrSiO
4In one or more above combinations, above-mentioned difference is 0.6%~8%; Best difference is 2%~8%.
A kind of manufacture method with Imitation Rock Porcelain Tiles of transparent or semitransparent color spot or color lump; it comprises adopts the existing employed feedstock production powder of production Imitation Rock Porcelain Tiles; powder with two or more prepares the shaping material that is used to be shaped again; and then produce the front with the material that is shaped and present two or more the color spot or the production method of the Imitation Rock Porcelain Tiles of color lump; described powders mixture contains the milkiness composition; the shaping material package contains powders mixture; in the powders mixture; have at least a kind of diameter to be not less than the particle of 2.5mm; the difference of the milkiness component content of the mixed powder of its milkiness component content and this powders mixture is 0.3%~8%, and the milkiness component content of this particle or this mixed powder is less than 0.5%.Contain P in the milkiness composition
2O
5Described milkiness composition is TiO
2, SnO
2, ZrO
2, ZrSiO
4In one or more above combinations, above-mentioned difference is 0.6%~8%; Best difference is 2%~8%.
A kind of manufacture method with Imitation Rock Porcelain Tiles of transparent or semitransparent color spot or color lump, it comprises adopts the existing employed feedstock production powder of production Imitation Rock Porcelain Tiles, powder with two or more prepares the shaping material that is used to be shaped again, and then produce the front with the material that is shaped and present two or more the color spot or the production method of the Imitation Rock Porcelain Tiles of color lump, contain the milkiness composition in the described shaping material, the material that is shaped is base-material and flower material, has a kind of material of spending at least at positive color spot or the color lump that is not less than 2.5mm that form of Imitation Rock Porcelain Tiles, the difference of the milkiness component content of the milkiness component content of the mixed powder of this flower material and the mixed powder of base-material is 0.3%~8%, and the milkiness component content of the mixed powder of this flower material or the mixed powder of base-material is less than 0.5%.Contain P in the described milkiness composition
2O
5Described milkiness composition is TiO
2, SnO
2, ZrO
2, ZrSiO
4In one or more above combinations, the difference of above-mentioned milkiness component content is 0.6%~8%; Best difference is 2%~8%.
The Imitation Rock Porcelain Tiles that adopts said method to make, the brick surface one or more color lumps occur or color spot has transparent or semitransparent texture, or the monoblock Imitation Rock Porcelain Tiles is similar to natural jade or marble, has translucent texture, more as lithotome.
This method is compared with the method that existing use frit or glass are made raw material, and its product has following advantage:
1. cost is low;
2. technology is simple; Need not to adopt operations such as complicated hot melt of the prior art;
3. surface quality is good, does not have big hole or hair check;
4. the surface abrasion resistance degree is good, both can do wall brick and also can do floor tile;
5. on the texture more as lithotome.
The specific embodiment
Be described further below in conjunction with embodiment
Example 1
Use usual method, use ceramic raw materials such as feldspar, quartz, clay, kaolin, lime stone, talcum, make powder 1., on the basis that 1. powder fills a prescription, add the zirconium silicate ZrSiO of 4%-5% by certain formula rate batching, ball milling, granulation
4, with usual way prepare burden, ball milling, granulation, make powder 2..On the basis that 1. powder fills a prescription, add the reddish brown colorant of 0.1-0.2%, by usual way prepare burden, ball milling, granulation, make powder 3..
In powder 2.: powder 3.=5: 95 ratio batch mixes, by common prilling process granulation, obtain 10 orders-4 purpose particle a, in powder 2.: particle a=90: 10 ratio prepares burden, mixes, by the usual method moulding, burn till, polish and obtain polished bricks, have transparent or semitransparent texture by granuloplastic color spot in the polished bricks.
Example 2
2. method by example 1 prepares powder, prepares powder 3. by the method for example 1.On 2. powder fills a prescription the basis, add 0.5% orange colorant, by usual way prepare burden, ball milling, granulation, make powder 4..4. with powder is base-material, and powder 2., 3. for spending material, the production method of pressing multitube cloth brick is pressed into adobe to powder, through burning till, polishing, obtains polished bricks.3. the diameter that is formed by powder in the polished bricks presents obvious transparent or translucent texture greater than the color spot of 2.5mm.
Example 3
By example 1 preparation powder 2., powder 3., by example 2 preparation powders 4..
By usual method 2. powder is ground the back and become micro mist a.By usual method 3. powder is ground the back and become micro mist b.Press powder 3.: powder 4.=1: 9 batching, mix, grind the back by usual method and become micro mist c.
In micro mist a: micro mist b: micro mist c=3: 4: 3 ratio batching, mix a little, but do not mix too evenly, promptly get micro mist d.In powder 2.: powder 3.: powder 4.=30: 43: 27 ratio, prepare burden, mix, obtain mixed powder 5..By the method for producing micro-powder brick usually, for the first time cloth mixed powder 5. cloth fill in the counterdie, again by the second time cloth micro mist d cloth fill in powder 5. on, the patrix of mould is the light face, by the usual method moulding, burn till, obtain the Imitation Rock Porcelain Tiles of translucent texture.Obtain having the polished bricks of the translucent texture that is similar to jade after the polishing.
Example 4
By example 1 preparation powder 2. with powder 3., prepare powder method 1. by example 1 and prepare the basic components powder 1. different 6. with powder.Because powder basic components 6. is 1. different with powder.After becoming porcelain, contained kind of crystalline, quantity, size and glass are formed also 1. different with powder, make powder light transmittance 6. be slightly smaller than powder 1., but 1. whiteness are higher than powder.On 1. powder fills a prescription the basis, add the orange colorant of 8% zirconium silicate and 0.5%, prepare powder 7. by usual method.
By example 1 preparation particle a, 3. in powder: powder 6.=1: 9 ratio prepares burden, the method for preparing particle a by example 1 prepares particle b.In particle a: particle b: powder 7.=1: 1: 8 ratio batching, mix, by the usual method moulding, burn till, polish and obtain polished bricks.The color spot that is formed by particle a, particle b on polished bricks surface will present transparent or semitransparent texture.
Example 5
By example 1 preparation powder 2., powder 3., by example 4 preparation powders 6., on the basis of powder prescription 6., add 0.7% zirconium silicate and 0.5%TiO
2, prepare powder 8. by usual method, by example 1 preparation particle a, in particle a: powder 6.: powder 8.=1: 1: 8 ratio batching, mix, by the usual method moulding, burn till, polish and obtain polished bricks, the polished bricks surface will present transparent or semitransparent texture by the color spot that particle a forms.
Example 6
By example 1 preparation powder 3., 3. prepare particle c with powder, prepare powder method 1. by example 1 and prepare the basic components powder 1. different 9., and the form with natural minerals is introduced 0.2% P in powder basic components 9. with powder by example 1 method
2O
5With 0.2% SnO
2In particle c: powder 9.=1: 9 ratio mixes, by the usual method moulding, burn till, polish and obtain polished bricks, particle c in the polished bricks is because its milkiness component content lacks 0.3-6% than the other parts of polished bricks, therefore, its light transmittance is big than other position of polished bricks significantly, setting off mutually down, and color lump or color spot that the particle c on polished bricks surface forms will present transparent or semitransparent texture.
Example 7
Prepare particle c by example 6 modes, prepare powder 1., prepare powder 3., add 2% SnO on the basis that 1. powder fills a prescription in example 1 by the method for example 1 by the method for example 1
2Prepare powder 10. by usual method, in powder 1.: powder 3.=2: 8 ratio mixes and obtains mixed powder (11), in particle c: powder 10.=1: 9 ratio mixes and obtains powders mixture (12), mixed powder (11) is expected as flower, powders mixture (12) as base-material by the production method moulding of common multitube cloth brick, burn till, polish and obtain polished bricks, color spot that the polished bricks surface is formed by particle c and the diameter that formed by mixed powder (11) present transparent or semitransparent texture greater than the color spot of 2.5mm.
Claims (9)
1, a kind of manufacture method with Imitation Rock Porcelain Tiles of transparent or semitransparent color spot or color lump, it comprises adopts the existing employed feedstock production powder of production Imitation Rock Porcelain Tiles, powder with two or more prepares the shaping material that is used to be shaped again, and then produce the front with the material that is shaped and present two or more the color spot or the production method of the Imitation Rock Porcelain Tiles of color lump, it is characterized in that, be added with the milkiness composition in the described shaping material, contain P in the milkiness composition
2O
5, TiO
2, SnO
2, ZrO
2, ZrSiO
4In one or more above combinations, the material that is shaped is micro mist and mixed powder, in the positive micro mist or mixed powder that forms greater than the color spot of 2.5mm or color lump of Imitation Rock Porcelain Tiles, have a kind of micro mist or mixed powder at least, its milkiness component content is less than 0.5%, at least also have another kind of micro mist, the difference of the milkiness component content of its milkiness component content and above-mentioned micro mist or mixed powder is 0.3%~8%.
2, manufacture method according to claim 1 is characterized in that, when the milkiness composition is TiO
2, SnO
2, ZrO
2, ZrSiO
4In one or more above combinations the time, the difference of described milkiness component content is 0.6%~8%.
3, manufacture method according to claim 3 is characterized in that, the difference of described milkiness component content is 2%~8%.
4, a kind of manufacture method with Imitation Rock Porcelain Tiles of transparent or semitransparent color spot or color lump, it comprises adopts the existing employed feedstock production powder of production Imitation Rock Porcelain Tiles, powder with two or more prepares the shaping material that is used to be shaped again, and then produce the front with the material that is shaped and present two or more the color spot or the production method of the Imitation Rock Porcelain Tiles of color lump, it is characterized in that, be added with the milkiness composition in the described shaping material, contain P in the milkiness composition
2O
5, TiO
2, SnO
2, ZrO
2, ZrSiO
4In one or more above combinations; the shaping material package contains powders mixture; in this powders mixture; have the particle of a kind of diameter at least greater than 2.5mm; the difference of the milkiness component content of the mixed powder of its milkiness component content and this powders mixture is 0.3%~8%, and the milkiness component content of the mixed powder in this particle or this powders mixture is less than 0.5%.
5, manufacture method according to claim 4 is characterized in that, when the milkiness composition is TiO
2, SnO
2, ZrO
2, ZrSiO
4In one or more above combinations the time, the difference of described milkiness component content is 0.6%~8%.
6, manufacture method according to claim 5 is characterized in that, the difference of described milkiness component content is 2%~8%.
7, a kind of manufacture method with Imitation Rock Porcelain Tiles of transparent or semitransparent color spot or color lump, it comprises adopts the existing employed feedstock production powder of production Imitation Rock Porcelain Tiles, powder with two or more prepares the shaping material that is used to be shaped again, and then produce the front with the material that is shaped and present two or more the color spot or the production method of the Imitation Rock Porcelain Tiles of color lump, it is characterized in that, be added with the milkiness composition in the described shaping material, contain P in the milkiness composition
2O
5, TiO
2, SnO
2, ZrO
2, ZrSiO
4In one or more above combinations, the material that is shaped is base-material and flower material, has a kind of material of spending at least at positive color spot or the color lump that forms greater than 2.5mm of Imitation Rock Porcelain Tiles, the difference of the milkiness component content of the milkiness component content of the mixed powder of this flower material and the mixed powder of base-material is 0.3%~8%, and the milkiness component content of the mixed powder of this flower material or the mixed powder of base-material is less than 0.5%.
8, manufacture method according to claim 7 is characterized in that, when the milkiness composition is TiO
2, SnO
2, ZrO
2, ZrSiO
4In one or more above combinations the time, the difference of described milkiness component content is 0.6%~8%.
9, manufacture method according to claim 8 is characterized in that, the difference of described milkiness component content is 2%~8%.
Priority Applications (1)
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CN 03139877 CN1208172C (en) | 2003-07-18 | 2003-07-18 | Method for manufacturing ceramic bricks possessing transparent or semitransparent colour spots or color lamps |
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CN 03139877 CN1208172C (en) | 2003-07-18 | 2003-07-18 | Method for manufacturing ceramic bricks possessing transparent or semitransparent colour spots or color lamps |
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CN1480308A CN1480308A (en) | 2004-03-10 |
CN1208172C true CN1208172C (en) | 2005-06-29 |
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CN 03139877 Expired - Fee Related CN1208172C (en) | 2003-07-18 | 2003-07-18 | Method for manufacturing ceramic bricks possessing transparent or semitransparent colour spots or color lamps |
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CN (1) | CN1208172C (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1300059C (en) * | 2004-08-26 | 2007-02-14 | 叶荣恒 | Ceramic tile making process |
CN101157542B (en) * | 2007-09-27 | 2011-10-05 | 广东金意陶陶瓷有限公司 | Production technique for ceramic title having semitransparent reflecting decorative surface |
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