CN1192819C - 一氧化碳和／或甲醇的催化氧化方法 - Google Patents
一氧化碳和／或甲醇的催化氧化方法 Download PDFInfo
- Publication number
- CN1192819C CN1192819C CNB011303948A CN01130394A CN1192819C CN 1192819 C CN1192819 C CN 1192819C CN B011303948 A CNB011303948 A CN B011303948A CN 01130394 A CN01130394 A CN 01130394A CN 1192819 C CN1192819 C CN 1192819C
- Authority
- CN
- China
- Prior art keywords
- catalyst
- gas
- gold
- carrier
- oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 39
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract description 34
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 29
- 230000003647 oxidation Effects 0.000 title claims abstract description 26
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract description 7
- 230000003197 catalytic effect Effects 0.000 title description 5
- 239000010931 gold Substances 0.000 claims abstract description 55
- 239000003054 catalyst Substances 0.000 claims abstract description 45
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 30
- 229910052737 gold Inorganic materials 0.000 claims abstract description 28
- 239000001257 hydrogen Substances 0.000 claims abstract description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 229910001868 water Inorganic materials 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 9
- 239000001569 carbon dioxide Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910020068 MgAl Inorganic materials 0.000 claims 1
- 229910052596 spinel Inorganic materials 0.000 abstract description 3
- 239000011029 spinel Substances 0.000 abstract description 2
- 229910026161 MgAl2O4 Inorganic materials 0.000 abstract 1
- 229910000836 magnesium aluminium oxide Inorganic materials 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 40
- 238000006243 chemical reaction Methods 0.000 description 20
- 238000002360 preparation method Methods 0.000 description 15
- 239000000243 solution Substances 0.000 description 11
- 150000002431 hydrogen Chemical class 0.000 description 7
- 241000282326 Felis catus Species 0.000 description 5
- 150000001722 carbon compounds Chemical class 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- GSWGDDYIUCWADU-UHFFFAOYSA-N aluminum magnesium oxygen(2-) Chemical compound [O--].[Mg++].[Al+3] GSWGDDYIUCWADU-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- AKXUUJCMWZFYMV-UHFFFAOYSA-M tetrakis(hydroxymethyl)phosphanium;chloride Chemical compound [Cl-].OC[P+](CO)(CO)CO AKXUUJCMWZFYMV-UHFFFAOYSA-M 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000000366 colloid method Methods 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 238000000192 extended X-ray absorption fine structure spectroscopy Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910016978 MnOx Inorganic materials 0.000 description 1
- 230000010718 Oxidation Activity Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- AIRPJJGSWHWBKS-UHFFFAOYSA-N hydroxymethylphosphanium;chloride Chemical compound [Cl-].OC[PH3+] AIRPJJGSWHWBKS-UHFFFAOYSA-N 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- -1 keeps 20 hours.Then Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000010412 oxide-supported catalyst Substances 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/005—Spinels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
- C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
- C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
- C01B3/583—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction the reaction being the selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/044—Selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA20001755 | 2000-11-22 | ||
| DKPA200001755 | 2000-11-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1354122A CN1354122A (zh) | 2002-06-19 |
| CN1192819C true CN1192819C (zh) | 2005-03-16 |
Family
ID=8159862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011303948A Expired - Fee Related CN1192819C (zh) | 2000-11-22 | 2001-11-22 | 一氧化碳和／或甲醇的催化氧化方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6692713B2 (enExample) |
| EP (1) | EP1209121A1 (enExample) |
| JP (1) | JP2002220205A (enExample) |
| CN (1) | CN1192819C (enExample) |
| AU (1) | AU779876B2 (enExample) |
| CA (1) | CA2363661A1 (enExample) |
| NO (1) | NO20015473L (enExample) |
| ZA (1) | ZA200109601B (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2359754C2 (ru) | 2003-09-26 | 2009-06-27 | Зм Инновейтив Пропертиз Компани | Наномерные золотые катализаторы, активаторы, твердые носители и соответствующие методики, применяемые для изготовления таких каталитических систем, особенно при осаждении золота на твердый носитель с использованием конденсации из паровой фазы |
| US7829035B2 (en) * | 2006-01-19 | 2010-11-09 | Massachusetts Institute Of Technology | Oxidation catalyst |
| JP5717732B2 (ja) | 2009-07-02 | 2015-05-13 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 酸化的脱水素化またはエポキシ化のための貴金属含有担持触媒 |
| US8258356B2 (en) | 2010-08-17 | 2012-09-04 | Uop Llc | Selective CO oxidation for acetylene converter feed CO control |
| CN112387267B (zh) * | 2019-08-13 | 2023-06-30 | 中国石油天然气股份有限公司 | 以镁铝尖晶石为载体的甲醇转化催化剂的制备方法和应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3216783A (en) | 1962-10-09 | 1965-11-09 | Engelhard Ind Inc | Process for selectively removing carbon monoxide from hydrogen-containing gases |
| US3666412A (en) * | 1968-10-21 | 1972-05-30 | Du Pont | Dispersed phase activated and stabilized metal catalysts |
| JPS62155937A (ja) | 1985-08-30 | 1987-07-10 | Agency Of Ind Science & Technol | 金および金系複合酸化物を担持した触媒体を製造する方法 |
| JPH02290251A (ja) * | 1989-01-24 | 1990-11-30 | Nkk Corp | 接触燃焼用金含有触媒 |
| GB9226434D0 (en) * | 1992-12-18 | 1993-02-10 | Johnson Matthey Plc | Catalyst |
| ES2132728T3 (es) | 1994-11-02 | 1999-08-16 | Anglo American Res Lab Pty Ltd | Catalizador con soporte de oxido de zirconio/oxido de cerio. |
| FR2729582A1 (fr) | 1995-01-25 | 1996-07-26 | Air Liquide | Procede pour l'elimination d'une impurete contenue dans un compose gazeux |
| KR960029226A (ko) | 1995-01-25 | 1996-08-17 | 띠에리 쉬에르 | 복합 기체내에 포함되어 있는 불순물의 제거 방법 |
| JPH08295502A (ja) * | 1995-04-25 | 1996-11-12 | Agency Of Ind Science & Technol | 金触媒による水素含有ガス中の一酸化炭素除去方法 |
| US5550093A (en) | 1995-06-14 | 1996-08-27 | National Science Council | Preparation of supported gold catalysts for carbon monoxide oxidation |
| US5702838A (en) | 1995-08-18 | 1997-12-30 | Matsushita Electric Industrial Co., Ltd. | Fuel cell device equipped with catalyst material for removing carbon monoxide and method for removing carbon monoxide |
| JP2832336B2 (ja) | 1995-11-07 | 1998-12-09 | 工業技術院長 | 金超微粒子固定化物質及びその製造方法 |
| DE19606286C1 (de) | 1996-02-21 | 1997-10-02 | Daimler Benz Ag | Verwendung eines Pt-Zeolith-Katalysatormaterials |
| DK174077B1 (da) | 1997-06-10 | 2002-05-21 | Topsoe Haldor As | Fremgangsmåde til carbonhydriddampreformering under anvendelse af en guldholdig nikkeldampreformingkatalysator |
| US6576203B2 (en) * | 1998-06-29 | 2003-06-10 | Ngk Insulators, Ltd. | Reformer |
| US6475454B1 (en) * | 1999-01-14 | 2002-11-05 | Ge Energy & Environmental Research Corporation | Thermally limited selective oxidation methods and apparatus |
| JP3715482B2 (ja) * | 1999-11-04 | 2005-11-09 | エヌ・イーケムキャット株式会社 | 水素含有ガス中の一酸化炭素選択酸化触媒並びに該触媒を用いた一酸化炭素除去方法及び固体高分子電解質型燃料電池システム |
| DE60036681T2 (de) * | 1999-12-21 | 2008-07-17 | Mitsubishi Gas Chemical Co., Inc. | Verfahren zur Verminderung der Kohlenstoffmonoxidkonzentration in einem Wasserstoff enthaltenden Gas und Katalysator dafür |
| DE10013894A1 (de) * | 2000-03-21 | 2001-10-04 | Dmc2 Degussa Metals Catalysts | Verfahren zur katalytischen Umsetzung von Kohlenmonoxid in einem Wasserstoff enthaltenden Gasgemisch mit verbessertem Kaltstartverhalten und Katalysator hierfür |
-
2001
- 2001-10-30 EP EP01125847A patent/EP1209121A1/en not_active Ceased
- 2001-11-08 NO NO20015473A patent/NO20015473L/no not_active Application Discontinuation
- 2001-11-13 US US10/010,792 patent/US6692713B2/en not_active Expired - Fee Related
- 2001-11-20 AU AU91427/01A patent/AU779876B2/en not_active Ceased
- 2001-11-21 CA CA002363661A patent/CA2363661A1/en not_active Abandoned
- 2001-11-21 JP JP2001356405A patent/JP2002220205A/ja active Pending
- 2001-11-21 ZA ZA200109601A patent/ZA200109601B/xx unknown
- 2001-11-22 CN CNB011303948A patent/CN1192819C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU779876B2 (en) | 2005-02-17 |
| NO20015473D0 (no) | 2001-11-08 |
| NO20015473L (no) | 2002-05-23 |
| CN1354122A (zh) | 2002-06-19 |
| JP2002220205A (ja) | 2002-08-09 |
| AU9142701A (en) | 2003-05-22 |
| US6692713B2 (en) | 2004-02-17 |
| CA2363661A1 (en) | 2002-05-22 |
| EP1209121A1 (en) | 2002-05-29 |
| US20020098141A1 (en) | 2002-07-25 |
| ZA200109601B (en) | 2002-09-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1269566C (zh) | 用于分解一氧化二氮的催化剂和分解含n2o气体中n2o的工艺的实施方法 | |
| CN1021636C (zh) | 用于醛加氢的改性的铜-氧化锌催化剂 | |
| EP0686615B2 (fr) | Procédé d'hydrogénation catalytique et catalyseur utilisable dans ce procédé | |
| JP2832336B2 (ja) | 金超微粒子固定化物質及びその製造方法 | |
| CN1306459A (zh) | 由化学蒸气淀积法生产壳层催化剂的工艺 | |
| JPH0592140A (ja) | 混合遷移金属酸化物触媒を用いる一酸化炭素の変換 | |
| CN109201048A (zh) | 一种单原子催化剂及其制备方法 | |
| CN1176292A (zh) | 改进的低级烃蒸汽转化催化剂 | |
| CN1044416A (zh) | 生产环氧乙烷用催化剂及其制法 | |
| CN103586022A (zh) | 室温条件下高效同步催化氧化低浓度气相甲醛、一氧化碳和氢气的催化剂及其制备方法 | |
| CN112108145A (zh) | 一种氧化铝负载铱团簇催化剂及其制备与应用 | |
| CN118616076B (zh) | 一种合金型催化剂及其制备方法和应用 | |
| CN1192819C (zh) | 一氧化碳和／或甲醇的催化氧化方法 | |
| JP3718092B2 (ja) | 水素含有ガス中の一酸化炭素選択酸化触媒、及び当該触媒を用いた一酸化炭素選択除去方法並びに固体高分子電解質型燃料電池システム | |
| CN1429217A (zh) | 使烃环氧化的方法 | |
| CN115121270B (zh) | 一种选择性加氢合成2-乙基己醛的催化剂及其应用方法 | |
| JP2002224570A (ja) | Ｃｏシフト反応用触媒 | |
| JPH08295502A (ja) | 金触媒による水素含有ガス中の一酸化炭素除去方法 | |
| US10668460B2 (en) | Composite catalyst, method for manufacturing composite catalyst and application thereof | |
| CN100336593C (zh) | 合成醋酸乙烯酯的负载型催化剂的制备方法 | |
| CN108654679A (zh) | 一种提高香茅醛选择性加氢的负载型催化剂的制备方法 | |
| JP2016175075A (ja) | 金クラスター触媒 | |
| Haruta | Relevance of Metal Nanoclusters Size Control in Gold (0) Catalytic Chemistry | |
| CN117019146B (zh) | 一种银基催化剂及其制备方法和在催化co氧化中的应用 | |
| CN1309692C (zh) | 富氢重组气中的co选择性甲烷化的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050316 Termination date: 20101122 |