CN1182948C - 多孔预聚物粒料的制备方法 - Google Patents
多孔预聚物粒料的制备方法 Download PDFInfo
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- CN1182948C CN1182948C CNB008141037A CN00814103A CN1182948C CN 1182948 C CN1182948 C CN 1182948C CN B008141037 A CNB008141037 A CN B008141037A CN 00814103 A CN00814103 A CN 00814103A CN 1182948 C CN1182948 C CN 1182948C
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- Prior art keywords
- prepolymer
- polycarbonate
- pellet
- temperature
- die head
- Prior art date
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- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
- RQCACQIALULDSK-UHFFFAOYSA-N 4-(4-hydroxyphenyl)sulfinylphenol Chemical compound C1=CC(O)=CC=C1S(=O)C1=CC=C(O)C=C1 RQCACQIALULDSK-UHFFFAOYSA-N 0.000 description 1
- GIXNHONPKYUROG-UHFFFAOYSA-N 4-(9h-fluoren-1-yl)phenol Chemical class C1=CC(O)=CC=C1C1=CC=CC2=C1CC1=CC=CC=C12 GIXNHONPKYUROG-UHFFFAOYSA-N 0.000 description 1
- OIFVQQSNDHJWTF-UHFFFAOYSA-N 4-(naphthalen-1-ylmethyl)phenol Chemical compound C1=CC(O)=CC=C1CC1=CC=CC2=CC=CC=C12 OIFVQQSNDHJWTF-UHFFFAOYSA-N 0.000 description 1
- CLMNUWIUDGZFCN-UHFFFAOYSA-N 4-[2-(4-hydroxyphenoxy)ethoxy]phenol Chemical compound C1=CC(O)=CC=C1OCCOC1=CC=C(O)C=C1 CLMNUWIUDGZFCN-UHFFFAOYSA-N 0.000 description 1
- CYYZDBDROVLTJU-UHFFFAOYSA-N 4-n-Butylphenol Chemical compound CCCCC1=CC=C(O)C=C1 CYYZDBDROVLTJU-UHFFFAOYSA-N 0.000 description 1
- KNDDEFBFJLKPFE-UHFFFAOYSA-N 4-n-Heptylphenol Chemical compound CCCCCCCC1=CC=C(O)C=C1 KNDDEFBFJLKPFE-UHFFFAOYSA-N 0.000 description 1
- SZWBRVPZWJYIHI-UHFFFAOYSA-N 4-n-Hexylphenol Chemical class CCCCCCC1=CC=C(O)C=C1 SZWBRVPZWJYIHI-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical class CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- KNLNMGIBGGIFJK-UHFFFAOYSA-N 9h-carbazole-2,7-diol Chemical compound OC1=CC=C2C3=CC=C(O)C=C3NC2=C1 KNLNMGIBGGIFJK-UHFFFAOYSA-N 0.000 description 1
- 241001253206 Andrias Species 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical group CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- IUCFPVGNXLLCNG-UHFFFAOYSA-N OC1=CC=C(C=C1)C(C)P(C1=CC=CC=C1)C1=CC=CC=C1 Chemical class OC1=CC=C(C=C1)C(C)P(C1=CC=CC=C1)C1=CC=CC=C1 IUCFPVGNXLLCNG-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- FNIATMYXUPOJRW-UHFFFAOYSA-N cyclohexylidene Chemical group [C]1CCCCC1 FNIATMYXUPOJRW-UHFFFAOYSA-N 0.000 description 1
- ACUZDYFTRHEKOS-UHFFFAOYSA-N decan-2-ol Chemical compound CCCCCCCCC(C)O ACUZDYFTRHEKOS-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- ZICQBHNGXDOVJF-UHFFFAOYSA-N diamantane Chemical compound C1C2C3CC(C4)CC2C2C4C3CC1C2 ZICQBHNGXDOVJF-UHFFFAOYSA-N 0.000 description 1
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical compound C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 1
- TUPADZRYMFYHRB-UHFFFAOYSA-N dibenzothiophene-3,6-diol Chemical compound C1=CC=C2C3=CC=C(O)C=C3SC2=C1O TUPADZRYMFYHRB-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000001640 fractional crystallisation Methods 0.000 description 1
- 150000002241 furanones Chemical class 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N n-butyl methyl ketone Natural products CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- YBKGERLDRMINOV-UHFFFAOYSA-N oxathiine Chemical compound O1SC=CC=C1 YBKGERLDRMINOV-UHFFFAOYSA-N 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- QKYIPVJKWYKQLX-UHFFFAOYSA-N pyrene-2,7-diol Chemical compound C1=C(O)C=C2C=CC3=CC(O)=CC4=CC=C1C2=C43 QKYIPVJKWYKQLX-UHFFFAOYSA-N 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- KOJDPIMLHMVCDM-UHFFFAOYSA-N thianthrene-1,7-diol Chemical compound C1=CC=C2SC3=CC(O)=CC=C3SC2=C1O KOJDPIMLHMVCDM-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/26—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3461—Making or treating expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/142—Compounds containing oxygen but no halogen atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/042—Elimination of an organic solid phase
- C08J2201/0422—Elimination of an organic solid phase containing oxygen atoms, e.g. saccharose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
批次 | 粒料 | 试剂 | 温度(℃)/时间(hr) | Tg | Tm | Mw *1000 | Mn *1000 | Mw/Mn |
1 | 蜂窝状 | MeOH | 230/4 | 141 | 273 | 36 | 15 | 2.4 |
2 | 标准 | MeOH | 230/4 | 139 | 263 | 25 | 11 | 2.3 |
3 | 蜂窝状 | MeOH | 230/10 | 142 | 295 | 28 | 12 | 2.3 |
4 | 标准 | MeOH | 230/10 | 133 | 284 | 21 | 9 | 2.3 |
5 | 蜂窝状 | 3-戊醇 | 210/1+230/1+240/6 | 142 | 282 | 41 | 17 | 2.4 |
6 | 标准 | 3-戊醇 | 210/1+230/1+240/6 | 137 | 270 | 29 | 11 | 2.3 |
阶段 | 温度/时间(℃/hr) | Tg(℃) | Tm(℃) | Mw | Mn |
1 | 初始样品 | 116 | 212 | 15400 | 5400 |
2 | 200/0.5+220/0.5+230/1 | 148 | 254 | 49150 | 21450 |
3 | 200/0.5+220/0.5+230/1+240/1 | 149.5 | 256 | 60400 | 26100 |
4 | 200/0.5+220/0.5+230/1+240/1.5 | 151 | 256 | 67900 | 27100 |
阶段 | 温度/时间(℃/hr) | Tg(℃) | Tm(℃) | Mw | Mn |
1 | 初始样品 | 120 | 224 | 19600 | 6000 |
2 | 200/0.5+220/0.5+230/1 | 149 | 255 | 49100 | 21300 |
3 | 200/0.5+220/0.5+230/1+240/1 | 149 | 256 | 59500 | 24400 |
4 | 200/0.5+220/0.5+230/1+240/1.5 | 152 | 260 | 64700 | 26500 |
阶段 | 温度/时间(℃/hr) | Tg(℃) | Tm(℃) | Mw | Mn |
1 | 初始样品 | 111 | 222 | ||
2 | 200/0.5+220/0.5+230/1 | 143 | 256 | 40800 | 16900 |
3 | 200/0.5+220/0.5+230/1+240/1 | 147 | 259 | 47600 | 19600 |
4 | 200/0.5+220/0.5+230/1+240/3 | 149 | 263 | 55000 | 23700 |
温度/时间 甲醇 3-戊醇 2-丙醇 叔丁醇(℃/h) Tg(℃) Mw Tg(℃) Mw Tg(℃) Mw Tg(℃) Mw初始样品 109 9540 109 9540 109 9540 109 9540结晶之后 105 6530 114 11200 121 16200 114 17270200/0.5+230/0.5+230/1 128 18473 148 47700 148 53400 146 42400200/0.5+230/0.5+230/1+240/1 133 23448 149 59870 151 63700 148 48450200/0.5+230/0.5+230/1+240/2 137 25508 151 64576 151 69950 149 55950 |
温度/时间 异丁醇 1-戊醇(℃/h) Tg(℃) Mw Tg(℃) Mw初始样品 109 9540 109 9540结晶之后 114 13713 9995200/0.5+230/0.5+230/1 145 42882 135 27550200/0.5+230/0.5+230/1+240/1 148 44050 139 32570200/0.5+230/0.5+230/1+240/2 148 48500 139 32350 |
批次 | 体系 | 反应温度/时间(℃/h) | Tm初始值℃ | Tm最终值℃ | ΔH初始值J/g | ΔH最终值J/g | Mw | Mn |
1 | 甲醇 | 200/0.5+220/0.5+230/1+240/2 | 225 | 291 | 39 | 68 | 25500 | 9408 |
2 | 己醇 | 200/3+230/2+240/8 | 224 | 299 | 22 | 61 | 48000 | 18800 |
3 | 3-戊醇 | 200/3+230/2+240/8 | 222 | 284 | 25 | 44 | 56000 | 23100 |
4 | 3-戊醇 | 200/0.5+220/0.5+230/1+240/3 | 263 | 31 | 55000 | 23750 | ||
5 | 甲醇+TEGDME(1%) | 200/0.5+220/0.5+230/1+240/1.5 | 225 | 280 | 34 | 62 | 31750 | 11700 |
6 | 3-戊醇+TEGDME(1%) | 200/0.5+220/0.5+230/1+240/2 | 224 | 255 | 28 | 18 | 69700 | 24700 |
7 | 3-戊醇+PETS(1%) | 200/0.5+220/0.5+230/1+240/2 | 212 | 256 | 32 | 14 | 67900 | 27100 |
8 | 3-戊醇+GMS(1%) | 200/0.5+220/0.5+230/1+240/2 | 224 | 260 | 25 | 22 | 64700 | 27300 |
批次 | 温度/时间(℃/hr) | Tg | Tm | Mw | Mn |
1 | 初始 | ||||
2 | 200/0.5+220/0.5+230/1 | 147 | 248 | 51300 | 19650 |
3 | 200/0.5+220/0.5+230/1+240/1 | 152 | 260 | 66000 | 24100 |
4 | 200/0.5+220/0.5+230/1+240/1.5 | 69700 | 24700 |
批次 | 温度/时间(℃/hr) | Tg | Tm | Mw | Mn |
1 | 初始 | 122 | 219 | ||
2 | 200/0.5+220/0.5+230/1 | 148 | 255 | 45400 | 20800 |
3 | 200/0.5+220/0.5+230/1+240/1 | 150 | 258 | 54000 | 23800 |
4 | 200/0.5+220/0.5+230/1+240/2 | 150 | 257 | 61300 | 28500 |
批次 | 温度/时间(℃/hr) | Tg | Tm | Mw | Mn |
1 | 初始 | ||||
2 | 200/0.5+220/0.5+230/1 | 146 | 258 | 45760 | 20900 |
3 | 200/0.5+220/0.5+230/1+240/1 | 149 | 260 | 53450 | 24670 |
4 | 200/0.5+220/0.5+230/1+240/2 | 150 | 262 | 57280 | 26230 |
批次 | 温度/时间(℃/hr) | Tg | Tm | Mw | Mn |
1 | 初始 | 111 | 222 | ||
2 | 200/0.5+220/0.5+230/1 | 143 | 256 | 40800 | 16900 |
3 | 200/0.5+220/0.5+230/1+240/1 | 147 | 259 | 47600 | 19600 |
4 | 200/0.5+220/0.5+230/1+240/3 | 149 | 263 | 55000 | 23700 |
批次 | 温度/时间(℃/hr) | Tg | Tm | Mw | Mn | Mw/Mn |
1 | 初始 | 116 | 224 | |||
2 | 200/0.5+220/0.5+230/1 | 147 | 276 | 48000 | 21100 | 2.27 |
3 | 200/0.5+220/0.5+230/1+240/2 | 149 | 269 | 60000 | 24350 | 2.46 |
4 | 200/0.5+220/0.5+230/1+240/3 | 150 | 282 | 61000 | 26000 | 2.35 |
5 | 200/0.5+220/0.5+230/1+240/4 | 153 | 273 | 65600 | 24500 | 2.57 |
6 | 200/0.5+220/0.5+230/1+240/6 | 155 | 268 | 85000 | 32600 | 2.6 |
批次 | 温度/时间(℃/hr) | Tg | Tm | Mw | Mn | Mw/Mn |
1 | 初始 | 111 | 222 | |||
2 | 200/0.5+220/0.5+230/1 | 143 | 256 | 40800 | 16900 | 2.41 |
3 | 200/0.5+220/0.5+230/1+240/1 | 147 | 259 | 47600 | 19600 | 2.42 |
4 | 200/0.5+220/0.5+230/1+240/3 | 149 | 263 | 55000 | 23700 | 2.32 |
5 | 220/3+230/2+240/6 | 154 | 284 | 56000 | 23700 | 2.32 |
试验号 | 溶剂(%) | Mwt | Tg(℃) | Tm(℃) | Tm开始(℃) | ΔH(J/g) |
1开始低聚物 | IPA+丙酮(95∶5) | 14550 | 106 | 228 | 185 | 30b |
产物 | 48500 | 147 | 277 | 240 | 44 | |
2开始低聚物 | IPA(100) | 12600 | 103 | 232 | 181 | 29b |
产物 | 42680 | 144 | 275 | 260 | 53 |
Claims (16)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/371451 | 1999-08-10 | ||
US09/371,451 US6339109B1 (en) | 1999-08-10 | 1999-08-10 | Method of pelletization of polymer |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1378498A CN1378498A (zh) | 2002-11-06 |
CN1182948C true CN1182948C (zh) | 2005-01-05 |
Family
ID=23464041
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB008141037A Expired - Fee Related CN1182948C (zh) | 1999-08-10 | 2000-06-09 | 多孔预聚物粒料的制备方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US6339109B1 (zh) |
EP (1) | EP1218159B1 (zh) |
JP (1) | JP2003510441A (zh) |
KR (1) | KR20020021684A (zh) |
CN (1) | CN1182948C (zh) |
AT (1) | ATE276863T1 (zh) |
AU (1) | AU5331600A (zh) |
DE (1) | DE60014123T2 (zh) |
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Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6821953B1 (en) * | 1999-12-16 | 2004-11-23 | University Of Southern California | Methods for treating and preventing damage to mucosal tissue |
US6790929B2 (en) * | 2002-06-12 | 2004-09-14 | General Electric Company | Method for making an aromatic polycarbonate |
US7951449B2 (en) * | 2002-06-27 | 2011-05-31 | Wenguang Ma | Polyester core materials and structural sandwich composites thereof |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
CN101724110B (zh) | 2002-10-15 | 2013-03-27 | 埃克森美孚化学专利公司 | 用于烯烃聚合的多催化剂体系和由其生产的聚合物 |
US7541402B2 (en) * | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
US7329723B2 (en) | 2003-09-18 | 2008-02-12 | Eastman Chemical Company | Thermal crystallization of polyester pellets in liquid |
CA2482056A1 (en) | 2003-10-10 | 2005-04-10 | Eastman Chemical Company | Thermal crystallization of a molten polyester polymer in a fluid |
US7459113B2 (en) | 2004-03-08 | 2008-12-02 | Eastman Chemical Company | Process of making a container from polyester polymer particles having a small surface to center intrinsic-viscosity gradient |
US20060047102A1 (en) * | 2004-09-02 | 2006-03-02 | Stephen Weinhold | Spheroidal polyester polymer particles |
US7935399B2 (en) * | 2004-09-02 | 2011-05-03 | Grupo Petrotemex, S.A. De C.V. | Low melting polyester polymers |
US7875184B2 (en) | 2005-09-22 | 2011-01-25 | Eastman Chemical Company | Crystallized pellet/liquid separator |
DE502007005555D1 (de) | 2006-03-22 | 2010-12-16 | Basf Se | Verfahren und vorrichtung zur granulierung von treibmittelhaltigen polymerschmelzen |
US7868125B2 (en) * | 2008-03-03 | 2011-01-11 | Eastman Chemical Company | Production of non-solid-stated polyester particles having solid-stated properties |
DE102014216992A1 (de) | 2014-08-26 | 2016-03-03 | Adidas Ag | Expandierte Polymerpellets |
JP6658086B2 (ja) * | 2016-02-26 | 2020-03-04 | 東洋製罐グループホールディングス株式会社 | ポリオキサレート共重合体及びその製造方法 |
US20240018329A1 (en) | 2020-11-16 | 2024-01-18 | Cryovac, Llc | Method and system for recycling polyvinylidene chloride containing composite material |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB886811A (en) * | 1957-11-29 | 1962-01-10 | Dow Chemical Co | Method of making a latent-foaming polymeric composition |
US3121132A (en) * | 1961-12-18 | 1964-02-11 | Koppers Co Inc | Stress relieving expandable plastic particles |
US3912800A (en) | 1970-09-21 | 1975-10-14 | Int Plastics | Method of producing porous polymeric articles |
DE2126146A1 (de) | 1971-05-26 | 1972-12-07 | Bayer | Treibmittel |
GB1507921A (en) | 1974-04-01 | 1978-04-19 | Gen Electric | Membranes |
US4224264A (en) * | 1979-01-18 | 1980-09-23 | Monsanto Company | Foam crystallization of condensation polymers |
US4473665A (en) * | 1982-07-30 | 1984-09-25 | Massachusetts Institute Of Technology | Microcellular closed cell foams and their method of manufacture |
US4597843A (en) | 1984-10-12 | 1986-07-01 | American Cyanamid Company | Enhanced bulk porosity of polymer structures via plasma technology |
US4644049A (en) | 1986-03-05 | 1987-02-17 | The Goodyear Tire & Rubber Company | Solid state polymerization |
US5000891A (en) * | 1986-09-29 | 1991-03-19 | Green James R | Expandable polystyrene pellets |
CA1305579C (en) | 1987-09-28 | 1992-07-21 | Shinsuke Fukuoka | Method for producing a crystallized aromatic polycarbonate, and a crystallized aromatic polycarbonate obtained thereby |
SG52381A1 (en) | 1988-12-27 | 1998-09-28 | Asahi Chemical Ind | A porous crystallized aromatic polycarbonate prepolymer a porous crystallized aromatic polycarbonate and production method |
EP0494445B1 (de) * | 1991-01-05 | 1997-02-12 | Bayer Ag | Verfahren zur Herstellung von Polycarbonatschaumformkörper |
US5158986A (en) * | 1991-04-05 | 1992-10-27 | Massachusetts Institute Of Technology | Microcellular thermoplastic foamed with supercritical fluid |
-
1999
- 1999-08-10 US US09/371,451 patent/US6339109B1/en not_active Expired - Lifetime
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2000
- 2000-06-09 WO PCT/US2000/015921 patent/WO2001010622A1/en active IP Right Grant
- 2000-06-09 AT AT00938247T patent/ATE276863T1/de not_active IP Right Cessation
- 2000-06-09 EP EP00938247A patent/EP1218159B1/en not_active Expired - Lifetime
- 2000-06-09 JP JP2001526639A patent/JP2003510441A/ja not_active Withdrawn
- 2000-06-09 AU AU53316/00A patent/AU5331600A/en not_active Abandoned
- 2000-06-09 DE DE60014123T patent/DE60014123T2/de not_active Expired - Lifetime
- 2000-06-09 KR KR1020027001819A patent/KR20020021684A/ko not_active Application Discontinuation
- 2000-06-09 CN CNB008141037A patent/CN1182948C/zh not_active Expired - Fee Related
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WO2001010622A8 (en) | 2001-06-14 |
US6339109B1 (en) | 2002-01-15 |
AU5331600A (en) | 2001-03-05 |
EP1218159A1 (en) | 2002-07-03 |
WO2001010622A1 (en) | 2001-02-15 |
ATE276863T1 (de) | 2004-10-15 |
EP1218159B1 (en) | 2004-09-22 |
CN1378498A (zh) | 2002-11-06 |
JP2003510441A (ja) | 2003-03-18 |
DE60014123D1 (de) | 2004-10-28 |
KR20020021684A (ko) | 2002-03-21 |
DE60014123T2 (de) | 2005-09-22 |
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