CN117625284A - 一种离心式空气压缩机润滑油组合物 - Google Patents

一种离心式空气压缩机润滑油组合物 Download PDF

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CN117625284A
CN117625284A CN202210964507.3A CN202210964507A CN117625284A CN 117625284 A CN117625284 A CN 117625284A CN 202210964507 A CN202210964507 A CN 202210964507A CN 117625284 A CN117625284 A CN 117625284A
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lubricating oil
air compressor
centrifugal air
oil composition
diphenylamine
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刘中国
朱江
王辉
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Petrochina Co Ltd
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Abstract

本发明公开了一种离心式空气压缩机润滑油组合物,按照质量百分数包括以下组分:离子液体0.5‑5%;抗氧剂0.1‑1%;防锈剂0.1‑1%;金属钝化剂0.05‑0.5%;破乳剂0.01‑0.1%;抗泡剂0.005‑0.05%;余量为基础油。该离心式空气压缩机润滑油组合物的主要添加剂组分为离子液体,其不仅溶解性能好,而且与其他组分搭配时能够表现出优良的配伍性能。另一方面,该离心式空气压缩机润滑油组合物兼具较为优异的抗氧化性、防锈性、抗腐蚀性、抗乳化性和抗泡性能,尤其是具有较为优异的防锈性。本发明的润滑油组合物能够起到优异的润滑作用,延长离心式空气压缩机的使用寿命,拓宽离心式空气压缩机的使用范围。

Description

一种离心式空气压缩机润滑油组合物
技术领域
本发明属于润滑油技术领域,具体涉及一种离心式空气压缩机润滑油组合物。
背景技术
离心式空气压缩机体积小,重量轻,结构紧凑,零部件少,维护简单,并且冷却性好,效率高,气体输送平稳,因此在压缩机设备领域应用广泛,尤其是在食品、药品、纺织、矿山等行业,离心式空气压缩机的市场占比上升趋势明显。为了进一步提升离心式空气压缩机的工作效率,降低维护成本,扩大使用范围,近些年来,离心式空气压缩机正朝着简单化、紧凑化以及轻量化等方向快速发展,同时设备压力、温度、级压比、排气量等条件不断提高,工况更加苛刻,相应的对离心式空气压缩机润滑油的使用寿命、抗氧化、防锈、抗腐蚀等性能要求也越来越高。
现阶段的离心式空气压缩机润滑油虽然能够在一定程度上改善离心式空气压缩机润滑油的各性能(例如,抗氧化性、防锈性、抗腐蚀性、抗乳化性和抗泡性等性能),但是其对离心式空气压缩机润滑油各性能的改善程度依然有限,使得离心式空气压缩机润滑油的各性能还有进一步改善的空间,尤其是离心式空气压缩机润滑油的防锈性还有进一步改善的空间。因此,亟需提供一种兼具更为优异的抗氧化性、锈性、抗腐蚀性、抗乳化性、抗泡性的离心式空气压缩机润滑油组合物。
发明内容
本发明的目的是提供一种离心式空气压缩机润滑油组合物,该离组合物兼具较为优良的抗氧化性、防锈性、抗腐蚀性、抗乳化性、抗泡性,可以满足苛刻工况下的离心式空气压缩机的润滑需求。
本发明所采用的技术方案是,一种离心式空气压缩机润滑油组合物,按照质量百分数包括以下组分:离子液体0.5-5%;抗氧剂0.1-1%;防锈剂0.1-1%;金属钝化剂0.05-0.5%;破乳剂0.01-0.1%;抗泡剂0.005-0.05%;余量为基础油。
本发明的特点还在于,
组合物按照质量百分数包括以下组分:离子液体2-4%;抗氧剂0.5-1%;防锈剂0.5-1%;金属钝化剂0.1-0.3%;破乳剂0.02-0.05%;抗泡剂0.01-0.03%;余量为基础油。
离子液体的结构式为:
抗氧剂为二辛基二苯胺、二壬基二苯胺、苯乙烯基辛基二苯胺、辛基丁基二苯胺、辛基戊基二苯胺、壬基丁基二苯胺和4,4’-亚甲基双(2,6-二叔丁基苯酚)中的至少一种。
防锈剂为二壬基萘磺酸钙、十二烯基丁二酸、异壬基苯氧基乙酸、十二烯基丁二酸半酯和十二烯基丁二酸单酯中的至少一种。
金属钝化剂为甲基苯并三氮唑、N,N’-二烷基氨基亚甲基苯三唑和N,N’-二亚水杨丙二胺中的至少一种。
破乳剂为油溶性聚醚DL32;抗泡剂为1#复合抗泡剂;基础油为加氢矿物油VHVI 6。
本发明的有益效果是:本发明的离心式空气压缩机润滑油组合物,一方面,该离心式空气压缩机润滑油组合物的主要添加剂组分为离子液体,其不仅溶解性能好,而且与其他组分搭配时能够表现出优良的配伍性能。另一方面,该离心式空气压缩机润滑油组合物兼具较为优异的抗氧化性(旋转氧弹高)、防锈性(液相锈蚀B法合格)、抗腐蚀性(100℃,3h铜片的腐蚀等级为1b及以上)、抗乳化性(油水分离时间小于等于10min)和抗泡性能(泡沫倾向性/泡沫稳定性小于等于10/0mL/mL),尤其是具有较为优异的防锈性。本发明的离心式空气压缩机润滑油组合物用于离心式空气压缩机的轴封、齿轮和轴承等处,能够起到优异的润滑作用,延长离心式空气压缩机的使用寿命,拓宽离心式空气压缩机的使用范围。
具体实施方式
下面结合具体实施方式对本发明进行详细说明。
本发明一种离心式空气压缩机润滑油组合物,按照质量百分数包括以下组分:离子液体0.5-5%;抗氧剂0.1-1%;防锈剂0.1-1%;金属钝化剂0.05-0.5%;破乳剂0.01-0.1%;抗泡剂0.005-0.05%;余量为基础油;
离子液体的结构式为:
本发明中,可以对抗氧剂、防锈剂、金属钝化剂、破乳剂、抗泡剂和基础油的原料进行进一步的选择,以期进一步提高各原料的配伍性,改善离心式空气压缩机润滑油组合物的综合性能。
进一步的,组合物按照质量百分数包括以下组分:离子液体2-4%;抗氧剂0.5-1%;防锈剂0.5-1%;金属钝化剂0.1-0.3%;破乳剂0.02-0.05%;抗泡剂0.01-0.03%;余量为基础油。该离心式空气压缩机润滑油组合物具有更为优异的综合性能(抗氧化性、防锈性、抗腐蚀性、抗乳化性和抗泡性)。
抗氧剂为二辛基二苯胺、二壬基二苯胺、苯乙烯基辛基二苯胺、辛基丁基二苯胺、辛基戊基二苯胺、壬基丁基二苯胺和4,4’-亚甲基双(2,6-二叔丁基苯酚)中的至少一种;
防锈剂为二壬基萘磺酸钙、十二烯基丁二酸、异壬基苯氧基乙酸、十二烯基丁二酸半酯和十二烯基丁二酸单酯中的至少一种;
金属钝化剂为甲基苯并三氮唑、N,N’-二烷基氨基亚甲基苯三唑和N,N’-二亚水杨丙二胺中的至少一种;
破乳剂为油溶性聚醚DL32;抗泡剂为1#复合抗泡剂;基础油为加氢矿物油VHVI 6。
本发明的离心式空气压缩机润滑油组合物可以通过将各原料按照上述的组成混合均匀得到。本发明对各原料的添加顺序、搅拌速率、混合温度不做特别限定。
本发明的离心式空气压缩机润滑油组合物,不仅兼具较为优良的综合性能(抗氧化性、防锈性、抗腐蚀性、抗乳化性和抗泡性),而且制备工艺简单,易于操作,应用范围广。
实施例1
本实施例的离心式空气压缩机润滑油组合物的组成见表1。其中,离子液体的结构式为:
表1离心式空气压缩机润滑油组合物的组成
实施例2
本实施例的离心式空气压缩机润滑油组合物的组成见表2。其中,离子液体的结构式为:
表2离心式空气压缩机润滑油组合物的组成
名称 质量百分含量/%
离子液体 2
二壬基二苯胺 0.5
辛基戊基二苯胺 0.5
十二烯基丁二酸单酯 1
N,N’-二烷基氨基亚甲基苯三唑 0.3
DL32 0.02
1#复合抗泡剂 0.01
VHVI 6 95.67
实施例3
本实施例的离心式空气压缩机润滑油组合物的组成见表3。其中,离子液体的结构式为:
表3离心式空气压缩机润滑油组合物的组成
名称 质量百分含量/%
离子液体 5
苯乙烯基辛基二苯胺 0.1
异壬基苯氧基乙酸 0.1
N,N’-二亚水杨丙二胺 0.5
DL32 0.01
1#复合抗泡剂 0.005
VHVI 6 94.285
实施例4
本实施例的离心式空气压缩机润滑油组合物的组成见表4。其中,离子液体的结构式为:
表4离心式空气压缩机润滑油组合物的组成
名称 质量百分含量/%
离子液体 0.5
壬基丁基二苯胺 1
二壬基萘磺酸钙 1
甲基苯并三氮唑 0.05
DL32 0.1
1#复合抗泡剂 0.05
VHVI 6 97.3
对比例1
本对比例的离心式空气压缩机润滑油组合物的组成见表5。
表5离心式空气压缩机润滑油组合物的组成
名称 质量百分含量/%
辛基丁基二苯胺 0.5
4,4’-亚甲基双(2,6-二叔丁基苯酚) 0.5
十二烯基丁二酸 0.5
甲基苯并三氮唑 0.3
DL32 0.02
1#复合抗泡剂 0.01
VHVI 6 98.17
对比例2
本对比例的离心式空气压缩机润滑油组合物的组成见表6。其中,离子液体的结构式为:
其中,n=2
表6离心式空气压缩机润滑油组合物的组成
名称 质量百分含量/%
离子液体 1
二壬基二苯胺 0.5
辛基戊基二苯胺 0.5
十二烯基丁二酸单酯 0.5
N,N’-二烷基氨基亚甲基苯三唑 0.3
DL32 0.02
1#复合抗泡剂 0.01
VHVI 6 97.17
对比例3
本对比例的离心式空气压缩机润滑油组合物的组成见表7。其中,离子液体的结构式为:
表7离心式空气压缩机润滑油组合物的组成
名称 质量百分含量/%
离子液体 5.5
苯乙烯基辛基二苯胺 0.08
异壬基苯氧基乙酸 0.08
N,N’-二亚水杨丙二胺 0.55
DL32 0.005
1#复合抗泡剂 0.003
VHVI 6 93.785
对比例4
本对比例的离心式空气压缩机润滑油组合物的组成见表8。其中,离子液体的结构式为:
表8离心式空气压缩机润滑油组合物的组成
性能表征
1、对基础油VHVI 6进行性能测试,测试结果见表9。
表9基础油VHVI 6性能测试结果
项目 VHVI 6 试验方法
运动黏度(40℃)/(mm2/s) 31.4 GB/T 265
黏度指数 126 GB/T 1995
倾点/℃ -18 GB/T 3535
闪点(开口)/℃ 240 GB/T 3536
2、对实施例和对比例中的离心式空气压缩机润滑油组合物进行性能测试,测试结果见表10。
表10离心式空气压缩机润滑油组合物性能测试结果
从表10可以看出,本发明实施例中制备的离心式空气压缩机润滑油组合物具有较为优异的抗氧化性、防锈性、抗腐蚀性、抗乳化性和抗泡性能,尤其是具有较为优异的防锈性。
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。

Claims (7)

1.一种离心式空气压缩机润滑油组合物,其特征在于,所述组合物按照质量百分数包括以下组分:离子液体0.5-5%;抗氧剂0.1-1%;防锈剂0.1-1%;金属钝化剂0.05-0.5%;破乳剂0.01-0.1%;抗泡剂0.005-0.05%;余量为基础油。
2.根据权利要求1所述的一种离心式空气压缩机润滑油组合物,其特征在于,所述组合物按照质量百分数包括以下组分:离子液体2-4%;抗氧剂0.5-1%;防锈剂0.5-1%;金属钝化剂0.1-0.3%;破乳剂0.02-0.05%;抗泡剂0.01-0.03%;余量为基础油。
3.根据权利要求1或2所述的一种离心式空气压缩机润滑油组合物,其特征在于,所述离子液体的结构式为:
4.根据权利要求1或2所述的一种离心式空气压缩机润滑油组合物,其特征在于,所述抗氧剂为二辛基二苯胺、二壬基二苯胺、苯乙烯基辛基二苯胺、辛基丁基二苯胺、辛基戊基二苯胺、壬基丁基二苯胺和4,4’-亚甲基双(2,6-二叔丁基苯酚)中的至少一种。
5.根据权利要求1或2所述的一种离心式空气压缩机润滑油组合物,其特征在于,所述防锈剂为二壬基萘磺酸钙、十二烯基丁二酸、异壬基苯氧基乙酸、十二烯基丁二酸半酯和十二烯基丁二酸单酯中的至少一种。
6.根据权利要求1或2所述的一种离心式空气压缩机润滑油组合物,其特征在于,所述金属钝化剂为甲基苯并三氮唑、N,N’-二烷基氨基亚甲基苯三唑和N,N’-二亚水杨丙二胺中的至少一种。
7.根据权利要求1或2所述的一种离心式空气压缩机润滑油组合物,其特征在于,所述破乳剂为油溶性聚醚DL32;所述抗泡剂为1#复合抗泡剂;所述基础油为加氢矿物油VHVI 6。
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