CN117625287A - 一种回转式空气压缩机润滑油组合物 - Google Patents
一种回转式空气压缩机润滑油组合物 Download PDFInfo
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- CN117625287A CN117625287A CN202210964639.6A CN202210964639A CN117625287A CN 117625287 A CN117625287 A CN 117625287A CN 202210964639 A CN202210964639 A CN 202210964639A CN 117625287 A CN117625287 A CN 117625287A
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- Prior art keywords
- air compressor
- rotary air
- lubricating oil
- oil composition
- compressor lubricating
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 69
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 53
- 239000002608 ionic liquid Substances 0.000 claims abstract description 30
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- 239000002199 base oil Substances 0.000 claims abstract description 12
- 239000003112 inhibitor Substances 0.000 claims abstract description 12
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 11
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 11
- -1 styryl octyl diphenylamine Chemical compound 0.000 claims description 23
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims description 11
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- QXIVQIQPZWALGC-UHFFFAOYSA-N 9-methyl-2-phenoxydecanoic acid Chemical compound CC(C)CCCCCCC(Oc1ccccc1)C(O)=O QXIVQIQPZWALGC-UHFFFAOYSA-N 0.000 claims description 5
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 claims description 5
- MXCXTEIZYLWFPB-UHFFFAOYSA-N 2-octyl-N-pentyl-N-phenylaniline Chemical compound C(CCCCCCC)C1=C(C=CC=C1)N(C1=CC=CC=C1)CCCCC MXCXTEIZYLWFPB-UHFFFAOYSA-N 0.000 claims description 4
- UUNBFTCKFYBASS-UHFFFAOYSA-N C(CCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCC Chemical compound C(CCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCC UUNBFTCKFYBASS-UHFFFAOYSA-N 0.000 claims description 4
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 4
- WERKSKAQRVDLDW-ANOHMWSOSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WERKSKAQRVDLDW-ANOHMWSOSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- QVXGKJYMVLJYCL-UHFFFAOYSA-N 2,3-di(nonyl)-N-phenylaniline Chemical compound C(CCCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCCC QVXGKJYMVLJYCL-UHFFFAOYSA-N 0.000 claims description 3
- HAQCMCPXROIUEN-UHFFFAOYSA-N N-butyl-2-nonyl-N-phenylaniline Chemical compound C(CCCCCCCC)C1=C(C=CC=C1)N(C1=CC=CC=C1)CCCC HAQCMCPXROIUEN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- MKFUUBCXQNCPIP-UHFFFAOYSA-L calcium;2,3-di(nonyl)naphthalene-1-sulfonate Chemical compound [Ca+2].C1=CC=C2C(S([O-])(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1.C1=CC=C2C(S([O-])(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1 MKFUUBCXQNCPIP-UHFFFAOYSA-L 0.000 claims description 3
- NAGJZTKCGNOGPW-UHFFFAOYSA-K dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [O-]P([O-])([S-])=S NAGJZTKCGNOGPW-UHFFFAOYSA-K 0.000 claims description 3
- RMKNTZWZQFIOOB-UHFFFAOYSA-N n-butyl-2-octyl-n-phenylaniline Chemical compound CCCCCCCCC1=CC=CC=C1N(CCCC)C1=CC=CC=C1 RMKNTZWZQFIOOB-UHFFFAOYSA-N 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 239000006078 metal deactivator Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 15
- 230000007797 corrosion Effects 0.000 abstract description 15
- 230000003647 oxidation Effects 0.000 abstract description 9
- 238000007254 oxidation reaction Methods 0.000 abstract description 9
- 238000004945 emulsification Methods 0.000 abstract description 7
- 238000005299 abrasion Methods 0.000 abstract description 5
- 239000006260 foam Substances 0.000 abstract description 4
- 238000005461 lubrication Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 9
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 8
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 230000003254 anti-foaming effect Effects 0.000 description 2
- 239000013556 antirust agent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 150000002466 imines Chemical class 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- RAADJDWNEAXLBL-UHFFFAOYSA-N 1,2-di(nonyl)naphthalene Chemical compound C1=CC=CC2=C(CCCCCCCCC)C(CCCCCCCCC)=CC=C21 RAADJDWNEAXLBL-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/124—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/288—Partial esters containing free carboxyl groups
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/043—Ammonium or amine salts thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/14—Metal deactivation
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
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- Lubricants (AREA)
Abstract
本发明公开了一种回转式空气压缩机润滑油组合物，按照质量百分数包括以下组分：离子液体0.5‑3％；防锈剂0.05‑2％；金属钝化剂0.05‑2％；抗氧剂0.5‑3％；极压抗磨剂0.02‑0.5％；破乳剂0.01‑0.06％；抗泡剂0.005‑0.03％；余量为基础油。该回转式空气压缩机润滑油组合物具有较为优异的防锈性、抗腐蚀性、抗氧化性、抗磨性、抗乳化性和抗泡性。本发明的回转式空气压缩机润滑油组合物用于回转式空气压缩机的转子、轴封、齿轮和轴承等处，能够起到优异的润滑作用，延长回转式空气压缩机的使用寿命，拓宽回转式空气压缩机的使用范围。
Description
技术领域
本发明属于润滑油技术领域，具体涉及一种回转式空气压缩机润滑油组合物。
背景技术
回转式空气压缩机体积小，重量轻，结构紧凑，零部件少，维护简单，并且冷却性好，效率高，气体输送平稳，因此在压缩机设备领域应用广泛，尤其是在食品、药品、纺织、矿山等行业，回转式空气压缩机的市场占比上升趋势明显。为了进一步提升回转式空气压缩机的工作效率，降低维护成本，扩大使用范围，近些年来，回转式空气压缩机正朝着简单化、紧凑化以及轻量化等方向快速发展，同时设备压力、温度、级压比、排气量等条件不断提高，工况更加苛刻，相应的对回转式空气压缩机润滑油的使用寿命、防锈、抗腐蚀、抗氧化、抗磨等性能要求也越来越高。
现阶段的回转式空气压缩机润滑油虽然能够在一定程度上改善回转式空气压缩机润滑油的各性能(例如，防锈性、抗腐蚀性、抗氧化性、抗磨性、抗乳化性和抗泡性等性能)，但是其对回转式空气压缩机润滑油各性能的改善程度依然有限，使得回转式空气压缩机润滑油的各性能还有进一步改善的空间，尤其是回转式空气压缩机润滑油的防锈性和抗腐蚀性还有进一步改善的空间。因此，亟需提供一种兼具更为优异的防锈性、抗腐蚀性、抗氧化性、抗磨性、抗乳化性、抗泡性的回转式空气压缩机润滑油组合物。
发明内容
本发明的目的是提供一种回转式空气压缩机润滑油组合物，该回转式空气压缩机润滑油组合物兼具较为优良的防锈性、抗腐蚀性、抗氧化性、抗磨性、抗乳化性和抗泡性，可以满足苛刻工况下的回转式空气压缩机的润滑需求。
本发明所采用的技术方案是，一种回转式空气压缩机润滑油组合物，按照质量百分数包括以下组分：离子液体0.5-3％；防锈剂0.05-2％；金属钝化剂0.05-2％；抗氧剂0.5-3％；极压抗磨剂0.02-0.5％；破乳剂0.01-0.06％；抗泡剂0.005-0.03％；余量为基础油。
本发明的特点还在于，
组合物按照质量百分数包括以下组分：离子液体1-2％；防锈剂0.2-1％；金属钝化剂0.2-1％；抗氧剂1-2％；极压抗磨剂0.1-0.3％；破乳剂0.02-0.04％；抗泡剂0.01-0.02％；余量为基础油。
离子液体的结构为：
其中，n为5-7的正整数。
防锈剂为二壬基萘磺酸钙、十二烯基丁二酸、异壬基苯氧基乙酸、十二烯基丁二酸半酯、十二烯基丁二酸单酯和山梨糖醇单油酸酯中的至少一种。
金属钝化剂为甲苯并三唑、N,N’-二烷基氨基亚甲基苯三唑、N,N’-二亚水杨丙二胺中的至少一种。
抗氧剂为二辛基二苯胺、二壬基二苯胺、苯乙烯基辛基二苯胺、辛基丁基二苯胺、辛基戊基二苯胺、壬基丁基二苯胺、辛基化苯基-α-萘胺、4,4’-亚甲基双(2,6-二叔丁基苯酚)、(3-甲基-5-叔丁基-4-羟基苯基)丙酸烷基酯、三(2,4-二叔丁基苯基)亚磷酸酯中的至少一种。
极压抗磨剂为丁基三苯基硫代磷酸酯、二烷基二硫代磷酸酯、脂肪磷酸酯胺盐中的至少一种。
破乳剂为油溶性聚醚DL32；抗泡剂为1#复合抗泡剂T921、2#复合抗泡剂T922中的至少一种；基础油为季戊四醇酯。
离子液体与防锈剂的质量比为1：0.3-0.6。
本发明的有益效果是：本发明回转式空气压缩机润滑油组合物的主要组分为离子液体，其不仅溶解性能好，而且与其他组分搭配时能够表现出优良的配伍性能。另一方面，该回转式空气压缩机润滑油组合物兼具较为优异的防锈性(液相锈蚀B法合格)、抗腐蚀性(100℃，3h铜片的腐蚀等级为1b及以上，氧化腐蚀表现好)、抗氧化性(旋转氧弹高)、抗磨性(FZG齿轮机失效级为10级及以上)、抗乳化性(油水分离时间小于等于10min)和抗泡性能(泡沫倾向性/泡沫稳定性小于等于10/0mL/mL)，尤其是具有较为优异的防锈性和抗腐蚀性。本发明的回转式空气压缩机润滑油组合物用于回转式空气压缩机的转子、轴封、齿轮和轴承等处，能够起到优异的润滑作用，延长回转式空气压缩机的使用寿命，拓宽回转式空气压缩机的使用范围。
具体实施方式
下面结合具体实施方式对本发明进行详细说明。
本发明一种回转式空气压缩机润滑油组合物，按照质量百分数包括以下组分：离子液体0.5-3％；防锈剂0.05-2％；金属钝化剂0.05-2％；抗氧剂0.5-3％；极压抗磨剂0.02-0.5％；破乳剂0.01-0.06％；抗泡剂0.005-0.03％；余量为基础油；
进一步的，组合物按照质量百分数包括以下组分：离子液体1-2％；防锈剂0.2-1％；金属钝化剂0.2-1％；抗氧剂1-2％；极压抗磨剂0.1-0.3％；破乳剂0.02-0.04％；抗泡剂0.01-0.02％；余量为基础油。
其中，离子液体与防锈剂的质量比为1：0.3-0.6；
离子液体的结构为：
其中，n为5-7的正整数；
本发明中，可以对防锈剂、金属钝化剂、抗氧剂、极压抗磨剂、破乳剂、抗泡剂和基础油的原料进行进一步的选择，以期进一步提高各原料的配伍性，改善回转式空气压缩机润滑油组合物的综合性能。
防锈剂为二壬基萘磺酸钙、十二烯基丁二酸、异壬基苯氧基乙酸、十二烯基丁二酸半酯、十二烯基丁二酸单酯和山梨糖醇单油酸酯中的至少一种。
金属钝化剂为甲苯并三唑、N,N’-二烷基氨基亚甲基苯三唑、N,N’-二亚水杨丙二胺中的至少一种。
抗氧剂为二辛基二苯胺、二壬基二苯胺、苯乙烯基辛基二苯胺、辛基丁基二苯胺、辛基戊基二苯胺、壬基丁基二苯胺、辛基化苯基-α-萘胺、4,4’-亚甲基双(2,6-二叔丁基苯酚)、(3-甲基-5-叔丁基-4-羟基苯基)丙酸烷基酯、三(2,4-二叔丁基苯基)亚磷酸酯中的至少一种。
极压抗磨剂为丁基三苯基硫代磷酸酯、二烷基二硫代磷酸酯、脂肪磷酸酯胺盐中的至少一种。
破乳剂为油溶性聚醚DL32。
抗泡剂为1#复合抗泡剂T921、2#复合抗泡剂T922中的至少一种。
基础油为季戊四醇酯。
本发明的回转式空气压缩机润滑油组合物可以通过将各原料按照上述的组成混合均匀得到。对各原料的添加顺序、搅拌速率、混合温度不做特别限定。
本发明的回转式空气压缩机润滑油组合物，不仅兼具较为优良的综合性能(防锈性、抗腐蚀性、抗氧化性、抗磨性、抗乳化性和抗泡性)，而且制备工艺简单，易于操作，应用范围广。
本发明组合物采用含偶氮类二(三氟甲基磺酰)亚胺的离子液体，从分子结构式可以看出，离子液体的偶氮结构及亚胺结构具有强烈的系统效应，在铜等金属表面可形成保护膜，降低金属的腐蚀速率，有效保护金属表面，起到防锈、抗腐蚀等作用。
实施例1
本实施例的回转式空气压缩机润滑油组合物的组成见表1，其中，离子液体的结构为：
其中，n＝5
表1回转式空气压缩机润滑油组合物的组成
| 名称 | 质量百分含量/％ |
| 离子液体 | 0.5 |
| 二壬基萘磺酸钙 | 2 |
| 甲苯并三唑 | 0.1 |
| 二辛基二苯胺 | 1.5 |
| 4,4’-亚甲基双(2,6-二叔丁基苯酚) | 1 |
| 丁基三苯基硫代磷酸酯 | 0.5 |
| DL32 | 0.01 |
| T921 | 0.005 |
| 季戊四醇酯 | 94.385 |
实施例2
本实施例的回转式空气压缩机润滑油组合物的组成见表2，其中，离子液体的结构为：
其中，n＝6
表2回转式空气压缩机润滑油组合物的组成
| 名称 | 质量百分含量/％ |
| 离子液体 | 1 |
| 十二烯基丁二酸单酯 | 1 |
| N,N’-二烷基氨基亚甲基苯三唑 | 0.2 |
| 辛基戊基二苯胺 | 1 |
| (3-甲基-5-叔丁基-4-羟基苯基)丙酸烷基酯 | 1 |
| 二烷基二硫代磷酸酯 | 0.1 |
| DL32 | 0.03 |
| T922 | 0.01 |
| 季戊四醇酯 | 95.66 |
实施例3
本实施例的回转式空气压缩机润滑油组合物的组成见表3，其中，离子液体的结构为：
其中，n＝7；
表3回转式空气压缩机润滑油组合物的组成
| 名称 | 质量百分含量/％ |
| 离子液体 | 1.6 |
| 十二烯基丁二酸半酯 | 0.8 |
| N,N’-二亚水杨丙二胺 | 0.5 |
| 苯乙烯基辛基二苯胺 | 0.6 |
| 4,4’-亚甲基双(2,6-二叔丁基苯酚) | 0.6 |
| 三(2,4-二叔丁基苯基)亚磷酸酯 | 0.3 |
| 脂肪磷酸酯胺盐 | 0.2 |
| DL32 | 0.02 |
| T921 | 0.02 |
| 季戊四醇酯 | 95.37 |
实施例4
本实施例的回转式空气压缩机润滑油组合物的组成见表4，其中，离子液体的结构为：
其中，n＝5；
表4回转式空气压缩机润滑油组合物的组成
| 名称 | 质量百分含量/％ |
| 离子液体 | 3 |
| 异壬基苯氧基乙酸 | 0.05 |
| 甲苯并三唑 | 0.05 |
| 辛基化苯基-α-萘胺 | 0.2 |
| 4,4’-亚甲基双(2,6-二叔丁基苯酚) | 0.3 |
| 脂肪磷酸酯胺盐 | 0.5 |
| DL32 | 0.06 |
| T921 | 0.005 |
| 季戊四醇酯 | 95.835 |
实施例5
本实施例的回转式空气压缩机润滑油组合物的组成见表5；其中，离子液体的结构为：
其中，n＝6；
表5回转式空气压缩机润滑油组合物的组成
| 名称 | 质量百分含量/％ |
| 离子液体 | 0.5 |
| 山梨糖醇单油酸酯 | 2 |
| N,N’-二亚水杨丙二胺 | 2 |
| 二壬基二苯胺 | 3 |
| 二烷基二硫代磷酸酯 | 0.02 |
| DL32 | 0.01 |
| T922 | 0.03 |
| 季戊四醇酯 | 92.44 |
对比例1
本对比例的回转式空气压缩机润滑油组合物的组成见表6；
表6回转式空气压缩机润滑油组合物的组成
对比例2
本对比例的回转式空气压缩机润滑油组合物的组成见表7，其中，离子液体的结构为：
其中，n＝2；
表7回转式空气压缩机润滑油组合物的组成
对比例3
本对比例的回转式空气压缩机润滑油组合物的组成见表8，其中，离子液体的结构为：
其中，n＝7；
表8回转式空气压缩机润滑油组合物的组成
对比例4
本对比例的回转式空气压缩机润滑油组合物的组成见表9。其中，离子液体的结构为：
其中，n＝5；
表9回转式空气压缩机润滑油组合物的组成
| 名称 | 质量百分含量/％ |
| 离子液体 | 3.2 |
| 异壬基苯氧基乙酸 | 0.03 |
| 甲苯并三唑 | 0.03 |
| 辛基化苯基-α-萘胺 | 0.2 |
| 4,4’-亚甲基双(2,6-二叔丁基苯酚) | 0.2 |
| 丁基三苯基硫代磷酸酯 | 0.6 |
| DL32 | 0.08 |
| T921 | 0.004 |
| 季戊四醇酯 | 95.656 |
性能表征
1、对基础油季戊四醇酯进行性能测试，测试结果见表10；
表10季戊四醇酯性能测试结果
| 项目 | 季戊四醇酯 | 试验方法 |
| 运动黏度(40℃)/(mm2/s) | 45.87 | GB/T 265 |
| 黏度指数 | 106 | GB/T 2541 |
| 倾点/℃ | -45 | GB/T 3535 |
| 闪点(开口)/℃ | 278 | GB/T 3536 |
| 酸值/(mgKOH/g) | 0.01 | GB/T 4945 |
2、对实施例和对比例中的回转式空气压缩机润滑油组合物进行性能测试，测试结果见表11。
表11回转式空气压缩机润滑油组合物性能测试结果
从表11可以看出，本发明实施例中制备的回转式空气压缩机润滑油组合物具有较为优异的防锈性、抗腐蚀性、抗氧化性、抗磨性、抗乳化性和抗泡性能，尤其是具有较为优异的防锈性和抗腐蚀性。
最后应说明的是：以上各实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述各实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分或者全部技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。
Claims (9)
1.一种回转式空气压缩机润滑油组合物，其特征在于，所述组合物按照质量百分数包括以下组分：离子液体0.5-3％；防锈剂0.05-2％；金属钝化剂0.05-2％；抗氧剂0.5-3％；极压抗磨剂0.02-0.5％；破乳剂0.01-0.06％；抗泡剂0.005-0.03％；余量为基础油。
2.根据权利要求1所述的一种回转式空气压缩机润滑油组合物，其特征在于，所述组合物按照质量百分数包括以下组分：离子液体1-2％；防锈剂0.2-1％；金属钝化剂0.2-1％；抗氧剂1-2％；极压抗磨剂0.1-0.3％；破乳剂0.02-0.04％；抗泡剂0.01-0.02％；余量为基础油。
3.根据权利要求1或2所述的一种回转式空气压缩机润滑油组合物，其特征在于，所述离子液体的结构为：
其中，n为5-7的正整数。
4.根据权利要求1或2所述的一种回转式空气压缩机润滑油组合物，其特征在于，所述防锈剂为二壬基萘磺酸钙、十二烯基丁二酸、异壬基苯氧基乙酸、十二烯基丁二酸半酯、十二烯基丁二酸单酯和山梨糖醇单油酸酯中的至少一种。
5.根据权利要求1或2所述的一种回转式空气压缩机润滑油组合物，其特征在于，所述金属钝化剂为甲苯并三唑、N,N’-二烷基氨基亚甲基苯三唑、N,N’-二亚水杨丙二胺中的至少一种。
6.根据权利要求1或2所述的一种回转式空气压缩机润滑油组合物，其特征在于，所述抗氧剂为二辛基二苯胺、二壬基二苯胺、苯乙烯基辛基二苯胺、辛基丁基二苯胺、辛基戊基二苯胺、壬基丁基二苯胺、辛基化苯基-α-萘胺、4,4’-亚甲基双(2,6-二叔丁基苯酚)、(3-甲基-5-叔丁基-4-羟基苯基)丙酸烷基酯、三(2,4-二叔丁基苯基)亚磷酸酯中的至少一种。
7.根据权利要求1或2所述的一种回转式空气压缩机润滑油组合物，其特征在于，所述极压抗磨剂为丁基三苯基硫代磷酸酯、二烷基二硫代磷酸酯、脂肪磷酸酯胺盐中的至少一种。
8.根据权利要求1或2所述的一种回转式空气压缩机润滑油组合物，其特征在于，所述破乳剂为油溶性聚醚DL32；所述抗泡剂为1#复合抗泡剂T921、2#复合抗泡剂T922中的至少一种；所述基础油为季戊四醇酯。
9.根据权利要求1或2所述的一种回转式空气压缩机润滑油组合物，其特征在于，所述离子液体与防锈剂的质量比为1：0.3-0.6。
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