CN117185839A - Phospho-pattern glazed ceramic for red fish and preparation method thereof - Google Patents
Phospho-pattern glazed ceramic for red fish and preparation method thereof Download PDFInfo
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- CN117185839A CN117185839A CN202311164657.7A CN202311164657A CN117185839A CN 117185839 A CN117185839 A CN 117185839A CN 202311164657 A CN202311164657 A CN 202311164657A CN 117185839 A CN117185839 A CN 117185839A
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- 241001290266 Sciaenops ocellatus Species 0.000 title claims abstract description 36
- 239000000919 ceramic Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000010304 firing Methods 0.000 claims abstract description 28
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 20
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011574 phosphorus Substances 0.000 claims abstract description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 12
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 11
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 10
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 16
- 239000002994 raw material Substances 0.000 claims description 15
- 239000010453 quartz Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 235000012239 silicon dioxide Nutrition 0.000 claims description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- 239000010433 feldspar Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000011775 sodium fluoride Substances 0.000 claims description 8
- 235000013024 sodium fluoride Nutrition 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000454 talc Substances 0.000 claims description 7
- 235000012222 talc Nutrition 0.000 claims description 7
- 229910052623 talc Inorganic materials 0.000 claims description 7
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 6
- 235000019738 Limestone Nutrition 0.000 claims description 6
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 229910021538 borax Inorganic materials 0.000 claims description 6
- 229960004887 ferric hydroxide Drugs 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 claims description 6
- 239000006028 limestone Substances 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004328 sodium tetraborate Substances 0.000 claims description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 6
- 238000005245 sintering Methods 0.000 claims description 5
- 241000219307 Atriplex rosea Species 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 210000003205 muscle Anatomy 0.000 claims 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 12
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract description 12
- 229910052845 zircon Inorganic materials 0.000 abstract description 8
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 abstract description 8
- 239000013078 crystal Substances 0.000 abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052799 carbon Inorganic materials 0.000 abstract description 5
- 238000002425 crystallisation Methods 0.000 abstract description 5
- 230000008025 crystallization Effects 0.000 abstract description 5
- 230000008021 deposition Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 230000033558 biomineral tissue development Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- NDUKHFILUDZSHZ-UHFFFAOYSA-N [Fe].[Zr] Chemical compound [Fe].[Zr] NDUKHFILUDZSHZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention relates to the field of ceramics and preparation processes thereof, in particular to a red-spotted-fish-phosphorus-pattern glazed ceramic and a preparation method thereof, wherein manganese oxide in red-fish-scale base glaze has strong crystallization capability and large crystal form, and dark brownish red fish-scale patterns are formed after firing; the iron oxide in the overglaze and the zirconia in the ground glaze form zircon with zircon red at the intersection surface, so that the scale pattern is strengthened, and the scale pattern is converted from dark brownish red to pink, so that the color is brighter; part of polyvinyl chloride powder in the overglaze is decomposed and volatilized in the glaze firing process, part of the polyvinyl chloride powder is not completely decomposed and remains in the glaze, and blackening and graying are caused by carbon deposition of organic matters in a reducing atmosphere to form light gray spots in a local range; after back firing, the original light gray spots are continuously enlarged, the color tone is different, the whole shape is similar to the red fish phosphorus stripe glaze effect with the spots, and the red fish phosphorus stripe glaze has unique aesthetic feeling.
Description
Technical Field
The invention relates to the field of ceramics and preparation processes thereof, in particular to a red fish-in-flower phosphor grain glazed ceramic and a preparation method thereof.
Background
The glaze is a colorless or colored vitreous thin layer covered on the surface of ceramic products, and is prepared by grinding mineral raw materials (feldspar, quartz, talcum, kaolin and the like) and raw materials according to a certain proportion (part of raw materials can be firstly prepared into a frit) to prepare glaze slurry, applying the glaze slurry to the surface of a green body and calcining the glaze slurry at a certain temperature, and has the characteristics of increasing the mechanical strength, the thermal stability and the dielectric strength of the products, beautifying the objects, being convenient to wipe and wash, being not corroded by dust and fishy. The glaze is of various types and classified into porcelain glaze, ceramic glaze and flint ware glaze according to the blank types; the high-temperature glaze and the low-temperature glaze can be separated according to the firing temperature; according to the appearance characteristics, transparent glaze, opaque glaze, colored glaze, glossy glaze, matt glaze, crack glaze (piece opening), crystalline glaze and the like can be separated; the glaze composition can be classified into stone ash glaze, feldspar glaze, lead glaze, leadless glaze, boron glaze, lead boron glaze and the like. The porcelain glaze is covered with a plurality of small cracks, has the advantages of being sparse, dense, thick, thin, long, short, curved, straight, and lines similar to cracks or ice cracks, and is called crack glaze. The original glaze cracks are a defect in firing, but when the glaze cracks of certain products are very special, the lines are uniform and clear, the cracks are distributed on the surface of the sleeve, and a special aesthetic feeling is given to people, so that people are inspired from the special cracks, and summarize experience, the cracks of the sleeve surface are intentionally caused, so that crack glaze is gradually created, the shape of the existing crack glaze is mostly shown as cracks or ice cracks, and in the traditional firing process, the crack shape and the color are single, so that the scheme is generated.
Disclosure of Invention
It is an object of the present invention to solve at least the above problems by a garter phosphor grain glazed ceramic and a method for preparing the same.
In order to solve the technical problems, the invention adopts the following technical scheme: the red fish-colored phosphorus-pattern glazed ceramic is characterized in that: the red fish scale glaze comprises a green body, wherein the surface of the green body is covered with a glaze surface, the glaze surface comprises red fish scale ground glaze and gray spot overglaze, and the glaze surface is distributed with flower spot textures and red fish phosphorus textures.
Preferably, the raw materials of the red fish scale base glaze comprise the following components in parts by weight: 10-12 parts of manganese oxide, 5-7 parts of zirconium oxide, 5-8 parts of stalactite, 2-4 parts of borax, 26-30 parts of potassium feldspar, 18-25 parts of glass, 18-20 parts of quartz, 4-6 parts of limestone, 7-8 parts of kaolin, 2-4 parts of zinc oxide and 4-6 parts of talcum.
Preferably, the raw materials of the red fish scale base glaze comprise the following components in parts by weight: 11 parts of manganese oxide, 6 parts of zirconium oxide, 6 parts of stalactite, 3 parts of borax, 27 parts of potassium feldspar, 20 parts of glass, 19 parts of quartz, 5 parts of limestone, 7.5 parts of kaolin, 3 parts of zinc oxide and 5 parts of talcum.
Preferably, the raw materials of the gray spot overglaze comprise the following components in parts by weight: 20-25 parts of sodium fluoride, 20-25 parts of quartz, 3-4 parts of polyvinyl chloride powder, 6-8 parts of yellow ferric hydroxide, 20-25 parts of feldspar, 5-8 parts of bentonite and 12-15 parts of Suzhou soil.
Preferably, the raw materials of the gray spot overglaze comprise the following components in parts by weight: 22 parts of sodium fluoride, 22 parts of quartz, 3.5 parts of polyvinyl chloride powder, 7 parts of yellow ferric hydroxide, 22 parts of feldspar, 6 parts of bentonite and 13 parts of Suzhou soil.
The preparation method of the red fish-strip-shaped phosphorus glazed ceramic comprises the following steps:
step a, preparing a blank body and drying;
b, applying a red fish scale base coat on the green body;
step c, firing in a kiln, taking out the ceramic, and forming brownish red scale patterns on the red fish scale ground glaze;
step d, applying gray spot overglaze on the red fish scale underglaze;
step e, re-firing in a kiln, taking out the ceramic, converting the scale patterns on the glaze from brownish red to pink, and generating grey spots;
f, returning to the kiln, and expanding the range of the mottle on the glaze after returning to the kiln.
Preferably, the firing schedule of the step c is as follows: heating to 1200-1250 ℃ within 4-5 hours, cooling to 1050-1100 ℃ within 30-40 minutes, preserving heat for 3-4 hours, and then naturally cooling.
Preferably, the firing temperature in the step e is 1050-1100 ℃.
Preferably, the firing schedule of the step f is as follows: heating to 800 ℃ within 8-12 hours, preserving heat for 4-5 hours, and then naturally cooling.
Preferably, the reducing atmosphere is maintained during the heat-preserving sintering process in the step e and the step f.
As can be seen from the description, the red fish-muscle phosphor grain glazed ceramic and the preparation method thereof provided by the invention have the following beneficial effects: manganese oxide in the red fish scale base glaze has strong crystallization capability and large crystal form, and dark brownish red fish scale grains are formed after firing; the iron oxide in the overglaze and the zirconia in the ground glaze form zircon with zircon red at the intersection surface, so that the scale pattern is strengthened, and the scale pattern is converted from dark brownish red to pink, so that the color is brighter; the sodium fluoride is taken as a mineralizer, and has strong mineralization effect, so that the iron oxide and the zirconia at the junction of the ground glaze and the surface glaze are combined to form a stable ferrozirconium red compound, thereby playing a role in brightening scale marks in the ground glaze; part of polyvinyl chloride powder in the overglaze is decomposed and volatilized in the glaze firing process, part of the polyvinyl chloride powder is not completely decomposed and remains in the glaze, and blackening and graying are caused by carbon deposition of organic matters in a reducing atmosphere to form light gray spots in a local range; after back firing, the original light gray spots are continuously enlarged, the color tone is different, the whole shape is similar to the red fish phosphorus stripe glaze effect with the spots, and the red fish phosphorus stripe glaze has unique aesthetic feeling.
Detailed Description
The invention is further described below by means of specific embodiments.
The invention is further described in connection with the following detailed description, in order to make the technical means, the creation characteristics, the achievement of the purpose and the effect of the invention easy to understand.
The invention relates to a red fish-colored phosphorus-pattern glazed ceramic, which comprises a green body, wherein the surface of the green body is covered with a glaze, the glaze comprises red fish-colored ground glaze and gray-colored overglaze, and the glaze is distributed with a red fish-colored phosphorus-colored pattern and a red fish phosphorus pattern.
The red fish scale base glaze comprises the following raw materials in parts by weight: 10-12 parts of manganese oxide, 5-7 parts of zirconium oxide, 5-8 parts of stalactite, 2-4 parts of borax, 26-30 parts of potassium feldspar, 18-25 parts of glass, 18-20 parts of quartz, 4-6 parts of limestone, 7-8 parts of kaolin, 2-4 parts of zinc oxide and 4-6 parts of talcum.
As a preferred embodiment, the red fish scale base glaze comprises the following raw materials in parts by weight: 11 parts of manganese oxide, 6 parts of zirconium oxide, 6 parts of stalactite, 3 parts of borax, 27 parts of potassium feldspar, 20 parts of glass, 19 parts of quartz, 5 parts of limestone, 7.5 parts of kaolin, 3 parts of zinc oxide and 5 parts of talcum.
The gray spot overglaze comprises the following raw materials in parts by weight: 20-25 parts of sodium fluoride, 20-25 parts of quartz, 3-4 parts of polyvinyl chloride powder, 6-8 parts of yellow ferric hydroxide, 20-25 parts of feldspar, 5-8 parts of bentonite and 12-15 parts of Suzhou soil.
As a preferred embodiment, the raw materials of the gray-spot overglaze comprise the following components in parts by weight: 22 parts of sodium fluoride, 22 parts of quartz, 3.5 parts of polyvinyl chloride powder, 7 parts of yellow ferric hydroxide, 22 parts of feldspar, 6 parts of bentonite and 13 parts of Suzhou soil.
The preparation method of the phospho-pattern glazed ceramic for the red fish with the flower spots comprises the following steps:
step a, preparing a blank body and drying;
b, applying a red fish scale base coat on the green body;
step c, firing in a kiln, taking out the ceramic, and forming brownish red scale patterns on the red fish scale ground glaze; manganese oxide in the red fish scale base glaze has strong crystallization capability and large crystal form, and forms fish scale grains after firing, but the color is dark and brownish red, and zircon in the base glaze is colorless.
Step d, applying gray spot overglaze on the red fish scale underglaze;
and e, re-firing in a kiln, taking out the ceramic, converting the scale patterns on the glaze from brownish red to pink, and generating grey spots. The iron oxide in the overglaze and the zirconia in the ground glaze form zircon with zircon red at the intersection surface, so that the scale pattern is strengthened, and the scale pattern is converted from dark brownish red to pink, so that the color is brighter; the sodium fluoride is taken as a mineralizer, and has strong mineralization effect, so that the iron oxide and the zirconia at the junction of the ground glaze and the surface glaze are combined to form a stable ferrozirconium red compound, thereby playing a role in brightening scale marks in the ground glaze; the polyvinyl chloride powder in the overglaze is partially decomposed and volatilized in the glaze firing process, and partially incompletely decomposed and remained in the glaze, and blackening and graying are caused by carbon deposition of organic matters in a reducing atmosphere to form light gray spots in a local range, so that the area of the formed spots is smaller.
F, returning to the kiln, and expanding the range of the mottle on the glaze after returning to the kiln. After back firing, the original light gray spots are continuously enlarged, the color tone is different, the whole shape of the red fish phosphorus pattern glaze with the spots is similar to the red fish phosphorus pattern glaze with the spots, and the red fish phosphorus pattern glaze has unique aesthetic feeling; in the process of back firing, the iron oxide and the zirconia at the junction of the ground glaze and the surface glaze are further mixed to form more zirconium iron red compounds.
Wherein, the firing schedule of the step c is as follows: heating to 1200-1250 ℃ within 4-5 hours, cooling to 1050-1100 ℃ within 30-40 minutes, preserving heat for 3-4 hours, and then naturally cooling. Firstly, quickly heating to the highest firing temperature, then quickly cooling to the crystallization heat preservation temperature in a short time, and preserving heat at the crystallization temperature to enable crystals to fully develop, and then slowly cooling to enable manganese oxide and zircon crystals in the base glaze to fully develop.
The sintering temperature in the step e is 1050-1100 ℃, the temperature is kept for 2-3 hours, and the sintering temperature in the step e is lower than that in the step c, so that the crystals in the glaze are prevented from being damaged.
The firing schedule of the step f is as follows: heating to 800 ℃ within 8-12 hours, preserving heat for 4-5 hours, and then naturally cooling. The area of the light gray flower spots formed by the carbon deposition of the organic matters is enlarged by slowly heating and slowly cooling, and the aim of the step is to enlarge the area of the flower spots, so that the temperature for heat preservation is further reduced.
And e, maintaining a reducing atmosphere in the heat-preserving sintering process in the step f, so that the carbon deposition of the organic matters is effectively reserved.
The foregoing is merely a few specific embodiments of the present invention, but the design concept of the present invention is not limited thereto, and any insubstantial modification of the present invention by using the concept should be construed as infringement of the protection scope of the present invention.
Claims (10)
1. The red fish-colored phosphorus-pattern glazed ceramic is characterized in that: the red fish scale glaze comprises a green body, wherein the surface of the green body is covered with a glaze surface, the glaze surface comprises red fish scale ground glaze and gray spot overglaze, and the glaze surface is distributed with flower spot textures and red fish phosphorus textures.
2. The red fish-strip phospho-glaze ceramic according to claim 1, wherein: the red fish scale base glaze comprises the following raw materials in parts by weight: 10-12 parts of manganese oxide, 5-7 parts of zirconium oxide, 5-8 parts of stalactite, 2-4 parts of borax, 26-30 parts of potassium feldspar, 18-25 parts of glass, 18-20 parts of quartz, 4-6 parts of limestone, 7-8 parts of kaolin, 2-4 parts of zinc oxide and 4-6 parts of talcum.
3. The red fish muscle phosphor grain glaze ceramic according to claim 2, wherein: the red fish scale base glaze comprises the following raw materials in parts by weight: 11 parts of manganese oxide, 6 parts of zirconium oxide, 6 parts of stalactite, 3 parts of borax, 27 parts of potassium feldspar, 20 parts of glass, 19 parts of quartz, 5 parts of limestone, 7.5 parts of kaolin, 3 parts of zinc oxide and 5 parts of talcum.
4. The red fish-strip phospho-glaze ceramic according to claim 1, wherein: the gray spot overglaze comprises the following raw materials in parts by weight: 20-25 parts of sodium fluoride, 20-25 parts of quartz, 3-4 parts of polyvinyl chloride powder, 6-8 parts of yellow ferric hydroxide, 20-25 parts of feldspar, 5-8 parts of bentonite and 12-15 parts of Suzhou soil.
5. The red fish-spotted phosphor pattern glazed ceramic according to claim 4, wherein: the gray spot overglaze comprises the following raw materials in parts by weight: 22 parts of sodium fluoride, 22 parts of quartz, 3.5 parts of polyvinyl chloride powder, 7 parts of yellow ferric hydroxide, 22 parts of feldspar, 6 parts of bentonite and 13 parts of Suzhou soil.
6. The method for preparing the garrupa phosphorus streak glazed ceramic according to claims 1-5, comprising the following steps:
step a, preparing a blank body and drying;
b, applying a red fish scale base coat on the green body;
step c, firing in a kiln, taking out the ceramic, and forming brownish red scale patterns on the red fish scale ground glaze;
step d, applying gray spot overglaze on the red fish scale underglaze;
step e, re-firing in a kiln, taking out the ceramic, converting the scale patterns on the glaze from brownish red to pink, and generating grey spots;
f, returning to the kiln, and expanding the range of the mottle on the glaze after returning to the kiln.
7. The red fish-spotted and phosphorus-streaked glazed ceramic and its preparation process as claimed in claim 6, wherein: the firing schedule of the step c is as follows: heating to 1200-1250 ℃ within 4-5 hours, cooling to 1050-1100 ℃ within 30-40 minutes, preserving heat for 3-4 hours, and then naturally cooling.
8. The red fish-spotted and phosphorus-streaked glazed ceramic and its preparation process as claimed in claim 6, wherein: the firing temperature in the step e is 1050-1100 ℃.
9. The red fish-spotted and phosphorus-streaked glazed ceramic and its preparation process as claimed in claim 6, wherein: the firing schedule of the step f is as follows: heating to 800 ℃ within 8-12 hours, preserving heat for 4-5 hours, and then naturally cooling.
10. The red fish-spotted and phosphorus-streaked glazed ceramic and its preparation process as claimed in claim 6, wherein: and e, maintaining a reducing atmosphere in the heat preservation sintering process of the step e and the step f.
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| CN111348891A (en) * | 2020-03-16 | 2020-06-30 | 福建省德化县鸿骏陶瓷有限公司 | Preparation method of ovalbumin ice-cracking glaze porcelain |
| CN115894084A (en) * | 2022-11-10 | 2023-04-04 | 福建省德化非凡陶瓷有限公司 | Dehua high-white porcelain decorated by tortoise back textures and preparation process thereof |
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