CN116730763A - Pesticide fertilizer granule containing chlorantraniliprole and clothianidin - Google Patents

Pesticide fertilizer granule containing chlorantraniliprole and clothianidin Download PDF

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Publication number
CN116730763A
CN116730763A CN202310434318.XA CN202310434318A CN116730763A CN 116730763 A CN116730763 A CN 116730763A CN 202310434318 A CN202310434318 A CN 202310434318A CN 116730763 A CN116730763 A CN 116730763A
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CN
China
Prior art keywords
pesticide
clothianidin
fertilizer granule
chlorantraniliprole
fertilizer
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Pending
Application number
CN202310434318.XA
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Chinese (zh)
Inventor
周志超
蒋华
周艳涵
覃桃
曾贤敏
覃宗武
陆华广
梁勋聂
韦家荣
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Guangxi Shoukong Biotechnology Co ltd
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Guangxi Shoukong Biotechnology Co ltd
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Priority to CN202310434318.XA priority Critical patent/CN116730763A/en
Publication of CN116730763A publication Critical patent/CN116730763A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00Arthropodicides
    • A01P7/04Insecticides
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/10Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12Granules or flakes

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Insects & Arthropods (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Fertilizers (AREA)

Abstract

The invention belongs to the technical field of pesticide fertilizers, and particularly relates to a pesticide fertilizer granule containing chlorantraniliprole and clothianidin and application thereof. The pesticide fertilizer granule containing chlorantraniliprole and clothianidin comprises the following components in percentage by weight: 0.01 to 0.5 percent of chlorantraniliprole, 0.01 to 0.5 percent of clothianidin, 20 to 60 percent of fertilizer, 1 to 10 percent of dispersing auxiliary, 2 to 5 percent of binder and 100 percent of filler. The pesticide fertilizer granule has good control effect on sugarcane borers, and can also prevent other sugarcane pests such as cotton aphids, thrips and the like.

Description

Pesticide fertilizer granule containing chlorantraniliprole and clothianidin
Technical Field
The invention belongs to the technical field of pesticide fertilizers, and particularly relates to a pesticide fertilizer granule containing chlorantraniliprole and clothianidin and application thereof.
Background
Guangxi is an important area for sugar industry development in China, and the planting area of the sugarcane is always stable in the first place in China, so that great contribution is made to sugar material development. In recent years, pests such as sugarcane borers, sugarcane thrips and the like are increasingly serious, and if no good prevention measures are adopted or prevention is not carried out in time, the yield of the sugarcane is affected, so that the yield of the sugarcane is seriously reduced. Especially in the pest damage of sugarcane, the pest damage caused by sugarcane borers is the most serious. The sugarcane borers are commonly called as borers and are mainly distributed in the sugarcane-saving areas of Guangdong, guangxi, yunnan, guizhou, hainan and the like, and the species comprise the borers, the two-point borers, huang Ming, the white borers, the big borers and the like. The sugarcane borers are generated for more than one generation in the year, often, a plurality of borers are generated at the same time, the fertility is strong, the concealment is strong, the generation overlap, the occurrence condition difference is large in each place, the control difficulty is large in production, the sugarcane borers are harmful in the whole growth period, and the seedling period is a dead center seedling caused by a harmful growth point; the drill in the middle and later stages of growth is harmful to the cane stems, damages the tissues of the cane stems, prevents the growth of the cane, reduces the yield and sugar, and causes wind break.
The pesticide agent for sugarcane in the market still has the problems of larger toxicity, serious residue, unstable pesticide effect, harm to natural enemies of organisms, no sugarcane registration and the like. Therefore, research on related problems is carried out, and related products which are more advanced, more stable are developed, produced and popularized, so that the method has very important significance for safe, efficient and stable production of sugarcane.
Disclosure of Invention
The invention discloses a pesticide fertilizer granule containing chlorantraniliprole and clothianidin, and application thereof.
The technical scheme provided by the invention is as follows:
the pesticide fertilizer granule containing chlorantraniliprole and clothianidin comprises the following components in percentage by weight: 0.01-0.5% of chlorantraniliprole, 0.01-0.5% of clothianidin, 20-60% of fertilizer, 1-10% of dispersing auxiliary, 2-5% of binder and 100% of filler; the fertilizer comprises the following components in percentage by weight: 1-15% of urea, 1-15% of ammonium chloride, 1-15% of monoammonium phosphate, 1-15% of diammonium phosphate and 1-20% of potassium chloride.
Preferably, the fertilizer comprises the following components in percentage by weight: urea 5-12%, ammonium chloride 5-12%, monoammonium phosphate 5-12%, diammonium phosphate 5-12% and potassium chloride 5-15%.
Preferably, the carrier is a mixture of white carbon black and attapulgite, and the mass ratio of the white carbon black to the attapulgite is 10:1-1:10.
Preferably, the dispersing auxiliary is one or more of Tersperse2700 and Morwet D-425; the binder is polyvinyl alcohol.
Preferably, the dispersing aid is a combination of Tersperse2700 and Morwet D-425, and the mass ratio of the Tersperse2700 to the Morwet D-425 is 10:1-1:10.
Preferably, in the pesticide fertilizer granule, the chlorantraniliprole accounts for 0.04 percent and the clothianidin accounts for 0.12 percent.
The invention also provides application of the pesticide fertilizer granule in controlling sugarcane pests.
Preferably, the insect pest is stem borer or thrips.
Compared with the prior art, the invention has the following beneficial effects:
(1) The pesticide fertilizer granule prepared by the invention has better prevention effect on sugarcane borers, and also can prevent cotton aphids, thrips and the like.
(2) The pesticide fertilizer granule prepared by the invention provides sufficient nutrients and medium trace elements for the sugarcane, promotes the developed and comprehensive growth of the root system of the sugarcane, and increases the node length, sugar content and weight of the sugarcane. Helps to increase the yield of sugarcane farmers and promote the benefit of sugar factories.
(3) The medicine fertilizer granules prepared by the invention have synergistic effect and the fertilizer is constructed at one time, so that the purposes of labor saving and effort saving are achieved.
(4) The prepared pesticide fertilizer granule can improve the absorption and utilization rate of the fertilizer and reduce the chemical quantity and the pesticide consumption.
(5) The pesticide fertilizer granule prepared by the invention has excellent preparation performance, so that the stability of the active ingredients is improved.
Detailed Description
The invention will be better understood from the following examples. However, it will be readily appreciated by those skilled in the art that the examples are described for illustrative purposes only and should not limit the invention as described in detail in the claims
Example 1: influence of different carriers on the stability of pesticide fertilizer granules
The preparation process comprises the following steps: the raw materials, the carrier, the fertilizer (N, P, K) and the auxiliary agent are weighed according to a certain proportion, uniformly mixed, added with the adhesive for kneading, granulated, dried at 60 ℃ for 8min, and screened to obtain the finished product.
The specific formula is as follows: the raw materials are as follows: 0.04% of chlorantraniliprole and 0.12% of clothianidin; dispersant nekal BX (Shanghai spectral vibration Biotechnology Co., ltd.) 6%; 5% of binder polyvinyl alcohol (Shanghai Ala Biochemical technology Co., ltd.); and (3) fertilizer: 15% of urea, 15% of monoammonium phosphate and 10% of potassium chloride; and (3) a carrier: the complement is 100 percent.
The testing method comprises the following steps: the measurement was performed as "2.3 other preparations" in GB/T19136-2003. After the sample is cooled to room temperature, the mass fraction of the active ingredients in the sample is determined within 24 hours, and the active ingredients are separated and determined by high performance liquid chromatography.
TABLE 1 influence of different carriers on the stability of pesticide fertilizer granules
From table 1, it can be seen that different carriers have a certain influence on the active ingredients of chlorantraniliprole and clothianidin, wherein bentonite and diatomite have a large influence on the stability of the chlorantraniliprole, and are not suitable for preparing the pesticide fertilizer granules. The kaolin, white carbon black, diatomite, attapulgite and bentonite have little influence on the stability of clothianidin; in particular to an attapulgite system, the decomposition rate of clothianidin is only 4.10 percent.
TABLE 2 influence of different carrier combinations on the stability of pesticide fertilizer granules
As can be seen from table 2, when the carrier white carbon black and the attapulgite are used in combination, the stability of the active ingredients can be complemented to a certain extent compared with the carrier alone; and the proportion between the white carbon black and the attapulgite is 10:1-1: when 10, the decomposition rate of chlorantraniliprole is between 5.22 and 5.74 percent, and the decomposition rate of clothianidin is between 4.35 and 4.72 percent. No antagonism appears between carrier compounding, and no significant improvement of the active decomposition rate is caused.
Example 2: influence of different fertilizer and carrier combinations on stability of active ingredient
The preparation process comprises the following steps: the raw materials, the binder, the carrier, the fertilizer and the auxiliary agent are weighed according to a certain proportion, then evenly mixed, added with the binder for kneading, granulated, dried at 60 ℃ for 8min, and screened to obtain the finished product.
The specific formula is as follows:
the raw materials are as follows: 0.04% of chlorantraniliprole and 0.12% of clothianidin; dispersant nekal BX (Shanghai spectral vibration Biotechnology Co., ltd.) 6%; 5% of binder polyvinyl alcohol (Shanghai Ala Biochemical technology Co., ltd.); and (3) fertilizer: 15%; the carrier (white carbon + attapulgite = 1:1) complements 100%.
The testing method comprises the following steps: the measurement was performed as "2.3 other preparations" in GB/T19136-2003. After the sample is cooled to room temperature, the mass fraction of the active ingredients in the sample is determined within 24 hours, and the active ingredients are separated and determined by high performance liquid chromatography.
TABLE 3 influence of several common fertilizers on the stability of active ingredients
As can be seen from table 3, the calcium magnesium phosphate fertilizer has a larger influence on the stability of the active ingredient chlorantraniliprole; the stability of the active ingredient clothianidin is greatly influenced by the ammonium sulfate; the rest urea, ammonium chloride, ammonium sulfate, monoammonium phosphate, diammonium phosphate and potassium chloride have little influence on the stability of the active ingredients.
Example 3:influence of different dispersants on the stability of pesticide fertilizer granules
The preparation process comprises the following steps: the raw materials, the binder, the carrier, the fertilizer (N, P, K) and the auxiliary agent are weighed according to a certain proportion, uniformly mixed, kneaded by the binder, granulated, dried at 60 ℃ for 8min, and screened to obtain the finished product.
The testing method comprises the following steps: the measurement was performed as "2.3 other preparations" in GB/T19136-2003. After the sample is cooled to room temperature, the mass fraction of the active ingredients in the sample is determined within 24 hours, and the active ingredients are separated and determined by high performance liquid chromatography.
Table 4 0.16% chlorantraniliprole clothianidin pesticide fertilizer granule formulation
As can be seen from table 4, the selection of the dispersing aid has a certain effect on the stability of the active ingredient; the dispersing agent is Tersperse2700 or Morwet D-425, which can reduce the decomposition of the active ingredient, especially when Tersperse2700 or Morwet D-425 is combined, the decomposition of the active ingredient can be obviously reduced.
Example 4: pesticide fertilizer granule with control effect on sugarcane borer
Experiment design: trial was located in the nan Ning, guangxi province, miscaning area of sugarcane seeds, 37013The planting garden is characterized in that the sugarcane field is a hillside terrace, the fertility is moderate, the soil type is purple sandy loam formed by weathering sandy surface rocks, and the soil layer is loose. The experiment was set up with 3 treatments, each repeated 3 times. Each cell area is 45m 2 A random block arrangement is used. Isolation lines are arranged between the blocks and between the cells, and protection lines are arranged around the isolation lines. The application time is that when the pesticide is applied during the root loosening, weeding and hilling of the seedling stage of the sugarcane, a small ditch is dug around the planting hole of the sugarcane, the pesticide is spread into the ditch according to the set treatment dosage of the pesticide, and the pesticide is completely covered by a soil layer. The blank area is only hilled, and no chemical and fertilizer are applied. And (5) investigation is carried out 45 days after the medicine, and data such as the total seedling number, the withered core seedling number and the like of the sugarcane in each cell are investigated.
The calculation formula is as follows:
withered heart rate (%) = number of withered heart seedlings/total number of seedlings x 100%;
relative control (%) = (control withered rate-treated withered rate)/control withered rate x 100%.
Table 5 effects of the pesticide fertilizer granules on preventing and controlling sugarcane borer
As shown in Table 5, the pesticide fertilizer granule prepared by the invention has excellent control effect on sugarcane borers, and the control effect is more than 88%.
The foregoing is merely a preferred embodiment of the present invention, and it will be apparent to those skilled in the art that modifications may be made without departing from the scope of the invention.

Claims (7)

1. The pesticide fertilizer granule containing chlorantraniliprole and clothianidin is characterized by comprising the following components in percentage by weight: 0.01-0.5% of chlorantraniliprole, 0.01-0.5% of clothianidin, 20-60% of fertilizer, 1-10% of dispersing auxiliary, 2-5% of binder and 100% of filler;
the fertilizer comprises the following components in percentage by weight: 1-15% of urea, 1-15% of ammonium chloride, 1-15% of monoammonium phosphate, 1-15% of diammonium phosphate and 1-20% of potassium chloride.
2. The medical fertilizer granule of claim 1, wherein the carrier is a mixture of white carbon black and attapulgite, and the mass ratio of the white carbon black to the attapulgite is 10:1-1:10.
3. The pesticide-fertilizer granule of claim 1, wherein the dispersing aid is one or more of Tersperse2700 and Morwet D-425; the binder is polyvinyl alcohol.
4. The pesticide fertilizer granule of claim 4, wherein the dispersing aid is a combination of Tersperse2700 and Morwet D-425 in a mass ratio of 10:1-1:10.
5. The pesticide-fertilizer granule of claim 1, wherein the chlorantraniliprole is 0.04% and the clothianidin is 0.12%.
6. Use of the pesticide-fertilizer granule according to any one of claims 1 to 5 for controlling sugarcane pests.
7. The use according to claim 6, wherein the pest is stem borer or thrips.
CN202310434318.XA 2023-04-21 2023-04-21 Pesticide fertilizer granule containing chlorantraniliprole and clothianidin Pending CN116730763A (en)

Priority Applications (1)

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CN202310434318.XA CN116730763A (en) 2023-04-21 2023-04-21 Pesticide fertilizer granule containing chlorantraniliprole and clothianidin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310434318.XA CN116730763A (en) 2023-04-21 2023-04-21 Pesticide fertilizer granule containing chlorantraniliprole and clothianidin

Publications (1)

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CN116730763A true CN116730763A (en) 2023-09-12

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