CN116282965A - 具有深的压缩深度的强化玻璃 - Google Patents
具有深的压缩深度的强化玻璃 Download PDFInfo
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- CN116282965A CN116282965A CN202310075381.9A CN202310075381A CN116282965A CN 116282965 A CN116282965 A CN 116282965A CN 202310075381 A CN202310075381 A CN 202310075381A CN 116282965 A CN116282965 A CN 116282965A
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- Prior art keywords
- glass
- mol
- depth
- compressive stress
- glass article
- Prior art date
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Links
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- 238000007906 compression Methods 0.000 title claims abstract description 81
- 239000006058 strengthened glass Substances 0.000 title abstract description 57
- 238000012360 testing method Methods 0.000 claims abstract description 47
- 238000007679 ring-on-ring test Methods 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims description 242
- 239000005358 alkali aluminosilicate glass Substances 0.000 claims description 38
- 230000007704 transition Effects 0.000 claims description 21
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
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- 238000000034 method Methods 0.000 abstract description 39
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 41
- 229910052593 corundum Inorganic materials 0.000 description 41
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- 150000002500 ions Chemical class 0.000 description 38
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- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 33
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 29
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 27
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 26
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 25
- 229910052681 coesite Inorganic materials 0.000 description 22
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- 230000006399 behavior Effects 0.000 description 14
- 150000001768 cations Chemical class 0.000 description 14
- 239000012634 fragment Substances 0.000 description 14
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 13
- 235000010344 sodium nitrate Nutrition 0.000 description 13
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 12
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 12
- 238000005259 measurement Methods 0.000 description 12
- 235000010333 potassium nitrate Nutrition 0.000 description 12
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 12
- 229910052700 potassium Inorganic materials 0.000 description 11
- 101100233916 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) KAR5 gene Proteins 0.000 description 10
- 230000003287 optical effect Effects 0.000 description 10
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 9
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- 239000011591 potassium Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
- 239000003513 alkali Substances 0.000 description 7
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- 230000006870 function Effects 0.000 description 6
- 239000005368 silicate glass Substances 0.000 description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 6
- 229910001413 alkali metal ion Inorganic materials 0.000 description 5
- 239000002241 glass-ceramic Substances 0.000 description 5
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- 229910001409 divalent cation oxide Inorganic materials 0.000 description 4
- 238000013467 fragmentation Methods 0.000 description 4
- 238000006062 fragmentation reaction Methods 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052701 rubidium Inorganic materials 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 229910052845 zircon Inorganic materials 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229910052788 barium Inorganic materials 0.000 description 3
- 229910052792 caesium Inorganic materials 0.000 description 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 3
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910001414 potassium ion Inorganic materials 0.000 description 3
- 238000007655 standard test method Methods 0.000 description 3
- 229910052712 strontium Inorganic materials 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
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- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
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- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
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- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
- 230000003678 scratch resistant effect Effects 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- 150000003388 sodium compounds Chemical class 0.000 description 2
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- CAOSCCRYLYQBES-UHFFFAOYSA-N 2-[[[4-hydroxy-2-oxo-1-(phenylmethyl)-3-quinolinyl]-oxomethyl]amino]acetic acid Chemical compound O=C1C(C(=O)NCC(=O)O)=C(O)C2=CC=CC=C2N1CC1=CC=CC=C1 CAOSCCRYLYQBES-UHFFFAOYSA-N 0.000 description 1
- JGRPKOGHYBAVMW-UHFFFAOYSA-N 8-hydroxy-5-quinolinecarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(O)C2=N1 JGRPKOGHYBAVMW-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- KOPBYBDAPCDYFK-UHFFFAOYSA-N Cs2O Inorganic materials [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 description 1
- 229910000760 Hardened steel Inorganic materials 0.000 description 1
- 101000827703 Homo sapiens Polyphosphoinositide phosphatase Proteins 0.000 description 1
- 102100023591 Polyphosphoinositide phosphatase Human genes 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
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- AKUNKIJLSDQFLS-UHFFFAOYSA-M dicesium;hydroxide Chemical compound [OH-].[Cs+].[Cs+] AKUNKIJLSDQFLS-UHFFFAOYSA-M 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
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- 150000002823 nitrates Chemical class 0.000 description 1
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- 229910001953 rubidium(I) oxide Inorganic materials 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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- 238000005406 washing Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N3/00—Investigating strength properties of solid materials by application of mechanical stress
- G01N3/30—Investigating strength properties of solid materials by application of mechanical stress by applying a single impulsive force, e.g. by falling weight
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Surface Treatment Of Glass (AREA)
- Investigating Strength Of Materials By Application Of Mechanical Stress (AREA)
- Glass Compositions (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462029075P | 2014-07-25 | 2014-07-25 | |
| US62/029,075 | 2014-07-25 | ||
| CN201580040362.6A CN107108345B (zh) | 2014-07-25 | 2015-07-24 | 具有深的压缩深度的强化玻璃 |
| PCT/US2015/041976 WO2016014937A1 (en) | 2014-07-25 | 2015-07-24 | Strengthened glass with deep depth of compression |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580040362.6A Division CN107108345B (zh) | 2014-07-25 | 2015-07-24 | 具有深的压缩深度的强化玻璃 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116282965A true CN116282965A (zh) | 2023-06-23 |
Family
ID=53836826
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310075381.9A Pending CN116282965A (zh) | 2014-07-25 | 2015-07-24 | 具有深的压缩深度的强化玻璃 |
| CN201810631709.XA Active CN108609866B (zh) | 2014-07-25 | 2015-07-24 | 具有深的压缩深度的强化玻璃 |
| CN201580040362.6A Active CN107108345B (zh) | 2014-07-25 | 2015-07-24 | 具有深的压缩深度的强化玻璃 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810631709.XA Active CN108609866B (zh) | 2014-07-25 | 2015-07-24 | 具有深的压缩深度的强化玻璃 |
| CN201580040362.6A Active CN107108345B (zh) | 2014-07-25 | 2015-07-24 | 具有深的压缩深度的强化玻璃 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP3169639B1 (enExample) |
| JP (2) | JP2017527513A (enExample) |
| KR (2) | KR20170036067A (enExample) |
| CN (3) | CN116282965A (enExample) |
| DK (1) | DK3169639T3 (enExample) |
| WO (1) | WO2016014937A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117292612A (zh) * | 2023-09-08 | 2023-12-26 | 昆山国显光电有限公司 | 盖板及显示面板 |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9359251B2 (en) | 2012-02-29 | 2016-06-07 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
| US9517968B2 (en) | 2014-02-24 | 2016-12-13 | Corning Incorporated | Strengthened glass with deep depth of compression |
| TWI697403B (zh) | 2014-06-19 | 2020-07-01 | 美商康寧公司 | 無易碎應力分布曲線的玻璃 |
| CN206580739U (zh) | 2014-10-08 | 2017-10-24 | 康宁股份有限公司 | 玻璃基制品 |
| US10150698B2 (en) * | 2014-10-31 | 2018-12-11 | Corning Incorporated | Strengthened glass with ultra deep depth of compression |
| DK3215471T3 (da) | 2014-11-04 | 2022-01-17 | Corning Inc | Dybe, ubrydelige belastningsprofiler og fremgangsmåde til fremstilling |
| US11613103B2 (en) | 2015-07-21 | 2023-03-28 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| US9701569B2 (en) | 2015-07-21 | 2017-07-11 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| TWI722069B (zh) | 2015-12-08 | 2021-03-21 | 美商康寧公司 | S型應力輪廓及製造方法 |
| KR102393206B1 (ko) | 2015-12-11 | 2022-05-03 | 코닝 인코포레이티드 | 금속 산화물 농도 구배를 포함하는 융합-형성가능한 유리계 제품 |
| CN109071316B (zh) | 2016-04-08 | 2020-03-27 | 康宁股份有限公司 | 包含金属氧化物浓度梯度的玻璃基制品 |
| EP3397597B1 (en) * | 2016-04-08 | 2023-11-08 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions, and methods of making |
| US11059744B2 (en) * | 2016-06-14 | 2021-07-13 | Corning Incorporated | Glasses having improved drop performance |
| KR20190112273A (ko) * | 2017-02-07 | 2019-10-04 | 에이지씨 가부시키가이샤 | 화학 강화 유리 |
| US11691911B2 (en) * | 2017-04-13 | 2023-07-04 | Samsung Display Co., Ltd. | Reinforced window member and method of manufacturing the same |
| US11795103B2 (en) | 2017-10-17 | 2023-10-24 | PGBC Intellectual Holdings, LLC | Chemically-strengthened thin glass substrates new paradigms for modified curvature and methods of manufacture |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN108609866B (zh) | 2021-12-07 |
| DK3169639T3 (da) | 2022-01-03 |
| KR20200045575A (ko) | 2020-05-04 |
| KR20170036067A (ko) | 2017-03-31 |
| EP3169639B1 (en) | 2021-11-10 |
| EP3169639A1 (en) | 2017-05-24 |
| JP2017527513A (ja) | 2017-09-21 |
| CN107108345A (zh) | 2017-08-29 |
| JP2020111504A (ja) | 2020-07-27 |
| WO2016014937A1 (en) | 2016-01-28 |
| CN108609866A (zh) | 2018-10-02 |
| CN107108345B (zh) | 2023-02-07 |
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