CN116097468A - 正极材料、正极极片、锂二次电池、电池模块、电池包及装置 - Google Patents
正极材料、正极极片、锂二次电池、电池模块、电池包及装置 Download PDFInfo
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- CN116097468A CN116097468A CN202080104510.7A CN202080104510A CN116097468A CN 116097468 A CN116097468 A CN 116097468A CN 202080104510 A CN202080104510 A CN 202080104510A CN 116097468 A CN116097468 A CN 116097468A
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- positive electrode
- active material
- electrode active
- battery
- iron phosphate
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- Secondary Cells (AREA)
Abstract
本申请涉及一种正极材料、正极极片、锂二次电池、电池模块、电池包及装置。本申请所涉及的正极材料包含磷酸铁锂单晶颗粒和磷酸铁锂二次颗粒。其中,磷酸铁锂二次颗粒具有低比表面积,可减少制浆过程中对粘结剂和溶剂的消耗、提升浆料固含量,提升厚涂布极片的加工性能。同时,磷酸铁锂单晶充分填充到磷酸铁锂二次颗粒的颗粒间隙中,可进一步提升极片的压实密度,同时降低正极极片的膜片电阻,从而提高锂二次电池的克容量发挥和循环性能。
Description
PCT国内申请,说明书已公开。
Claims (14)
- PCT国内申请,权利要求书已公开。
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PCT/CN2020/113286 WO2022047705A1 (zh) | 2020-09-03 | 2020-09-03 | 正极材料、正极极片、锂二次电池、电池模块、电池包及装置 |
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CN116097468A true CN116097468A (zh) | 2023-05-09 |
CN116097468A8 CN116097468A8 (zh) | 2024-05-24 |
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US (1) | US20230108289A1 (zh) |
EP (1) | EP4170755A4 (zh) |
CN (1) | CN116097468A (zh) |
WO (1) | WO2022047705A1 (zh) |
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EP4318672A4 (en) * | 2022-04-27 | 2024-09-04 | Contemporary Amperex Technology Co Ltd | LITHIUM-IRON-PHOSPHATE POSITIVE ELECTRODE PLATE AND SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK AND ELECTRICAL DEVICE THEREFOR |
CN115832183A (zh) * | 2022-05-05 | 2023-03-21 | 宁德时代新能源科技股份有限公司 | 正极极片及其制备方法、二次电池、电池模块、电池包及用电装置 |
CN115472898B (zh) * | 2022-10-27 | 2023-09-15 | 欣旺达动力科技股份有限公司 | 一种二次电池及用电设备 |
KR20240088617A (ko) * | 2022-12-13 | 2024-06-20 | 주식회사 엘지화학 | 양극 및 이를 포함하는 리튬 이차전지 |
CN117355974A (zh) * | 2023-02-23 | 2024-01-05 | 宁德时代新能源科技股份有限公司 | 二次电池及包含其的用电装置 |
CN115986056B (zh) * | 2023-03-17 | 2023-06-13 | 宁德新能源科技有限公司 | 二次电池及电子装置 |
CN117727914B (zh) * | 2024-02-07 | 2024-05-14 | 晶科储能科技有限公司 | 正极材料及其制备方法、二次电池 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008159495A (ja) * | 2006-12-26 | 2008-07-10 | Hitachi Maxell Ltd | リチウムイオン二次電池用正極活物質およびその製造方法 |
CN105185982A (zh) * | 2015-08-31 | 2015-12-23 | 宁波金和锂电材料有限公司 | 一种正极材料及其制备方法和锂离子电池 |
CN109309227A (zh) * | 2017-07-26 | 2019-02-05 | 宁德时代新能源科技股份有限公司 | 锂离子电池及其正极活性材料 |
CN111384372A (zh) * | 2018-12-29 | 2020-07-07 | 宁德时代新能源科技股份有限公司 | 一种高压实密度正极材料及电化学储能装置 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE556447T1 (de) * | 2006-12-26 | 2012-05-15 | Santoku Corp | Positivelektroden-aktivmaterial für eine sekundärbatterie mit wasserfreiem elektrolyt, positivelektrode und sekundärbatterie |
CN102306791B (zh) * | 2011-08-18 | 2014-08-06 | 合肥国轩高科动力能源股份公司 | 一种碳包覆非化学计量比氧化锂铁磷材料的制备方法 |
CN104505493B (zh) * | 2014-12-05 | 2017-01-04 | 东莞新能源科技有限公司 | 一种锂离子电池正极材料的制备方法及应用 |
JP2018049775A (ja) * | 2016-09-23 | 2018-03-29 | トヨタ自動車株式会社 | 非水電解質二次電池 |
CN109301179A (zh) * | 2018-08-22 | 2019-02-01 | 江苏元景锂粉工业有限公司 | 一种锂电池用磷酸铁锂正极材料及其制备方法 |
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2020
- 2020-09-03 WO PCT/CN2020/113286 patent/WO2022047705A1/zh active Application Filing
- 2020-09-03 EP EP20951952.9A patent/EP4170755A4/en active Pending
- 2020-09-03 CN CN202080104510.7A patent/CN116097468A/zh active Pending
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2022
- 2022-12-08 US US18/063,623 patent/US20230108289A1/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008159495A (ja) * | 2006-12-26 | 2008-07-10 | Hitachi Maxell Ltd | リチウムイオン二次電池用正極活物質およびその製造方法 |
CN105185982A (zh) * | 2015-08-31 | 2015-12-23 | 宁波金和锂电材料有限公司 | 一种正极材料及其制备方法和锂离子电池 |
CN109309227A (zh) * | 2017-07-26 | 2019-02-05 | 宁德时代新能源科技股份有限公司 | 锂离子电池及其正极活性材料 |
CN111384372A (zh) * | 2018-12-29 | 2020-07-07 | 宁德时代新能源科技股份有限公司 | 一种高压实密度正极材料及电化学储能装置 |
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US20230108289A1 (en) | 2023-04-06 |
WO2022047705A1 (zh) | 2022-03-10 |
EP4170755A1 (en) | 2023-04-26 |
EP4170755A4 (en) | 2023-08-16 |
CN116097468A8 (zh) | 2024-05-24 |
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Correction item: PCT international application to national stage day Correct: 2023.01.30 False: 2023.01.29 Number: 19-01 Page: The title page Volume: 39 Correction item: PCT international application to national stage day Correct: 2023.01.30 False: 2023.01.29 Number: 19-01 Volume: 39 |