CN116096674A - 氢气方法 - Google Patents

氢气方法 Download PDF

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Publication number
CN116096674A
CN116096674A CN202180063000.4A CN202180063000A CN116096674A CN 116096674 A CN116096674 A CN 116096674A CN 202180063000 A CN202180063000 A CN 202180063000A CN 116096674 A CN116096674 A CN 116096674A
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China
Prior art keywords
gas
hydrogen
catalyst
content
range
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Pending
Application number
CN202180063000.4A
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English (en)
Chinese (zh)
Inventor
崔友馨
M·加西亚
P·E·格伦
N·麦克劳德
N·米斯特里
M·T·尼克尔森
S·罗洛夫-斯坦德林
托马斯·史密斯
H·E·斯坦内斯
M·A·斯坦威
K·尤恩丁
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Johnson Matthey Davy Technologies Ltd
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Johnson Matthey PLC
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Publication of CN116096674A publication Critical patent/CN116096674A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/12—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/005—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CN202180063000.4A 2020-10-09 2021-09-14 氢气方法 Pending CN116096674A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB2016050.3A GB202016050D0 (en) 2020-10-09 2020-10-09 Hydrogen process
GB2016050.3 2020-10-09
PCT/GB2021/052374 WO2022074356A1 (en) 2020-10-09 2021-09-14 Hydrogen process

Publications (1)

Publication Number Publication Date
CN116096674A true CN116096674A (zh) 2023-05-09

Family

ID=73460453

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202180063000.4A Pending CN116096674A (zh) 2020-10-09 2021-09-14 氢气方法

Country Status (12)

Country Link
US (1) US20230303392A1 (enExample)
EP (1) EP4225696A1 (enExample)
JP (1) JP7828331B2 (enExample)
KR (1) KR20230088681A (enExample)
CN (1) CN116096674A (enExample)
AU (1) AU2021358460A1 (enExample)
BR (1) BR112023004839A2 (enExample)
CA (1) CA3189868A1 (enExample)
GB (2) GB202016050D0 (enExample)
MX (1) MX2023003330A (enExample)
UA (1) UA130629C2 (enExample)
WO (1) WO2022074356A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12534676B2 (en) * 2022-10-07 2026-01-27 CLEAN ENERGY ENTERPRISES Inc. Device for making hydrogen from heterogenous waste
US12565423B2 (en) 2023-01-26 2026-03-03 Valero Services, Inc. Process for producing hydrogen from natural gas

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000126597A (ja) * 1998-10-28 2000-05-09 Agency Of Ind Science & Technol 一酸化炭素転化触媒および該触媒を用いる一酸化炭素転化方法
US6303092B1 (en) * 1995-04-10 2001-10-16 Air Products And Chemicals, Inc. Process for operating equilibrium controlled reactions
US20120202681A1 (en) * 2009-06-17 2012-08-09 Johnson Matthey Plc Carbon oxides conversion process
CN102695669A (zh) * 2009-11-05 2012-09-26 约翰森·马瑟公开有限公司 水煤气变换反应方法
US20150111975A1 (en) * 2012-06-04 2015-04-23 Mitsui Chemicals, Inc. Catalyst for methanol production, method of producing the same and process of methanol production
US20200087576A1 (en) * 2018-09-18 2020-03-19 Gas Technology Institute Processes and catalysts for reforming of impure methane-containing feeds

Family Cites Families (9)

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GB8512684D0 (en) 1985-05-20 1985-06-26 Ici Plc Oxidation process
JP2007313487A (ja) * 2006-05-29 2007-12-06 National Institute Of Advanced Industrial & Technology 水性ガス転化反応用触媒及びそれを用いた水性ガス転化反応方法。
GB0816709D0 (en) 2008-09-12 2008-10-22 Johnson Matthey Plc Shaped heterogeneneous catalysts
GB201522396D0 (en) * 2015-12-18 2016-02-03 Johnson Matthey Plc Process
US11027984B2 (en) * 2017-03-07 2021-06-08 Haldor Topsoe A/S Urea process with controlled excess of CO2 and/or NH3
GB2571136A (en) * 2018-02-20 2019-08-21 Reinertsen New Energy As Gas processing
KR102199485B1 (ko) * 2018-10-18 2021-01-06 연세대학교 원주산학협력단 일단 수성가스 전이 반응을 위한 촉매의 제조 방법
CN112206763A (zh) * 2019-07-12 2021-01-12 中石化南京化工研究院有限公司 一种铜系低温变换催化剂及其制备方法
WO2021189137A1 (en) * 2020-03-23 2021-09-30 G4 Insights Inc. Hydrogen production with sequestration

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6303092B1 (en) * 1995-04-10 2001-10-16 Air Products And Chemicals, Inc. Process for operating equilibrium controlled reactions
JP2000126597A (ja) * 1998-10-28 2000-05-09 Agency Of Ind Science & Technol 一酸化炭素転化触媒および該触媒を用いる一酸化炭素転化方法
US20120202681A1 (en) * 2009-06-17 2012-08-09 Johnson Matthey Plc Carbon oxides conversion process
CN102695669A (zh) * 2009-11-05 2012-09-26 约翰森·马瑟公开有限公司 水煤气变换反应方法
US20150111975A1 (en) * 2012-06-04 2015-04-23 Mitsui Chemicals, Inc. Catalyst for methanol production, method of producing the same and process of methanol production
US20200087576A1 (en) * 2018-09-18 2020-03-19 Gas Technology Institute Processes and catalysts for reforming of impure methane-containing feeds

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张高良: "《工业催化剂的生产》", 31 December 1988, 上海科学技术出版社, pages: 297 *

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GB2600238B (en) 2024-06-05
JP7828331B2 (ja) 2026-03-11
KR20230088681A (ko) 2023-06-20
JP2023544675A (ja) 2023-10-25
GB2600238A (en) 2022-04-27
BR112023004839A2 (pt) 2023-04-18
US20230303392A1 (en) 2023-09-28
UA130629C2 (uk) 2026-04-01
EP4225696A1 (en) 2023-08-16
CA3189868A1 (en) 2022-04-14
GB202016050D0 (en) 2020-11-25
MX2023003330A (es) 2023-03-27
AU2021358460A1 (en) 2023-03-09
WO2022074356A1 (en) 2022-04-14
GB202113057D0 (en) 2021-10-27

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