CN116033942A - 水包油型乳化组合物 - Google Patents
水包油型乳化组合物 Download PDFInfo
- Publication number
- CN116033942A CN116033942A CN202180056315.6A CN202180056315A CN116033942A CN 116033942 A CN116033942 A CN 116033942A CN 202180056315 A CN202180056315 A CN 202180056315A CN 116033942 A CN116033942 A CN 116033942A
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- China
- Prior art keywords
- oil
- water emulsion
- mass
- alcohol
- acrylic acid
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 65
- 239000007764 o/w emulsion Substances 0.000 title claims abstract description 38
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920001577 copolymer Polymers 0.000 claims abstract description 20
- IWWCATWBROCMCW-UHFFFAOYSA-N batyl alcohol Natural products CCCCCCCCCCCCCCCCCCOC(O)CO IWWCATWBROCMCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 12
- 239000002736 nonionic surfactant Substances 0.000 claims description 10
- 229920002125 Sokalan® Polymers 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 abstract description 20
- 229920000642 polymer Polymers 0.000 abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 4
- 125000000217 alkyl group Chemical group 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 37
- 235000019198 oils Nutrition 0.000 description 37
- -1 polyoxyethylene Polymers 0.000 description 34
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 22
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 20
- 239000002537 cosmetic Substances 0.000 description 16
- 150000002148 esters Chemical class 0.000 description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 14
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000004359 castor oil Substances 0.000 description 10
- 235000019438 castor oil Nutrition 0.000 description 10
- 229920006037 cross link polymer Polymers 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 10
- PSFDQSOCUJVVGF-UHFFFAOYSA-N harman Chemical compound C12=CC=CC=C2NC2=C1C=CN=C2C PSFDQSOCUJVVGF-UHFFFAOYSA-N 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 229920001296 polysiloxane Polymers 0.000 description 8
- 239000001993 wax Substances 0.000 description 8
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 6
- BTFJIXJJCSYFAL-UHFFFAOYSA-N icosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- HEAHZSUCFKFERC-IWGRKNQJSA-N [(2e)-2-[[4-[(e)-[7,7-dimethyl-3-oxo-4-(sulfomethyl)-2-bicyclo[2.2.1]heptanylidene]methyl]phenyl]methylidene]-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonic acid Chemical group CC1(C)C2CCC1(CS(O)(=O)=O)C(=O)\C2=C\C(C=C1)=CC=C1\C=C/1C(=O)C2(CS(O)(=O)=O)CCC\1C2(C)C HEAHZSUCFKFERC-IWGRKNQJSA-N 0.000 description 5
- 229960004050 aminobenzoic acid Drugs 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 4
- OIQXFRANQVWXJF-QBFSEMIESA-N (2z)-2-benzylidene-4,7,7-trimethylbicyclo[2.2.1]heptan-3-one Chemical class CC1(C)C2CCC1(C)C(=O)\C2=C/C1=CC=CC=C1 OIQXFRANQVWXJF-QBFSEMIESA-N 0.000 description 3
- JGUMTYWKIBJSTN-UHFFFAOYSA-N 2-ethylhexyl 4-[[4,6-bis[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 JGUMTYWKIBJSTN-UHFFFAOYSA-N 0.000 description 3
- 239000013531 ACULYN rheology modifier Substances 0.000 description 3
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 229960000735 docosanol Drugs 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229960001679 octinoxate Drugs 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- TYWMIZZBOVGFOV-UHFFFAOYSA-N tetracosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCO TYWMIZZBOVGFOV-UHFFFAOYSA-N 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 2
- RKJGFHYCZPZJPE-UHFFFAOYSA-N 2,2-bis(16-methylheptadecanoyloxymethyl)butyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C RKJGFHYCZPZJPE-UHFFFAOYSA-N 0.000 description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 2
- KXTAOXNYQGASTA-UHFFFAOYSA-N 2-benzylidenepropanedioic acid Chemical class OC(=O)C(C(O)=O)=CC1=CC=CC=C1 KXTAOXNYQGASTA-UHFFFAOYSA-N 0.000 description 2
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 description 2
- DWYHDSLIWMUSOO-UHFFFAOYSA-N 2-phenyl-1h-benzimidazole Chemical class C1=CC=CC=C1C1=NC2=CC=CC=C2N1 DWYHDSLIWMUSOO-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- JAZBEHYOTPTENJ-JLNKQSITSA-N all-cis-5,8,11,14,17-icosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O JAZBEHYOTPTENJ-JLNKQSITSA-N 0.000 description 2
- UBNYRXMKIIGMKK-RMKNXTFCSA-N amiloxate Chemical compound COC1=CC=C(\C=C\C(=O)OCCC(C)C)C=C1 UBNYRXMKIIGMKK-RMKNXTFCSA-N 0.000 description 2
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical class NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- XVAMCHGMPYWHNL-UHFFFAOYSA-N bemotrizinol Chemical compound OC1=CC(OCC(CC)CCCC)=CC=C1C1=NC(C=2C=CC(OC)=CC=2)=NC(C=2C(=CC(OCC(CC)CCCC)=CC=2)O)=N1 XVAMCHGMPYWHNL-UHFFFAOYSA-N 0.000 description 2
- 150000008366 benzophenones Chemical class 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- 239000010495 camellia oil Substances 0.000 description 2
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- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical class C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000020673 eicosapentaenoic acid Nutrition 0.000 description 2
- 229960005135 eicosapentaenoic acid Drugs 0.000 description 2
- JAZBEHYOTPTENJ-UHFFFAOYSA-N eicosapentaenoic acid Natural products CCC=CCC=CCC=CCC=CCC=CCCCC(O)=O JAZBEHYOTPTENJ-UHFFFAOYSA-N 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- UVCJGUGAGLDPAA-UHFFFAOYSA-N ensulizole Chemical compound N1C2=CC(S(=O)(=O)O)=CC=C2N=C1C1=CC=CC=C1 UVCJGUGAGLDPAA-UHFFFAOYSA-N 0.000 description 2
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- 239000010696 ester oil Substances 0.000 description 2
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 2
- XKUKSGPZAADMRA-UHFFFAOYSA-N glycyl-glycyl-glycine Chemical compound NCC(=O)NCC(=O)NCC(O)=O XKUKSGPZAADMRA-UHFFFAOYSA-N 0.000 description 2
- FIPPFBHCBUDBRR-UHFFFAOYSA-N henicosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCO FIPPFBHCBUDBRR-UHFFFAOYSA-N 0.000 description 2
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- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 2
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- 150000002430 hydrocarbons Chemical class 0.000 description 2
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- 235000014593 oils and fats Nutrition 0.000 description 2
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- 239000002245 particle Substances 0.000 description 2
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Abstract
[课题]使水包油型乳化组合物即使高分子乳化，乳化稳定性也优异，具有更水润的使用感。[解决手段]一种水包油型乳化组合物，其包含(A)(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物、(B)鲨肝醇、和(C)相对于组合物总量为10质量％以上的极性油。
Description
技术领域
本发明涉及水包油型乳化组合物。
背景技术
一般而言，油包水型乳化化妆品由于在油相中配合紫外线吸收剂，因此，防晒效果高、稳定性优异。但是，油包水型乳化化妆品多数难以用通常的清洗剂、肥皂简单地冲掉，此外由于包含大量紫外线吸收剂，因此，有时会产生干燥感等在使用感上存在问题。另一方面，水包油型乳化化妆品有能够容易地冲掉、干燥感也少的优点。
例如，专利文献1中，记载了一种水包油型乳化化妆品，其通过配合(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物而得到独特的柔滑的使用触感。
现有技术文献
专利文献
专利文献1：国际公开第2018/221606号
发明内容
发明要解决的问题
一般对于将高分子作为乳化剂配合而成的所谓高分子乳化体系而言，难以稳定地配合抗紫外线剂。专利文献1中记载的化妆品中，配合的高级醇与非离子性表面活性剂和水一起形成具有层状液晶结构的缔合物(也称为“α凝胶”)，从而稳定地配合抗紫外线剂，但在进一步提高乳化稳定性的同时，期望更水润的使用感。
本发明是鉴于上述情况而完成的，其目的在于，提供一种水包油型乳化组合物，其即使高分子乳化，乳化稳定性也优异，具有更水润的使用感。
用于解决问题的方案
本发明的水包油型乳化组合物包含：
(A)(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物、
(B)鲨肝醇、和
(C)相对于组合物总量为10质量％以上的极性油。
本发明的水包油型乳化组合物优选还包含(D)高级醇。
本发明的水包油型乳化组合物优选还包含(E)烷基改性羧乙烯基聚合物。
(C)极性油优选为紫外线吸收剂。
(B)鲨肝醇和(D)高级醇的质量比优选为1：1～1：3。
本发明的水包油型乳化组合物包含表面活性剂时，表面活性剂优选为(F)HLB为10～20的非离子表面活性剂，其配合量相对于组合物总量优选为0.6质量％以下。
发明的效果
本发明的水包油型乳化组合物包含：(A)(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物、(B)鲨肝醇、和(C)相对于组合物总量为10质量％以上的极性油，因此，乳化稳定性优异，具有更水润的使用感。
具体实施方式
以下，详细说明本发明。
本发明的水包油型乳化组合物包含：
(A)(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物、
(B)鲨肝醇、和
(C)相对于组合物总量为10质量％以上的极性油。以下，对各成分进行详细说明。
需要说明的是，本说明书中，POE为聚氧乙烯、POP为聚氧丙烯、PEG为聚乙二醇、DPG为一缩二丙二醇的简称。
(A)(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物
(A)(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物(以下也简称为(A)成分)是指：
(a1)丙烯酸或甲基丙烯酸、
(a2)丙烯酸烷基酯或甲基丙烯酸烷基酯、
(a3)丙烯酸或甲基丙烯酸与聚氧乙烯烷基醚的酯
的共聚物。
这些是例如可列举出以国际化妆品成分词典(ICID，International CosmeticIngredient Dictionary)收录名的丙烯酸(酯)类/鲸蜡醇聚醚-20甲基丙烯酸酯共聚物、丙烯酸(酯)类/硬脂醇聚醚-20甲基丙烯酸酯共聚物、丙烯酸(酯)类/硬脂醇聚醚-25甲基丙烯酸酯共聚物、丙烯酸(酯)类/硬脂醇聚醚-50甲基丙烯酸酯共聚物、丙烯酸(酯)类/山嵛醇聚醚-25甲基丙烯酸酯共聚物、丙烯酸(酯)类/硬脂醇聚醚-20甲基丙烯酸酯交联聚合物、丙烯酰二甲基牛磺酸铵/山嵛醇聚醚-25甲基丙烯酸酯交联聚合物等，作为水分散液(聚合物乳液)被市售。
作为本发明的水包油型乳化组合物中使用的(A)成分，优选选自丙烯酸(酯)类/硬脂醇聚醚-20甲基丙烯酸酯共聚物(ACULYN 22；ROHM AND HAAS公司)、丙烯酸(酯)类/硬脂醇聚醚-25甲基丙烯酸酯共聚物(ACULYN28；ROHM AND HAAS公司)、丙烯酸(酯)类/硬脂醇聚醚-20甲基丙烯酸酯交联聚合物(ACULYN 88；ROHM AND HAAS公司)和丙烯酰二甲基牛磺酸铵/山嵛醇聚醚-25甲基丙烯酸酯交联聚合物(Aristoflex HMB；Clariant Production UkLtd制)。其中，尤其优选为丙烯酸(酯)类/硬脂醇聚醚-20甲基丙烯酸酯共聚物或丙烯酸(酯)类/硬脂醇聚醚-20甲基丙烯酸酯交联聚合物。
上述丙烯酸系聚合物的水分散液根据需要用水等稀释，通过添加碱剂进行中和而增稠。作为共聚物中和用的碱剂，没有特别限定，可以使用氢氧化钠或氢氧化钾等无机碱、三乙醇胺或异丙醇胺、碱性氨基酸等有机碱。
对于(A)成分的配合量，相对于组合物总量，以聚合物实际含量计优选0.01～3.0质量％，更优选0.05～2.0质量％，进而优选0.1～1.4质量％，进而更优选0.2～1.0质量％。通过使配合量为0.01质量％以上，能够进一步得到乳化稳定性，通过为3.0质量％以下，能够进一步提高涂布时的水润且崩坏那样的使用性。
(B)鲨肝醇
鲨肝醇(C21H44O3)也称为十八碳甘油醚、甘油单硬脂醚等，是碳原子数18的长链脂肪醇在甘油的sn-1位上醚键合而成的一种甘油单烷基醚。通过(B)鲨肝醇，能够实现(A)成分的高分子乳化的稳定性的提高。
对于(B)鲨肝醇的配合量，相对于组合物总量优选0.02～3质量％，进一步优选0.1～1.0质量％。通过使配合量为0.02质量％以上，能够进一步提高乳化稳定性。另外，通过为3质量％以下，能够得到无粘腻、且水润的使用感。
(C)极性油
本发明的水包油型乳化组合物包含相对于组合物总量为10质量％以上的(C)极性油。(C)极性油只要为通常化妆品、药品、食品中可使用者就没有特别限定。IOB值没有特别限定，优选0.05～0.80。
需要说明的是，IOB值是指Inorganic/Organic Balance(无机性/有机性比)的简称，是表示无机性值相对于有机性值的比率的值，成为表示有机化合物的极性的程度的指标。具体而言，IOB值表示为IOB值＝无机性值/有机性值。
此处，关于“无机性值”、“有机性值”，例如，对分子中1个碳原子设定“有机性值”为20、对1个同羟基设定“无机性值”为100这样设定与各种原子或官能团对应的“无机性值”、“有机性值”，通过累计有机化合物中的所有原子和官能团的“无机性值”、“有机性值”，可以算出该有机化合物的IOB值(例如，参照藤田著、《化学の領域》第11卷、第10号、第719页～第725页、1957年)。
对于(C)极性油的配合量，相对于组合物总量更优选12～40质量％，进一步优选15～30质量％。一般而言，极性油存在使水包油型乳化组合物的稳定性劣化的倾向，但本发明的水包油型乳化组合物即使包含相对于组合物总量为10质量％以上的(C)极性油，也能够稳定地配合极性油。
作为极性油的代表例，可列举出酯油和紫外线吸收剂。
作为酯油的具体例，可列举出二新戊酸三丙二醇酯、异壬酸异壬酯、肉豆蔻酸异丙酯、辛酸十六烷基酯、肉豆蔻酸辛基十二烷基酯、棕榈酸异丙酯、硬脂酸丁酯、月桂酸己酯、肉豆蔻酸肉豆蔻酯、油酸癸酯、二甲基辛酸己癸酯、十六烷基乳酸酯、十四烷基乳酸酯、乙酰化羊毛脂、异鲸蜡醇硬脂酸酯、异鲸蜡醇异硬脂酸酯、胆甾醇12-羟基硬脂酸酯、鲸蜡醇乙基己酸酯、乙二醇二(2-乙基己酸)酯、二季戊四醇脂肪酸酯、单异硬脂酸-N-烷基二醇酯、新戊二醇二癸酸酯、二异硬脂醇苹果酸酯、甘油二(2-庚基十一烷酸)酯、三羟甲基丙烷三(2-乙基己酸)酯、三羟甲基丙烷三异硬脂酸酯、季戊四醇四(2-乙基己酸)酯、三异辛酸甘油酯(2-乙基己酸三甘油酯)、三辛酸甘油酯、三异棕榈酸甘油酯、三羟甲基丙烷三异硬脂酸酯、十六烷基-2-乙基己酸酯、棕榈酸2-乙基己酯、甘油三肉豆蔻酸酯、甘油三(2-庚基十一烷酸)酯、蓖麻油脂肪酸甲酯、油酸油酯、乙酰甘油酯、棕榈酸2-庚基十一烷基酯、己二酸二异丁酯、N-月桂酰基-L-谷氨酸-2-辛基十二烷基酯、二(2-庚基十一烷醇)己二酸酯、月桂酸乙酯、癸二酸二(2-乙基己基)酯、肉豆蔻酸2-己基癸酯、棕榈酸2-己基癸酯、己二酸2-己基癸酯、癸二酸二异丙酯、琥珀酸2-乙基己酯、柠檬酸三乙酯等。
作为紫外线吸收剂，没有特别限定，可广泛列举出一般而言化妆品中可使用的紫外线吸收剂。例如，可示例出苯甲酸衍生物、水杨酸衍生物、肉桂酸衍生物、二苯甲酰甲烷衍生物、β,β-二苯基丙烯酸酯衍生物、二苯甲酮衍生物、亚苄基樟脑衍生物、苯基苯并咪唑衍生物、三嗪衍生物、苯并三唑衍生物、邻氨基苯甲酸衍生物、咪唑啉衍生物、亚苄基丙二酸酯衍生物、4,4-二芳基丁二烯衍生物等。以下列举具体例和商品名等，但不限定于这些。
作为苯甲酸衍生物，可示例出对氨基苯甲酸(PABA)乙酯、二羟丙基PABA乙酯、二甲基PABA乙基己酯(例如“ESCALOL 507”；ISP公司)、甘油PABA酯、PEG-25-PABA(例如“UvinulP25”；BASF公司)、二乙氨羟苯甲酰基苯甲酸己酯(例如“Uvinul APlus”)等。
作为水杨酸衍生物，可示例出胡莫柳酯(“Eusolex HMS”；RONA/EM industries公司)、水杨酸乙基己酯(水杨酸辛酯、例如“Neo Heliopan OS”；Harman and Raymer公司)、水杨酸二丙二醇酯(例如“Dipsal”；Skell公司)、TEA水杨酸盐(例如“Neo Heliopan TS”；Harman and Raymer公司)等。
作为肉桂酸衍生物，可示例出甲氧基肉桂酸辛酯或甲氧基肉桂酸乙基己酯(例如“PARSOL MCX”；Hoffmann-La Roche)、甲氧基肉桂酸异丙酯、甲氧基肉桂酸异戊酯(例如“Neo Heliopan E1000”；Harman and Raymer公司)、西诺沙酯、甲氧基肉桂酸DEA盐、二异丙基肉桂酸甲酯、甘油乙基己酸酯二甲氧基肉桂酸酯、二(2-乙基己基)-4’-甲氧基亚苄基丙二酸酯等。
作为二苯甲酰甲烷衍生物，可示例出4-叔丁基-4’-甲氧基二苯甲酰甲烷(例如“PARSOL 1789”)等。
作为β,β-二苯基丙烯酸酯衍生物，可示例出奥克立林(例如“Uvinul N539T”；BASF公司)等。
作为二苯甲酮衍生物，可示例出二苯甲酮-1(例如“Uvinul 400”；BASF公司)、二苯甲酮-2(例如“Uvinul D50”；BASF公司)、二苯甲酮-3或羟苯甲酮(例如“Uvinul M40”；BASF公司)、二苯甲酮-4(例如“Uvinul MS40”；BASF公司)、二苯甲酮-5、二苯甲酮-6(例如“Helisorb 11”；Norquay公司)、二苯甲酮-8(例如“Spectra-Sorb UV-24”；Americancyanamide公司)、二苯甲酮-9(例如“Uvinul DS-49”；BASF公司)、二苯甲酮-12等。
作为亚苄基樟脑衍生物，可示例出3-亚苄基樟脑(例如“Mexoryl SD”；Chimex公司)、4-甲基亚苄基樟脑、亚苄基樟脑磺酸(例如“Mexoryl SL”；Chimex公司)、甲基硫酸樟脑苄烷铵(例如“Mexoryl SO”；Chimex公司)、对苯二亚甲基二樟脑磺酸(例如“Mexoryl SX”；Chimex公司)、聚丙烯酰氨甲基亚苄基樟脑(例如“Mexoryl SW”；Chimex公司)等。
作为苯基苯并咪唑衍生物，可示例出苯基苯并咪唑磺酸(例如“Eusolex232”；默克公司)、苯基二苯并咪唑四磺酸酯二钠(例如“Neo Heliopan AP”；Harman and Raymer公司)等。
作为三嗪衍生物，可示例出双-乙基己氧苯酚甲氧苯基三嗪(例如“Tinosorb S”；Ciba Specialty Chemicals公司)、乙基己基三嗪酮(例如“Uvinul T150”；BASF公司)、二乙基己基丁酰胺基三嗪酮(例如“Uvasorb HEB”；3V Sigma公司)、2,4,6-三(二异丁基-4’-氨基亚苄基丙二酸酯)-均三嗪、2,4,6-三[4-(2-乙基己基氧基羰基)苯胺基]-1,3,5-三嗪等。
作为苯并三唑衍生物，可示例出甲酚曲唑三硅氧烷(例如“Silatrizole”；RodiaSymi公司)、亚甲基双-苯并三唑基四甲基丁基酚(例如“Tinosorb M”(Ciba SpecialtyChemicals公司))等。
作为邻氨基苯甲酸衍生物，可示例出薄荷醇邻氨基苯甲酸酯(例如“Neo HeliopanMA”；Harman and Raymer公司)等。
作为咪唑啉衍生物，可示例出二甲氧亚苄基二氧代咪唑烷基丙酸乙基己酯等。
作为亚苄基丙二酸酯衍生物，可示例出具有亚苄基丙二酸酯官能团的聚有机硅氧烷(例如，聚硅氧烷-15；“PARSOL SLX”；DSM Nutrition JAPAN公司)等。
作为4,4-二芳基丁二烯衍生物，可示例出1,1-二羧基(2,2’-二甲基丙基)-4,4-二苯基丁二烯等。
极性油优选包含紫外线吸收剂，其全部也可以为紫外线吸收剂。另外，紫外线吸收剂可以配合1种或2种以上的组合。
(D)高级醇
本发明的水包油型乳化组合物优选包含高级醇。作为高级醇，只要为化妆品、药品、准药物等领域中可使用的碳数6以上的高级醇，就没有特别限定，可列举出饱和直链一元醇、不饱和一元醇等。
作为饱和直链一元醇，可列举出十二醇(月桂醇)、十三醇、十四醇(肉豆蔻醇)、十五醇、十六醇(鲸蜡醇)、十七醇、十八醇(硬脂醇)、十九醇、二十醇(花生醇)、二十一醇、二十二醇(山嵛醇)、二十三醇、二十四醇(木蜡醇)、二十五醇、二十六醇(蜡醇)等。
作为不饱和一元醇，可列举出反9-十八烯醇等。本发明中从经时稳定性的观点出发，优选饱和直链一元醇。
本发明中的高级醇可以使用上述1种或2种以上的组合。本发明中优选使用碳数16～22的一元脂肪醇。需要说明的是，本发明中，在使用多种高级醇的情况下，从稳定性的观点出发，特别优选其混合物的熔点为60℃以上的组合的混合物。
对于(D)高级醇的配合量，相对于组合物总量优选0.02～9质量％，更优选0.05～5.0质量％，进一步优选0.1～3.0质量％，特别优选0.2～1质量％。通过使配合量为0.02质量％以上，能够进一步提高乳化稳定性。另外，通过为9质量％以下，能够得到无粘腻、且水润的使用感。
本发明的水包油型乳化组合物包含(D)高级醇时，(B)鲨肝醇和(D)高级醇的质量比优选1：1～1：3。包含(D)高级醇时，(B)鲨肝醇和(D)高级醇形成α型的水合晶体结构。由此，能够进一步提高稳定性弱的高分子乳化的乳化稳定性，并且能够进一步提高水润、使用时无粘腻的使用性。
(E)烷基改性羧乙烯基聚合物
作为烷基改性羧乙烯基聚合物，从具有良好的乳化稳定性和水润的使用感的观点出发，可以适宜列举出丙烯酸(酯)类/C10-30烷醇丙烯酸酯交联聚合物。丙烯酸(酯)类/C10-30烷醇丙烯酸酯交联聚合物可以使用市售品，可列举出Pemulen TR-2聚合物乳化剂(Lubrizol Advanced Materials,Inc.制)。
对于(E)烷基改性羧乙烯基聚合物的配合量，相对于组合物总量优选为0.01～1质量％的范围，更优选0.03～0.5质量％，进一步优选0.03～0.2质量％的范围。通过为0.01质量％以上，能够使稳定性更好。另外，通过为1质量％以下，能够形成更水润、轻盈的使用感。
(F)HLB为10～20的非离子表面活性剂
本发明的水包油型乳化组合物中，表面活性剂的配合量相对于组合物总量优选1质量％以下。通过表面活性剂的配合量为1质量％以下，能够进一步提高水润、使用时无粘腻的使用性。特别是，本发明的水包油型乳化组合物由于乳化稳定性高，因此，也可以不包含。根据组合物的形态等进行配合的情况下，优选的是HLB(亲水亲油平衡，Hydrophilic-Lypophilic Balance)为10～20的非离子表面活性剂。更优选的是HLB为12～20的非离子表面活性剂。(F)非离子表面活性剂的配合量相对于组合物总量优选0.01～1质量％，更优选0.05～0.8质量％，进一步优选0.1～0.6质量％。通过为0.01质量％以上，能够有利于α凝胶的形成，通过为1质量％以下，能够进一步提高使用时无粘腻的使用性。
作为非离子表面活性剂，可以选自甘油或聚甘油脂肪酸脂类、丙二醇脂肪酸酯类、POE山梨糖醇酐脂肪酸酯类、POE山梨醇脂肪酸酯类、POE甘油脂肪酸酯类、POE脂肪酸酯类、POE烷基醚类、POE烷基苯基醚类、POE·POP烷基醚类、POE蓖麻油或氢化蓖麻油衍生物、POE蜂蜡·羊毛脂衍生物、链烷醇酰胺类、POE丙二醇脂肪酸酯类、POE烷基胺、POE脂肪酰胺等。具体例中，包含PEG-40氢化蓖麻油、PEG-50氢化蓖麻油、PEG-60氢化蓖麻油、PEG-60甘油异硬脂酸酯、PEG-50氢化蓖麻油琥珀酸酯等氢化蓖麻油衍生物、鲸蜡醇聚醚-25等。
本发明的水包油型乳化组合物除了上述(A)～(F)以外，可以在不有损稳定性的范围内，从(C)极性油、(D)高级醇以外的、通常化妆品中可使用的油分中选择。作为期望的油分，可列举出液体油脂、固体油脂、蜡类、烃油、高级脂肪酸、硅油等。
作为液体油脂，例如可列举出鳄梨油、山茶籽油、澳洲坚果籽油、玉米油、橄榄油、菜籽油、芝麻油、桃仁油、小麦胚芽油、山茶花油、蓖麻油、亚麻籽油、红花油、棉籽油、紫苏油、大豆油、花生油、茶籽油、榧子油、米糠油、泡桐油、日本桐油、霍霍巴油、胚芽油、三甘油等。
作为固体油脂，例如可列举出可可脂、椰子油、氢化椰子油、棕榈油、棕榈仁油、木蜡仁油、氢化油、木蜡、氢化蓖麻油等。
作为蜡类，例如可列举出蜜蜡、小烛树蜡、棉蜡、巴西棕榈蜡、杨梅蜡、虫蜡、褐煤蜡、糠蜡、木棉蜡、甘蔗蜡、霍霍巴蜡、虫胶蜡、POE胆甾醇醚等。
作为烃油，例如可列举出液体石蜡、地蜡、角鲨烷、姥鲛烷、石蜡、纯地蜡、角鲨烯、凡士林、微晶蜡、氢化聚癸烯等。
作为高级脂肪酸，例如可列举出月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、山萮酸、油酸、十一碳烯酸、妥尔酸、异硬脂酸、亚油酸、亚麻酸、二十碳五烯酸(EPA)、二十二碳六烯酸(DHA)等。
作为硅油，例如可列举出链状聚硅氧烷(例如，二甲基硅油、甲基苯基聚硅氧烷、二苯基聚硅氧烷等)；环状聚硅氧烷(例如，八甲基环四硅氧烷、十甲基环五硅氧烷、十二甲基环六硅氧烷等)、形成三维网络结构的有机硅树脂、硅橡胶、各种改性聚硅氧烷(氨基改性聚硅氧烷、聚醚改性聚硅氧烷、烷基改性聚硅氧烷、氟改性聚硅氧烷等)等。
上述各油分可以使用1种或适宜组合2种以上而使用。
在配合(C)极性油、(D)高级醇以外的上述油分的情况下，其配合量相对于组合物总量优选1.0～20质量％，更优选5.0～15质量％。通过使配合量为1.0质量％以上，能够确保紫外线吸收剂的析出抑制、油分的相溶性，通过为20质量％以下，能够进一步使乳化稳定性和使用性变得良好。
本发明的水包油型乳化组合物在不有损本发明的效果的范围内，能够配合通常化妆品、准药物中可配合的其他任意成分。作为其他任意成分，没有限定，例如可列举出粉末成分、色料、保湿剂、水性增稠剂、分散剂、防腐剂、香料、各种药剂等。
作为粉末成分，可列举出氧化锌、氧化钛等紫外线散射剂、滑石、云母、高岭土等体质颜料、聚乙烯粉末、聚甲基丙烯酸甲酯粉末、尼龙粉末等聚合物粉末等。
作为保湿剂，例如可列举出甘油、1,3-丁二醇、一缩二丙二醇、丙二醇等多元醇、海藻糖、透明质酸、硫酸软骨素等水溶性高分子等。
作为水性增稠剂，例如可列举出琥珀酰聚糖、二甲基丙烯酰胺/丙烯酰基二甲基牛磺酸钠交联聚合物、纤维素胶、羧乙烯基聚合物、黄原胶、丙烯酸羟乙酯/丙烯酰二甲基牛磺酸钠共聚物等。
本发明的水包油型乳化组合物可以通过例如分别将构成油相的成分与构成水相的成分混合、并且将油相添加到水相中进行乳化等之类的水包油型乳化组合物(化妆品)的常规方法来制造。
本发明的水包油型乳化组合物可以作为液态、乳液态、乳霜状、凝胶状、巴伐露(Bavarois)状等各种剂型的化妆品而提供。
另外，本发明的水包油型乳化组合物可以作为护肤化妆品、防晒化妆品、配合有色料的化妆品、粉底液、打底霜、BB乳霜而提供。
本发明的水包油型乳化组合物可以得到通过使用(A)(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物的高分子乳化所带来的特有的水润的使用触感，此外，通过组合使用(B)鲨肝醇而使乳化稳定性提高，因此，能够配合10％以上的以紫外线吸收剂为代表的(C)极性油。因此，如果配合作为(C)极性油的紫外线吸收剂，则能够得到具有水润的使用触感和高的紫外线防御能力的乳化稳定性优异的化妆品。
实施例
以下列举实施例来进一步具体地说明本发明，但本发明不限于这些。配合量只要没有特别说明，则均为质量％。
(实施例1～6和比较例1)
以下述表1所示的配方制作水包油型乳化组合物，关于制作的组合物，以以下基准进行评价。
(滚动试验)
在圆筒形容器中，半量填充制备的水包油型乳化组合物，利用滚动检验机(浊川理化工业株式会社制)在室温下对试样以45rpm施加4小时的旋转运动，关于组合物的状态变化进行观察，以以下基准进行评价。
A：未见变化
B：可见稍有粘度变化或乳化颗粒增大，但使用时没有问题
C：可见很多的粘度变化或乳化颗粒增大，给使用带来障碍
D：可见油的脱离
(使用性)
由10名专门小组成员使用制备的水包油型乳化组合物，对涂布后的粘稠度进行评价。评价基准如下所述。
＜评分＞
5分：非常好
4分：良好
3分：普通
2分：不良
1分：非常不良
＜评价基准＞
A：平均分为4.5分以上
B：平均分为3.5点以上且低于4.5分
C：平均分为2.5点以上且低于3.5分
D：平均分低于2.5分
将配方和评价结果示于表1。需要说明的是，表所示成分中的主要物质的市售品名示于以下。
·丙烯酸(酯)类/C10-30烷醇丙烯酸酯交联聚合物：PEMULENTR-2(LubrizolAdvanced Materials,Inc.制)
·丙烯酰二甲基牛磺酸铵/山萮醇聚醚-25甲基丙烯酸酯交联聚合物：ARISTOFLEXHMB(Clariant GMBH公司制)
·PEG-60甘油异硬脂酸酯：EMALEX GWIS-160(NIHON EMULSION Co.,Ltd.)
·PEG-60氢化蓖麻油：NIKKOL HCO-60(NIPPON SURFACTANT INDUSTRIES CO.,LTD.制)
·月桂基甜菜碱：ANON BL-SF(日油株式会社制)
·双-丁基聚二甲基硅氧烷聚甘油-3：Silicone KF-6109(信越化学工业株式会社制)
·聚硅氧烷-11：Gransil DMG-3(GRANTINDUSTRIES公司制)
[表1]
如表1所示，包含(A)(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物、(B)鲨肝醇、和(C)相对于组合物总量为10质量％以上的极性油的实施例1～6即使高分子乳化，乳化稳定性也优异，可以得到涂布后无粘腻的水润使用感。另一方面，不含(B)鲨肝醇的比较例1中，即使包含高级醇，也无法得到乳化稳定性。
Claims (6)
1.一种水包油型乳化组合物，其包含：
(A)(甲基)丙烯酸/(甲基)丙烯酸烷基酯/(甲基)丙烯酸POE单烷基醚酯共聚物、
(B)鲨肝醇、和
(C)相对于组合物总量为10质量％以上的极性油。
2.根据权利要求1所述的水包油型乳化组合物，其还包含(D)高级醇。
3.根据权利要求1或2所述的水包油型乳化组合物，其还包含(E)烷基改性羧乙烯基聚合物。
4.根据权利要求3所述的水包油型乳化组合物，其中，所述(C)极性油为紫外线吸收剂。
5.根据权利要求2、3或4所述的水包油型乳化组合物，其中，所述(B)鲨肝醇和所述(D)高级醇的质量比为1：1～1：3。
6.根据权利要求1～5中任一项所述的水包油型乳化组合物，其中，(F)HLB为10～20的非离子表面活性剂相对于组合物总量为0.6质量％以下。
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