CN115869216A - Sweat-resistant foundation liquid and preparation method thereof - Google Patents
Sweat-resistant foundation liquid and preparation method thereof Download PDFInfo
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- CN115869216A CN115869216A CN202211649203.4A CN202211649203A CN115869216A CN 115869216 A CN115869216 A CN 115869216A CN 202211649203 A CN202211649203 A CN 202211649203A CN 115869216 A CN115869216 A CN 115869216A
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- 239000007788 liquid Substances 0.000 title claims abstract description 37
- 210000004243 sweat Anatomy 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 40
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 40
- 239000003381 stabilizer Substances 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 17
- 239000003974 emollient agent Substances 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000003086 colorant Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 10
- 239000003906 humectant Substances 0.000 claims abstract description 10
- 239000003755 preservative agent Substances 0.000 claims abstract description 10
- 230000002335 preservative effect Effects 0.000 claims abstract description 9
- 239000002738 chelating agent Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000004034 viscosity adjusting agent Substances 0.000 claims abstract description 5
- 239000012071 phase Substances 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 239000003921 oil Substances 0.000 claims description 25
- -1 polydimethylsiloxane Polymers 0.000 claims description 24
- 230000001166 anti-perspirative effect Effects 0.000 claims description 20
- 239000003213 antiperspirant Substances 0.000 claims description 20
- 239000000839 emulsion Substances 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 19
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 17
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 16
- 230000001804 emulsifying effect Effects 0.000 claims description 12
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 12
- 229910000271 hectorite Inorganic materials 0.000 claims description 12
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 12
- 229920000936 Agarose Polymers 0.000 claims description 11
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 claims description 10
- 239000000284 extract Substances 0.000 claims description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 239000008346 aqueous phase Substances 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 230000003020 moisturizing effect Effects 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 241000980780 Cladosiphon okamuranus Species 0.000 claims description 2
- 241001598113 Laminaria digitata Species 0.000 claims description 2
- 241000015177 Saccharina japonica Species 0.000 claims description 2
- 241001148683 Zostera marina Species 0.000 claims description 2
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 2
- 235000010418 carrageenan Nutrition 0.000 claims description 2
- 229940074992 chondrus crispus extract Drugs 0.000 claims description 2
- 229940020856 fucus serratus extract Drugs 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 229940031518 ulva lactuca extract Drugs 0.000 claims description 2
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 claims 1
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 claims 1
- PKPOVTYZGGYDIJ-UHFFFAOYSA-N dioctyl carbonate Chemical compound CCCCCCCCOC(=O)OCCCCCCCC PKPOVTYZGGYDIJ-UHFFFAOYSA-N 0.000 claims 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 claims 1
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 claims 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims 1
- 229940032044 quaternium-18 Drugs 0.000 claims 1
- 229940101631 quaternium-18 hectorite Drugs 0.000 claims 1
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 35
- 239000000243 solution Substances 0.000 description 31
- 238000003756 stirring Methods 0.000 description 18
- 229940008099 dimethicone Drugs 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 239000002537 cosmetic Substances 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- 230000000087 stabilizing effect Effects 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- 229960001631 carbomer Drugs 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 230000001815 facial effect Effects 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 230000037303 wrinkles Effects 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- 239000004909 Moisturizer Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 208000026935 allergic disease Diseases 0.000 description 2
- 230000007815 allergy Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000001333 moisturizer Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000000284 resting effect Effects 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000013517 stratification Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 244000288157 Passiflora edulis Species 0.000 description 1
- 235000000370 Passiflora edulis Nutrition 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 229940049676 bismuth hydroxide Drugs 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229940085262 cetyl dimethicone Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002339 glycosphingolipids Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 229940084032 paeonia lactiflora root extract Drugs 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
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- 238000003860 storage Methods 0.000 description 1
- 230000037331 wrinkle reduction Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The application discloses a sweat-resistant foundation liquid and a preparation method thereof, wherein the foundation liquid comprises the following raw materials in percentage by weight: film-forming agent: 3 to 10 percent; and (3) an emollient: 8.5 to 42 percent; humectant: 3.5 to 15 percent; filling agent: 0.5 to 5 percent; emulsifier: 1 to 10 percent; skin conditioner: 0.7 to 21 percent; viscosity modifier: 0.1 to 2 percent; a stabilizer: 0.2 to 6 percent; chelating agent: 0.001 to 0.5 percent; colorant: 0 to 40 percent; preservative: 0 to 1 percent; the film forming agent adopts 1-3 mass ratio of acrylate/polydimethylsiloxane copolymer to 2-5 mass ratio of cyclopentadimethylsiloxane. The foundation liquid has excellent waterproof and sweat-resistant performances and has a good beautifying and skin-care effect.
Description
Technical Field
The application relates to the field of cosmetics, in particular to a sweat-resistant foundation liquid and a preparation method thereof.
Background
The foundation liquid is an emulsion type cosmetic added with powder, can be used for facial cosmetic modification on one hand, and can form a smooth covering layer on the surface of skin to effectively cover the flaws of the face; on the other hand, the skin care composition can be combined with skin care ingredients to achieve the effects of beautifying and protecting the skin.
Most of the foundation liquid in the market adopts hydrophilic raw materials, particularly hydrophilic film-forming materials, so that the foundation liquid is light and thin in texture, is not greasy and is easy to spread on the surface of skin. However, the hydrophilic property of the foundation liquid leads to poor waterproof and sweat-resistant performance, and the foundation liquid is easy to remove when meeting water.
Disclosure of Invention
In order to improve the waterproof and sweat-resistant performance of the foundation liquid and reduce the makeup removal phenomenon, the application provides the sweat-resistant foundation liquid and the preparation method thereof.
In a first aspect, the present application provides a sweat-resistant foundation liquid, which comprises the following raw materials by weight:
film-forming agent: 3 to 10 percent;
and (3) an emollient: 8.5 to 42 percent;
humectant: 3.5 to 15 percent;
filling agent: 0.5 to 5 percent;
emulsifier: 1 to 10 percent;
skin conditioner: 0.7 to 21 percent;
viscosity modifier: 0.1 to 2 percent;
a stabilizer: 0.2 to 6 percent;
chelating agent: 0.001 to 0.5 percent;
colorant: 0 to 40 percent;
preservative: 0 to 1 percent;
the film forming agent adopts 1-3 mass ratio of acrylate/polydimethylsiloxane copolymer to 2-5 mass ratio of cyclopentadidimethylsiloxane to cyclopentadimethylsiloxane.
The conventional foundation solution usually takes xanthan gum, carbomer, cellulose and other hydrophilic substances as film forming agents, so that the performance of the foundation solution after film forming is poor. Therefore, the foundation liquid adopts the film-forming agent based on the acrylate/polydimethylsiloxane copolymer, and the copolymer contains a hydrophilic acrylate chain segment and a hydrophobic organic silicon chain segment, so that the property of the foundation liquid can be effectively improved, and the makeup removal phenomenon caused by sweat is not easy to occur after the film is formed on the surface of skin.
The acrylate/polydimethylsiloxane copolymer has high viscosity, greatly reduces the fluidity of the foundation fluid and is not beneficial to dispersion coating. Therefore, the cyclopentadimethylsiloxane is compounded, so that the fluidity of the powder base is effectively compensated, and the uniformity of film forming of the powder base solution is improved.
The pigment has no special requirement on the colorant, and the pigment or the pigment solution is selected as required.
Preferably, the emulsifier is prepared from the following raw materials in a mass ratio of 0.5-5: 0.5 to 5 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane and PEG-10 polydimethylsiloxane.
The introduction of the hydrophobic chain segment in the film forming agent improves the performance, and simultaneously prevents the hydrophilic skin conditioner and the emollient from penetrating and acting on the skin to a certain extent, thereby influencing the skin care effect of the foundation liquid. The emulsifier adopted by the application contains the hydrophobic polysiloxane chain segment and the hydrophilic polyether chain segment, can promote the release and permeation of the skin conditioner, the emollient and water from the hydrophobic film layer to the surface of the skin, and can form a channel on the film layer along with the release of the hydrophilic substances, further promote the release of the skin conditioner and the moisture, and ensure good skin care effect.
In addition, the cetyl PEG/PPG-10/1 polydimethylsiloxane and the PEG-10 polydimethylsiloxane have a synergistic cooperation effect, the permeability of a membrane layer of the PEG-10 polydimethylsiloxane is good, and the formation of a channel is facilitated, and the steric hindrance effect of the cetyl PEG/PPG-10/1 polydimethylsiloxane is strong, so that the common expansion is facilitated, and the permeation of a skin conditioner, an emollient and moisture to the surface of the skin is promoted.
Preferably, the water phase stabilizer is one or a combination of agarose, xanthan gum, hydroxyethyl cellulose and carbomer; the oil phase stabilizer is one or a combination of more of quaternary ammonium salt-18 hectorite and quaternary ammonium salt-18 bentonite. More preferably, the aqueous phase stabilizer is agarose, and the oil phase stabilizer is quaternary ammonium salt-18 hectorite.
The stabilizer can form a network structure in a system, plays a role in thickening, reduces the phenomena of precipitation and delamination, and improves the stability of the product.
Preferably, the mass ratio of the stabilizer is 0.1-3: 0.1-3 of water phase stabilizer and oil phase stabilizer, wherein the water phase stabilizer and the oil phase stabilizer are agarose and quaternary ammonium salt-18 hectorite respectively.
The quaternary ammonium salt-18 hectorite has lipophilicity and can play a good stabilizing role in an oil phase solution, and the agarose contains a large number of hydroxyl groups and can be swelled into colloid in a water phase solution to play a stabilizing role. After the oil phase and the water phase are mixed, hydroxyl in the agarose can form hydrogen bonds with carbonyl or silicon hydroxyl of the acrylate/polydimethylsiloxane copolymer, so that a stabilizing effect is achieved, the possibility of segregation of silicone oil such as cyclopentadimethylsiloxane and the like is effectively reduced, and the film forming stability of the foundation solution is guaranteed.
Preferably, the humectant adopts a mass ratio of 0.5-5: 3-10 of butanediol and glycerol.
The moisturizing agent is a micromolecular compound, has outstanding permeability, can quickly penetrate through a foundation liquid film layer and acts on skin, and plays a role in moisturizing. Meanwhile, the formation of the hydrophilic channel can be promoted, and the beautifying and skin-care effects of the foundation liquid are improved.
Preferably, the filler is selected from one or a combination of more of kaolin, bentonite, talcum powder and aluminum hydroxide; more preferably mica or a suspension thereof is used.
Preferably, the skin conditioner is one or more selected from Laminaria digitata extract, cladosiphon okamuranus extract, fucus serratus extract, laminaria japonica extract, zostera marina extract, ulva lactuca extract, and Chondrus crispus extract.
The plant extract contains natural pigment and antioxidant, and has effects of inhibiting skin peroxidation, regulating and repairing skin defect, delaying aging, preventing wrinkle, and resisting aging.
Preferably, the viscosity modifier is an inorganic salt such as sodium chloride or ammonium chloride, and more preferably sodium chloride.
In a second aspect, the present application provides a method for preparing a sweat-resistant foundation comprising the steps of:
preparing an oil phase: under the heating condition, uniformly mixing a film-forming agent, an emollient, a preservative, an emulsifier and 10-90 wt% of a stabilizer to obtain an emulsion; uniformly mixing part of the emulsion with the filler and the colorant, grinding to obtain an oil phase solution, and keeping the temperature for later use;
preparation of an aqueous phase: under the heating condition, adding the moisturizing agent, the viscosity regulator and the chelating agent into water, dissolving and uniformly mixing to obtain a water phase solution;
preparing a finished product: mixing the water phase solution and the oil phase solution, homogenizing, emulsifying, and vacuumizing to obtain the sweat-resistant foundation solution;
preferably, the heating temperature is 70-85 ℃;
preferably, the rotation speed of the homogeneous emulsification is 2500-3000rpm, and the time of the homogeneous emulsification is 5-10 minutes.
By the preparation process, the homogeneous and stable foundation liquid can be obtained, and the foundation liquid has good beautifying and skin-care effects. Meanwhile, the emulsion is easy to smear and push away, and the uniformity of the makeup surface is effectively guaranteed.
In summary, the present application has the following beneficial effects:
1. according to the foundation liquid, the composite of the acrylate/polydimethylsiloxane copolymer and the cyclopenta polydimethylsiloxane is used as the film forming agent of the foundation liquid, so that the performance of the foundation liquid can be remarkably improved on the premise of ensuring the push-away performance of the foundation liquid during smearing.
2. The emulsifier adopts cetyl PEG/PPG-10/1 polydimethylsiloxane and PEG-10 polydimethylsiloxane to carry out cooperative matching, and when the emulsifying and homogenizing effects are achieved, a channel structure can be formed on a foundation fluid film layer, the passing rate of hydrophilic substances of the film layer is compensated, the penetration of the hydrophilic substances such as skin conditioners, emollients and the like to the skin surface is promoted, and the beautifying and skin-care effects of the skin conditioner are guaranteed.
3. The stabilizing agent disclosed by the application adopts agarose and quaternary ammonium salt-18 hectorite for synergistic cooperation, can play a good role in resisting precipitation delamination and seeing the separation of silicone oil, and ensures the stability of film formation and storage of the foundation solution.
Detailed Description
Examples
Example 1, a antiperspirant powder base was prepared as follows:
preparing an oil phase: under heating conditions, putting the acrylic acid (ester)/polydimethylsiloxane copolymer, the cyclopentasiloxane film-forming agent, the emollient, the preservative, the emulsifier and the quaternary ammonium salt-18 hectorite into an emulsifying pot, stirring and heating to 80 +/-2 ℃, and uniformly stirring to obtain an emulsion; uniformly mixing 40wt% of emulsion, a filler and a colorant, grinding, uniformly mixing with the rest emulsion in an emulsion pot to obtain an oil phase solution, and keeping the temperature at 78 +/-2 ℃ for later use;
preparation of an aqueous phase: putting the humectant, the viscosity regulator, the chelating agent and water into a water phase pot, stirring and heating to 70-85 ℃, dissolving and uniformly stirring to obtain a water phase solution;
and (3) preparing a finished product: adding the water phase solution into an emulsifying pot, mixing with the oil phase solution, homogenizing and emulsifying at 2500rpm for 8min, vacuumizing, and discharging to obtain the sweat-resistant powder base solution.
Example 3, a antiperspirant powder base was prepared as follows:
preparing an oil phase: under heating conditions, putting an acrylic acid (ester)/polydimethylsiloxane copolymer, a cyclopentadimethylsiloxane film-forming agent, an emollient, a preservative, an emulsifier and quaternary ammonium salt-18 hectorite into an emulsifying pot, stirring and heating to 82 +/-2 ℃, and uniformly stirring to obtain an emulsion; uniformly mixing 30wt% of emulsion, a filler and a colorant, grinding, uniformly mixing with the rest emulsion in an emulsion pot to obtain an oil phase solution, and keeping the temperature at 78 +/-2 ℃ for later use;
preparation of an aqueous phase: putting the moisturizing agent, the viscosity regulator, the chelating agent and water into a water phase pot, stirring and heating to 70-85 ℃, and dissolving and uniformly stirring to obtain a water phase solution;
and (3) preparing a finished product: adding the water phase solution into an emulsifying pot, mixing with the oil phase solution, homogenizing and emulsifying at 2500rpm for 10min, vacuumizing, and discharging to obtain the sweat-resistant powder base solution.
Example 3, a antiperspirant powder base was prepared as follows:
preparing an oil phase: under heating conditions, putting an acrylic acid (ester)/polydimethylsiloxane copolymer, a cyclopentadimethylsiloxane film-forming agent, an emollient, a preservative, an emulsifier and quaternary ammonium salt-18 hectorite into an emulsifying pot, stirring and heating to 75 +/-2 ℃, and uniformly stirring to obtain an emulsion; uniformly mixing 50wt% of emulsion, a filler and a colorant, grinding, and uniformly mixing with the rest emulsion in an emulsion pot to obtain an oil phase solution, and keeping the temperature of 78 +/-2 ℃ for later use;
preparation of an aqueous phase: putting the moisturizing agent, the viscosity regulator, the chelating agent and water into a water phase pot, stirring and heating to 70-85 ℃, and dissolving and uniformly stirring to obtain a water phase solution;
and (3) preparing a finished product: adding the water phase solution into an emulsifying pot, mixing with the oil phase solution, homogenizing and emulsifying at 3000rpm for 5min, vacuumizing, and discharging to obtain the sweat-resistant foundation solution.
TABLE 1, EXAMPLES 1-3 raw materials proportioning
Example 4, a antiperspirant base, differs from example 1 in that the equivalent amount of cetyl PEG/PPG-10/1 dimethicone was used in place of PEG-10 dimethicone in the emulsifier.
Example 5, a antiperspirant base, differs from example 1 in that the cetyl PEG/PPG-10/1 dimethicone was replaced with an equal amount of PEG-10 dimethicone in the emulsifier.
Example 6, a antiperspirant base, differs from example 1 in that the equivalent amount of PEG/PPG-8/3 laurate was used in the emulsifier in place of the PEG-10 dimethicone and cetyl PEG/PPG-10/1 dimethicone.
Example 7, a antiperspirant base, differs from example 1 in that the equivalent amount of cetyl dimethicone was used in the emulsifier in place of the PEG-10 dimethicone and the cetyl PEG/PPG-10/1 dimethicone.
Example 8, a antiperspirant base, differs from example 1 in that the agarose is replaced with an equal amount of carbomer in the stabilizer.
Example 9, a antiperspirant powder base, differs from example 1 in that the quaternary ammonium salt-18 hectorite is replaced with an equivalent amount of quaternary ammonium salt-18 bentonite in the stabilizer.
Example 10, a antiperspirant powder base, differs from example 1 in that the same amount of glycerin is used in the humectant in place of butylene glycol.
Example 11, a antiperspirant powder base, differs from example 1 in that the glycerin is replaced with an equal amount of butylene glycol in the humectant.
Example 12, a antiperspirant powder base, differs from example 1 in that the humectant employs equal amounts of peg-4 in place of butylene glycol and glycerin.
Comparative example
Comparative example 1, a antiperspirant powder base, differs from example 1 in that the film former uses an equivalent amount of acrylate/dimethicone in place of cyclopentadecyldimethicone.
Comparative example 2, a antiperspirant powder base, differs from example 1 in that the same amount of cyclopentadimethylsiloxane is used in place of the acrylate/polydimethylsiloxane in the film former.
Comparative example 3, a liquid foundation comprising, based on 100kg of total weight, the following components in mass:
dispersing agent: comprising 3.8 kg of cetyl polydimethylsiloxane and 1.3 kg of polyethylene; 0.3 kg of quaternary ammonium salt-18 kg of bentonite; 6 kilograms of colorant; 2.2 kg of bismuth hydroxide; 4 kilograms of emollient; thickening agent: comprises 5 kg of carbomer (2% aqueous solution) and 5 kg of xanthan gum (2% aqueous solution); conditioner (2): comprises 0.2 kg of passion fruit extract, 3.6 kg of glycosphingolipids, 0.22 kg of paeonia lactiflora root extract, 3 kg of glycerin and 3 kg of 1 and 3-butanediol; the preservatives included 1 kg of octyl glycol; 59.38 kilograms of water.
The liquid foundation is prepared by the following steps:
s1: weighing and mixing quaternary ammonium salt-18 bentonite, emollient and cetyl polydimethylsiloxane, and homogenizing for 5min at a stirring speed of 6000 r/min; adding colorant, and homogenizing at 6000r/min stirring speed for 5min; adding polyethylene and bismuth oxychloride, heating to 80 ℃, and preserving heat to obtain a mixture A;
s2: weighing and mixing the thickening agent, the conditioner, the preservative and water, heating to 80 ℃, and stirring for 2 hours at a stirring speed of 800r/min to obtain a mixture B;
s3: adding the mixture A into the mixture B, and stirring for 10s at a stirring speed of 800r/min to obtain a liquid foundation.
Performance test
1. Testing of waterproof and sweat-resistant performance and smearing and dispersing performance of foundation liquid
Selecting a female subject with 18-35 years old health and no allergy history, cleaning the face with the same mild facial cleanser, wiping, smearing the same toner, beating to completely absorb, and finally making up on the powder. Each test subject was subjected to makeup by 3 cosmetic workers who had been on for 3-5 years.
Waterproof and sweat-resistant performance: after finishing the dressing, the testee needs to use a running machine to exercise in an indoor environment with the temperature of 30 ℃ and the relative humidity of 50RH percent, the speed of the running machine is 6-8 < 13214 >/h, and the running time of each time is 5-10min; resting for 20-30min after running, uniformly spraying water to face with a spray can during resting period to moisten the face, wherein the water spraying amount is 10-20ml each time, and naturally drying. The running and water spraying operations are repeated for 5 times, whether the makeup is removed from the foundation liquid or not is observed, the number of times of performing the test when the makeup is removed is recorded, and the average value of 3 samples is taken as a test result and is recorded as the number (times) of waterproof and sweat-resistant tests.
Smearing and dispersing performance: after finishing makeup, a cosmetic operator needs to grade the smearing and dispersing performance (smoothness) and the shape and face uniformity of the foundation liquid, and the results are scored according to 1-5 points, wherein 1 point is the worst, 5 points are the best, and the average value of 3 samples is taken as a test result.
2. Foundation make-up cosmetic skin care performance test
And selecting female subjects with no allergy history in the age of 30-45 years, and applying makeup by using the above groups of foundation liquid samples, wherein each group of the test subjects has 3 times, and the using time is 1 month. The same mild facial cleanser is used for cleaning and wiping the face, the same toner is smeared, the face is flapped and completely absorbed, and finally the foundation is made up, and other skin care products are not used in the test period. Before and after the test is finished, the face photos are taken by using the same camera under the condition of the same light and lens parameters, the wrinkle change conditions before and after the face wrinkles are used are scored by a professional cosmetologist, and the scores are scored according to 1-5, wherein the higher the score is, the more obvious the face wrinkle reduction or skin repair effect is.
3. Foundation fluid stability test
And (3) taking 75ml of samples from each group of prepared foundation solutions, putting the samples into a transparent glass bottle, then putting the bottles into a 45 ℃ oven for standing for 1h, and taking out the bottles to observe whether the phenomena of precipitation and oil-water stratification exist.
TABLE 2 results of the experiments
And (3) analyzing an experimental result:
(1) By combining examples 1-12 and comparative example 3 and table 2, it can be seen that compared with the conventional hydrophilic film forming agent or thickening agent, the waterproof and sweat-resistant performance of the foundation fluid can be remarkably improved and the makeup-holding performance of the foundation fluid can be improved by adopting the acrylate/polydimethylsiloxane copolymer and the cyclopenta polydimethylsiloxane. By combining example 1 and comparative examples 1-2 with table 2, it can be seen that cyclopentadimethylsiloxane can effectively compensate for the reduced fluidity caused by the use of the acrylate/polydimethylsiloxane copolymer, thereby improving the smoothness and cosmetic surface uniformity of the antiperspirant base.
(2) By combining the example 1 and the examples 4 to 7 and combining the table 2, the cetyl PEG/PPG-10/1 polydimethylsiloxane and the PEG-10 polydimethylsiloxane are used as the emulsifier together, so that the problem of the decrease of the passing rate of hydrophilic substances caused by the introduction of the organic silicon hydrophobic chain segment in the film forming agent can be remarkably improved, the permeability of skin care ingredients such as a skin conditioner, an emollient, a humectant and the like is promoted, and the beautifying and skin care effects of the foundation liquid are guaranteed. And the combination of the two components is more beneficial to expanding the hydrophilic channel and promoting the effective skin care ingredients to pass through the film layer and act on the skin.
(3) In the present application, it can be seen from the combination of example 1 and examples 8 to 9 and table 2 that agarose and quaternary ammonium salt-18 hectorite are used as the water phase stabilizer and the oil phase stabilizer, respectively, to suppress the precipitation of the silicone oil component such as cyclopentamethyldimethicone in the foundation solution or the separation and stratification of the silicone oil component. The reason for this may be that the above two stabilizers have stabilizing effects such as conventional thickening and viscosity increasing, and the quaternary ammonium salt-18 hectorite also has a siloxysilicon segment, and has a good affinity with silicone oil. And hydroxyl in the agarose can form hydrogen bonds with carbonyl or silicon hydroxyl of the acrylate/polydimethylsiloxane copolymer, so that a stabilizing effect is achieved, the possibility of segregation of silicon oil such as cyclopentadimethylsiloxane and the like is further effectively reduced, and the film forming stability of the foundation solution is guaranteed.
(4) In combination with example 1 and examples 10 to 12 and table 2, it can be seen that, compared to polyethylene glycol-4, the present application is helpful to ensure the beauty and skin care effects of the foundation lotion by using glycerin and butylene glycol as moisturizers. The cosmetic composition has excellent permeability such as glycerin and butylene glycol, and thus has good permeability in the foundation liquid film layer, and can effectively promote diffusion of substances such as skin conditioners. And the action effect of macromolecular moisturizers such as polyethylene glycol-4 or sodium hyaluronate is poor.
The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.
Claims (10)
1. The sweat-resistant foundation liquid is characterized by comprising the following raw materials in percentage by weight:
film-forming agent: 3 to 10 percent;
and (3) an emollient: 8.5 to 42 percent;
humectant: 3.5 to 15 percent;
filling agent: 0.5 to 5 percent;
emulsifier: 1 to 10 percent;
skin conditioner: 0.7 to 21 percent;
viscosity modifier: 0.1 to 2 percent;
a stabilizer: 0.2 to 6 percent;
chelating agent: 0.001 to 0.5 percent;
colorant: 0 to 40 percent;
preservative: 0 to 1 percent;
the film forming agent adopts 1-3 mass ratio of acrylate/polydimethylsiloxane copolymer to 2-5 mass ratio of cyclopentadidimethylsiloxane to cyclopentadimethylsiloxane.
2. The sweat-resistant foundation liquid as claimed in claim 1, wherein the emulsifier is used in a mass ratio of 0.5-5: 0.5 to 5 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane and PEG-10 polydimethylsiloxane.
3. The sweat-resistant foundation of claim 1 wherein the stabilizer is selected from the group consisting of agarose, quaternium-18 hectorite, quaternium-18 bentonite, and combinations thereof.
4. The sweat-resistant foundation solution as claimed in claim 3, wherein the stabilizer is used in a mass ratio of 0.1-3: 0.1-3 of water phase stabilizer and oil phase stabilizer, wherein the water phase stabilizer and the oil phase stabilizer are agarose and quaternary ammonium salt-18 hectorite respectively.
5. The sweat-resistant foundation liquid as claimed in claim 1, wherein the humectant is selected from the group consisting of 0.5 to 5: 3-10 butanediol and glycerol.
6. The antiperspirant base of claim 1, wherein the filler is mica or a suspension thereof.
7. The antiperspirant powder base of claim 1, wherein the skin conditioner is selected from one or more of Laminaria digitata extract, cladosiphon okamuranus extract, fucus serratus extract, laminaria japonica extract, zostera marina extract, ulva lactuca extract, and Chondrus crispus extract.
8. The antiperspirant powder base of claim 1, wherein the emollient is selected from one or more of caprylic/capric triglyceride, dioctyl carbonate, isododecane, polydimethylsiloxane, hydrogenated polydecene, and cetyl ethyl hexanoate.
9. The antiperspirant powder base of claim 1, wherein the viscosity modifier is sodium chloride.
10. A method of preparing a antiperspirant powder base according to any of claims 1 to 9, comprising the steps of:
preparing an oil phase: under the heating condition, uniformly mixing a film-forming agent, an emollient, a preservative, an emulsifier and 10-90 wt% of a stabilizer to obtain an emulsion; mixing and grinding part of the emulsion, the filler and the colorant, uniformly mixing the ground emulsion with the rest of the emulsion to obtain an oil phase solution, and keeping the temperature for later use;
preparation of an aqueous phase: under the heating condition, adding the moisturizing agent, the viscosity regulator and the chelating agent into water, dissolving and uniformly mixing to obtain a water phase solution;
and (3) preparing a finished product: mixing the water phase solution and the oil phase solution, homogenizing, emulsifying, and vacuumizing to obtain the sweat-resistant foundation solution;
preferably, the heating temperature is 70-85 ℃;
preferably, the rotation speed of the homogenizing emulsification is 2500-3000rpm, and the time of the homogenizing emulsification is 5-10 minutes.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103356441A (en) * | 2013-07-28 | 2013-10-23 | 娇时化妆品（杭州）有限公司 | Plant essence-containing sunscreen foundation cream |
| CN111012708A (en) * | 2019-12-26 | 2020-04-17 | 娇时日化（杭州）股份有限公司 | Foundation make-up liquid and preparation method thereof |
| CN113940899A (en) * | 2021-09-29 | 2022-01-18 | 广州卓芬化妆品有限公司 | Waterproof foundation composition and preparation method thereof |
| CN115364011A (en) * | 2022-08-25 | 2022-11-22 | 皓雨(广州)化妆品制造有限公司 | Spherical skin care matrix and preparation method and application thereof |
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- 2022-12-21 CN CN202211649203.4A patent/CN115869216A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103356441A (en) * | 2013-07-28 | 2013-10-23 | 娇时化妆品（杭州）有限公司 | Plant essence-containing sunscreen foundation cream |
| CN111012708A (en) * | 2019-12-26 | 2020-04-17 | 娇时日化（杭州）股份有限公司 | Foundation make-up liquid and preparation method thereof |
| CN113940899A (en) * | 2021-09-29 | 2022-01-18 | 广州卓芬化妆品有限公司 | Waterproof foundation composition and preparation method thereof |
| CN115364011A (en) * | 2022-08-25 | 2022-11-22 | 皓雨(广州)化妆品制造有限公司 | Spherical skin care matrix and preparation method and application thereof |
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