CN115843814A - Bactericide composition containing chlorofluoromethrizole and amino-oligosaccharin and application thereof - Google Patents
Bactericide composition containing chlorofluoromethrizole and amino-oligosaccharin and application thereof Download PDFInfo
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide bactericide composition for preventing and treating diseases such as powdery mildew of cucumber, anthracnose of mango and the like and application thereof. According to the application, the cloroxen and the amino-oligosaccharin are compounded to generate a synergistic effect, so that the formed pesticide bactericide has a good sterilization effect and has good activity on diseases such as cucumber powdery mildew and mango anthracnose; the bactericidal composition has the advantages of different action mechanisms of the effective components in the bactericidal composition, increased action sites, expanded control spectrum, reduced single selection pressure on pathogenic bacteria, favorable delay of the generation speed of the drug resistance of diseases, low dosage, low cost, low side effect, no influence on the safety, yield and the like of crops, and the like.
Description
Technical Field
The invention relates to the technical field of pesticides, in particular to a pesticide bactericide containing cloroxen and amino-oligosaccharin for preventing and treating diseases such as cucumber powdery mildew and mango anthracnose and application thereof.
Background
Cucumber powdery mildew is one of the main diseases in the current cucumber production. The cucumber powdery mildew is commonly called as 'white hair disease', the damage of leaves is the heaviest, then, the leaves and stems are the second, after the leaves and tender stems are infected by the powdery mildew, the symptoms are similar to those on the leaves, the scab is smaller, and the powder is less. Yellow spots begin to appear on the leaves, then the yellow spots expand and develop into round or oval spots, and white powdery mildew layers appear on the surfaces. Typically, there are more lower blades than upper blades, and more blades on the back than on the front. The mildew stains are independently dispersed at the early stage and then combined into a large mildew spot, even the large mildew spot can cover the whole leaves, the photosynthesis is seriously influenced, the normal metabolism is interfered, the premature senility is caused, and the cucumber yield is lost; mango is one of the most important tropical fruits and widely planted in tropical and subtropical regions, china is the second largest mango producing area in the world, and the mango anthracnose (Colletotrichum Corda) fungus is a type of globally distributed phytopathogen, the caused mango anthracnose is one of the most main diseases on mango, latent infection is formed on immature mango, and huge economic loss is caused by the attack of the mango during storage and transportation after picking; at present, powdery mildew of cucumber and anthracnose of mango are mainly prevented and controlled by chemical agents, but pesticide residues are easily caused by using a large amount of chemical agents, harm is caused to human health, and meanwhile, the drug resistance is easily generated by applying a single chemical pesticide for a long time.
In view of the severity of diseases such as powdery mildew of cucumber, colletotrichum gloeosporioides and the like and the harmfulness of chemical pesticides, the invention provides a method for preventing and treating diseases by utilizing amino-oligosaccharins and chlorofluoroethanoxazole in a compound combination, which has the advantages of different action mechanisms, increased action sites, expanded control spectrum, reduced single selection pressure on pathogenic bacteria, contribution to avoiding the generation of disease resistance and delaying the generation speed of disease resistance, low dosage, low cost, low side effect of the bactericidal composition, no influence on the safety, yield and the like of crops and the like.
Chlorofloxacin (mefentrifluconazole) is the first triazole bactericide containing an isopropanol structure and has the chemical name of (2 RS) -2- [4- (4-chlorophenoxy) -alpha, alpha-trifluoro-o-tolyl]-1- (1H-1,2,4-triazol-1-yl) propan-2-ol with CAS number 1417782-03-6 and molecular formula C 18 H 15 ClF 3 N 3 O 2 The relative molecular mass is 397.8, and the molecular structural formula of the chlorofluoromethane is shown as formula 1. The chlorofluoromethane can be dissolved in water and an organic solvent, the solubility of the chlorofluoromethane in water is 0.81mg/L at the temperature of 20 ℃, the water solubility is lower, the volatility is lower, and the chlorofluoromethane cannot enter underground water through leaching; the solubilities in the organic solvents acetone, ethyl acetate, xylene and 1,2-dichloroethane were 93.2, 116.2, 8.5 and 55.3mg/L, respectively. Chlorofloxacin has a melting point of 126 deg.C and a degradation point of 300 deg.C, and decomposes under boiling conditions, but is not flammable.
The chlorofluoromethane is a novel isopropyl alcohol triazole bactericide which has broad spectrum, high efficiency and systemic effect and has the functions of eradicating and protecting, and belongs to sterol demethylation inhibitors. Different from the widely used triazole bactericide, the chlorofluoroether oxazole contains an isopropanol structure, so that the mutation of pathogenic bacteria can be reduced, and the drug resistance of the pathogenic bacteria can be delayed.
Amino-oligosaccharin, english name: oligosaccharins are low-toxicity bactericides extracted by microorganism metabolism and have an anti-disease effect, and amino-oligosaccharins can inhibit the growth of some pathogenic bacteria, influence fungal spore germination, induce hypha morphological variation, spore biochemical change and the like. Can excite the gene in the plant body, produce chitinase, glucanase, preservative, PR protein and the like with disease-resistant function, has the function of activating cells, is beneficial to the recovery of the damaged plant, promotes the roots and the seedlings, enhances the stress resistance of crops, and promotes the growth and the development of the plants. The amino-oligosaccharin solution can be widely used for preventing and treating diseases caused by viruses, bacteria and fungi of fruit trees, vegetables, underground rhizomes, tobacco, traditional Chinese medicinal materials and grain and cotton crops.
Because the control difficulty of cucumber powdery mildew and mango anthracnose is high, the harm is serious, the control medicaments commonly used at present, such as prochloraz and the like, are old medicaments with long time and high resistance, and the control effect is poor. In the published reports, the activities of the chlorofluoromethane and the amino-oligosaccharin on cucumber powdery mildew and mango anthracnose are not deeply researched, and the compounding of the chlorofluoromethane and the amino-oligosaccharin is not reported at present. Therefore, in the prior art, different medicaments are combined to control diseases, but the effect of the combination of different medicaments is uncertain, and the combination of different medicaments can produce synergistic effect and antagonistic effect. And the effect of combinations of different agents on different diseases is also uncertain.
Disclosure of Invention
In order to solve the technical problems in the background technology, the application provides a pesticide bactericide containing chlorofluoromethane and amino-oligosaccharin for preventing and treating diseases such as cucumber powdery mildew, mango anthracnose and the like.
The purpose of the invention is realized by the following technical scheme:
a pesticide bactericide containing chlorofluoromethrin and amino-oligosaccharin, the active ingredients of the pesticide bactericide are the chlorofluoromethrin and the amino-oligosaccharin, and the pesticide bactericide is characterized in that: the mass ratio of the chlorofluoromethane to the amino-oligosaccharin is 1-50.
The mass of the chlorofluoromethrin accounts for 1-50% of that of the pesticide bactericide; the mass of the amino-oligosaccharin accounts for 1-30% of the mass of the pesticide bactericide.
As a preferable technical solution, the method is characterized in that: the mass of the chlorofluoroether oxazole accounts for 18 percent of the mass of the pesticide bactericide; the mass of the amino-oligosaccharin accounts for 6% of the mass of the pesticide bactericide.
As a preferable technical solution, the method is characterized in that: the bactericidal composition further comprises the following substances in percentage by mass: 1 to 9 percent of dispersant, 1 to 5.5 percent of wetting agent, 0.1 to 2.5 percent of thickening agent, 0.1 to 4 percent of preservative, 0.9 to 8 percent of antifreeze and the balance of water.
Compared with the prior art, the invention has the following beneficial effects:
in the published reports, the activities of the chlorofluoromethane and the amino-oligosaccharin on cucumber powdery mildew and mango anthracnose are not deeply researched, and the combination of the chlorofluoromethane and the amino-oligosaccharin for preventing and treating the cucumber powdery mildew and the mango anthracnose is not reported at present. The bactericide composition containing the cloroxen conazole and the amino-oligosaccharin is compounded, has obvious synergistic effect, can effectively improve the control effect on diseases such as cucumber powdery mildew, mango anthracnose and the like, can reduce the using dosage of active ingredients, reduces the production cost and reduces the environmental pollution.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
The embodiment of the invention provides a pesticide bactericide, and the raw materials of active ingredients of the pesticide bactericide comprise chlorofluoromethane and amino-oligosaccharin. The embodiment of the invention specifically selects the chlorofluoroethane bacteria azole and the amino-oligosaccharin for compounding, and the chlorofluoroethane bacteria azole and the amino-oligosaccharin can generate synergistic action, so that the formed pesticide bactericide has good bactericidal effect and a large control spectrum, and particularly has good control effect on powdery mildew of cucumber and anthracnose of mango.
The dispersant provided by the embodiment of the invention includes but is not limited to the existing dispersant such as sodium lignosulfonate, the wetting agent includes but is not limited to the existing surfactant such as sodium dodecyl sulfate, the thickening agent includes but is not limited to the existing thickening agent such as xanthan gum, the preservative includes but is not limited to the existing preservative such as sodium benzoate, and the antifreeze includes but is not limited to the existing antifreeze such as ethylene glycol.
The bactericide provided by the invention is used for preventing and treating diseases of crops including but not limited to cucumber powdery mildew, mango anthracnose and the like, and the pesticide bactericide has better prevention and treatment effects on the cucumber powdery mildew and the mango anthracnose. In addition, the pesticide bactericide can not influence the normal growth of plants. The pesticide bactericide is a liquid preparation, preferably a suspending agent, and it should be noted that the embodiment of the invention only exemplifies the suspending agent, but it is understood that other types of liquid preparations are also within the scope of the embodiment of the invention.
The features and properties of the present invention are described in further detail below with reference to examples.
Example 1
The embodiment of the invention provides a sterilization composition, the effective components of the sterilization composition are chlorofluoromethane and amino-oligosaccharin, and the mass ratio of the chlorofluoromethane to the amino-oligosaccharin is 18.
Example 2
The embodiment of the invention provides a sterilization composition, the effective components of the sterilization composition are chlorofluoromethane and amino-oligosaccharin, and the mass ratio of the chlorofluoromethane to the amino-oligosaccharin is 18.
Example 3
The embodiment of the invention provides a sterilization composition, the effective components of the sterilization composition are chlorofluoromethane and amino-oligosaccharin, and the mass ratio of the chlorofluoromethane to the amino-oligosaccharin is 18.
Example 4
The embodiment of the invention provides a sterilization composition, the effective components of the sterilization composition are chlorofluoromethane and amino-oligosaccharin, and the mass ratio of the chlorofluoromethane to the amino-oligosaccharin is 18.
Example 5
The embodiment of the invention provides a sterilization composition, the effective components of the sterilization composition are chlorofluoromethane and amino-oligosaccharin, and the mass ratio of the chlorofluoromethane to the amino-oligosaccharin is 18.
Example 6
The embodiment provides a bactericidal composition, which comprises the following components in percentage by mass:
TABLE 1 fungicidal compositions
Name of ingredient | Content (%) |
Chlorofloxacin hydrochloride | 18 |
Amino-oligosaccharins | 10 |
Lignosulfonic acid sodium salt | 1.9 |
Sodium dodecyl sulfate | 2.7 |
Xanthan gum | 0.2 |
Sodium benzoate | 0.3 |
Ethylene glycol | 2.7 |
Water (W) | Make up the balance |
Example 7
The embodiment provides a bactericidal composition, which comprises the following components in percentage by mass:
TABLE 2 composition of the bactericidal composition
Name of ingredient | Content (%) |
Chlorofloxacin hydrochloride | 18 |
Amino-oligosaccharins | 8 |
Lignosulfonic acid sodium salt | 2.0 |
Sodium dodecyl sulfate | 3.1 |
Xanthan gum | 0.15 |
Sodium benzoate | 0.5 |
Ethylene glycol | 2 |
Water (W) | Make up the balance |
Example 8
The embodiment provides a bactericidal composition, which comprises the following components in percentage by mass:
TABLE 3 the ratio of the components in the bactericidal composition
Name of ingredient | Content (%) |
Chlorofloxacin hydrochloride | 18 |
Amino-oligosaccharins | 6 |
Lignosulfonic acid sodium salt | 2.1 |
Sodium dodecyl sulfate | 3.2 |
Xanthan gum | 0.2 |
Sodium benzoate | 0.6 |
Ethylene glycol | 0.9 |
Water (W) | Make up the balance |
Example 9
The embodiment provides a bactericidal composition, which comprises the following components in percentage by mass:
TABLE 4 composition of bactericidal composition
Name of ingredient | Content (%) |
Chlorofloxacin hydrochloride | 18 |
Amino-oligosaccharins | 4 |
Lignosulfonic acid sodium salt | 2.3 |
Sodium dodecyl sulfate | 3.5 |
Xanthan gum | 0.2 |
Sodium benzoate | 0.5 |
Ethylene glycol | 3.1 |
Water (W) | Make up the balance |
Example 10
The embodiment provides a bactericidal composition, which comprises the following components in percentage by mass:
TABLE 5 composition of the composition
Names of ingredients | Content (%) |
Chlorofloxacin (CFR) azole | 18 |
Amino-oligosaccharins | 2 |
Lignosulfonic acid sodium salt | 3.2 |
Sodium dodecyl sulfate | 2.7 |
Xanthan gum | 0.2 |
Sodium benzoate | 0.4 |
Ethylene glycol | 3.5 |
Water (W) | Make up the balance |
Experimental example 1 biological Activity test
According to the indoor bioassay test guidelines NY/T1156.11-2008 and NY/T1156.6-2006 of pesticides, the optimal mixing mass ratio of the two bactericides is screened by measuring the effect of blending of the chlorofluoromethane, the amino-oligosaccharin and different mass ratios thereof on cucumber powdery mildew.
A. Cucumber powdery mildew (Sphaerotheca fuliginea (Schlecht.) Pollacci) was provided by the university of Qingdao agriculture plant pathology laboratory, and the mildew layer on the leaf surface was washed with deionized water to obtain a mother liquor of conidium suspension, which was then adjusted to a concentration of 1X 10 under a microscope 5 The single spore/ml is the conidium suspension of the powdery mildew of cucumber, and the conidium suspension is preserved in a refrigerator at 4 ℃ for standby.
B. The test agents were 97% chlorofluoromethane technical (from Pasteur Europe), 85% amino-oligosaccharin technical (from Qingdao agriculture technology Co., ltd.)
C. Chlorofluoromethrizole: the mixing ratio of the amino-oligosaccharin is as follows: 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4 formulation concentrations are shown in Table 6:
TABLE 6 dosage ratio of each substance of the bactericidal composition
D. Virulence test method
Selecting potted cucumber seedlings with 4-6 leaves and consistent growth vigor, dissolving the potted cucumber seedlings with acetone according to the treatment dosage shown in the table 6, preparing the solution with corresponding concentration, uniformly spraying liquid medicines with different treatment concentrations on the cucumber leaves to be tested respectively by using a spraying pot with the capacity of 1 kilogram and the diameter of a spraying hole of 1 millimeter, and naturally drying the cucumber seedlings. The treatment of spraying clear water was set as a blank control. Each treatment had 5 pots, 2 plants per pot; after the medicament is treated for 24 hours, uniformly spraying the spore suspension liquid in the step A on cucumber leaves by using a throat sprayer (the pressure is 0.1 MPa), inoculating pathogenic bacteria, culturing in a greenhouse for 10-15 days, investigating and recording the disease condition after the clear water is fully used for controlling the disease, calculating the control effect by adopting a formula,
the classification criteria are as follows:
level 0: no disease spots;
level 1: the lesion area accounts for less than 5% of the whole leaf area;
and 3, level: the lesion area accounts for 5 to 15 percent of the whole leaf area;
and 5, stage: the lesion area accounts for 15 to 25 percent of the whole leaf area;
and 7, stage: the lesion spot area accounts for 25-50% of the whole leaf area;
and 9, stage: the lesion area accounts for more than 50-75% of the whole leaf area;
stage 11: the lesion area accounts for more than 75% of the whole leaf area;
using DPS statistical software to carry out regression analysis on the treatment concentration logarithmic value and the corresponding inhibition rate probability value of each single agent and the mixed combination with different proportions, and calculating a toxicity regression curve and EC 50 Value, correlation coefficient, and calculating co-toxicity coefficient (CTC value) of the mixture according to Sun cloud Peel method.
The co-toxicity coefficient (CTC value) of the mixture is calculated according to the formula (1), the formula (2) and the formula (3):
in the formula: ATI-measured toxicity index of mixed agent;
S-EC of Standard Fungicide 50 In milligrams per liter (mg/L);
EC of M-mixtures 50 In milligrams per liter (mg/L).
TTI=A×P A +B×P B ···················(2)
In the formula: TTI-theoretical virulence index of the mixture;
A-A agent virulence index;
P A -the percentage of agent a in the mixture in percent (%);
B-B agent virulence index;
P B the percentage of the B agent in the mixture is in percentage (%).
In the formula: CTC-co-toxicity coefficient; ATI-measured toxicity index of mixed agent; TTI-theoretical virulence index of the mixture.
The co-toxicity coefficient (CTC) of the compound combination is more than or equal to 120, which shows a synergistic effect; CTC is less than or equal to 80 and shows antagonism; 80 < CTC < 120 showed additive effects.
E. The results are shown in tables 7 and 8:
TABLE 7 toxicity test results of CFR, amino-oligosaccharin and 7 ratios
TABLE 8 measurement results of combined toxicity of CFR (chlorofluorocarbon Ether-myclobutanil) and amino-oligosaccharin on cucumber powdery mildew
The research shows (Table 8) that the effective inhibition of cucumber powdery mildew by 7 proportioning agents (Chlorofloxacin: amino-oligosaccharin =4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4) has 0.7832, 0.8466, 1.0852, 1.5306, 2.8259, 4.3017 and 5.2493mg/L respectively, the co-toxicity coefficient (CTC) is 3725 zxft 25, 139.18, 121.23, 112.08 5252, 87.21, 73.29 and 58 zxft 6258, and the proportioning agents show the synergistic effects of the Chlorofloxacin 6258, 87.21 and 87.21.
Experimental example 2 field drug effect test
The first field pesticide effect test: the bactericidal composition prepared in application example 8 is used for preventing and controlling cucumber powdery mildew in the field.
1. Test method
The test agents are shown in table 9 below:
TABLE 9 Scale for each drug test
The city of Qingdao, shandong province Jiang Mazhuang village (36.052071, east longitude 119.878151). The area of the test field is 2 mu, the pH value of the soil is 6.4, and the organic matter content is 1.8%. The test crop is cucumber, the cucumber is glossy No. 2, the plant spacing is 30cm, the row spacing is 80cm, the field management is uniform and consistent, the method accords with the local agricultural production practice, and the cucumber is transplanted in 2021, 4 months and 15 days. Cultivation management is performed according to local scientific cultivation measures. The test target is cucumber powdery mildew. The application method is that the application is carried out for the 1 st time in the early stage (5 months and 25 days) of the powdery mildew of the cucumber by the conventional spraying method, the application is carried out for the 2 nd time at intervals of 7 days and 6 months and 1 day, and the application is carried out for 2 times in the test.
The liquid medicine is sprayed by a common pressure storage type manual sprayer (commercially available), a conical nozzle can be adjusted, the pressure is 0.3MPa, the spraying speed is 0.6 liter/minute, and the liquid medicine usage amount per hectare is 750 liters; the disease incidence of powdery mildew of cucumber is investigated on the field before the first pesticide application, the investigation is carried out on the 10 th day after the last pesticide application, four-point sampling is randomly carried out in each plot, all leaves of two plants are investigated at each point, and grading record is carried out according to the percentage of the lesion area on the leaves to the whole leaf area of the leaves.
The classification criteria are as follows:
level 0: no lesion spots;
stage 1: the lesion area accounts for less than 5% of the whole leaf area;
and 3, level: the lesion area accounts for 6 to 10 percent of the whole leaf area;
stage 5: the lesion area accounts for 11% -20% of the whole leaf area;
and 7, stage: the lesion area accounts for 21-40% of the whole leaf area;
and 9, stage: the lesion area accounts for more than 41% of the whole leaf area.
2. Test results
The control effect of different medicament treatments on cucumber powdery mildew is shown in table 10 below.
TABLE 10 control of cucumber powdery mildew by different treatments
According to the table, the results of the control effect survey show that: example 8, the control effect of the preparation with the dosage of 40 ml/mu is the best, and the control effect is 87.74%, which is remarkably superior to the control effects of two single-dose control medicaments. Through field observation, the tested medicament and the control medicament are safe to cucumber serving as a test crop, and no phytotoxicity symptoms (such as dwarfing, chlorosis, deformity and the like) are found.
And (2) field efficacy test II: the bactericidal composition prepared in application example 8 is used for preventing and controlling mango anthracnose in fields.
1. The test method comprises the following steps:
the test agents are shown in table 11 below:
TABLE 11 Scale for each drug test
Hokkiso Mao Zhuocun (north latitude 18.758, east longitude 109.406) in Hainan province. The test field area is 2 mu, the pH value of the soil is 6.5, and the organic matter content is 1.9%. The test crop is mango, the tree age is 5 years, the mango is in the early stage of growth of new shoots, the field management is uniform, and the local agricultural production practice is met. The test target is mango anthracnose. The application method is that the application is carried out for the 1 st time in the early stage of mango anthracnose attack (1 month and 18 days 2021), the application is carried out for the 2 nd time at intervals of 7 days, and the application is carried out for the 2 nd time in 1 month and 25 days 2021, wherein the application is carried out for 2 times in the test.
The liquid medicine is sprayed by a common pressure storage type manual sprayer (commercially available), a conical nozzle can be adjusted, the pressure is 0.3MPa, the spraying speed is 0.6 liter/min, and the liquid medicine usage amount per hectare is 900 liters; the disease condition of mango anthracnose is investigated in the field before the first pesticide application, the investigation is carried out on the 7 th day after the last pesticide application, 3 plants are investigated in each plot, each plant investigates all 2 tips of leaves according to each point of five directions of east, south, west, north and middle, the total leaf number and the diseased leaf number of each grade are recorded, and the grading record is carried out according to the percentage of the diseased spot area on the leaves to the whole leaf area of the leaves.
The classification criteria are as follows:
level 0: no disease spots;
level 1: the lesion area accounts for less than 5% of the whole leaf area;
and 3, level: the lesion area accounts for 6 to 15 percent of the whole leaf area;
and 5, stage: the lesion area accounts for 16-25% of the whole leaf area;
and 7, stage: the lesion area accounts for 26-50% of the whole leaf area;
and 9, stage: the lesion area accounts for more than 51% of the whole leaf area.
2. Test results
The control effect of different agent treatments on mango anthracnose is shown in table 12 below.
TABLE 12 control of mango anthracnose by different pharmacological treatments
According to the table, the control effect investigation result shows that in example 8, the effect of controlling mango anthracnose is the best when the dosage of the preparation is 1200 times of that of the diluted solution, and the control effect is 86.70%, which is remarkably superior to that of two single-dose control medicaments. Through field observation, the test agent and the control agent are safe to mango serving as a test crop, and no phytotoxicity symptoms (such as dwarfing, chlorosis, deformity and the like) are found.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (6)
1. A pesticide bactericide containing chlorofluoroether oxazole and amino-oligosaccharin is characterized in that: the pesticide bactericide is used for preventing and treating diseases such as powdery mildew of cucumber, anthracnose of mango and the like.
2. The pesticidal fungicide containing chlorofluoroether azole and amino-oligosaccharins according to claim 1, characterized in that: the mass ratio of the chlorofluoroether azole to the amino-oligosaccharin is 1 to 50.
3. The pesticidal fungicide containing chlorofluoromethrizole and amino-oligosaccharins according to claim 1, characterized in that: the mass of the chlorofluoromethrin accounts for 1-50% of that of the pesticide bactericide; the mass of the amino-oligosaccharin accounts for 1-30% of the mass of the pesticide bactericide.
4. The pesticidal fungicide containing chlorofluoromethrizole and amino-oligosaccharins according to claim 1, characterized in that: the mass of the chlorofluoroether oxazole accounts for 18 percent of the mass of the pesticide bactericide; the mass of the amino-oligosaccharin accounts for 6% of the mass of the pesticide bactericide.
5. The bactericidal composition containing chlorofluoromethrizole and amino-oligosaccharins according to any one of claims 1 to 4, characterized in that: the dosage form of the bactericidal composition is a liquid preparation.
6. The bactericidal composition containing difenoconazole and amino-oligosaccharin according to claim 5, wherein: the bactericidal composition further comprises the following substances in percentage by mass: 1 to 9 percent of dispersant, 1 to 5.5 percent of wetting agent, 0.1 to 2.5 percent of thickening agent, 0.1 to 4 percent of preservative, 0.9 to 8 percent of antifreezing agent and the balance of water.
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CN103649057A (en) * | 2011-07-13 | 2014-03-19 | 巴斯夫欧洲公司 | Fungicidal substituted 2-[2-halogenalkyl-4-(phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds |
CN103648281A (en) * | 2011-07-15 | 2014-03-19 | 巴斯夫欧洲公司 | Fungicidal alkyl-substituted 2-[2-chloro-4-(4-chloro-phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds |
CN105050406A (en) * | 2012-12-20 | 2015-11-11 | 巴斯夫农业公司 | Compositions comprising a triazole compound |
CN114946862A (en) * | 2022-06-24 | 2022-08-30 | 陕西康禾立丰生物科技药业有限公司 | Bactericide containing amino-oligosaccharin and meperflutonazol |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103649057A (en) * | 2011-07-13 | 2014-03-19 | 巴斯夫欧洲公司 | Fungicidal substituted 2-[2-halogenalkyl-4-(phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds |
CN103648281A (en) * | 2011-07-15 | 2014-03-19 | 巴斯夫欧洲公司 | Fungicidal alkyl-substituted 2-[2-chloro-4-(4-chloro-phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds |
CN105050406A (en) * | 2012-12-20 | 2015-11-11 | 巴斯夫农业公司 | Compositions comprising a triazole compound |
CN114946862A (en) * | 2022-06-24 | 2022-08-30 | 陕西康禾立丰生物科技药业有限公司 | Bactericide containing amino-oligosaccharin and meperflutonazol |
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