CN1158315C - 制备乙烯/烯烃共聚合物的方法 - Google Patents

制备乙烯/烯烃共聚合物的方法 Download PDF

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Publication number
CN1158315C
CN1158315C CNB998168750A CN99816875A CN1158315C CN 1158315 C CN1158315 C CN 1158315C CN B998168750 A CNB998168750 A CN B998168750A CN 99816875 A CN99816875 A CN 99816875A CN 1158315 C CN1158315 C CN 1158315C
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China
Prior art keywords
ethylene
properties
ether
correcting agent
methyl
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Expired - Lifetime
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CNB998168750A
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English (en)
Chinese (zh)
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CN1367800A (zh
Inventor
R・R・福特
R·R·福特
范德比尔特
J·J·范德比尔特
威廉斯
D·S·威廉斯
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Westlake Longview Corp
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Eastman Chemical Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CNB998168750A 1999-06-07 1999-10-14 制备乙烯/烯烃共聚合物的方法 Expired - Lifetime CN1158315C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13798099P 1999-06-07 1999-06-07
US60/137980 1999-06-07
US09/387,364 US6417299B1 (en) 1999-06-07 1999-08-31 Process for producing ethylene/olefin interpolymers
US09/387364 1999-08-31

Publications (2)

Publication Number Publication Date
CN1367800A CN1367800A (zh) 2002-09-04
CN1158315C true CN1158315C (zh) 2004-07-21

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CNB998168750A Expired - Lifetime CN1158315C (zh) 1999-06-07 1999-10-14 制备乙烯/烯烃共聚合物的方法

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Country Link
US (1) US6417299B1 (enExample)
EP (1) EP1187857B1 (enExample)
JP (1) JP2003506493A (enExample)
CN (1) CN1158315C (enExample)
BR (1) BR9917353B1 (enExample)
CA (1) CA2375629A1 (enExample)
DE (1) DE69914381T2 (enExample)
MX (1) MXPA01012647A (enExample)
WO (1) WO2000075203A1 (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6417301B1 (en) * 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417298B1 (en) * 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
EP1194459B1 (en) * 1999-06-25 2005-12-14 Eastman Chemical Company Process for the polymerization of olefins; polyolefins, and films and articles produced therefrom
SG95635A1 (en) * 2000-03-30 2003-04-23 Sumitomo Chemical Co Process for producing catalyst for ethylene polymerization and process for producing ehtylene polymer
FR2806930B1 (fr) * 2000-04-04 2002-06-28 Rhodia Chimie Sa Utilisation d'un derive de bore a titre de catalyseur thermoactivable pour la polymerisation et/ou reticulation de silicone par deshydrogenocondensation
US7393910B2 (en) * 2003-09-23 2008-07-01 Dow Global Technologies Inc. Catalyst composition for ethylene polymerization
US7238756B2 (en) * 2003-10-15 2007-07-03 Univation Technologies, Llc Polymerization process and control of polymer composition properties
US6828395B1 (en) 2003-10-15 2004-12-07 Univation Technologies, Llc Polymerization process and control of polymer composition properties
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
WO2008052673A1 (en) * 2006-10-30 2008-05-08 Basell Polyolefine Gmbh Process for the polymerization of olefins using catalyst systems based on an organic transition metal complex
EP2062924A1 (en) 2007-11-22 2009-05-27 Ineos Europe Limited Process for polymerising ethylene
CN102344507A (zh) * 2010-07-30 2012-02-08 中国石油化工股份有限公司 一种用于乙烯聚合反应的催化剂组分及其催化剂
CN102344506A (zh) * 2010-07-30 2012-02-08 中国石油化工股份有限公司 用于乙烯聚合的催化剂组分及其催化剂
CN102372799B (zh) * 2010-08-19 2013-03-27 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分及其制备方法
CN102372800B (zh) * 2010-08-19 2013-03-27 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分及其制备方法
CN102372803B (zh) * 2010-08-19 2013-03-27 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其制备方法
CN102453132B (zh) * 2010-10-19 2013-03-27 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分及制备方法
CN102453126B (zh) * 2010-10-19 2013-03-27 中国石油化工股份有限公司 烯烃聚合的催化剂组份、制备方法及应用
CN102372802B (zh) * 2010-08-19 2013-03-27 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分及其制备方法
MY163741A (en) 2010-08-19 2017-10-31 China Petroleum & Chem Corp Cataltic component for polymerization of olefin and preparation method thereof
CN102372801B (zh) * 2010-08-19 2013-05-01 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分及其制备方法
CN102372798B (zh) * 2010-08-19 2013-03-27 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其制备方法
US9617355B2 (en) * 2010-10-07 2017-04-11 Saudi Basic Industries Corporation Process for polymerisation of ethylene
CN112279950B (zh) * 2019-07-25 2022-12-02 中国石油天然气股份有限公司 用于乙烯气相聚合工艺的催化剂、催化剂组分及制备方法
WO2021221987A1 (en) * 2020-04-30 2021-11-04 Dow Global Technologies Llc Ziegler-natta (pro)catalyst systems made with azaheterocyclic compound

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USB632416I5 (enExample) 1956-03-01 1976-03-09
BE559727A (enExample) 1956-08-02
US4003712A (en) 1970-07-29 1977-01-18 Union Carbide Corporation Fluidized bed reactor
NO136797C (no) 1970-09-25 1977-11-09 Union Carbide Corp Fremgangsm}te for polymerisering av etylen med modifisert katalysator
US4012573A (en) 1970-10-09 1977-03-15 Basf Aktiengesellschaft Method of removing heat from polymerization reactions of monomers in the gas phase
US3709853A (en) 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
LU65587A1 (enExample) 1972-06-22 1973-12-27
US3917575A (en) 1972-11-11 1975-11-04 Nippon Oil Co Ltd Process for production of polyolefins
US4011382A (en) 1975-03-10 1977-03-08 Union Carbide Corporation Preparation of low and medium density ethylene polymer in fluid bed reactor
US4234710A (en) 1976-07-08 1980-11-18 Phillips Petroleum Company Catalyst and a polymerization process employing the catalyst
GR63148B (en) 1976-05-17 1979-09-25 Mitsui Toatsu Chemicals Process for the polymerization of ethylene of a-olefins and catalyst therefor
US4256866A (en) 1976-06-16 1981-03-17 Standard Oil Company (Indiana) Polymerization process
US4302566A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
US4302565A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
JPS588686B2 (ja) 1978-12-01 1983-02-17 チッソ株式会社 α↓−オレフイン重合体の製造方法
US4293673A (en) 1978-12-28 1981-10-06 Union Carbide Corporation Spheroidal polymerization catalyst, process for preparing, and use for ethylene polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4564647A (en) 1983-11-14 1986-01-14 Idemitsu Kosan Company Limited Process for the production of polyethylene compositions
JPS60135409A (ja) 1983-12-23 1985-07-18 Chisso Corp オレフイン重合用触媒とその製造法
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
FI881337A7 (fi) 1987-03-23 1988-09-24 Idemitsu Petrochemical Co Foerfarande foer framstaellning av polyolefiner.
FR2616789B1 (fr) 1987-06-16 1991-07-26 Atochem Procede de traitement de composante catalytique sur support d'oxyde metallique poreux pour la polymerisation des olefines en phase gazeuse. application du catalyseur obtenu a la polymerisation des olefines
FR2618786B1 (fr) 1987-07-31 1989-12-01 Bp Chimie Sa Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
FR2640273B1 (fr) 1988-12-14 1992-09-04 Atochem Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire
US5244987A (en) 1988-12-22 1993-09-14 Bf Chemicals Limited Process for alpha-olefin gas-phase polymerization controlled by the simultaneous addition of an activator and an activity retarder to the polymerization medium
US5227440A (en) 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2656314B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
KR940000014B1 (ko) 1990-10-10 1994-01-05 한국과학기술원 Hdpe 및 lldpe 중합용 고활성 찌이글러-나타 촉매의 합성
US5466766A (en) 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
EP0515132B2 (en) 1991-05-20 2003-08-27 Mitsui Chemicals, Inc. Olefin polymerization catalyst and olefin polymerization
US5470812A (en) 1991-11-06 1995-11-28 Mobil Oil Corporation High activity polyethylene catalysts prepared with alkoxysilane reagents
CA2082678C (en) 1991-11-12 1996-07-30 Naoki Kataoka Catalyst components for polymerization of olefins
IT1262933B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Processo per la polimerizzazione in fase gas di alfa-olefine
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
EP0564211A3 (en) 1992-04-03 1993-10-20 BP Chemicals Limited Process for the preparation of a ziegler-natta catalyst
EP0578838A1 (en) 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
JP3202349B2 (ja) 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
JPH06128331A (ja) * 1992-10-15 1994-05-10 Showa Denko Kk エチレン共重合体の製造方法
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5376743A (en) 1993-03-11 1994-12-27 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of sticky polymers
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
AU6596694A (en) 1993-06-28 1995-01-05 Union Carbide Chemicals & Plastics Technology Corporation Use of lewis bases for activity reduction in metallocene catalyzed olefin polymerization process
FR2707651B1 (fr) 1993-07-13 1995-08-25 Bp Chemicals Snc Procédé pour augmenter l'activité d'un catalyseur de type Ziegler-Natta.
ES2165425T3 (es) 1994-06-24 2002-03-16 Exxonmobil Chem Patents Inc Sistemas cataliticos de polimerizacion, su produccion y uso.
US5468702A (en) 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
US6015867A (en) 1994-09-28 2000-01-18 Showa Denko K.K. 3-alkoxypropionic ester derivative, olefin polymerization catalyst, and process for preparation of polyolefin
JP3517471B2 (ja) 1994-12-28 2004-04-12 三井化学株式会社 環状オレフィン共重合体の製造方法
US5880241A (en) 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
US6114477A (en) * 1996-02-09 2000-09-05 Exxon Chemical Patents Inc. Polymerization process
CZ170897A3 (en) 1996-06-06 1997-12-17 Union Carbide Chem Plastic Control of static charge in the course of polymerization process during which metallocene catalyst is used
US5777120A (en) 1997-03-14 1998-07-07 University Of Iowa Research Foundation Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts

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Publication number Publication date
EP1187857A1 (en) 2002-03-20
DE69914381D1 (de) 2004-02-26
CN1367800A (zh) 2002-09-04
CA2375629A1 (en) 2000-12-14
BR9917353A (pt) 2002-02-26
US6417299B1 (en) 2002-07-09
BR9917353B1 (pt) 2009-08-11
EP1187857B1 (en) 2004-01-21
MXPA01012647A (es) 2002-06-04
WO2000075203A1 (en) 2000-12-14
DE69914381T2 (de) 2004-12-02
JP2003506493A (ja) 2003-02-18

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