CN1155750C - Health-care multi-element fabric and its preparing process - Google Patents
Health-care multi-element fabric and its preparing process Download PDFInfo
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- CN1155750C CN1155750C CNB99109882XA CN99109882A CN1155750C CN 1155750 C CN1155750 C CN 1155750C CN B99109882X A CNB99109882X A CN B99109882XA CN 99109882 A CN99109882 A CN 99109882A CN 1155750 C CN1155750 C CN 1155750C
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- 239000007788 liquid Substances 0.000 claims abstract description 28
- 239000000835 fiber Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000009792 diffusion process Methods 0.000 claims abstract description 9
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- 239000000395 magnesium oxide Substances 0.000 claims abstract description 8
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- 239000000203 mixture Substances 0.000 claims description 17
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- 238000004061 bleaching Methods 0.000 claims description 4
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- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
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- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
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- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 1
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- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
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- GQNBIMLHUAWKHJ-UHFFFAOYSA-N [4-(methoxymethyl)phenyl]methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound C1=CC(COC)=CC=C1COC(=O)C1C(C)(C)C1C=C(C)C GQNBIMLHUAWKHJ-UHFFFAOYSA-N 0.000 description 1
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- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention belongs to healthy multi-element fabric which is multifunctional fabric containing a plurality of elements, and a making method thereof. The making method comprises the steps of the preparation of a multi-element finishing agent of the fabric and the establishment of the technology. The finishing agent comprises the components of magnesium oxide, titanium dioxide, alumina, silicon dioxide, a repellent, a diffusion liquid, etc. A finishing liquid made by adding a printing and dyeing auxiliary adopts a padding method to treat the fabric to make the finishing agent of the healthy multi-element fabric stuck in the fabric fiber. The fabric after being finished has the multiple functions of far-infrared health care, ultra-violet light resistance, mosquito repelling, antisepsis and deodorization, and can be made into articles for wearing such as shirts and knitting underwear, and bedding articles such as bed sheets, quilts, mattresses, etc.
Description
The invention relates to a kind of health care fabric, more particularly about a kind of health-care multi-element fabric that constitutes by multiple element and preparation method thereof with far infrared health care, antiultraviolet, mosquito repellent and antibacterial deodourizing.
Far infrared and ultraviolet ray are two kinds of invisible rays in the sunshine, the wavelength of far infrared is 4～1000 μ M, the optimal absorption wave band of human body is 4～14 μ M, life science confirms that human body is a far infrared radiation source, electromagnetic wave as absorption of human body 4～14 μ M, when identical with the regular movements frequency of hydrone motion in the human cell tissue, hydrone is activated, energy sharply increases, and the temperature at hypodermis deep layer position is raise, and has quickened the formation of biology enzyme, thereby the power of regeneration of enhancing body's immunological function and human-body biological cell, improved microcirculation, enhanced metabolism, strengthened healthy.
Ultraviolet wavelength is 200～400 μ M, can be divided into three wave bands according to wavelength: (1) UVC wavelength is 200～290 μ M; (2) the UVB wavelength is 290～320 μ M; (3) the UVA wavelength is 320～400 μ M, and wherein UVC is stopped that by atmosphere to shine ground less.In recent years because the destruction of atmospheric ozone layer, the energy that harmful ultraviolet (UV) B, UVA arrive ground strengthens, especially its energy of UVB is 1000 times of UVA, be subjected to the influence of this wave band, can make that human brain is slow in reacting, failure of memory, skin are aging rapidly, swelling, get blister even bring out lupus erythematosus and skin cancer, can make eyes cause cataract prematurely simultaneously, how to prevent harmful ultraviolet ray, especially the excessive width of cloth of UVB is penetrated, and becomes the focus that current society payes attention to.
Mosquito beats one's brains the people to the mankind's invasion, and bite by mosquitos was sucked blood of human body, caused red swelling of the skin to scratch where it itches summer, and influence is slept and worked and spreads disease.It has not only destroyed the arduous degree that the comfortableness of living has also increased field work, the World Health Organization points out: the control of indoor pest will be based on repellent, high lethal agricultural chemicals all constitutes great harm to the mankind of pest natural enemy, useful insect and the Room of living together, on healthy fabric, increase the function of mosquito repellent, will be of value to the general level of the health and the life that improve people.
In the prior art, both at home and abroad to far infrared and ultraviolet prevention fiber and fabric, all once made report respectively, open clear 61-12908 " fibre that contains ceramic powder " as the Japan Patent spy, comprise fine far infrared powder, add in the solution of spinning, make the far IR fibre goods.Chinese patent publication number CN1186885A, exercise question are " far infrared thermal insulation, health, anti-stink fabric and preparation method thereof ", with the far infrared attritive powder by pad, coating process makes the far infrared micro mist attached on the fabric.The antiultraviolet aspect, Japanese clear 56-118963 discloses a kind of processing method of ultraviolet prevention fiber, and the spy opens flat 5-179568 " anti-ultraviolet finishing agent reaches and puts cloth thereafter in order " and discloses a kind of with putting cloth in order behind the rolling antiultraviolet of inorganic oxide solution.But these methods all are that the attritive powder of far infrared and antiultraviolet is dosed in the working solution of fibre spinning and the arrangement of dyeing back individually, fiber of making and fabric only possess the simple function of far infrared and antiultraviolet, do not possess total multiple function, promptly have simultaneously in the anti-ultraviolet function in summer and the far infrared thermal insulation, health function of autumn and winter.
What mosquito repellent fabric people adopted for a long time is the method for medicine dipping, promptly comprises that with pesticide organochlorine, organophosphor, carbamate, synthetic pyrethroid etc. soak fabrics.Though organochlorine, organophosphor have insecticidal effect preferably, bigger to human allergy's property, excitant, long-term use easily causes poisoning, and the time that the method for soaking is kept is short, not wash resistant.Chinese patent publication number CN1094105A discloses a kind of expelling parasite cloth and expelling parasite protective articles, is that the Chinese medicine tuber of stemona is refined into the wide spectrum pest repellant, permeates among cloth with chemical method, but is difficult for promoting because of the taste of its Chinese medicine and washing resistance difference.
One of purpose of the present invention provides a kind of health-care multi-element fabric, and the existing far infrared thermal insulation, health effect of this fabric has the function that prevents harmful ultraviolet radiation and mosquito repellent again.
Another object of the present invention provides a kind of preparation method of health-care multi-element fabric, the finishing agent that soon has the multiple element composition of far infrared, antiultraviolet, mosquito repellent characteristic is simultaneously made dressing liquid, by the process of padding, make these finishing agents securely attached in the fabric, make fabric have far infrared thermal insulation, health simultaneously and prevent that harmful ultraviolet ray, mosquito repellent are antibiotic, the function of deodorization, do not lose the original style of fabric.
These and other purposes of the present invention will further be set forth and embody by following description and explanation.
In health-care multi-element fabric of the present invention, in set between the fabric fibre or on the fiber polynary finishing agent is arranged, this finishing agent has following composition:
Magnesia 5～10 weight portions, titanium dioxide 10～30 weight portions,
Alundum (Al 5～20 weight portions, silica 5～20 weight portions,
Repellant 8～20 weight portions, diffusion liquid 40～70 weight portions.
Further, this health-care multi-element fabric has polynary finishing agent in set between the fabric fibre or on the fiber, and this finishing agent has following composition:
Magnesia 5～10 weight portions, titanium dioxide 20～30 weight portions,
Alundum (Al 10～20 weight portions, silica 1 0～20 weight portion,
Repellant 8～20 weight portions, diffusion liquid 40～70 weight portions.
Be preferably, health-care multi-element fabric of the present invention has polynary finishing agent in set between the fabric fibre or on the fiber, and this finishing agent has following composition:
Magnesia 7～10 weight portions, titanium dioxide 20～30 weight portions,
Alundum (Al 10～20 weight portions, silica 1 0～20 weight portion,
Repellant 14～20 weight portions, diffusion liquid 50～70 weight portions.
In the present invention, the dressing liquid that can adopt above-mentioned polynary finishing agent to be mixed with is handled fabric, and this dressing liquid has following composition:
Polynary finishing agent 10～25 weight portions, adhesive 5～20 weight portions,
Crosslinking agent 2～4 weight portions, softener 2～4 weight portions,
Catalyst 1～3 weight portion, all the other amount to 100 weight portions for water.
Further, this dressing liquid has following composition:
Polynary finishing agent 15～25 weight portions, adhesive 10～20 weight portions,
Crosslinking agent 2～4 weight portions, softener 2～4 weight portions,
Catalyst 1～3 weight portion, all the other amount to 100 weight portions for water.
Be more preferably, this dressing liquid has following composition:
Polynary finishing agent 20～25 weight portions, adhesive 15～20 weight portions,
Crosslinking agent 2～4 weight portions, softener 2～4 weight portions,
Catalyst 1～3 weight portion, all the other amount to 100 weight portions for water.
Can adopt the following method of padding in the present invention, comprise fabric through singe, boiling-off, mercerising, bleaching, stamp (or dyeing), padding finishing liquid then, one soaks one rolls or two soaks two and roll, pick-up rate 65～75%, give baking 1.0～2.0 minutes at 80～90 ℃ then, baked 0.5～1.5 minute at 130～135 ℃ again.
In the present invention, set has polynary finishing agent between the yarn of fabric or on the yarn, this finishing agent can reflect the far infrared wave of 4～14 μ M in a large number, and rely on its surperficial polyhedron that the light transmittance of fabric is descended, and stopped harmful ultraviolet ray, this obstruction and reflection are different along with the variation of external environment, when weather is hot, to stop ultraviolet ray, when outside air is colder, then lay particular emphasis on the reflection far infrared.Far infrared is by the hydrone in Transdermal absorption, the activation blood, and microcirculation improvement forms little electric current at skin surface simultaneously, produces thermogenetic effect owing to there is resistance in skin surface, the various diseases of stopping harmful ultraviolet (UV) B and UVA and bringing out thus.Polynary finishing agent can also suppress colibacillus, staphylococcus and beriberi fungi growth by mosquito repellent, can decompose the anti-bacterial anti-foul function of foul smell such as different lucky oxalic acid.
In the present invention, the composition of polynary finishing agent micro mist mixture is very important, magnesia, alundum (Al, silica is based on the reflection far infrared, titanium dioxide then lays particular emphasis on stops harmful ultraviolet ray, the grain fineness of micro mist and whiteness should be suitable for textile printing and dyeing processing, especially the fineness maximum of micro mist primary granule can not surpass 1 μ M, in order to prevent gathering of micro powder granule, it is very important selecting suitable diffusant and forming diffusion liquid, diffusant can be an anionic according to the state of solution, it also can be nonionic, diffusant can be naphthalene sulfonic acid-formaldehyde condensation product CNF, MF, N, AT-H841, S, IA etc., also can be fatty alcohol-polyoxyethylene ether WA, IA, diffusant has WA preferably, N and S.Select that a kind of diffusant, should be compatible with micro mist.Diffusant being dissolved in ion or the distilled water, making polynary finishing agent, is favourable to the preparation dressing liquid, micro mist can be solid-state, also can be moisture liquid state, but with solid-state for well, also micro mist can be adopted suitable technology carry out the coating surface treatment, make it have good suspension.
It is necessary selecting suitable micro mist mixture addition among the present invention, excessive micro mist mixture, and the processing of the post processing that is unfavorable for printing and dyeing, and fastness, also poor, the too small micro mist mixture content of feel can reduce the intensity of far infrared, antiultraviolet.
The repellant that possesses function of driving mosquitoes among the present invention has toluamide, methothrin, d-allethrin, Permethrin, tetramethrin, repefral etc. between carbamate, N, N diethyl, and repellant has toluamide, Permethrin, repefral between N, N diethyl preferably.Repellant with in addition emulsification of emulsifying agent, is put into and spread good micro mist diffusion liquid and stir, promptly make polynary finishing agent.
It is very important choosing adhesive, and adhesive has high temperature modification and low form, and high temperature modification adhesive fastness is relatively good, fixed favourable to polynary finishing agent.It is identical and can buy from market that dyeing in adhesive, crosslinking agent, softener etc. and the textile printing and dyeing, printing technology use.
Dressing liquid of the present invention can be prepared as follows:
The water that the polynary finishing agent of having made is added capacity fully stir add again adhesive, crosslinking agent, softener, catalyst be placed on rotating speed be stir evenly in 700～1400 rev/mins the mixer stand-by.
The present invention is cemented in dressing liquid on the fabric to pad method, fabric through singe, boiling-off, mercerising, bleaching, dyeing or stamp, padding finishing liquid then, one soaks one rolls or two soaks two and roll, pick-up rate is 65～75%, give baking 1.5 minutes at 80～90 ℃, baked 0.5～1.5 minute at 130～135 ℃ then.
Fabric among the present invention can be a natural fabric, as cotton, hair, fiber crops, silk, also can be the mixture of natural fabric and chemical fibre, based on cotton and polyester cotton fabric, can be woven fabric, knitted fabric or bondedfibre fabric preferably.
The present invention is through the fabric of arrangement, possesses the original softness of fabric, characteristics such as ventilative, these fabrics can be made by furnishings such as bedding such as, cotton-padded mattress, pillow, pad, sheet and shirt, skirt, underwear, panties, vest, shoe-pad, knee-pad, waist supports.When people's bedding, when dressing these products, can make the body temperature of human epidermal improve 2～3 ℃, can improve microcirculation, the activating cell of blood simultaneously, strengthen metabolism, improve immunity, have certain heat-preserving health-care health effect.Summer can the blocking harmful ultraviolet irradiation, reduces the generation of skin aging, redness, lupus erythematosus and cataract disease and can avoid biting of mosquito, also has the function of antibacterial, moldproof, anti-odour.
In the present invention, all raw materials, auxiliary agent, additive etc. comprise that adhesive, crosslinking agent, softener, diffusant etc. can be buied by auxiliary reagent factory, Shanghai, auxiliary reagent factory, Tianjin, and polynary finishing agent raw material can be buied by market.
Below further specify the present invention by specific embodiment, but embodiment only be used for the explanation, can not limit the scope of the invention.
In the present invention, if not refer in particular to, all parts, amount are the unit of weight based on gross weight.
Example 1
Fabric polyester-cotton blend 45
S* 45
S110 * 76 (bleachings)
Polynary finishing agent prescription:
Magnesia 5KG, titanium dioxide 15KG, alundum (Al 10KG, silica 1 0KG, chlorine chlorine ester 6KG, emulsifying agent TX-10 4KG, the diffusion liquid 50KG of NNO 0.5%.
The dressing liquid prescription:
Polynary finishing agent 20KG, adhesive 14KG, crosslinking agent 2.5KG, catalyst 2KG, softener 2KG, all the other amount to 100KG for deionized water.
Pad technology:
Fabric → singe → boiling-off → mercerising → bleach → pad (one soaks one rolls pick-up rate 70～75%) → give baking (80～90 ℃) 1.5～2 minutes → baked (130～135 ℃) 1～1.5 minute.
Employing standard black matrix normal direction total radiation brightness comparative approach, recording far infrared 2～18M wave band normal direction full width, to penetrate emissivity be 93%, wash 20 times after the total radiation emissivity be 92%.
To harmful ultraviolet ray test geometrical condition O/D, wavelength 290～380nM wave band, it soaks transmittance is 0.025, wherein 290～320 μ M-bands soak transmittance 0.015, are 0.06～0.07 after wash 20 times, employing counter point mosquito repelling rate 98%.
Example 2:
Fabric cotton textiles 40
S* 40
S133 * 72 (light color)
Polynary finishing agent prescription:
Magnesia 5KG, titanium dioxide 20KG, alundum (Al 1 5KG, silica 1 0KG, toluamide 6KG between N, N-diethyl, emulsifying agent T-60 4KG, the diffusion liquid 40KG of WA 0.3%.
The dressing liquid prescription:
Polynary finishing agent 15KG, adhesive 8KG, crosslinking agent 1.5KG, catalyst 1KG, softener 2KG, all the other amount to 100KG for water.
Pad technology with embodiment 1.
Employing standard black matrix normal direction total radiation brightness comparative approach records far infrared band 2～18 μ M, normal direction total radiation emissivity 94%, wash 20 times after total radiation emissivity 93%.
To harmful ultraviolet ray test geometrical condition O/D, 290～380 μ M-bands its to soak transmittance be 0.02, wherein 290～320 μ M-bands soak transmittance 0.013, are 0.06～0.07 after wash 20 times, employing counter point, mosquito repelling rate 99%.
Claims (4)
1, a kind of health-care multi-element fabric is characterized in that in set between the fabric fibre or on the fiber polynary finishing agent being arranged, and the micro mist mixture particle diameter in the described finishing agent is less than 1 micron, and this finishing agent has following composition:
Magnesia 5～10 weight portions, titanium dioxide 10～30 weight portions,
Alundum (Al 5～20 weight portions, silica 5～20 weight portions,
Repellant 8～20 weight portions, diffusion liquid 40～70 weight portions,
Wherein said repellant is one of toluamide, Permethrin, repefral between N, N diethyl.
2, health-care multi-element fabric as claimed in claim 1 is characterized in that the dressing liquid that is mixed with polynary finishing agent handles fabric, and this dressing liquid has following composition:
Polynary finishing agent 10～25 weight portions, adhesive 5～20 weight portions,
Crosslinking agent 2～4 weight portions, softener 2～4 weight portions,
Catalyst 1～3 weight portion, all the other amount to 100 weight portions for water.
3, health-care multi-element fabric dressing liquid as claimed in claim 2 is characterized in that described processing method is a padding method.
4, health-care multi-element fabric dressing liquid as claimed in claim 3 pads method, it is characterized in that adopting the following method of padding:
Fabric through singe, boiling-off, mercerising, bleaching, stamp or dyeing, padding finishing liquid then, one soaks one rolls or two soaks two and roll, pick-up rate 65～75% is given baking 1.0～2.0 minutes at 80～90 ℃ then, bakes 0.5～1.5 minute at 130～135 ℃ again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB99109882XA CN1155750C (en) | 1999-07-20 | 1999-07-20 | Health-care multi-element fabric and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB99109882XA CN1155750C (en) | 1999-07-20 | 1999-07-20 | Health-care multi-element fabric and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1281071A CN1281071A (en) | 2001-01-24 |
| CN1155750C true CN1155750C (en) | 2004-06-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB99109882XA Expired - Fee Related CN1155750C (en) | 1999-07-20 | 1999-07-20 | Health-care multi-element fabric and its preparing process |
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| Country | Link |
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| CN (1) | CN1155750C (en) |
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- 1999-07-20 CN CNB99109882XA patent/CN1155750C/en not_active Expired - Fee Related
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|---|---|
| CN1281071A (en) | 2001-01-24 |
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