CN1587493A - Tuomalin function fabric and its preparing method - Google Patents

Tuomalin function fabric and its preparing method Download PDF

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Publication number
CN1587493A
CN1587493A CN 200410070764 CN200410070764A CN1587493A CN 1587493 A CN1587493 A CN 1587493A CN 200410070764 CN200410070764 CN 200410070764 CN 200410070764 A CN200410070764 A CN 200410070764A CN 1587493 A CN1587493 A CN 1587493A
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fabric
tourmaline
weight portion
tuomalin
slurry
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CN1272500C (en
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许翼霖
刘光恩
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荆玉堂
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Abstract

The present invention discloses one kind of functional Tuomalin fabric and its preparation process. The functional Tuomalin fabric has Tuomalin grains of 0.1-0.5 micron size in at least one side of the fabric and/or between fibers and yarns, and the Tuomalin grains accounts for 1-8 wt% of the fabric. The functional Tuomalin fabric of the present invention can improve and regulate body's microcirculation, activate cell, promote metabolism, raise immunity, purify blood, purify air and eliminate bad smell, and has many other health functions.

Description

Tuomalin function fabric and preparation method thereof
Invention field
The invention relates to a kind of function fabric and preparation method thereof, more particularly about a kind of Tuomalin function fabric and preparation method thereof
Background technology
Along with the progress of society, people's health care consciousness progressively strengthens, and aspect textile function fiber and function fabric exploitation, has the promote health fiber and the fabric of health care such as far infrared, tourmaline fiber, insect protected mite, far-infrared fabric to produce in succession.
The Chinese patent ZL 94102823.2 " function textiles and manufacture method thereof " and the patent No. 02111545.1 " a kind of Ag-carried multifunctional tourmalinite fibre and manufacture method thereof " are set forth tourmaline viscose preparation method and functional tourmaline respectively.Aspect function fabric, patent of invention ZL 96110168.7 " far infrared thermal insulation, health anti-stink fabric and preparation method thereof " and ZL98117890.1 " dustproof mite allergic asthma textiles and preparation method thereof " are to the processing and fabricating method of far infrared, dustproof mite fabric single performance, discuss clear, effect is also better, but certain limitation is arranged.
Summary of the invention
One of purpose of the present invention provide a kind of have emitting far-infrared, discharge anion, produce the Tuomalin function fabric of multiple functions such as bioelectricity and deodorizing be antibacterial.
Two of purpose of the present invention provides a kind of preparation method of Tuomalin function fabric.
These and other objects of the present invention will further embody by detailed description below and illustrate.
Tuomalin function fabric of the present invention is comprising the Tourmaline particle that fineness is the 0.1-0.5 micron on the one side at least of fabric and/or between the fiber of fabric, yarn, and than being 1-8%, described Tourmaline particle comprises described Tourmaline particle to fabric weight:
SiO 240-50 weight portion Al 2O 3The 30-40 weight portion
B 2O 310-15 weight portion LiO 3-5 weight portion
MgO 0.8-1.8 weight portion Fe 2O 30.4-1 weight portion
TiO 20.5-1 weight portion CaO 0.5-1 weight portion
K 2O 0.2-0.5 weight portion Na 2O 0.3-0.6 weight portion.
Further, in Tuomalin function fabric of the present invention, the fineness of described Tourmaline particle is the 0.3-0.5 micron, described fabric is the independent or BLENDED FABRIC of natural fabric or synthetic fiber, can be woven fabric, knitted fabric or bondedfibre fabric, fabric can be a fabric behind BLEACHED FABRIC, DYED FABRICS or the stamp.
The preparation method of Tuomalin function fabric of the present invention comprises the steps:
A, with the Tourmaline bulky grain through broken, pulverize, add the crystal and grind into the slurry that granularity is the 0.1-0.5 micron, the ratio of Tourmaline particle and water is 1 in slurry: 4-8;
B, with the above-mentioned slurry that contains the Tourmaline particle in 1: the ratio of 2-10 is mixed with water;
C, the ratio of mixing the back product in 100 parts (B) add 2-10 part adhesive, 0.5-2 part crosslinking agent, and 1-3 part softener fully mixes into finishing agent;
D, fabric one is soaked one and rolls in finishing agent, pick-up rate is 70-80%, 80-100 ℃ of oven dry 1-4 minute, bakes 1-4 minute at 110-140 ℃ then.
Be preferably, the preparation method of Tuomalin function fabric of the present invention comprises the steps:
A, with the Tourmaline bulky grain through broken, pulverize, add the crystal and grind into the slurry that granularity is the 0.3-0.5 micron, the ratio of Tourmaline particle and water is 1 in slurry: 4-6;
B, with the above-mentioned slurry that contains the Tourmaline particle in 1: the ratio of 2-8 is mixed with water;
C, the ratio of mixing the back product in 100 parts (B) add 2-5 part adhesive, 0.5-2 part crosslinking agent, and 1-3 part softener fully mixes into finishing agent;
D, fabric one is soaked one and rolls in finishing agent, pick-up rate is 70-80%, 80-100 ℃ of oven dry 1-3 minute, bakes 1-3 minute at 110-140 ℃ then.
In the present invention, in dressing liquid, can also add if desired and drive mite agent, antistatic additive or antiseptic.
That Tuomalin function fabric of the present invention has is emitting far-infrared, discharge anion, produce multiple functions such as bioelectricity and deodorizing be antibacterial.
Further, Tuomalin function fabric of the present invention, can improve and regulate microcirculation, the activating cell of human body, enhance metabolism, improve immunity, can purify the blood, purify air, eliminate peculiar smell, hypnosis, antibechic, adjustment blood pressure, can suppress bacterium and eliminate various foul smell, be the Multifunction fabric of health, health, health care.
Tourmaline (Tourmaline) has another name called tourmaline, be a kind of of natural gemstone ore deposit, it is the complicated silicate mineral that contains boron, be rich in volatilization component boron and water in its composition, and act on mutually with air, this ore can gather the electrical the two poles of the earth of charge generation at the crystal two ends, produce N with permanent magnet, the S permanent magnet poles is similar, each crystal grain all has positive and negative opposite electric charge, has the character that forever, spontaneously produces static, and is quite high by the electrostatic pressure of measuring the two poles of the earth, but because of resistance big, its current value is little, only is 0.06mA, and is suitable with the bioelectricity of human body.Therefore, claim that again it is charged stone.
Tourmaline is because its crystal structure and multiple compound composition, decapacitation is spontaneous for good and all to produce outside the static, when its crystal is subjected to the environment's heat influence and gives pressure, the charged phenomenon of easier generation, it is electrical forever that it is had, pyroelectricity and piezoelectricity, the textiles made from it, be subjected to body temperature, when friction and pressure, its molecule and atom inside have been subjected to judder, make the dipole moment generation acute variation of electric dipole, polar molecule is energized into higher energy level, and discharges electromagnetic wave in the mode of photon energy, act on human epidermal and each acupuncture point, simultaneously, electronics takes place and shifts under electric field action in the Tourmaline particle, to the electrolysis of water in air molecule, form hydration hydroxyl ion (negative hydroxidion) H 3O 2 -, act on human body and purify air.
Tourmaline is according to contained different atom chemistry compositions, presents black, powder, shades of colour such as green, blue, yellow, brown and colourless, can be divided into three kinds of iron Tourmalines, lithium Tourmaline, magnesium Tourmaline, wherein, and the iron content height of iron Tourmaline, the opaque black that is; The lithium content height of lithium Tourmaline, by transparent to translucent; Be powder, green, blue, yellow, white; The magnesium Tourmaline is opaque, is yellow, dark green, brown, black; The iron Tourmaline accumulates root of Dahurian angelica amount maximum, and is widely used, and daily said Tourmaline mainly refers to iron agate beautiful jade, and its color is darker, is unsuitable for the textile finishing processing and fabricating, and Tourmaline used in the present invention is the lithium Tourmaline, also claims colorful Tourmaline.
The key property of Tourmaline:
1, can launch far infrared to the human body beneficial
Far infrared is the invisible ray of sunshine, its wave-length coverage 4-1000 micron, and Tourmaline can give off the 4-14 micron far infrared that human body needs, when the far infrared of this wave band of absorption of human body can produce thermogenetic effect and resonance effect, make the water molecule activation in blood of human body and the body fluid, thereby quicken the blood circulation of fine vascular, activating cell, quicken metabolism, promote health, the far infrared transmissivity of Tourmaline powder, can be up to more than 94%.
2, can discharge human body and the useful anion of environment
Tourmaline is the stone that can discharge, and the hydrone in its negatron (e) and the surrounding air can form negative hydroxidion H 3O 2 -, this anion is to the influence of human body and surrounding environment: (1) is not had the oxygen radical of human body to poison, can reduce the harm of too much oxygen radical to human body.(2) can make the body fluid of human body be alkalescent.Anion through capillary absorbs can make the pH value of body fluid remain on pH value about 7.4, thereby guarantee the eubolism of human body cell.(3) air quality of space environment is improved, reduce the harm to human body of contaminated air and various peculiar smell, Tourmaline can produce 4000 anion/cm after tested 3Its textiles can discharge 1000 above anion/cm 3, and general residential area, city only is 40-50/cm 3
The anion of Tourmaline can make cell activation, purifies the blood, purify air, and blood pressure is adjusted in energy antibechic, hypnosis.
3, can produce bioelectricity.
Tourmaline can natural, for good and all produce the little electric current of biological level, its size is 0.06mA, bioelectricity 0.06mA lucky and human body is complementary, cause bioelectrical effect, promoted metabolism, regulated maincenter and automatic nervous system, exchanged the inside and outside ion-exchange body fluid accommodation zone of ganglion cell and come good signal.
4, the energy deodorizing is antibacterial
The anion that Tourmaline discharges, peculiar smell such as sour smelly, the body odor in gas such as the benzene that volatilizes after can the decontamination chamber interior decoration, formaldehyde, ketone and the daily life, cigarette.Tourmaline can be eliminated foul smell compositions such as lucky oxalic acid, hydrogen sulfide, ammonia after tested, can not only destroy foul odors with its textiles of making, and can suppress Escherichia coli, staphylococcus aureus, Candida albicans, and its bacteriostasis rate can reach 73-76%.
Tourmaline is the polar substances that has static, and particle after crushed can directly observe intergranular mutual repulsion of Tourmaline and attraction with electron probe.Therefore, in making Tourmaline powder process, can put into ionized water, also can add suitable dispersant (conventional dispersant), make the Tourmaline slurry of pulpous state,, help the making of dressing liquid to reduce intergranular attraction of Tourmaline and repulsion.
It is very important selecting the proper content of Tourmaline in fabric, and in the present invention, the weight ratio of preferred Tourmaline and fabric is 1-8: 99-92.Tourmaline is pulled in content in the fabric less than 1, and the far infrared effect of fabric is poor, and the anion burst size is low, and the deodorizing fungistatic effect is poor, can not bring into play the health care comprehensive function effect of Tourmaline in fabric.The content of Tourmaline in fabric is higher than 8, and the feel of fabric is poor, and fixed fastness is low.Tourmaline through broken, pulverize, correct grinding makes granularity less than 0.5 micron slurry, the Tourmaline slurry is placed on fully is mixed and made into the Tourmaline aqueous solution in the water, the weight ratio of control Tourmaline and fabric adds adhesive, crosslinking agent, softener, additive etc. then and makes fabric finishing liquor.Described additive can be to drive mite agent, antistatic additive and antiseptic etc.Adhesive wherein is divided into high temperature modification and low form, the high temperature modification time of baking is 1-1.5 minute, the low form time of baking be 2-4 minute to through singe, boiling-off, mercerising, drift, the fabric of dyeing or stamp, soaking one with the method one of padding rolls or two soaks two and roll, pick-up rate 70-80%, through 80-100 ℃ of oven dry (with water content degree of being not), 110-140 ℃ bakes (1-4 minute), can form Tuomalin function fabric.
With the fabric after the inventive method arrangement, still possess characteristics such as original softness, ventilative, moisture absorption, these fabrics can be made furnishings such as bedding such as pad, pillow, quilt, sheet and underwear, panties, shirt and knee-pad, waist support, wrister, elbow support.When people's bedding and these products of wearing, can make the body temperature of human epidermal increase 1-2 ℃, can improve microcirculation, the activating cell of blood, enhance metabolism, increase immunity, can purify the blood, purify air simultaneously, eliminate peculiar smell, deodorizing is antibacterial, accomplishes cool in summer and warm in winterly, is health, health, health care novel multifunctional fabric.
Among the present invention except that the Tourmaline slurry, driving mite agent, antistatic additive and antiseptic can be buied by market, adhesive, crosslinking agent, softener and dispersant etc. are identical with the auxiliary agent of textile printing and dyeing, concrete these breed selection are known for those skilled in the art, typically can be with reference to the similar patent of patent application before the inventor of present patent application, these patents are incorporated herein by reference.
Dispersant can be fatty glyceride, phenolic resins sulfonate AT-H841 in this application, dioctyl sodium sulfosuccinate or 16 carbocyclic aliphatic amine quaternary ammonium salts, 1631 surfactants etc.
Below in conjunction with embodiment in detail the present invention is described in detail, can not limits this but embodiment only is used for explanation
Scope of invention.
In the present invention, if not refer in particular to, all part, percentages are unit of weight, and all equipment and raw material etc. all can be buied from market or the industry is commonly used.
The specific embodiment
Embodiment 1:
Fabric: textile 40 S* 40 S133 * 72 bleached cotton fabrics
Tourmaline through broken, pulverize, the ratio correct grinding that adds 6 kilograms of ionized waters in 1 kilogram of Tourmaline particle is made granularity less than 0.5 micron slurry, the weight ratio of Tourmaline and water is 1: 6.
Get 28 kilograms in Tourmaline slurry, be placed on to mix in 64 kg of water and stir 5 kilograms in adhesive of back adding, 1 kilogram of crosslinking agent, 2 kilograms of softeners, fully stir and make 100 kilograms of fabric finishing liquors.
Technology: fabric through singe, boiling-off, mercerising, bleaching, one soaks one rolls, pick-up rate 75% 80-100 ℃ of oven dry 3 minutes, baked 3 minutes at 110-120 ℃ then, the weight ratio of control Tourmaline and fabric is 3: 97.
Embodiment 2:
Fabric: polyester-cotton blend T/C 65,/35 45 S* 45 SAfter 110 * 76 dyeing
Get 10.5 kilograms of (weight ratios of Tourmaline and water 1: 6 of Tourmaline slurry, the dispersant that contains 0.5-1% in the slurry) insert in 85 kg of water and stir and add 3 kilograms in adhesive, 0.5 kilogram of crosslinking agent, 1 kilogram of softener then, modulator approach and embodiment 1 be identical to make 100 kilograms of dressing liquids.
The dyed back of fabric one was soaked and one is rolled, pick-up rate 75%, 80-100 ℃ of oven dry 2 minutes.Baked 1 minute at 130-135% then, the weight ratio of control Tourmaline and fabric is 1.125: 98.875.
Embodiment 3:
Fabric: textile 21 S* 21 SBehind 60 * 60 stamps
42 kilograms in Tourmaline slurry (weight ratio of Tourmaline and water 1: 6) is placed on and stirs 10 kilograms in adhesive of back adding, 2 kilograms of crosslinking agents, 2 kilograms of softeners in 44 kg of water, makes 100 kilograms of dressing liquids, and modulator approach and technology are identical with embodiment 1.
The weight ratio of control Tourmaline and fabric is 4.5: 95.5.
In order to the fabric that the top method is made, the far infrared radiation rate 90% after tested, and the anion burst size is 1150/CM 3

Claims (7)

1, a kind of Tuomalin function fabric, it is characterized in that comprising the Tourmaline particle that fineness is the 0.1-0.5 micron on the one side at least of fabric and/or between the fiber of fabric, yarn, than being 1-8%, described Tourmaline particle comprises described Tourmaline particle to fabric weight:
SiO 240-50 weight portion Al 2O 3The 30-40 weight portion
B 2O 310-15 weight portion LiO 3-5 weight portion
MgO 0.8-1.8 weight portion Fe 2O 30.4-1 weight portion
TiO 20.5-1 weight portion CaO 0.5-1 weight portion
K 2O 0.2-0.5 weight portion Na 2O 0.3-0.6 weight portion.
2, Tuomalin function fabric according to claim 1, the fineness that it is characterized in that described Tourmaline particle is the 0.3-0.5 micron.
3, Tuomalin function fabric according to claim 1 is characterized in that described fabric is the independent or BLENDED FABRIC of natural fabric or synthetic fiber, can be woven fabric, knitted fabric or bondedfibre fabric.
4, Tuomalin function fabric according to claim 3 is characterized in that described fabric can be a fabric behind BLEACHED FABRIC, DYED FABRICS or the stamp.
5,, it is characterized in that comprising the steps: according to the preparation method of one of claim 1-4 described Tuomalin function fabric
A, with the Tourmaline bulky grain through broken, pulverize, add the crystal and grind into the slurry that granularity is the 0.1-0.5 micron, the ratio of Tourmaline particle and water is 1 in slurry: 4-8;
B, with the above-mentioned slurry that contains the Tourmaline particle in 1: the ratio of 2-10 is mixed with water;
C, the ratio of mixing the back product in 100 parts (B) add 2-10 part adhesive, 0.5-2 part crosslinking agent, and 1-3 part softener fully mixes into finishing agent;
D, fabric one is soaked one and rolls in finishing agent, pick-up rate is 70-80%, 80-100 ℃ of oven dry 1-4 minute, bakes 1-4 minute at 110-140 ℃ then.
6, the preparation method of Tuomalin function fabric according to claim 5 is characterized in that comprising the steps:
A, with the Tourmaline bulky grain through broken, pulverize, add the crystal and grind into the slurry that granularity is the 0.3-0.5 micron, the ratio of Tourmaline particle and water is 1 in slurry: 4-6;
B, with the above-mentioned slurry that contains the Tourmaline particle in 1: the ratio of 2-8 is mixed with water;
C, the ratio of mixing the back product in 100 parts (B) add 2-5 part adhesive, 0.5-2 part crosslinking agent, and 1-3 part softener fully mixes into finishing agent;
D, fabric one is soaked one and rolls in finishing agent, pick-up rate is 70-80%, 80-100 ℃ of oven dry 1-3 minute, bakes 1-3 minute at 110-140 ℃ then.
7,, it is characterized in that in dressing liquid, can also adding and drive mite agent, antistatic additive or antiseptic according to the preparation method of claim 5 or 6 described Tuomalin function fabrics.
CN 200410070764 2004-07-26 2004-07-26 Tuomalin function fabric and its preparing method Expired - Fee Related CN1272500C (en)

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102085383A (en) * 2010-12-28 2011-06-08 胡冰 Method for improving indoor air quality by using tourmaline
CN101509188B (en) * 2009-03-06 2012-08-08 东华大学 Milled finishing agent with excitated negative oxygen ion, preparation method and uses thereof
CN102808268A (en) * 2012-07-06 2012-12-05 吴阳璐 Method and purpose of textile fabric including crystal combination energy
CN102824064A (en) * 2012-09-19 2012-12-19 宁波市鄞州黎明工艺品有限公司 Health-care mat
CN103361966A (en) * 2013-07-25 2013-10-23 宁波康赛妮毛绒制品有限公司 Active negative oxygen ion cashmere yarn after-treatment method
CN103360657A (en) * 2012-03-31 2013-10-23 中国科学院合肥物质科学研究院 Composite material with negative ion releasing function and preparation method thereof
CN105887470A (en) * 2016-04-25 2016-08-24 龚思彬 Formula and application process of multifunctional liquid for textile
CN107916569A (en) * 2017-11-29 2018-04-17 无锡昊瑜节能环保设备有限公司 A kind of preparation method of environment-friendly type UV resistance moisture regain looped fabric
CN108301237A (en) * 2018-01-15 2018-07-20 宏杰内衣股份有限公司 A kind of far infrared and anion multifunctional fabric
CN108797102A (en) * 2018-03-08 2018-11-13 徐建敏 3D ventilation elastic three-dimensional fabrics quantum wave energy wear and production method
CN108969883A (en) * 2017-05-31 2018-12-11 李宇光 The production method and application of graphene bioelectricity sports chip
CN109505113A (en) * 2018-10-29 2019-03-22 大连理工常熟研究院有限公司 A kind of negative ion antibiotic fabric post-processing rubber cement
CN109853243A (en) * 2018-12-17 2019-06-07 江南大学 A kind of method for sorting assigning fabric negative ion health function
CN109868645A (en) * 2019-02-10 2019-06-11 宜兴新乐祺纺织印染有限公司 A kind of cotton class fabric surface covering of the releasable negative oxygen ion antimicrobial of Low emissivity and preparation method thereof, application method
CN110172820A (en) * 2018-06-27 2019-08-27 安徽农业大学 The biomass fiber material of negative ionization arrangement, preparation method and applications
CN110878438A (en) * 2018-09-06 2020-03-13 上海安娜奥环境科技有限公司 Environment-friendly chemical fiber velvet capable of releasing negative ions and preparation method thereof
CN112411210A (en) * 2020-11-11 2021-02-26 韩从祥 Tourmaline self-heating dot matrix warm clothes and trousers and production process thereof

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101509188B (en) * 2009-03-06 2012-08-08 东华大学 Milled finishing agent with excitated negative oxygen ion, preparation method and uses thereof
CN102085383A (en) * 2010-12-28 2011-06-08 胡冰 Method for improving indoor air quality by using tourmaline
CN103360657A (en) * 2012-03-31 2013-10-23 中国科学院合肥物质科学研究院 Composite material with negative ion releasing function and preparation method thereof
CN102808268A (en) * 2012-07-06 2012-12-05 吴阳璐 Method and purpose of textile fabric including crystal combination energy
CN102808268B (en) * 2012-07-06 2015-12-02 吴阳璐 The method of the woven fabric containing crystal combination energy and purposes
CN102824064A (en) * 2012-09-19 2012-12-19 宁波市鄞州黎明工艺品有限公司 Health-care mat
CN102824064B (en) * 2012-09-19 2014-12-17 宁波市鄞州黎明工艺品有限公司 Health-care mat
CN103361966A (en) * 2013-07-25 2013-10-23 宁波康赛妮毛绒制品有限公司 Active negative oxygen ion cashmere yarn after-treatment method
CN105887470A (en) * 2016-04-25 2016-08-24 龚思彬 Formula and application process of multifunctional liquid for textile
CN108969883A (en) * 2017-05-31 2018-12-11 李宇光 The production method and application of graphene bioelectricity sports chip
CN108969883B (en) * 2017-05-31 2021-12-28 李宇光 Manufacturing method and application of graphene bioelectricity health chip
CN107916569A (en) * 2017-11-29 2018-04-17 无锡昊瑜节能环保设备有限公司 A kind of preparation method of environment-friendly type UV resistance moisture regain looped fabric
CN108301237A (en) * 2018-01-15 2018-07-20 宏杰内衣股份有限公司 A kind of far infrared and anion multifunctional fabric
CN108797102A (en) * 2018-03-08 2018-11-13 徐建敏 3D ventilation elastic three-dimensional fabrics quantum wave energy wear and production method
CN110172820A (en) * 2018-06-27 2019-08-27 安徽农业大学 The biomass fiber material of negative ionization arrangement, preparation method and applications
CN110878438A (en) * 2018-09-06 2020-03-13 上海安娜奥环境科技有限公司 Environment-friendly chemical fiber velvet capable of releasing negative ions and preparation method thereof
CN109505113A (en) * 2018-10-29 2019-03-22 大连理工常熟研究院有限公司 A kind of negative ion antibiotic fabric post-processing rubber cement
CN109853243A (en) * 2018-12-17 2019-06-07 江南大学 A kind of method for sorting assigning fabric negative ion health function
CN109853243B (en) * 2018-12-17 2021-10-26 江南大学 Finishing method for endowing fabric with negative ion health care function
CN109868645A (en) * 2019-02-10 2019-06-11 宜兴新乐祺纺织印染有限公司 A kind of cotton class fabric surface covering of the releasable negative oxygen ion antimicrobial of Low emissivity and preparation method thereof, application method
CN112411210A (en) * 2020-11-11 2021-02-26 韩从祥 Tourmaline self-heating dot matrix warm clothes and trousers and production process thereof

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