CN115466956A - Method for preparing random fancy glaze for enamel decoration - Google Patents
Method for preparing random fancy glaze for enamel decoration Download PDFInfo
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- CN115466956A CN115466956A CN202211145280.6A CN202211145280A CN115466956A CN 115466956 A CN115466956 A CN 115466956A CN 202211145280 A CN202211145280 A CN 202211145280A CN 115466956 A CN115466956 A CN 115466956A
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- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000005034 decoration Methods 0.000 title claims abstract description 12
- 238000010304 firing Methods 0.000 claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 238000004040 coloring Methods 0.000 claims abstract description 3
- 238000001035 drying Methods 0.000 claims description 22
- 239000007921 spray Substances 0.000 claims description 14
- 239000000049 pigment Substances 0.000 claims description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 238000005507 spraying Methods 0.000 claims description 12
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 9
- 239000011268 mixed slurry Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003086 colorant Substances 0.000 claims description 6
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 229910052573 porcelain Inorganic materials 0.000 claims description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 claims description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- MTKRXXSLFWZJTB-UHFFFAOYSA-N oxo(oxoboranyl)borane Chemical compound O=BB=O MTKRXXSLFWZJTB-UHFFFAOYSA-N 0.000 claims description 3
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 3
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 230000002747 voluntary effect Effects 0.000 claims 3
- 230000000694 effects Effects 0.000 abstract description 13
- 239000002245 particle Substances 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000919 ceramic Substances 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 239000002585 base Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000012736 patent blue V Nutrition 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D5/00—Coating with enamels or vitreous layers
- C23D5/02—Coating with enamels or vitreous layers by wet methods
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to the technical field of enamel plates, and discloses a method for preparing random fancy glaze for enamel decoration. The method comprises the steps of enamel slab pretreatment, coloring of the pretreated enamel slab, and preparation of the random fancy glaze enamel plate. After the glaze is applied to the surface of the base material, particles naturally bloom, lines randomly change, the particles are well fused with the base glaze, random textures are formed after firing, the texture of the patterns is clear, the layers are distinct, and a good decorative effect is achieved; after high-temperature sintering, the high-temperature sintered ceramic has excellent physical and chemical properties, and improves the surface hardness, the wear resistance, the thermal stability, the acid-base corrosion resistance, the pollution resistance and the like. The preparation method provided by the invention has the advantages of simple process, low cost, low requirements on formula composition, firing system and the like, high production stability, smooth natural patterns and wide applicability, and can be applied to building, sanitary, daily-use and technical enamels.
Description
Technical Field
The invention relates to the technical field of enamel plates, in particular to a method for manufacturing random fancy glaze for enamel decoration.
Background
Two or more kinds of glaze are applied on the iron blank, and various glaze effects which are rich in variation and naturally flow through the difference of glazing methods of different glaze layers, the thickness of pigment, firing temperature and the like are formed, and the glaze effects are called fancy glaze. It is mainly used for decorating artistic porcelain, and its colour is magnificent and pattern is natural.
If the color and pattern shapes of each enamel plate are different, the process needs to be finished by manufacturing a template of a pattern on each enamel plate and then adopting an ink-jet or silk-screen printing mode, so that the cost of manpower and material resources is very high, the consumed time is long, and the yield is low.
Aiming at the defects of the prior art, the invention provides the preparation method of the enamel fancy glaze with simple process, low cost, low requirements on formula composition, firing system and the like, high production stability and smooth natural patterns
Disclosure of Invention
In view of the above, the present invention provides a method for preparing a casual fancy glaze enamel for decorative use. The preparation method provided by the invention has the advantages of simple process, low cost, low requirements on formula composition, firing system and the like, high production stability and smooth natural patterns
In order to achieve the purpose, the invention adopts the following technical scheme:
a method for preparing a random fancy glaze for enamel decoration comprises the following steps:
1. enamel slab pretreatment
Forming a glaze layer with the thickness of 120-150 mu m on the enamel slab by methods of glaze spraying, glaze pouring and the like, then drying by a dryer, and firing for 2-5 minutes after drying;
2. coloring the pretreated enamel slab
After natural cooling, spraying 200-400 mu m colored glaze, drying by using a dryer, and firing for 2-5min to prepare a colored enamel plate;
3. preparation of random fancy glaze enamel plate
And (3) randomly spraying the glaze pigment mixed slurry by using a large-aperture spray gun or a small-aperture spray gun or operating the colored enamel plate by adopting a glaze pouring method to form a glaze layer with the thickness of 200-400 mu m, drying by using a dryer, and firing for 2-5min after drying to prepare the randomly fancy glaze enamel plate.
Further, in the step 1-3, the drying temperature is 70-100 ℃; the firing temperature is 790-840 ℃.
Further, when the colored glaze in the step 2 is a blue glaze, the composition comprises the following components in parts by mass: 2 parts of 3# antimony white, 510 parts of TMS, 0.12 part of Tianguang Tianlan, 0.08 part of Tianguang cobalt blue, 0.01 part of FA9201 part, 1.5 parts of clay, 0.04 part of potassium carbonate, 10 parts of water and 201000.6 parts of FM.
Further, in the step 3, the aperture of the large-aperture spray gun is 3.5-4.0mm; the aperture of the small-aperture spray gun is 1.2-2.0mm.
Further, in step 3, the preparation method of the glaze pigment mixed slurry comprises the following steps:
cleaning and drying a dispersion tank, adding a pigment, slowly adding a diluent under the condition of a rotating speed of 1000-2000r/min, fully dispersing and uniformly mixing, then adding 15-45% of glaze dry powder, 1-10% of inorganic colorant and 0.6-1.3% of additive for enamel, fully dispersing and uniformly mixing, and standing for 24 hours to prepare glaze pigment mixed slurry;
further, the mass fraction is the mass percentage of the raw materials in the glaze pigment mixed slurry.
Preferably, the additives for the enamel glaze are a defoaming agent and a dispersing agent, and the addition ratio is (4-8) to (2-5).
Preferably, the ratio of the pigment to the diluent is 1:4.
it is worth explaining that the added defoaming agent can reduce bubbles in the stirring and placing process of the glaze and improve the spraying performance of the glaze; the added dispersant can play a role in improving the fluidity of the glaze and stabilizing the viscosity of the glaze.
Further, the method for manufacturing the random fancy glaze for enamel decoration also comprises the step 4: in order to make the multi-color board look more stereoscopic, the transparency is good, the gloss is high, the porcelain surface is smoother, and then a layer of 6108 glaze slip is sprayed on the surface and fired for 3 to 5 minutes.
Preferably, in step 4, the components of the 6108 glaze slurry comprise, by mass: sodium oxide Na 2 O14.50%, potassium oxide K 2 0.50%, barium oxide BaO 4.35%, diboron dioxide B 2 O 2 35.50 percent of aluminum dioxide Al 2 O 3 1.25 percent, zinc oxide ZnO 1.45 percent and phosphorus pentoxide P 2 O 5 1.03% and silicon dioxide SiO 2 33.05%, caO 1.00% of calcium oxide, li oxide 2 O 5.37％。
Preferably, in the step 4, the drying temperature is 70-100 ℃; the firing temperature is 790-840 DEG C
Through the technical scheme, compared with the prior art, the invention has the following beneficial effects:
the preparation method of the enamel fancy glaze has wide applicability, and can be applied to architectural, sanitary, daily-use and craft enamels. The enamel fancy glaze has the advantages of showing the random texture effect of natural interweaving in multiple colors and planar shapes, and particularly:
1. the process is simple, the cost is low, the main equipment only needs a stepless speed change paddle type stirrer, a small ball mill and a spray gun with a certain caliber to finish the rapid preparation, the production stability is high, and the repeatability is good.
2. The glaze material type can be selected widely aiming at the glaze material related in the glaze material soft particles and the basic glaze of the continuous phase. The glaze has good adaptability to different glaze formulas, and the glaze can realize the fancy glaze effects of various colors, glossiness, texture and the like through differential combination and collocation. For example, different fancy glaze effects may be obtained by adjusting soft particle and base glaze parameters, such as proportions, colors, and the like.
3. The used glaze soft particles have adjustable size, natural and beautiful particle shape and better fluidity, and are suitable for spray gun operation. After the coating is applied to the surface of a base material, particles naturally bloom, lines change randomly, the particles are better fused with the base glaze, random textures are formed after firing, the texture of the patterns is clear, the layers are distinct, and the coating has better decorative effect.
4. The enamel glaze is applied to the surface of a base material and has excellent physical and chemical properties such as surface hardness, wear resistance, thermal stability, acid and alkali corrosion resistance, pollution resistance and the like after being sintered at high temperature (790-840 ℃)
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the provided drawings without creative efforts.
Figure 1 is a schematic drawing of a conventional colored enamel plate.
FIG. 2 is a drawing showing the effect of a normal enamel plate sprayed randomly with a small bore (1.2-2.0 mm) spray gun.
FIG. 3 is a drawing showing the effect of a normal enamel plate sprayed with a large-diameter (3.5-4.0 mm) spray gun.
FIG. 4 is the drawing showing the glaze pouring effect of a normal enamel plate.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Example 1
A method for preparing a casual fancy glaze enamel for decorative use, comprising the steps of:
1. spraying a first firing white primer on the enamel slab to form a glaze layer with the thickness of 150 mu m, drying by using a dryer at the drying temperature of 80 ℃, and firing for 3 minutes after drying;
2. then, spraying blue glaze powder on the blank to form a glaze layer with the thickness of 300 mu m, drying by using a dryer at the drying temperature of 100 ℃, and firing for 5 minutes at the temperature of 800 ℃;
the blue glaze powder comprises the following components: 20KG of 3# antimony white, TMS510 180KG, sky light sky blue 1.2KG, sky light cobalt blue 0.8KG, FA9201 0.1KG, clay 15KG, potassium carbonate 0.4KG, water 100KG, FM20100 KG.
3. Preparing glaze pigment mixed slurry,
adding 10g of light selenium red pigment into a cleaned and dried dispersion tank, slowly adding 40g of diluent under the condition of 1500r/min of rotation speed dispersion, fully and uniformly dispersing and mixing, then adding 30% of glaze dry powder by mass fraction, 5% of inorganic colorant by mass fraction, 0.6% of dispersing agent by mass fraction and 0.3% of defoaming agent by mass fraction, fully dispersing and uniformly mixing, and standing for 24 hours to obtain glaze mixed slurry;
randomly spraying by using a large-aperture (3.5-4.0 mm) glaze spray gun, drying by using a dryer at 100 ℃, and firing for 5min at 800 ℃ after drying;
4. spraying a layer of 6108 glaze slip to make the colorful board look more stereoscopic, good transparency, high gloss and smoother porcelain surface, and firing for 3min at 840 ℃;
the 6108 glaze slurry comprises the following components: sodium oxide Na 2 O14.50%, potassium oxide K 2 0.50 percent of barium oxide BaO, 4.35 percent of diboron dioxide B 2 O 2 35.50 percent of aluminum dioxide Al 2 O 3 1.25 percent, zinc oxide ZnO 1.45 percent and phosphorus pentoxide P 2 O 5 1.03% and silicon dioxide SiO 2 33.05%, calcium oxide CaO 1.00%, lithium oxide Li 2 O 5.37％。
Wherein, the implementation effect is shown in figure 3
Example 2
A method for the preparation of casual fancy glaze enamel for decorative purposes, differing from example 1 in that in step 3 casual spraying is carried out using a small-bore spray gun (1.2-2.0 mm).
The implementation effect is shown in fig. 2.
Example 3
A method for preparing a fancy glaze enamel for decorative use, differing from example 1 in that in step 3 a showering of the glaze is used for optional treatment.
The implementation effect is shown in fig. 4.
The embodiments in the present description are described in a progressive manner, each embodiment focuses on differences from other embodiments, and the same and similar parts among the embodiments are referred to each other.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
Claims (9)
1. A method for preparing random fancy glaze for enamel decoration is characterized by comprising the following steps:
1) Enamel slab pretreatment
Forming a glaze layer with the thickness of 120-150 mu m on the enamel slab by using methods of glaze spraying, glaze pouring and the like, drying by using a dryer, and firing for 2-5 minutes after drying;
2) Coloring the pretreated enamel slab
After natural cooling, spraying 200-400 mu m colored glaze, drying by using a dryer, and firing for 2-5min to prepare a colored enamel plate;
3) Preparation of random fancy glaze enamel plate
And (3) randomly spraying the glaze pigment mixed slurry by using a large-aperture spray gun or a small-aperture spray gun or operating the colored enamel plate by adopting a glaze pouring method to form a glaze layer with the thickness of 200-400 mu m, drying by using a dryer, and firing for 2-5min after drying to prepare the randomly fancy glaze enamel plate.
2. The method for preparing a voluntary fancy glaze for enamel decoration according to claim 1, wherein the drying temperature is 70-100 ℃ in the step 1-3; the firing temperature is 790-840 ℃.
3. The method for producing a free fancy glaze for enamel decorating according to claim 1, wherein in the step 3, the large-diameter spray gun has a bore diameter of 3.5 to 4.0mm; the aperture of the small-aperture spray gun is 1.2-2.0mm.
4. The method for preparing a casual fancy glaze for enamel decoration according to claim 1, wherein the glaze pigment mixing paste is prepared by the method comprising the steps of, in the step 3:
cleaning and drying a dispersion tank, adding a pigment, slowly adding a diluent at the rotation speed of 1000-2000r/min, fully dispersing and uniformly mixing, then adding 15-45% of glaze dry powder, 1-10% of inorganic colorant and 0.6-1.3% of additive for enamel glaze, fully dispersing and uniformly mixing, and standing for 24 hours to prepare the glaze pigment mixed slurry.
5. The method for preparing a free fancy glaze for enamel decorating according to claim 4, wherein the additives for enamel glaze are an antifoaming agent and a dispersing agent, and the addition ratio is (4-8): 2-5).
6. The method for preparing a free fancy glaze for enamel decorating according to claim 4, wherein the pigment and the diluent are added in a ratio of 1:4.
7. the method for producing a voluntary fancy glaze for enamel decoration according to claim 1, further comprising the step 4: in order to make the multi-color board look more stereoscopic, the transparency is good, the gloss is high, the porcelain surface is smoother, and then a layer of 6108 glaze slip is sprayed on the surface and fired for 3 to 5 minutes.
8. The method for preparing a casual fancy glaze for enamel decoration according to claim 7, wherein in the step 4, the 6108 glaze slip comprises the following components by mass percent: sodium oxide Na 2 O14.50%, potassium oxide K 2 O2.50%, barium oxide BaO 4.35%, diboron dioxide B 2 O 2 35.50 percent of aluminum dioxide Al 2 O 3 1.25 percent, zinc oxide ZnO 1.45 percent and phosphorus pentoxide P 2 O 5 1.03 percent of silicon dioxide SiO 2 33.05%, caO 1.00% of calcium oxide, li oxide 2 O 5.37％。
9. The method for producing a voluntary fancy glaze for enamel decoration according to claim 7, wherein said firing temperature is 790 to 840 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202211145280.6A CN115466956A (en) | 2022-09-20 | 2022-09-20 | Method for preparing random fancy glaze for enamel decoration |
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| CN202211145280.6A CN115466956A (en) | 2022-09-20 | 2022-09-20 | Method for preparing random fancy glaze for enamel decoration |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106116697A (en) * | 2016-07-06 | 2016-11-16 | 江苏新嘉理生态环境材料股份有限公司 | A kind of preparation method of pottery fancy glaze |
| CN210314489U (en) * | 2019-06-06 | 2020-04-14 | 浙江开尔新材料股份有限公司 | Crack-like underglaze color enamel plate |
| CN114315137A (en) * | 2021-12-20 | 2022-04-12 | 浙江开尔新材料股份有限公司 | Noctilucent glaze material for enamel, noctilucent enamel plate and manufacturing method thereof |
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2022
- 2022-09-20 CN CN202211145280.6A patent/CN115466956A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106116697A (en) * | 2016-07-06 | 2016-11-16 | 江苏新嘉理生态环境材料股份有限公司 | A kind of preparation method of pottery fancy glaze |
| CN210314489U (en) * | 2019-06-06 | 2020-04-14 | 浙江开尔新材料股份有限公司 | Crack-like underglaze color enamel plate |
| CN114315137A (en) * | 2021-12-20 | 2022-04-12 | 浙江开尔新材料股份有限公司 | Noctilucent glaze material for enamel, noctilucent enamel plate and manufacturing method thereof |
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