CN114315137A - Noctilucent glaze material for enamel, noctilucent enamel plate and manufacturing method thereof - Google Patents
Noctilucent glaze material for enamel, noctilucent enamel plate and manufacturing method thereof Download PDFInfo
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- CN114315137A CN114315137A CN202111563863.6A CN202111563863A CN114315137A CN 114315137 A CN114315137 A CN 114315137A CN 202111563863 A CN202111563863 A CN 202111563863A CN 114315137 A CN114315137 A CN 114315137A
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- glaze
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- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 86
- 239000000463 material Substances 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000000049 pigment Substances 0.000 claims abstract description 52
- 238000001035 drying Methods 0.000 claims abstract description 19
- 238000001816 cooling Methods 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 238000007650 screen-printing Methods 0.000 claims abstract description 7
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 8
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 8
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 6
- QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical compound [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 claims description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 6
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 6
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 claims description 6
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 4
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 4
- MTKRXXSLFWZJTB-UHFFFAOYSA-N oxo(oxoboranyl)borane Chemical compound O=BB=O MTKRXXSLFWZJTB-UHFFFAOYSA-N 0.000 claims description 4
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 4
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 4
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- XURCIPRUUASYLR-UHFFFAOYSA-N Omeprazole sulfide Chemical compound N=1C2=CC(OC)=CC=C2NC=1SCC1=NC=C(C)C(OC)=C1C XURCIPRUUASYLR-UHFFFAOYSA-N 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 claims description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 3
- 229910001386 lithium phosphate Inorganic materials 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 3
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 claims description 3
- 235000011151 potassium sulphates Nutrition 0.000 claims description 3
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 8
- 238000005507 spraying Methods 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 239000000843 powder Substances 0.000 description 7
- 238000004020 luminiscence type Methods 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 206010049155 Visual brightness Diseases 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Images
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- Luminescent Compositions (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a noctilucent enamel glaze which comprises a noctilucent pigment component and a basic glaze component; the mass parts of the two are as follows according to 100 parts by mass percent: the noctilucent pigment component accounts for 8 to 12 parts; the balance of basic glaze; a preparation method of a noctilucent enamel plate comprises the following steps: step one, preparing the enamel luminous glaze into glaze slip, spraying the glaze slip on a white enamel plate, drying, quickly burning and naturally cooling; step two, pasting the required pattern on the silk-screen printing stained paper after cooling, and naturally drying; step three, quickly burning the enamel plate with the pattern obtained in the step two; obtaining a luminous artistic enamel plate; the metal enamel plate obtained by the invention has stable noctilucent effect and is more artistic.
Description
Technical Field
The invention relates to the technical field of enamel glaze and enamel plates, in particular to an enamel noctilucent glaze, a noctilucent enamel plate and a manufacturing method thereof.
Background
The invention with the publication number of CN105777198B discloses a luminous powder, which is environment-friendly, non-radiative and high in brightness, and the luminous powder can be stored for a long time without affecting the quality of a luminous enamel product; meanwhile, the light storage capacity of the noctilucent enamel product is enhanced, the light emitting time of the noctilucent enamel product is prolonged, the light emitting time can reach at least more than 12 hours after the noctilucent enamel product is irradiated for 2 minutes by sunlight or 10 minutes by a fluorescent lamp, and further, the noctilucent enamel produced by the method stores light and emits light with different colors by adopting different kinds of noctilucent powder, so that the noctilucent enamel can be widely popularized and applied to the field of noctilucent enamel production.
Disclosure of Invention
The invention aims to provide an enamel luminous glaze, which combines the luminous effect and the light transmission property simultaneously through the matching of a luminous pigment component and a basic glaze.
In order to solve the technical problem, the technical scheme of the invention is as follows: a luminous enamel glaze comprises a luminous pigment component and a basic glaze component; the mass parts of the two are as follows according to 100 parts by mass percent:
the noctilucent pigment component accounts for 8 to 12 parts;
the balance of basic glaze.
Preferably, the basic glaze comprises the following components in percentage by mass:
14.50% of sodium oxide; 2.50 percent of potassium oxide; 4.35 percent of barium oxide; 35.50% of diboron dioxide; 1.25 percent of aluminum dioxide; 1.45 percent of zinc oxide; 1.03 percent of phosphorus pentoxide; 33.05 percent of silicon dioxide; 1.00 percent of calcium oxide; 5.37 percent of lithium oxide.
Preferably, the noctilucent pigment is red;
the noctilucent pigment comprises the following components in parts by weight:
55 parts of barium sulfate; 40 parts of magnesium sulfate; 2 parts of lithium phosphate; 3 parts of copper nitrate.
Preferably, the noctilucent pigment is blue;
the noctilucent pigment comprises the following components in parts by weight:
63 parts of calcium sulfide; 5 parts of sodium sulfate; 5 parts of potassium sulfate; 10 parts of strontium sulfate; 6 parts of sodium chloride; 1 part of silver nitrate; 10 parts of magnesium sulfide.
Preferably, the noctilucent pigment is purple;
the noctilucent pigment comprises the following components in parts by weight:
63 parts of calcium sulfide; 26 parts of magnesium sulfide; 10 parts of sodium sulfide; and 1 part of strontium nitrate.
Preferably, the noctilucent pigment is green;
the noctilucent pigment comprises the following components in parts by weight:
55 parts of calcium sulfide; 1 part of potassium sulfide; 10 parts of sodium sulfide; 12 parts of barium nitrate; and 13 parts of indium nitrate.
Preferably, the noctilucent pigment component is 10 parts.
The invention aims to provide a preparation method of a noctilucent enamel plate, and the metal enamel plate obtained by the preparation method is stable in noctilucent effect and more artistic.
In order to solve the technical problem, the technical scheme of the invention is as follows: a preparation method of a noctilucent enamel plate comprises the following steps:
step one, preparing the enamel luminous glaze material prepared by the invention into glaze slip, spraying the glaze slip on a white enamel plate, drying, quickly burning and naturally cooling;
step two, pasting the required pattern on the silk-screen printing stained paper after cooling, and naturally drying;
step three, quickly burning the enamel plate with the pattern obtained in the step two;
obtaining the luminous artistic enamel plate.
Preferably, the glaze layer obtained in the first step is 200-400 μm;
the drying temperature in the first step is 100 ℃;
in the first step, the fast burning temperature is 800-850 ℃, and the fast burning time is 2-5 minutes;
the temperature of the quick firing in the third step is 700 ℃ to 800 ℃, and the time of the quick firing is 2 minutes to 5 minutes.
The invention aims to provide a noctilucent enamel plate which is stable in noctilucent effect and more artistic.
In order to solve the technical problem, the technical scheme of the invention is as follows: the invention discloses a noctilucent artistic enamel plate.
By adopting the technical scheme, the invention has the beneficial effects that:
according to the invention, the noctilucent pigment component is mixed with the basic glaze material, the noctilucent pigment component is 8-12 parts, the noctilucent pigment component is effectively and uniformly dispersed through the basic glaze material, direct contact between noctilucent powder and metal is effectively reduced, the unsaturated state of the noctilucent pigment component is ensured, and the luminescence of the glaze material is ensured;
the glaze slip obtained by the invention can not be directly rubbed at high temperature and rapidly, so that the original structure of the noctilucent powder is prevented from being changed, and the glaze slip is uniformly mixed and then is sprayed on the metal enamel plate;
the glaze slip prepared by mixing the noctilucent pigment component and the basic glaze material has good transparency, is beneficial to the luminescence of noctilucent powder, and has high gloss and smoother porcelain surface;
the noctilucent pigment component absorbs the energy of various visible light sources and stores the light energy, the excitation time is short, the luminescence and afterglow time is long, and the brightness is high; the lamp can automatically emit light in the dark after receiving illumination, can be circularly applied for infinite times, and has a repeated service life of more than 20 years;
the enamel plate obtained by the method has extremely stable physical and chemical properties, extremely strong environmental adaptability and ordinary service life; the method is safe, reliable, energy-saving and environment-friendly; the particles are small, the fineness and the particle size distribution are uniform, the particles can be used for signals and attention writing, and the emergency evacuation channel, the subway station, an underground channel, a civil air defense project, a hospital, a railway station, an airport, a wharf, a refuge place and the like can play a role in preventing dangers; the enamel plate obtained by the invention has the temperature resistance of more than 500 ℃, the highest temperature of green light can reach 950 ℃, and the highest temperature of blue light can reach 1050 ℃.
Thereby achieving the above object of the present invention.
Drawings
FIG. 1 is a view of the effect of the luminous enamel art plate according to the present invention;
FIG. 2 is an effect diagram of the noctilucent enamel art plate manufactured by the invention under dark environment;
FIG. 3 is a diagram of the effect of the enamel art plate manufactured by the prior art under the lighting;
FIG. 4 shows the effect of the enamel art plate manufactured by the prior art in dark environment.
Detailed Description
In order to further explain the technical solution of the present invention, the present invention is explained in detail by the following specific examples.
Example 1
This example discloses an enamel luminescent glaze comprising a luminescent pigment component and a basic glaze component; the mass parts of the two are as follows according to 100 parts by mass percent:
8 parts of noctilucent pigment component;
the balance of basic glaze.
Preferably, the noctilucent pigment is red;
the noctilucent pigment comprises the following components in parts by weight:
55 parts of barium sulfate; 40 parts of magnesium sulfate; 2 parts of lithium phosphate; 3 parts of copper nitrate.
The basic glaze comprises the following components in percentage by mass:
14.50% of sodium oxide; 2.50 percent of potassium oxide; 4.35 percent of barium oxide; 35.50% of diboron dioxide; 1.25 percent of aluminum dioxide; 1.45 percent of zinc oxide; 1.03 percent of phosphorus pentoxide; 33.05 percent of silicon dioxide; 1.00 percent of calcium oxide; 5.37 percent of lithium oxide.
The embodiment also discloses a preparation method for preparing the noctilucent enamel plate by using the enamel noctilucent glaze material, which comprises the following steps:
the method comprises the following steps:
step one, preparing the enamel luminous glaze material prepared by the invention into glaze slip, spraying the glaze slip on a white enamel plate, drying, quickly burning and naturally cooling; preferably, the glaze layer obtained in the first step is 200-400 μm;
the drying temperature in the first step is 100 ℃;
in the first step, the fast burning temperature is 800-850 ℃, and the fast burning time is 2-5 minutes;
step two, pasting the required pattern on the silk-screen printing stained paper after cooling, and naturally drying;
step three, quickly burning the enamel plate with the pattern obtained in the step two;
the temperature of the quick firing in the third step is 700 ℃ to 800 ℃, and the time of the quick firing is 2 minutes to 5 minutes.
Obtaining the luminous artistic enamel plate.
Example 2
The main differences between this embodiment and embodiment 1 are:
a luminous enamel glaze comprises a luminous pigment component and a basic glaze component; the mass parts of the two are as follows according to 100 parts by mass percent:
10 parts of noctilucent pigment component;
the balance of basic glaze.
Example 3
The main differences between this embodiment and embodiment 1 are:
the enamel luminous glaze of the embodiment comprises a luminous pigment component and a basic glaze component; the mass parts of the two are as follows according to 100 parts by mass percent:
12 parts of noctilucent pigment component;
the balance of basic glaze.
Example 4
The main differences between this embodiment and embodiment 1 are:
the enamel luminous glaze of the embodiment comprises a luminous pigment component and a basic glaze component; the mass parts of the two are as follows according to 100 parts by mass percent:
15 parts of noctilucent pigment component;
the balance of basic glaze.
Example 5
This example discloses an enamel luminescent glaze comprising a luminescent pigment component and a basic glaze component; the mass parts of the two are as follows according to 100 parts by mass percent:
10 parts of noctilucent pigment component;
the balance of basic glaze.
Preferably, the noctilucent pigment is blue;
the noctilucent pigment comprises the following components in parts by weight:
63 parts of calcium sulfide; 5 parts of sodium sulfate; 5 parts of potassium sulfate; 10 parts of strontium sulfate; 6 parts of sodium chloride; 1 part of silver nitrate; 10 parts of magnesium sulfide.
The basic glaze comprises the following components in percentage by mass:
14.50% of sodium oxide; 2.50 percent of potassium oxide; 4.35 percent of barium oxide; 35.50% of diboron dioxide; 1.25 percent of aluminum oxide; 1.45 percent of zinc oxide; 1.03 percent of phosphorus pentoxide; 33.05 percent of silicon dioxide; 1.00 percent of calcium oxide; 5.37 percent of lithium oxide.
The embodiment also discloses a preparation method for preparing the noctilucent enamel plate by using the enamel noctilucent glaze material, which comprises the following steps:
the method comprises the following steps:
step one, preparing the enamel luminous glaze material prepared by the invention into glaze slip, spraying the glaze slip on a white enamel plate, drying, quickly burning and naturally cooling; preferably, the glaze layer obtained in the first step is 200 μm;
the drying temperature in the first step is 100 ℃;
in the first step, the fast burning temperature is 800 ℃, and the fast burning time is 2 minutes;
step two, pasting the required pattern on the silk-screen printing stained paper after cooling, and naturally drying;
step three, quickly burning the enamel plate with the pattern obtained in the step two;
in the third step, the temperature of the quick burning is 700 ℃, and the time of the quick burning is 2 minutes.
Obtaining the luminous artistic enamel plate.
Example 6
The main technical features of the present embodiment and embodiment 5 are:
preferably, the noctilucent pigment is purple;
the noctilucent pigment comprises the following components in parts by weight:
63 parts of calcium sulfide; 26 parts of magnesium sulfide; 10 parts of sodium sulfide; and 1 part of strontium nitrate.
The embodiment also discloses a preparation method for preparing the noctilucent enamel plate by using the enamel noctilucent glaze material, which comprises the following steps:
the method comprises the following steps:
step one, preparing the enamel luminous glaze material prepared by the invention into glaze slip, spraying the glaze slip on a white enamel plate, drying, quickly burning and naturally cooling; preferably, the glaze layer obtained in the first step is 300 mu m;
the drying temperature in the first step is 100 ℃;
in the first step, the fast burning temperature is 820 ℃, and the fast burning time is 3 minutes;
step two, pasting the required pattern on the silk-screen printing stained paper after cooling, and naturally drying;
step three, quickly burning the enamel plate with the pattern obtained in the step two;
in the third step, the temperature of the quick burning is 800 ℃, and the time of the quick burning is 5 minutes.
Obtaining the luminous artistic enamel plate.
Example 7
The main differences between this example and example 5 are:
preferably, the noctilucent pigment is green;
the noctilucent pigment comprises the following components in parts by weight:
55 parts of calcium sulfide; 1 part of potassium sulfide; 10 parts of sodium sulfide; 12 parts of barium nitrate; and 13 parts of indium nitrate.
Preferably, the noctilucent pigment component is 10 parts.
The embodiment also discloses a preparation method for preparing the noctilucent enamel plate by using the enamel noctilucent glaze material, which comprises the following steps:
the method comprises the following steps:
step one, preparing the enamel luminous glaze material prepared by the invention into glaze slip, spraying the glaze slip on a white enamel plate, drying, quickly burning and naturally cooling; preferably, the glaze layer obtained in the first step is 400 μm;
the drying temperature in the first step is 100 ℃;
in the first step, the fast burning temperature is 850 ℃, and the fast burning time is 5 minutes;
step two, pasting the required pattern on the silk-screen printing stained paper after cooling, and naturally drying;
step three, quickly burning the enamel plate with the pattern obtained in the step two;
in the third step, the temperature of the quick burning is 800 ℃, and the time of the quick burning is 5 minutes.
Obtaining the luminous artistic enamel plate.
The enamel plates obtained in examples 1 to 7 were subjected to performance tests, including transparency and luminescence of the enamel platesThe glossy surface and the porcelain surface are smoother; the specific test method for the luminous performance of the enamel plate comprises the following steps: the luminous ceramic product is irradiated by a 200W fluorescent lamp for 10 minutes, and the afterglow time is at the visual brightness (not less than 0.32 mcd/m)2) The time of (d); specific test data are shown in table 1.
As can be seen from the data in Table 1, the glaze slip prepared by mixing the noctilucent pigment component and the basic glaze material has good transparency, is beneficial to the luminescence of noctilucent powder, and has high gloss and smoother porcelain surface; the noctilucent pigment component absorbs the energy of various visible light sources and stores the light energy, the excitation time is short, the luminescence and afterglow time is long, and the brightness is high; the lamp can automatically emit light in the dark after receiving illumination, can be circularly applied for infinite times, and has a repeated service life of more than 20 years.
The above embodiments and drawings are not intended to limit the form and style of the present invention, and any suitable changes or modifications thereof by those skilled in the art should be considered as not departing from the scope of the present invention.
Claims (10)
1. An enamel luminous glaze material, which is characterized in that: comprises a noctilucent pigment component and a basic glaze component; the mass parts of the two are as follows according to 100 parts by mass percent:
the noctilucent pigment component accounts for 8 to 12 parts;
the balance of basic glaze.
2. The enamel luminous glaze of claim 1, wherein:
the basic glaze comprises the following components in percentage by mass:
14.50% of sodium oxide; 2.50 percent of potassium oxide; 4.35 percent of barium oxide; 35.50% of diboron dioxide; 1.25 percent of aluminum dioxide; 1.45 percent of zinc oxide; 1.03 percent of phosphorus pentoxide; 33.05 percent of silicon dioxide; 1.00 percent of calcium oxide; 5.37 percent of lithium oxide.
3. The enamel luminous glaze of claim 1, wherein:
the noctilucent pigment is red;
the noctilucent pigment comprises the following components in parts by weight:
55 parts of barium sulfate; 40 parts of magnesium sulfate; 2 parts of lithium phosphate; 3 parts of copper nitrate.
4. The enamel luminous glaze of claim 1, wherein:
the noctilucent pigment is blue;
the noctilucent pigment comprises the following components in parts by weight:
63 parts of calcium sulfide; 5 parts of sodium sulfate; 5 parts of potassium sulfate; 10 parts of strontium sulfate; 6 parts of sodium chloride; 1 part of silver nitrate; 10 parts of magnesium sulfide.
5. The enamel luminous glaze of claim 1, wherein:
the noctilucent pigment is purple;
the noctilucent pigment comprises the following components in parts by weight:
63 parts of calcium sulfide; 26 parts of magnesium sulfide; 10 parts of sodium sulfide; and 1 part of strontium nitrate.
6. The enamel luminous glaze of claim 1, wherein:
the noctilucent pigment is green;
the noctilucent pigment comprises the following components in parts by weight:
55 parts of calcium sulfide; 1 part of potassium sulfide; 10 parts of sodium sulfide; 12 parts of barium nitrate; and 13 parts of indium nitrate.
7. The enamel luminous glaze of claim 1, wherein: the noctilucent pigment component is 10 parts.
8. A preparation method of a luminous enamel plate is characterized by comprising the following steps:
the method comprises the following steps:
firstly, the enamel luminous glaze material of any one of claims 1 to 7 is made into glaze slip and sprayed on a white enamel plate, and the enamel plate is dried, quickly fired and naturally cooled;
step two, pasting the required pattern on the silk-screen printing stained paper after cooling, and naturally drying;
step three, quickly burning the enamel plate with the pattern obtained in the step two;
obtaining the luminous artistic enamel plate.
9. The method of claim 8, wherein: the glaze layer obtained in the first step is 200-400 μm;
the drying temperature in the first step is 100 ℃;
in the first step, the fast burning temperature is 800-850 ℃, and the fast burning time is 2-5 minutes;
the temperature of the quick firing in the third step is 700 ℃ to 800 ℃, and the time of the quick firing is 2 minutes to 5 minutes.
10. A luminous artistic enamel plate manufactured by the manufacturing method according to claim 8.
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| CN202111563863.6A CN114315137A (en) | 2021-12-20 | 2021-12-20 | Noctilucent glaze material for enamel, noctilucent enamel plate and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202111563863.6A CN114315137A (en) | 2021-12-20 | 2021-12-20 | Noctilucent glaze material for enamel, noctilucent enamel plate and manufacturing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115466956A (en) * | 2022-09-20 | 2022-12-13 | 浙江开尔新材料股份有限公司 | Method for preparing random fancy glaze for enamel decoration |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
| CN105777198A (en) * | 2014-12-23 | 2016-07-20 | 苏德良 | Noctilucent glaze, noctilucent ceramic and preparation method thereof |
| CN109231836A (en) * | 2018-10-22 | 2019-01-18 | 贵阳市白云区科创生产力促进中心 | Imitative engraving noctilucent glaze material and its manufacture craft |
| CN111777332A (en) * | 2020-06-15 | 2020-10-16 | 黄冈市蕲春县新天地瓷业有限公司 | Noctilucent glaze, noctilucent ceramic and preparation method thereof |
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| CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
| CN105777198A (en) * | 2014-12-23 | 2016-07-20 | 苏德良 | Noctilucent glaze, noctilucent ceramic and preparation method thereof |
| CN109231836A (en) * | 2018-10-22 | 2019-01-18 | 贵阳市白云区科创生产力促进中心 | Imitative engraving noctilucent glaze material and its manufacture craft |
| CN111777332A (en) * | 2020-06-15 | 2020-10-16 | 黄冈市蕲春县新天地瓷业有限公司 | Noctilucent glaze, noctilucent ceramic and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115466956A (en) * | 2022-09-20 | 2022-12-13 | 浙江开尔新材料股份有限公司 | Method for preparing random fancy glaze for enamel decoration |
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