CN115369653A - 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍方法及所获得的复合材料 - Google Patents

用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍方法及所获得的复合材料 Download PDF

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Publication number
CN115369653A
CN115369653A CN202210267124.0A CN202210267124A CN115369653A CN 115369653 A CN115369653 A CN 115369653A CN 202210267124 A CN202210267124 A CN 202210267124A CN 115369653 A CN115369653 A CN 115369653A
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CN
China
Prior art keywords
meth
acrylic
liquid
mpa
fibrous substrate
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Pending
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CN202210267124.0A
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English (en)
Chinese (zh)
Inventor
P.热拉尔
M.格洛坦
J-P.科舒瓦（波尔普拉斯特吉德莱斯特）
C.奎因滕
M.米哈卢塔
Q.林
M.费里奥尔
M.科谢
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Welding research institute
Institut National Polytechnique de Lorraine
Arkema France SA
Original Assignee
Welding research institute
Institut National Polytechnique de Lorraine
Arkema France SA
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Application filed by Welding research institute, Institut National Polytechnique de Lorraine, Arkema France SA filed Critical Welding research institute
Publication of CN115369653A publication Critical patent/CN115369653A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/02—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers
    • B29C70/021—Combinations of fibrous reinforcement and non-fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04—Polymers of esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2505/00—Use of metals, their alloys or their compounds, as filler
    • B29K2505/02—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/34—Electrical apparatus, e.g. sparking plugs or parts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)
CN202210267124.0A 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍方法及所获得的复合材料 Pending CN115369653A (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR1352157A FR3002943B1 (fr) 2013-03-11 2013-03-11 Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.
FR1352157 2013-03-11
PCT/FR2014/050538 WO2014140465A1 (fr) 2013-03-11 2014-03-10 Sirop (meth) acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
CN201480026478.XA CN105377972A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201480026478.XA Division CN105377972A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料

Publications (1)

Publication Number Publication Date
CN115369653A true CN115369653A (zh) 2022-11-22

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Application Number Title Priority Date Filing Date
CN202210267124.0A Pending CN115369653A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍方法及所获得的复合材料
CN201480026478.XA Pending CN105377972A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料

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CN201480026478.XA Pending CN105377972A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料

Country Status (8)

Country Link
US (1) US10131768B2 (https=)
EP (1) EP2970635B1 (https=)
JP (1) JP6499978B2 (https=)
CN (2) CN115369653A (https=)
CA (1) CA2905866C (https=)
FR (1) FR3002943B1 (https=)
MX (1) MX380319B (https=)
WO (1) WO2014140465A1 (https=)

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FR2993581B1 (fr) * 2012-07-18 2016-01-22 Arkema France Procede d'impregnation pour un substrat fibreux, sirop (meth)acrylique liquide pour le procede d'impregnation, son procede de polymerisation et produit structure obtenu a partir de celui-ci
FR3002941B1 (fr) 2013-03-08 2015-04-10 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
FR3016642B1 (fr) * 2014-01-22 2020-02-21 Arkema France Procede d'impregnation pour un substrat fibreux, sirop monomere liquide pour le procede d'impregnation, sa methode de polymerisation et article structurel obtenu
FR3019824B1 (fr) * 2014-04-15 2017-10-13 Arkema France Procede pour materiau composite avec impregnation par polymere thermoplastique, issu d'un prepolymere et d'un allongeur de chaine
FR3037066B1 (fr) * 2015-06-05 2019-06-21 Arkema France Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique comprenant une substance ignifugeante
CN105603741A (zh) * 2016-01-26 2016-05-25 吴江市震宇缝制设备有限公司 一种环保纺织缝纫纱线浆料
WO2017168006A1 (en) * 2016-04-01 2017-10-05 Dsm Ip Assets B.V. Beverages comprising stable granules of milled lutein
CN106084606B (zh) * 2016-05-30 2018-06-19 敖然 连续纤维增强热塑性复合材料及其制备方法
FR3053693B1 (fr) * 2016-07-11 2018-08-17 Arkema France Composition liquide comprenant un additif a base de phosphore, son utilisation et materiau ou composition obtenu apres polymerisation de la composition
FR3073855B1 (fr) * 2017-11-21 2020-12-18 Arkema France Composition liquide adaptee a des applications de composites thermoplastiques moulees a base de smc
MX2021005845A (es) * 2018-11-19 2021-07-15 Arkema France Compuestos acrilicos con propiedades superficiales mejoradas.
FR3105228B1 (fr) * 2019-12-18 2021-11-26 Arkema France Composition comprenant un hemiperoxyacetal, son procédé de polymérisation, son utilisation et matériau de composition obtenu après polymérisation de la composition
ES2906674B2 (es) * 2020-10-15 2022-11-17 Consejo Superior Investigacion Polimeros reforzados con fibras basados en matrices termoplasticas
CN117999315A (zh) * 2021-08-31 2024-05-07 盛禧奥欧洲有限责任公司 非卤化自熄性树脂组合物及其制备方法
US20240010828A1 (en) * 2022-07-08 2024-01-11 B/E Aerospace, Inc. Fire resistant polymer matrix composite
CN118406335A (zh) * 2023-01-28 2024-07-30 慈溪七诺新材料科技有限公司 一种阻燃型连续纤维增强丙烯酸类热塑性纳米复合材料及其制备方法
CN118406336A (zh) * 2023-01-28 2024-07-30 慈溪七诺新材料科技有限公司 一种阻燃型连续纤维增强丙烯酸类热塑性纳米复合材料及其制备方法
CN116082778B (zh) * 2023-03-02 2024-04-26 江苏盈韧新材料科技有限公司 一种阻燃天然纤维增强热塑性复合材料及其制造方法

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FR3002941B1 (fr) 2013-03-08 2015-04-10 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
FR3002942B1 (fr) 2013-03-11 2016-01-22 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.

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US3287155A (en) * 1962-11-08 1966-11-22 Du Pont Process for impregnating glass fiber mat with methyl methacrylate polymer
CN1902275A (zh) * 2003-12-19 2007-01-24 罗狄亚工程塑料有限责任公司 基于热塑性基质的阻燃组合物
CN102549050A (zh) * 2009-05-12 2012-07-04 阿克马法国公司 纤维基材、这样的纤维基材的制备方法及用途

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MX380319B (es) 2025-03-12
US20160032080A1 (en) 2016-02-04
EP2970635A1 (fr) 2016-01-20
JP6499978B2 (ja) 2019-04-10
JP2016510086A (ja) 2016-04-04
WO2014140465A1 (fr) 2014-09-18
FR3002943B1 (fr) 2015-03-27
CN105377972A (zh) 2016-03-02
FR3002943A1 (fr) 2014-09-12
CA2905866A1 (en) 2014-09-18
CA2905866C (en) 2021-04-13
MX2015012080A (es) 2016-07-06
US10131768B2 (en) 2018-11-20
EP2970635B1 (fr) 2017-06-07

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