CN115304957A - 一种水性油墨分散体及其制备方法 - Google Patents
一种水性油墨分散体及其制备方法 Download PDFInfo
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- CN115304957A CN115304957A CN202210852658.XA CN202210852658A CN115304957A CN 115304957 A CN115304957 A CN 115304957A CN 202210852658 A CN202210852658 A CN 202210852658A CN 115304957 A CN115304957 A CN 115304957A
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- Prior art keywords
- acid
- water
- monomer
- methacrylate
- acrylate
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 90
- 239000006185 dispersion Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims description 40
- 239000008367 deionised water Substances 0.000 claims description 28
- 229910021641 deionized water Inorganic materials 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 22
- 239000003999 initiator Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 18
- 239000007810 chemical reaction solvent Substances 0.000 claims description 16
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 15
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 14
- -1 glycerol ester Chemical class 0.000 claims description 14
- 238000004321 preservation Methods 0.000 claims description 13
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 7
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000012986 chain transfer agent Substances 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 235000007586 terpenes Nutrition 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- 239000011976 maleic acid Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 4
- WOZHZOLFFPSEAM-UHFFFAOYSA-N 3-butene-1,2,3-tricarboxylic acid Chemical compound OC(=O)CC(C(O)=O)C(=C)C(O)=O WOZHZOLFFPSEAM-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 4
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 claims description 4
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 claims description 4
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 claims description 4
- 150000003505 terpenes Chemical class 0.000 claims description 4
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 4
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 4
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 3
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 3
- WHBAYNMEIXUTJV-UHFFFAOYSA-N 2-chloroethyl prop-2-enoate Chemical compound ClCCOC(=O)C=C WHBAYNMEIXUTJV-UHFFFAOYSA-N 0.000 claims description 3
- IEVADDDOVGMCSI-UHFFFAOYSA-N 2-hydroxybutyl 2-methylprop-2-enoate Chemical compound CCC(O)COC(=O)C(C)=C IEVADDDOVGMCSI-UHFFFAOYSA-N 0.000 claims description 3
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 3
- SPGHPHFQNQIZME-UHFFFAOYSA-N 2-n-ethylethane-1,1,2-triamine Chemical compound CCNCC(N)N SPGHPHFQNQIZME-UHFFFAOYSA-N 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 3
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 claims description 3
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- AKNUHUCEWALCOI-UHFFFAOYSA-N N-ethyldiethanolamine Chemical compound OCCN(CC)CCO AKNUHUCEWALCOI-UHFFFAOYSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
- MGFFVSDRCRVHLC-UHFFFAOYSA-N butyl 3-sulfanylpropanoate Chemical compound CCCCOC(=O)CCS MGFFVSDRCRVHLC-UHFFFAOYSA-N 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 3
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 claims description 3
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 claims description 3
- RGNRTCKDPBJEHU-UHFFFAOYSA-N pent-4-ene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)C(C(O)=O)C(=C)C(O)=O RGNRTCKDPBJEHU-UHFFFAOYSA-N 0.000 claims description 3
- 238000010025 steaming Methods 0.000 claims description 3
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 2
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 claims description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 2
- GPOGMJLHWQHEGF-UHFFFAOYSA-N 2-chloroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCl GPOGMJLHWQHEGF-UHFFFAOYSA-N 0.000 claims description 2
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 claims description 2
- YUZJZPMLAIYVGM-UHFFFAOYSA-N 2-n-methylethane-1,1,2-triamine Chemical compound CNCC(N)N YUZJZPMLAIYVGM-UHFFFAOYSA-N 0.000 claims description 2
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims description 2
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims description 2
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 125000005336 allyloxy group Chemical group 0.000 claims description 2
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- KJQQZMROZXQVEP-UHFFFAOYSA-N hex-3-ene-1,1,6,6-tetracarboxylic acid Chemical compound OC(=O)C(C(O)=O)CC=CCC(C(O)=O)C(O)=O KJQQZMROZXQVEP-UHFFFAOYSA-N 0.000 claims description 2
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 claims description 2
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 claims description 2
- 235000020778 linoleic acid Nutrition 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
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- 230000003472 neutralizing effect Effects 0.000 claims description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 2
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims description 2
- OAUDNTNYSCNXJD-UHFFFAOYSA-N pent-1-ene-1,1,4,4-tetracarboxylic acid Chemical compound OC(=O)C(C(O)=O)(C)CC=C(C(O)=O)C(O)=O OAUDNTNYSCNXJD-UHFFFAOYSA-N 0.000 claims description 2
- QWFQZTFNZZNHLR-UHFFFAOYSA-N pent-4-ene-1,2,4-tricarboxylic acid Chemical compound OC(=O)CC(C(O)=O)CC(=C)C(O)=O QWFQZTFNZZNHLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920001289 polyvinyl ether Polymers 0.000 claims description 2
- FWFUWXVFYKCSQA-UHFFFAOYSA-M sodium;2-methyl-2-(prop-2-enoylamino)propane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(C)(C)NC(=O)C=C FWFUWXVFYKCSQA-UHFFFAOYSA-M 0.000 claims description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 2
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- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 claims 1
- XKBHBVFIWWDGQX-UHFFFAOYSA-N 2-bromo-3,3,4,4,5,5,5-heptafluoropent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(Br)=C XKBHBVFIWWDGQX-UHFFFAOYSA-N 0.000 claims 1
- 125000005394 methallyl group Chemical group 0.000 claims 1
- 125000001844 prenyl group Chemical group [H]C([*])([H])C([H])=C(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
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- JZFHXRUVMKEOFG-UHFFFAOYSA-N tert-butyl dodecaneperoxoate Chemical compound CCCCCCCCCCCC(=O)OOC(C)(C)C JZFHXRUVMKEOFG-UHFFFAOYSA-N 0.000 description 2
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
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- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
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Abstract
本发明公开了一种水性油墨分散体及其制备方法。通过在分散体树脂主链中引入特殊的分子基团，提高了分散体对颜料的分散性和润湿性。以该水性油墨分散体制备的水性油墨，具有良好的复溶性和抗水性，油墨层的光泽度较乳液型水性油墨有显著提高。
Description
技术领域
本发明属于水性油墨技术领域，特别涉及一种水性油墨分散体及其制备方法。
背景技术
水性油墨是以水为主要溶剂制成的油墨，通常水性油墨使用的连接料有水性松香、酪素、水性聚氨酯、丙烯酸乳液等。相比于油性油墨，水性油墨具有巨大的环保优势，近年来科技工作者对水性油墨开展了广泛的研究：专利CN103571262A公开了一种环保性水性油墨，该水性油墨主要包括：有机颜料、聚四氟乙烯树脂、二甲基萘磺酸钠、润湿剂、消泡剂和水。由该方法制得的水性油墨pH较低，可能会导致版面起脏。专利CN106479266A公开了一种快干水性UV油墨，该水性UV油墨中的原料主要包括：水性聚氨酯丙烯酸酯、颜填料、无水乙醇、表面活性剂、助剂、光引发剂和去离子水。该专利加入表面活性剂，降低表面张力，可加快油墨的干燥速度。但该水性UV油墨的耐溶剂性较差，影响印刷效果。专利CN101054490A公开了一种采用水溶性固体丙烯酸研磨色浆加入丙烯酸酯乳液，制备的水性油墨。专利CN101519557A公开了一种采用水溶性丙烯酸-苯乙烯共聚树脂和聚丙烯酸树脂制备的水性油墨。专利CN102153909A公开了一种以不同玻璃化温度的水性丙烯酸乳液、水溶性丙烯酸树脂液、颜料、助剂等制备的水性油墨。专利CN101429359A以水性聚氨酯乳液、水性丙烯酸树脂、颜料、助剂等制备了一种水基塑料复合里印油墨。
但是目前水性油墨依然存在干燥速度慢、光泽度低等缺陷，难以媲美溶剂型油墨。
发明内容
为了解决背景技术中水性油墨的使用缺陷，提高水性油墨的印刷适性，本发明提供的一种水性油墨分散体及其制备方法。
为达到上述目的，本发明提供了如下的技术方案：
一种水性油墨分散体，按重量百分比计，由如下组分制备而成：
引发剂 0.1～0.5wt%
反应溶剂 20～30wt%
硬单体 5～15wt%
软单体 5～15wt%
功能单体 5～10wt%
羧酸类单体 5～15wt%
反应型乳化剂 0.5～5wt%
链转移剂 0.05～2wt%
中和剂 5～15wt%
去离子水 40～50wt%
增粘树脂 1～10wt%；
该水性油墨分散体制备方法如下：
（1）将引发剂溶解于10wt%的反应溶剂中，配制成引发剂溶液；将硬单体、软单体、功能单体、羧酸类单体、反应型乳化剂和链转移剂混合为单体混合物；
（2）将余量的反应溶剂加入反应釜中，搅拌状态下升温至70～85℃，同时开始滴加单体混合物和引发剂溶液，滴加时间2～4小时，滴加完成后保温反应2～3小时；
（3）保温结束后，加入中和剂，搅拌0.5～1小时后，加入20～40wt%的去离子水，分散均匀后减压蒸除反应溶剂；
（4）加入剩余去离子水和增粘树脂，搅拌均匀，降至室温出料，得到水性油墨分散体。
需要说明的是，上述制备步骤中，反应溶剂按照重量被分为10wt%、90wt%两份，步骤（1）中 “溶解于10%的反应溶剂中”即溶解于反应溶剂总重量10%的反应溶剂中，步骤（2）“余量的反应溶剂”即反应溶剂总重量90%的反应溶剂；去离子水按照重量被分为20～40wt%的第一份，余量为第二份，步骤（3）中“20～40wt%的去离子水”即去离子水总重量20～40wt%的去离子水。
优选的，所述引发剂选自偶氮二异丁腈、偶氮二异庚腈、过氧化二乙酰、过氧化二苯甲酰、叔丁基过氧化氢、二叔丁基过氧化物、过氧化二叔戊基、叔丁基过氧化月桂酸酯、过氧化二月桂酰、过氧化二异丙苯、过氧化苯甲酸叔丁基酯中任一种或多种。
优选的，所述反应溶剂选自乙醇、丙酮、异丙醇中任一种或多种。
优选的，所述硬单体选自甲基丙烯酸甲酯、甲基丙烯酸乙酯、甲基丙烯酸丙酯、甲基丙烯酸十八烷基脂、苯乙烯、丙烯腈、醋酸乙烯酯、叔碳酸乙烯酯中任一种或多种。
优选的，所述软单体选自丙烯酸丁酯、丙烯酸叔丁酯、丙烯酸月桂酯、丙烯酸正辛酯、丙烯酸异辛酯中任一种或多种。
优选的，所述功能单体选自丙烯酸羟乙酯、甲基丙烯酸羟乙酯、丙烯酸羟丙酯、甲基丙烯酸羟丙酯、丙烯酸羟丁酯、甲基丙烯酸羟丁酯、丙烯酰胺、甲基丙烯酸二甲氨基乙酯、烯丙基缩水甘油醚、丙烯酸缩水甘油酯、甲基丙烯酸缩水甘油酯、丙烯酸-2-氯乙基酯、甲基丙烯酸-2-氯乙基酯、松香、松香甘油酯、松香季戊四醇酯、松香酚醛树脂、萜烯树脂中任一种或多种。
优选的，所述羧酸类单体选自丙烯酸、甲基丙烯酸、巴豆酸、衣康酸、马来酸、马来酸酐、马来酸单酯、富马酸、富马酸单酯、乙烯基乙酸、丙烯-1，2，3-三羧酸、3-丁烯-1，2，3-三羧酸、4-戊烯-1，2，4-三羧酸、1-戊烯-1，1，4，4-四羧酸、4-戊烯-1，2，3，4-四羧酸、3-己烯-1，1，6，6-四羧酸、亚油酸中任一种或多种。
优选的，所述反应型乳化剂选自烯丙基聚氧乙烯醚、甲基烯丙基聚氧乙烯醚、烯丙氧基壬基酚聚氧乙烯醚硫酸铵、烯丙氧基癸基聚氧乙烯醚硫酸铵、烯丙基壬基酚聚氧乙烯醚磷酸铵、异丁烯醇聚氧乙烯醚、异戊烯醇聚乙烯醚、2-丙烯酰胺基-2-甲基丙磺酸钠中任一种或多种。
优选的，所述链转移剂选自十二烷基硫醇、叔十二烷基硫醇、巯基乙醇、巯基乙酸、3-巯基丙酸、3-巯基丙酸丁酯、α-甲基苯乙烯二聚体中任一种或多种；
所述中和剂选自三乙胺、N-甲基二乙醇胺、N-乙基二乙醇胺、N-甲基二氨基乙基胺、N-乙基二氨基乙基胺、2-氨基-2-甲基-1-丙醇中任一种或多种。
优选的，所述增粘树脂选自水性酚醛、萜烯酚醛乳液、水性氯化聚丙烯、水性马来酸树脂、氯乙烯/醋酸乙烯共聚乳液、环氧树脂乳液、水性酚醛环氧树脂乳液中任一种或多种。
与现有技术相比，本发明具有以下有益效果：
传统乳液型丙烯酸水性油墨，由于乳液乳胶粒对颜料包裹效果很差，所制水墨中的颜料颗粒偏大，分散不均匀，油墨干燥成膜时表面不平整，造成水墨印刷图案光泽暗淡，与溶剂型油墨的印刷效果相比，差异很大。本发明通过制备特殊设计的水性丙烯酸分散体，提高油墨树脂对颜料的分散性能，平衡水性油墨的复溶性和耐水性，改善水性油墨的成膜状态，提高油墨印刷图案的光泽度。
具体实施方式
下面通过具体实施例对本发明做进一步的详述，但不应理解为是对本发明保护范围的限制。凡基于上述技术思想，利用本领域普通技术知识和惯用的技术手段所做的修改、替换、变更，均属于本发明的范围。
实施例1
水性油墨分散体的制备：
（1）将0.1公斤偶氮二异丁腈溶解于2.5公斤乙醇中，配制成引发剂溶液；将6.4公斤甲基丙烯酸甲酯、10公斤丙烯酸丁酯、10公斤丙烯酸羟乙酯、5.5公斤甲基丙烯酸、0.5公斤烯丙基聚氧乙烯醚和2公斤巯基乙醇混合为单体混合物；
（2）将22.5公斤乙醇加入反应釜中，搅拌状态下升温至70℃，同时开始滴加单体混合物和引发剂溶液，滴加时间3小时，滴加完成后保温反应2小时。
（3）保温结束后，加入5.5公斤三乙胺，搅拌0.5小时后，加入5公斤去离子水，分散均匀后减压蒸除乙醇；
（4）加入20公斤去离子水和10公斤水性酚醛，搅拌均匀，降至室温出料，得到水性油墨分散体。
实施例2
水性油墨分散体的制备：
（1）将0.5公斤过氧化二苯甲酰溶解于2公斤异丙醇中，配制成引发剂溶液；将10公斤甲基丙烯酸丙酯、5公斤丙烯酸叔丁酯、5公斤甲基丙烯酸羟丁酯、8公斤4-戊烯-1，2，3，4-四羧酸、5公斤烯丙基壬基酚聚氧乙烯醚磷酸铵和1公斤3-巯基丙酸丁酯混合为单体混合物；
（2）将18公斤异丙醇加入反应釜中，搅拌状态下升温至85℃，同时开始滴加单体混合物和引发剂溶液，滴加时间2小时，滴加完成后保温反应3小时；
（3）保温结束后，加入8公斤N-甲基二乙醇胺，搅拌1小时后，加入9公斤去离子水，分散均匀后减压蒸除异丙醇；
（4）加入21公斤去离子水和7.5公斤环氧树脂乳液，搅拌均匀，降至室温出料，得到水性油墨分散体。
实施例3
水性油墨分散体的制备：
（1）将0.3公斤叔丁基过氧化月桂酸酯溶解于3公斤乙醇中，配制成引发剂溶液；将14.9公斤甲基丙烯酸十八烷基脂、15公斤丙烯酸异辛酯、10公斤烯丙基缩水甘油醚、3公斤3-丁烯-1，2，3-三羧酸、2.75公斤异丁烯醇聚氧乙烯醚和0.05公斤α-甲基苯乙烯二聚体混合为单体混合物；
（2）将27公斤乙醇加入反应釜中，搅拌状态下升温至77.5℃，同时开始滴加单体混合物和引发剂溶液，滴加时间4小时，滴加完成后保温反应2.5小时；
（3）保温结束后，加入3公斤2-氨基-2-甲基-1-丙醇，搅拌0.75小时后，加入8公斤去离子水，分散均匀后减压蒸除乙醇；
（4）加入12公斤去离子水和1公斤萜烯酚醛乳液，搅拌均匀，降至室温出料，得到水性油墨分散体。
实施例4
水性油墨分散体的制备：
（1）将0.5公斤过氧化二月桂酰溶解于2.9公斤异丙醇中，配制成引发剂溶液；将15公斤苯乙烯、9.975公斤丙烯酸正辛酯、7.5公斤丙烯酸-2-氯乙基酯、3公斤3-丁烯-1，2，3-三羧酸、3公斤2-丙烯酰胺基-2-甲基丙磺酸钠和1.025公斤巯基乙醇混合为单体混合物。
（2）将26.1公斤异丙醇加入反应釜中，搅拌状态下升温至75℃，同时开始滴加单体混合物和引发剂溶液，滴加时间2.5小时，滴加完成后保温反应2.2小时。
（3）保温结束后，加入6公斤N-乙基二氨基乙基胺，搅拌0.6小时后，加入6.6公斤去离子水，分散均匀后减压蒸除异丙醇。
（4）加入15.4公斤去离子水和3公斤水性马来酸树脂，搅拌均匀，降至室温出料，得到水性油墨分散体。
实施例5
水性油墨分散体的制备：
（1）将0.4公斤过氧化二异丙苯溶解于2.8公斤丙酮中，配制成引发剂溶液；将5公斤叔碳酸乙烯酯、9公斤丙烯酸叔丁酯、7.6公斤萜烯树脂、6公斤富马酸、2公斤烯丙氧基壬基酚聚氧乙烯醚硫酸铵和1.5公斤3-巯基丙酸混合为单体混合物；
（2）将25.2公斤丙酮加入反应釜中，搅拌状态下升温至80℃，同时开始滴加单体混合物和引发剂溶液，滴加时间3.5小时，滴加完成后保温反应2.7小时；
（3）保温结束后，加入7公斤N-乙基二乙醇胺，搅拌0.8小时后，加入11.2公斤去离子水，分散均匀后减压蒸除丙酮；
（4）加入16.8公斤去离子水和5.5公斤氯乙烯/醋酸乙烯共聚乳液，搅拌均匀，降至室温出料，得到水性油墨分散体。
实施例6
水性油墨的制备：
将8公斤酞菁蓝、20公斤实施例1所制水性油墨分散体、5公斤去离子水加入配料器，用高速分散机搅拌30分钟，使其混合均匀；将混合均匀的物料取出，送入砂磨机进行砂磨，待细度低于 10μm后取出，加入10公斤水性油墨分散体、7公斤去离子水混合均匀，过滤；经检验合格后，包装，制得凹版水性油墨。
制得的凹版水性油墨主要技术指标如表1所示。
表1
以上检测结果依据GB/T26394-2011标准测试。
对比例1
水性油墨分散体、水性油墨的制备：
（1）将0.3公斤过氧化二异丙苯溶解于2.5公斤异丙醇中，配制成引发剂溶液；将10公斤甲基丙烯酸丙酯、10公斤丙烯酸叔丁酯、5公斤甲基丙烯酸混合为单体混合物；
（2）将22.5公斤异丙醇加入反应釜中，搅拌状态下升温至75℃，同时开始滴加单体混合物和引发剂溶液，滴加时间3小时，滴加完成后保温反应2.5小时；
（3）保温结束后，加入3公斤三乙胺，搅拌0.75小时后，加入7.5公斤去离子水，分散均匀后减压蒸除异丙醇；
（4）加入17.5公斤去离子水，搅拌均匀，降至室温出料，得到水性油墨分散体。
将8公斤酞菁蓝、20公斤上述所制水性油墨分散体、5公斤去离子水加入配料器，用高速分散机搅拌30分钟，使其混合均匀；将混合均匀的物料取出，送入砂磨机进行砂磨，待细度低于 10μm后取出，加入10公斤水性油墨分散体、7公斤去离子水混合均匀，过滤,制得凹版水性油墨。制得的凹版水性油墨主要技术指标如表2所示。
表2
以上检测结果依据GB/T26394-2011标准测试。
最后应说明的是：以上各实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述各实施例对本发明进行了详细的说明，但本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分或者全部技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。
Claims (10)
1.一种水性油墨分散体，其特征在于，按重量百分比计，由如下组分制备而成：
引发剂 0.1～0.5wt%
反应溶剂 20～30wt%
硬单体 5～15wt%
软单体 5～15wt%
功能单体 5～10wt%
羧酸类单体 5～15wt%
反应型乳化剂 0.5～5wt%
链转移剂 0.05～2wt%
中和剂 5～15wt%
去离子水40～50wt%
增粘树脂 1～10wt%；
该水性油墨分散体制备方法如下：
（1）将引发剂溶解于10%的反应溶剂中，配制成引发剂溶液；将硬单体、软单体、功能单体、羧酸类单体、反应型乳化剂和链转移剂混合为单体混合物；
（2）将余量的反应溶剂加入反应釜中，搅拌状态下升温至70～85℃，同时开始滴加单体混合物和引发剂溶液，滴加时间2～4小时，滴加完成后保温反应2～3小时；
（3）保温结束后，加入中和剂，搅拌0.5～1小时后，加入20～40wt%的去离子水，分散均匀后减压蒸除反应溶剂；
（4）加入剩余去离子水和增粘树脂，搅拌均匀，降至室温出料，得到水性油墨分散体。
2.根据权利要求1所述的水性油墨分散体，其特征在于，所述引发剂选自偶氮二异丁腈、偶氮二异庚腈、过氧化二乙酰、过氧化二苯甲酰、叔丁基过氧化氢、二叔丁基过氧化物、过氧化二叔戊基、叔丁基过氧化月桂酸酯、过氧化二月桂酰、过氧化二异丙苯、过氧化苯甲酸叔丁基酯中任一种或多种。
3.根据权利要求1所述的水性油墨分散体，其特征在于，所述反应溶剂选自乙醇、丙酮、异丙醇中任一种或多种。
4.根据权利要求1所述的水性油墨分散体，其特征在于，所述硬单体选自甲基丙烯酸甲酯、甲基丙烯酸乙酯、甲基丙烯酸丙酯、甲基丙烯酸十八烷基脂、苯乙烯、丙烯腈、醋酸乙烯酯、叔碳酸乙烯酯中任一种或多种。
5.根据权利要求1所述的水性油墨分散体，其特征在于，所述软单体选自丙烯酸丁酯、丙烯酸叔丁酯、丙烯酸月桂酯、丙烯酸正辛酯、丙烯酸异辛酯中任一种或多种。
6.根据权利求1所述的水性油墨分散体，其特征在于，所述功能单体选自丙烯酸羟乙酯、甲基丙烯酸羟乙酯、丙烯酸羟丙酯、甲基丙烯酸羟丙酯、丙烯酸羟丁酯、甲基丙烯酸羟丁酯、丙烯酰胺、甲基丙烯酸二甲氨基乙酯、烯丙基缩水甘油醚、丙烯酸缩水甘油酯、甲基丙烯酸缩水甘油酯、丙烯酸-2-氯乙基酯、甲基丙烯酸-2-氯乙基酯、松香、松香甘油酯、松香季戊四醇酯、松香酚醛树脂、萜烯树脂中任一种或多种。
7.根据权利要求1所述的水性油墨分散体，其特征在于，所述羧酸类单体选自丙烯酸、甲基丙烯酸、巴豆酸、衣康酸、马来酸、马来酸酐、马来酸单酯、富马酸、富马酸单酯、乙烯基乙酸、丙烯-1，2，3-三羧酸、3-丁烯-1，2，3-三羧酸、4-戊烯-1，2，4-三羧酸、1-戊烯-1，1，4，4-四羧酸、4-戊烯-1，2，3，4-四羧酸、3-己烯-1，1，6，6-四羧酸、亚油酸中任一种或多种。
8.根据权利要求1所述的水性油墨分散体，其特征在于，所述反应型乳化剂选自烯丙基聚氧乙烯醚、甲基烯丙基聚氧乙烯醚、烯丙氧基壬基酚聚氧乙烯醚硫酸铵、烯丙氧基癸基聚氧乙烯醚硫酸铵、烯丙基壬基酚聚氧乙烯醚磷酸铵、异丁烯醇聚氧乙烯醚、异戊烯醇聚乙烯醚、2-丙烯酰胺基-2-甲基丙磺酸钠中任一种或多种。
9.根据权利要求1所述水性油墨分散体，其特征在于，所述链转移剂选自十二烷基硫醇、叔十二烷基硫醇、巯基乙醇、巯基乙酸、3-巯基丙酸、3-巯基丙酸丁酯、α-甲基苯乙烯二聚体中任一种或多种；
所述中和剂选自三乙胺、N-甲基二乙醇胺、N-乙基二乙醇胺、N-甲基二氨基乙基胺、N-乙基二氨基乙基胺、2-氨基-2-甲基-1-丙醇中任一种或多种。
10.根据权利要求1所述的水性油墨分散体，其特征在于，所述增粘树脂选自水性酚醛、萜烯酚醛乳液、水性氯化聚丙烯、水性马来酸树脂、氯乙烯/醋酸乙烯共聚乳液、环氧树脂乳液、水性酚醛环氧树脂乳液中任一种或多种。
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