CN115207136A - Manufacturing method of P-type IBC battery - Google Patents

Manufacturing method of P-type IBC battery Download PDF

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Publication number
CN115207136A
CN115207136A CN202210854522.2A CN202210854522A CN115207136A CN 115207136 A CN115207136 A CN 115207136A CN 202210854522 A CN202210854522 A CN 202210854522A CN 115207136 A CN115207136 A CN 115207136A
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China
Prior art keywords
layer
type
doping
silicon substrate
intrinsic
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CN202210854522.2A
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Chinese (zh)
Inventor
张博
屈小勇
刘大伟
高嘉庆
张婷
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Qinghai Huanghe Hydropower Development Co Ltd
Huanghe Hydropower Development Co Ltd
Xian Solar Power Branch of Qinghai Huanghe Hydropower Development Co Ltd
Xining Solar Power branch of Qinghai Huanghe Hydropower Development Co Ltd
Original Assignee
Qinghai Huanghe Hydropower Development Co Ltd
Huanghe Hydropower Development Co Ltd
Xian Solar Power Branch of Qinghai Huanghe Hydropower Development Co Ltd
Xining Solar Power branch of Qinghai Huanghe Hydropower Development Co Ltd
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Application filed by Qinghai Huanghe Hydropower Development Co Ltd, Huanghe Hydropower Development Co Ltd, Xian Solar Power Branch of Qinghai Huanghe Hydropower Development Co Ltd, Xining Solar Power branch of Qinghai Huanghe Hydropower Development Co Ltd filed Critical Qinghai Huanghe Hydropower Development Co Ltd
Priority to CN202210854522.2A priority Critical patent/CN115207136A/en
Publication of CN115207136A publication Critical patent/CN115207136A/en
Priority to PCT/CN2023/101137 priority patent/WO2024012162A1/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • H01L31/02168Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells the coatings being antireflective or having enhancing optical properties for the solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/06Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier
    • H01L31/075Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PIN type
    • H01L31/076Multiple junction or tandem solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/06Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier
    • H01L31/075Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PIN type
    • H01L31/077Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PIN type the devices comprising monocrystalline or polycrystalline materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic System
    • H01L31/182Special manufacturing methods for polycrystalline Si, e.g. Si ribbon, poly Si ingots, thin films of polycrystalline Si
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses a manufacturing method of a P-type IBC battery, which comprises the following steps: sequentially laminating a first SiO layer on one side surface of a P-type silicon substrate 2 A layer and a first intrinsic polysilicon layer; carrying out phosphorus doping on the first intrinsic polycrystalline silicon layer to form an N-type doping layer; forming a mask layer on the N-type doping layer, and carrying out patterning slotting on the mask layer; using the mask layer as a mask to sequentially etch the N-type doped layer and the first SiO 2 A layer exposing a partial region of one side surface of the P-type silicon substrate; sequentially laminating a second SiO layer on the partial region 2 A layer and a second intrinsic polysilicon layer; carrying out boron doping on the second intrinsic polycrystalline silicon layer to form a P-type doped layer; and forming electrodes on the N-type doped layer and the P-type doped layer respectively.The invention improves the photoelectric conversion efficiency of the P-type IBC battery.

Description

Manufacturing method of P-type IBC battery
Technical Field
The invention relates to the technical field of photovoltaic power generation, in particular to a manufacturing method of a P-type IBC battery.
Background
At present, with the gradual depletion of fossil energy, solar cells are increasingly widely used as a new energy alternative. A solar cell is a device that converts solar energy into electrical energy. The solar cell generates current carriers by utilizing a photovoltaic principle, and then the current carriers are led out by using the electrodes, so that the electric energy is effectively utilized.
The IBC cell is one of the photovoltaic cells with the highest conversion efficiency at present, the cell takes monocrystalline silicon as a substrate, a p-n junction and a metal electrode are positioned on the back surface of the cell, and the front surface is not shaded by the metal electrode, so that very high short-circuit current and conversion efficiency can be obtained. The IBC battery can be divided into an N-type IBC battery and a P-type IBC battery according to the type of a substrate, and the P-type IBC is more and more favored by the industry at present due to simple process and lower cost.
However, due to the surface passivation problem, the conversion efficiency of the P-type IBC battery is restricted, and the conversion efficiency of the P-type IBC battery can be greatly improved by overlapping and passivating the contact structure.
Disclosure of Invention
In view of the defects in the prior art, the invention provides a manufacturing method of a P-type IBC battery, which comprises the following steps:
sequentially laminating a first SiO layer on one side surface of a P-type silicon substrate 2 A layer and a first intrinsic polysilicon layer;
carrying out phosphorus doping on the first intrinsic polycrystalline silicon layer to form an N-type doping layer;
forming a mask layer on the N-type doping layer, and carrying out patterning slotting on the mask layer;
sequentially etching the N-type doped layer and the first SiO by taking the mask layer as a mask 2 A layer exposing a partial region of one side surface of the P-type silicon substrate;
sequentially laminating to form a second SiO on the partial region 2 A layer and a second intrinsic polysilicon layer;
carrying out boron doping on the second intrinsic polycrystalline silicon layer to form a P-type doped layer;
and forming electrodes on the N-type doped layer and the P-type doped layer respectively.
Preferably, the phosphorus doping the first intrinsic polycrystalline silicon layer comprises:
diffusing phosphorus impurities for 20 minutes at the temperature of 850-900 ℃;
the phosphosilicate glass formed during the doping process is cleaned by an HF solution.
Preferably, the boron doping the second intrinsic polycrystalline silicon layer comprises:
depositing a borosilicate glass layer on the second intrinsic polycrystalline silicon layer;
diffusing boron particles of the borosilicate glass layer into the second intrinsic polycrystalline silicon layer by adopting a laser doping process, wherein the width of a laser spot of the laser doping process is 10-300 um, the laser power is 20-80W, the pulse width is 0.5-2 us, and the laser frequency is more than or equal to 20KHz;
the borosilicate glass layer and the borosilicate glass formed during the doping process are cleaned by an HF solution.
Preferably, before forming electrodes on the N-type doped layer and the P-type doped layer, respectively, the method further comprises:
putting the P-type silicon substrate into 5-20% KOH solution to corrode for 10-300 s, and then cleaning with pure water;
putting the cleaned P-type silicon substrate into a KOH solution with the volume concentration of 1-3% for texturing for 7-10 min;
annealing and oxidizing the textured P-type silicon substrate;
and forming a back silicon nitride layer and a front silicon nitride layer.
Preferably, the temperature of the annealing oxidation is 850-950 ℃, the duration is 10-30 min, and the oxygen introduction amount is more than or equal to 8000sccm.
Preferably, the mask layer is a silicon nitride film with a thickness of 50nm to 70nm.
Preferably, a first SiO is formed on one side surface of the P-type silicon substrate by stacking in sequence 2 The layer and the first intrinsic polycrystalline silicon layer comprise:
putting the P-type silicon substrate into H with the volume concentration of 0.2-1% 2 O 2 Cleaning oil stains on the surface in the solution;
then, the P-type silicon substrate is put into NaOH solution with the mass concentration of 5% -20% for neutralization, and metal ions and an oxide layer are cleaned;
and then washing and drying.
In the P-type IBC battery structure manufactured by the manufacturing method, the tunneling oxide layers are arranged between the P-type silicon substrate and the N-type doping layer as well as between the P-type silicon substrate and the P-type doping layer, so that the photoelectric conversion efficiency of the P-type IBC battery is improved.
Drawings
Fig. 1 is a flowchart of a method for manufacturing a P-type IBC battery according to an embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, embodiments of the present invention are described in detail below with reference to the accompanying drawings. Examples of these preferred embodiments are illustrated in the accompanying drawings. The embodiments of the invention shown in the drawings and described in accordance with the drawings are merely exemplary and the invention is not limited to these embodiments.
It should be noted that, in order to avoid obscuring the present invention with unnecessary details, only the structures and/or processing steps closely related to the scheme according to the present invention are shown in the drawings, and other details not so relevant to the present invention are omitted.
The embodiment provides a method for manufacturing a P-type IBC battery, which comprises the following steps:
s1, sequentially laminating a first SiO on one side surface of a P-type silicon substrate 2 A layer and a first intrinsic polysilicon layer.
And S2, carrying out phosphorus doping on the first intrinsic polycrystalline silicon layer to form an N-type doped layer.
And S3, forming a mask layer on the N-type doping layer, and carrying out patterning slotting on the mask layer. Wherein the mask layer is a silicon nitride film with a thickness of 50 nm-70 nm.
S4, with the mask layer as a mask, sequentially etching the N-type doped layer and the first SiO 2 And the layer is used for exposing partial area of one side surface of the P-type silicon substrate.
S5, sequentially laminating and forming second SiO on the partial area 2 A layer and a second intrinsic polysilicon layer.
And S6, carrying out boron doping on the second intrinsic polycrystalline silicon layer to form a P-type doped layer.
And S7, forming electrodes on the N-type doped layer and the P-type doped layer respectively.
Specifically, phosphorus doping the first intrinsic polycrystalline silicon layer includes: diffusing the phosphorus impurities for 20min at the temperature of 850-900 ℃. The phosphosilicate glass formed during the doping process is then cleaned by an HF solution.
Specifically, boron doping the second intrinsic polysilicon layer includes:
and depositing and forming a borosilicate glass layer on the second intrinsic polycrystalline silicon layer. And then diffusing the boron particles of the borosilicate glass layer into the second intrinsic polycrystalline silicon layer by adopting a laser doping process. The laser doping process is characterized in that the width of a laser spot is 10-300 um, the laser power is 20-80W, the pulse width is 0.5-2 us, and the laser frequency is more than or equal to 20KHz. The borosilicate glass layer and the borosilicate glass formed during the doping process are then cleaned by means of an HF solution.
Preferably, before forming electrodes on the N-type doped layer and the P-type doped layer, respectively, the method further comprises:
and putting the P-type silicon substrate into a KOH solution with the mass concentration of 5-20% for corrosion for 10-300 s, and then cleaning by using pure water. And then putting the cleaned P-type silicon substrate into a KOH solution with the volume concentration of 1-3% for texture surface making for 7-10 min. And then annealing and oxidizing the textured P-type silicon substrate. And then forming a back silicon nitride layer and a front silicon nitride layer. Wherein the temperature of the annealing oxidation is 850-950 ℃, the duration is 10-30 min, and the oxygen introduction amount is more than or equal to 8000sccm.
Preferably, a first SiO is formed on one side surface of the P-type silicon substrate by stacking in sequence 2 The layer and the first intrinsic polycrystalline silicon layer comprise:
putting the P-type silicon substrate into H with the volume concentration of 0.2-1% 2 O 2 And cleaning oil stains on the surface in the solution. And then, the P-type silicon substrate is placed into a NaOH solution with the mass concentration of 5% -20% for neutralization, and metal ions and an oxide layer are cleaned. And then washing and drying.
In the P-type IBC cell structure manufactured by the manufacturing method of the embodiment, tunneling oxide layers are arranged between the P-type silicon substrate and the N-type doping layer and between the P-type silicon substrate and the P-type doping layer, so that the photoelectric conversion efficiency of the P-type IBC cell is improved.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (7)

1. A manufacturing method of a P-type IBC battery is characterized by comprising the following steps:
sequentially laminating a first SiO layer on one side surface of a P-type silicon substrate 2 A layer and a first intrinsic polysilicon layer;
carrying out phosphorus doping on the first intrinsic polycrystalline silicon layer to form an N-type doping layer;
forming a mask layer on the N-type doping layer, and carrying out patterning slotting on the mask layer;
sequentially etching the N-type doped layer and the first SiO by taking the mask layer as a mask 2 A layer exposing a partial region of one side surface of the P-type silicon substrate;
sequentially laminating to form a second SiO on the partial region 2 A layer and a second intrinsic polysilicon layer;
carrying out boron doping on the second intrinsic polycrystalline silicon layer to form a P-type doped layer;
and forming electrodes on the N-type doped layer and the P-type doped layer respectively.
2. The method of claim 1, wherein phosphorus doping the first intrinsic polysilicon layer comprises:
diffusing phosphorus impurities for 20 minutes at the temperature of 850-900 ℃;
the phosphosilicate glass formed during the doping process is cleaned by an HF solution.
3. The method of claim 1, wherein the boron doping the second intrinsic polysilicon layer comprises:
depositing and forming a borosilicate glass layer on the second intrinsic polycrystalline silicon layer;
diffusing boron particles of the borosilicate glass layer into the second intrinsic polycrystalline silicon layer by adopting a laser doping process;
the borosilicate glass layer and the borosilicate glass formed during the doping process are cleaned by an HF solution.
4. The method of claim 3, wherein before forming electrodes on the N-doped layer and the P-doped layer respectively, the method comprises:
putting the P-type silicon substrate into 5-20% KOH solution to corrode for 10-300 s, and then cleaning with pure water;
putting the cleaned P-type silicon substrate into a KOH solution with the volume concentration of 1-3% for texturing for 7-10 min;
annealing and oxidizing the textured P-type silicon substrate;
and forming a back silicon nitride layer and a front silicon nitride layer.
5. The manufacturing method of the P-type IBC battery according to claim 4, wherein the annealing oxidation temperature is 850-950 ℃, the time duration is 10-30 min, and the oxygen introduction amount is more than or equal to 8000sccm.
6. The method for manufacturing the P-type IBC battery of claim 1, wherein the mask layer is a silicon nitride film with a thickness of 50nm to 70nm.
7. The method of claim 1, wherein the first SiO is formed on the surface of the P-type silicon substrate by stacking in sequence 2 The layer and the first intrinsic polycrystalline silicon layer comprise:
putting the P-type silicon substrate into H with the volume concentration of 0.2-1% 2 O 2 Cleaning oil stains on the surface in the solution;
then, the P-type silicon substrate is put into NaOH solution with the mass concentration of 5% -20% for neutralization, and metal ions and an oxide layer are cleaned;
and then washing and drying.
CN202210854522.2A 2022-07-15 2022-07-15 Manufacturing method of P-type IBC battery Pending CN115207136A (en)

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PCT/CN2023/101137 WO2024012162A1 (en) 2022-07-15 2023-06-19 Manufacturing method for p-type ibc battery

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024012162A1 (en) * 2022-07-15 2024-01-18 青海黄河上游水电开发有限责任公司西宁太阳能电力分公司 Manufacturing method for p-type ibc battery

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN210926046U (en) * 2019-10-29 2020-07-03 苏州阿特斯阳光电力科技有限公司 Solar cell
CN113921625A (en) * 2021-09-30 2022-01-11 泰州隆基乐叶光伏科技有限公司 Back contact battery and manufacturing method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114695593A (en) * 2020-12-30 2022-07-01 苏州阿特斯阳光电力科技有限公司 Preparation method of back contact battery and back contact battery
CN113921626A (en) * 2021-09-30 2022-01-11 泰州隆基乐叶光伏科技有限公司 Manufacturing method of back contact battery
CN115207136A (en) * 2022-07-15 2022-10-18 青海黄河上游水电开发有限责任公司西宁太阳能电力分公司 Manufacturing method of P-type IBC battery

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN210926046U (en) * 2019-10-29 2020-07-03 苏州阿特斯阳光电力科技有限公司 Solar cell
CN113921625A (en) * 2021-09-30 2022-01-11 泰州隆基乐叶光伏科技有限公司 Back contact battery and manufacturing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024012162A1 (en) * 2022-07-15 2024-01-18 青海黄河上游水电开发有限责任公司西宁太阳能电力分公司 Manufacturing method for p-type ibc battery

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