CN115124380B - Organic-inorganic compound fertilizer with mesoporous core-shell type and preparation method thereof - Google Patents
Organic-inorganic compound fertilizer with mesoporous core-shell type and preparation method thereof Download PDFInfo
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- CN115124380B CN115124380B CN202210653727.4A CN202210653727A CN115124380B CN 115124380 B CN115124380 B CN 115124380B CN 202210653727 A CN202210653727 A CN 202210653727A CN 115124380 B CN115124380 B CN 115124380B
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 164
- 229910010272 inorganic material Inorganic materials 0.000 title claims abstract description 20
- 239000011258 core-shell material Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 230000000813 microbial effect Effects 0.000 claims abstract description 69
- CUIXPEFFBZVMAI-UHFFFAOYSA-L calcium;magnesium;potassium;sulfate Chemical group [Mg+2].[K+].[Ca+2].[O-]S([O-])(=O)=O CUIXPEFFBZVMAI-UHFFFAOYSA-L 0.000 claims abstract description 59
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 57
- 239000010902 straw Substances 0.000 claims abstract description 45
- 210000003608 fece Anatomy 0.000 claims description 46
- 240000008042 Zea mays Species 0.000 claims description 42
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 42
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 42
- 235000005822 corn Nutrition 0.000 claims description 42
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
- 239000010871 livestock manure Substances 0.000 claims description 33
- 238000003756 stirring Methods 0.000 claims description 33
- 238000002156 mixing Methods 0.000 claims description 32
- 241000196324 Embryophyta Species 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 239000000835 fiber Substances 0.000 claims description 22
- 238000007873 sieving Methods 0.000 claims description 22
- 238000001035 drying Methods 0.000 claims description 21
- 239000002002 slurry Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 241000894006 Bacteria Species 0.000 claims description 15
- 241001465754 Metazoa Species 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 13
- 229920001661 Chitosan Polymers 0.000 claims description 12
- 229920000875 Dissolving pulp Polymers 0.000 claims description 11
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 11
- 238000007605 air drying Methods 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 11
- 230000001804 emulsifying effect Effects 0.000 claims description 11
- 238000000227 grinding Methods 0.000 claims description 11
- 239000011259 mixed solution Substances 0.000 claims description 11
- 239000001632 sodium acetate Substances 0.000 claims description 11
- 235000017281 sodium acetate Nutrition 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 3
- 241000194108 Bacillus licheniformis Species 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 abstract description 58
- 239000001913 cellulose Substances 0.000 abstract description 58
- 239000000017 hydrogel Substances 0.000 abstract description 57
- 239000010410 layer Substances 0.000 abstract description 47
- 239000010815 organic waste Substances 0.000 abstract description 25
- 239000012792 core layer Substances 0.000 abstract description 22
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000000050 nutritive effect Effects 0.000 abstract description 2
- 239000003895 organic fertilizer Substances 0.000 description 105
- 239000002994 raw material Substances 0.000 description 33
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 230000012010 growth Effects 0.000 description 18
- 239000002689 soil Substances 0.000 description 17
- 229910052700 potassium Inorganic materials 0.000 description 16
- 239000011591 potassium Substances 0.000 description 15
- 241001494479 Pecora Species 0.000 description 14
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- 240000008067 Cucumis sativus Species 0.000 description 11
- 229910001607 magnesium mineral Inorganic materials 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- 238000010298 pulverizing process Methods 0.000 description 10
- 235000009849 Cucumis sativus Nutrition 0.000 description 9
- 241000220223 Fragaria Species 0.000 description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 9
- 244000005700 microbiome Species 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 239000011574 phosphorus Substances 0.000 description 9
- 229910052698 phosphorus Inorganic materials 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000008635 plant growth Effects 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 240000002234 Allium sativum Species 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 201000010099 disease Diseases 0.000 description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 5
- 235000004611 garlic Nutrition 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 235000021012 strawberries Nutrition 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 208000035240 Disease Resistance Diseases 0.000 description 4
- 235000016623 Fragaria vesca Nutrition 0.000 description 4
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000035558 fertility Effects 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 235000016709 nutrition Nutrition 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 230000004083 survival effect Effects 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 244000046052 Phaseolus vulgaris Species 0.000 description 3
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 230000035764 nutrition Effects 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000009629 microbiological culture Methods 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000589151 Azotobacter Species 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- 102000009025 Endorphins Human genes 0.000 description 1
- 108010049140 Endorphins Proteins 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000002154 agricultural waste Substances 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- OKYDTGSQPZBYTF-UHFFFAOYSA-J calcium;magnesium;disulfate Chemical compound [Mg+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OKYDTGSQPZBYTF-UHFFFAOYSA-J 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 235000015816 nutrient absorption Nutrition 0.000 description 1
- 235000013348 organic food Nutrition 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000010152 pollination Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000002786 root growth Effects 0.000 description 1
- 230000010496 root system development Effects 0.000 description 1
- 230000009758 senescence Effects 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
- C05D1/02—Manufacture from potassium chloride or sulfate or double or mixed salts thereof
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/40—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
- C05G5/35—Capsules, e.g. core-shell
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to an organic-inorganic compound fertilizer with a mesoporous core-shell type and a preparation method thereof, wherein the organic-inorganic compound fertilizer comprises a core layer and a shell layer, and the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts inorganic fertilizer; the inorganic fertilizer is potassium calcium magnesium sulfate; the honeycomb tube type organic waste is made of excrement and straw. The compound fertilizer has the advantages that the application of the compound fertilizer improves the taste of agricultural products and the nutritive value, and is more favored by customers.
Description
Technical Field
The invention relates to the technical field of chemical fertilizers, in particular to an organic-inorganic compound fertilizer with mesoporous core-shells and a preparation method thereof.
Background
The biological organic fertilizer is prepared by taking organic wastes such as livestock manure, crop straws, household garbage and the like as matrixes and carrying out harmless and decomposing treatment, and the biological organic fertilizer has the effects of both organic fertilizer and microorganisms, contains inorganic components such as nitrogen, phosphorus, potassium, trace elements and the like, and is favorable for improving soil fertility, promoting crop absorption, releasing elements and the like. The reasonable application of the bio-organic fertilizer can not only reduce the discharge of pollutants such as livestock and poultry manure, but also reduce the consumption of chemical fertilizers and pesticides by randomly burning and stacking agricultural wastes such as crop straws, and can also improve the quality of agricultural products, promote the production of organic foods and increase the income of farmers. Therefore, the development of the bio-organic fertilizer industry accords with the national agricultural development direction, and has important significance for environmental protection and agricultural sustainable development.
However, microbial fertilizers also suffer from disadvantages: 1) At present, most of the existing microbial fertilizers are single in bacterial species, such as azotobacter fertilizer, potassium bacterial fertilizer and seaweed fertilizer, the microbial fertilizers are single in effect, the problems of bacterial species inappropriateness and degeneration exist, and meanwhile, the effect is difficult to achieve the expected effect due to the lack of disease-resistant microbial flora; 2) The microbial fertilizer produced by individual fertilizer factories has the phenomena of lag production process, production by using unidentified strains, low content of effective bacteria, excessive foreign bacteria and the like, and severely restricts the healthy development of the microbial fertilizer industry. 3) Most importantly, most of the biological organic fertilizers at present are slow in fertilizer efficiency, most of the organic fertilizers are poor in stability, the external environment such as sunlight and ultraviolet rays can inactivate organic microorganisms, and the organic fertilizers can lose effectiveness in about half a year in general, so that the losses to manufacturers and users are large. Currently 2600 families of organic fertilizer production enterprises with large and small sizes exist nationwide, the market credit of the organic fertilizer is lower and the general fertility is not high and the stability is poor due to the fact that the production raw materials are disordered, the production technology is poor, the detection means is poor, and the like. Therefore, the development of the organic fertilizer with high fertilizer efficiency and high stability is a requirement of industries and users.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provides an organic-inorganic compound fertilizer with mesoporous core-shell type and a preparation method thereof. The multi-layer mesoporous core-shell type bio-organic fertilizer can stabilize microorganisms, effectively fuse inorganic and organic fertilizers, and realize high efficiency, high stability and high disease resistance, thereby obtaining the multi-layer mesoporous core-shell type bio-organic fertilizer with long-acting multi-trace element addition.
The invention is realized by the following technical scheme: in one aspect, an organic-inorganic compound fertilizer with a mesoporous core-shell type is provided, the organic-inorganic compound fertilizer comprises a core layer and a shell layer, and the core layer contains a microbial agent, cellulose hydrogel and honeycomb-tube type organic waste; the shell layer adopts inorganic fertilizer;
through the technical scheme, the invention adopts the honeycomb tube type structure in the mesoporous core-shell type, when the fertilizer is used, the inorganic fertilizer of the outermost layer is firstly absorbed by plants and used as nutrition of the plants to support the growth of the plants, and after the fertilizer of the outer layer is utilized, the organic fertilizer is gradually decomposed; the microbial flora wrapped by cellulose is released into soil after swelling in water to form microbial colonies; after the microorganisms are swelled, the microorganisms fall off from the bio-organic fertilizer to form ordered pore channels, and moisture enters the bio-organic fertilizer through the pore channels to be swelled continuously, so that the microorganisms are released continuously, and the long-acting, lasting and slow-release targets are realized; meanwhile, the organic fertilizer and the chemical fertilizer are applied in a matched manner, so that the effect of improving soil by the organic fertilizer can be achieved, the utilization rate of nitrogen, phosphorus and potassium can be improved, the high efficiency of the chemical fertilizer can be achieved, and further the chemical fertilizer, the organic fertilizer and the microbial flora are fully and effectively combined, and three-in-one effect is achieved.
Further, the inorganic fertilizer is a potassium sulfate calcium magnesium mineral fertilizer.
By the technical scheme, the inorganic fertilizer potassium magnesium calcium sulfate raw ore contains 10 elements of potassium, calcium, magnesium, sulfur, boron, iron, nickel, manganese, zinc, copper and the like, which are supplemented simultaneously, so that nutrition is balanced, the resistance is improved, and the disease resistance and the high efficiency are improved; the fertilizer is characterized in that:
1) Nutrient absorption capacity, and high yield potential;
2) The long-acting controlled-release nitrogen fertilizer has longer fertilizer efficiency, reduces ammonium toxicity and is safe to apply;
3) The fertilizer contains sulfur, zinc and boron, reduces the occurrence of lobular disease, improves the resistance, reduces the occurrence degree of disease, improves the pollination fruit setting capability, reduces the size and grain, and produces high-quality high-grade fruits and vegetables;
4) The potassium sulfate calcium magnesium is especially suitable for soil with low potassium, magnesium and sulfur content and crops with more potassium, magnesium and sulfur, and has better effect as base fertilizer and early topdressing.
Potassium calcium magnesium sulfate [ K ] 2 CazMg(SO 4 ) 4 ·2(H 2 O)]The chemical name polyhalite is a mineral fertilizer (48% SO) containing four nutrients of sulfur, potassium, magnesium and calcium 3 14% K,6% MgO and 17% CaO), mainly distributed on the North sea floor of the United kingdom. The potassium sulfate calcium magnesium is used as a single crystal mineral fertilizer, has stable property, is not easy to absorb moisture and deliquesce, and has comprehensive nutrients; the potassium calcium magnesium sulfate is suitable for chlorine sensitive crops, especially for crops with more calcium, magnesium and sulfur, and for improving acidified soil and salinized soil, and is generally applied as a base fertilizer and an early topdressing or applied as a soil conditioner.
Further, the honeycomb tube type organic waste is made of feces and straw.
Further, the honeycomb tube type organic waste is made of cow dung and corn straw.
Through the technical scheme, the invention adopts a unique honeycomb shell type framework, a degradable cellulose hydrogel protection technology and a specific process improvement to realize high-efficiency stability, and solves the problems of slow effect and easy failure of the microbial fertilizer; in addition, the organic-inorganic multi-element fertilizer with honeycomb tube type is prepared from waste resources such as sheep manure, corn straw and the like, is rich in a large amount of nitrogen, phosphorus and potassium, and is beneficial to the growth of plants and the improvement of crop yield.
Further, the microbial agent is selected from bacillus licheniformis XS2-450 strain with the preservation number of CGMCC NO.9430, and the viable count is more than or equal to 10 12 CFU/g. Specifically, the strain has a accession number ofCGMCC No.9430, deposited on the national institutes of microbiological culture collection of China general microbiological culture Collection center (selected from the group consisting of a biological emulsifier with the authorized publication number CN106701835B and its application, invention patent) at national institute of microbiological culture collection, national academy of sciences of China, no. 3, north Chen, west Lu, 1, of the Korean area, at 7.09, 2014.
Through the technical scheme, the microbial flora is wrapped by the degradable cellulose hydrogel, and the microbial flora can be separated from the organic fertilizer and the inorganic fertilizer and can be protected from being damaged by sunlight ultraviolet rays through the wrapped cellulose hydrogel, so that the stability of the bacterial fertilizer is improved. The microbial agent has the following action and effects:
1) The strain can perform field planting around rhizosphere and interact with root system, release endorphin, polysaccharide and other matters, promote root system development, help root system resist various adverse environments, resist various germ infection, improve root system activity and strongly root. Releasing phosphorus and potassium in the soil and helping plants fix nitrogen. 2) Can form a protective film around seeds and root systems, prevent harmful pathogen infection, and help the seeds to sprout and the root systems to grow healthily. 3) Effectively preventing various soil-borne diseases and plant root diseases from dying the wrinkled of the plant, and realizing high disease resistance.
On the other hand, the method for preparing the organic-inorganic compound fertilizer with the mesoporous core-shell comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH; adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with corn straw/cow dung fertilizer to form a biological microbial agent which takes corn straw organic fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form B1 for later use.
Preparing potassium calcium magnesium sulfate slurry, then placing the B1 obtained in the step II into the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the B1 to form a fertilizer C1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
Further, in the first step, the microbial agent wrapped by the cellulose hydrogel is fully dispersed on the surface of the organic fertilizer framework and in the honeycomb-shaped gaps.
Further, the biological agent is released into soil after being swelled by water, microorganisms are fallen from the biological organic fertilizer after being swelled to form ordered pore channels, and water enters the biological organic fertilizer through the pore channels to be swelled continuously, so that the microorganisms are released continuously.
The invention has the beneficial effects that: the advantages of the organic fertilizer and the fertilizer are combined, so that the effect of improving soil by the organic fertilizer can be achieved, the utilization rate of nitrogen, phosphorus and potassium can be improved, the high efficiency of the fertilizer can be achieved, and further, the fertilizer, the organic fertilizer and the microbial flora are combined effectively, and three effects are combined;
in addition, the organic-inorganic multi-element fertilizer with honeycomb tube type is prepared from waste resources such as sheep manure, corn straw and the like, and is beneficial to the growth of plants and the improvement of crop yield; all the components are environment-friendly raw materials, and are easy to degrade and absorb; the selected chitosan cellulose hydrogel can protect the stability of microorganisms, is easy to degrade, is beneficial to increasing nitrogen, phosphorus and potassium elements of soil and increasing the nutrition of the soil. According to the different nutritional requirements of plant growth periods, the multi-element fertilizer is designed, the synergistic effect of three components is well exerted, the plant growth is facilitated, and various wastes are adopted as main raw materials, so that the multi-element fertilizer has good social and economic benefits in the aspect of environmental protection.
Drawings
FIG. 1 is a schematic diagram of the structure of the present invention;
FIG. 2 shows the growth of crops after the organic-inorganic compound fertilizer solution of the present invention is applied to garlic (left drawing is a comparative illustration, right drawing is an illustration of the present invention);
FIG. 3 is a comparative plot of the growth of the present invention applied to corn (left plot is control plot, right plot is inventive plot);
FIG. 4 is a comparative graph of root growth of the present invention applied to cucumber (left graph is a comparative graph, right graph is a graph of the present invention);
FIG. 5 is a comparative plot of initial growth of the invention applied to strawberries (left plot is a control plot, right plot is a plot of the invention);
FIG. 6 is a comparative plot of end-stage growth of the invention applied to strawberries (left plot is a control plot, right plot is a plot of the invention);
FIG. 7 is a comparative view of the growth of the present invention applied to cucumber (left view is a comparative illustration, right view is an illustration of the present invention);
FIG. 8 is a graph showing the growth comparison of different crops (hole fertilizer (8 a), ditch fertilizer (8 b) and water fertilizer (8 c));
wherein: 1-honeycomb tube type organic waste (feces + straw); 2-cellulose hydrogel; 3-microbial agents; 4-potassium calcium magnesium sulfate layer (composition and thickness are adjustable).
Detailed Description
The following description of the embodiments of the present invention will be made clearly and fully with reference to the accompanying drawings, in which it is evident that the embodiments described are only some, but not all embodiments of the invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
An organic-inorganic compound fertilizer with a mesoporous core-shell type comprises a core layer and a shell layer, wherein the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts potassium sulfate calcium magnesium mineral fertilizer; the honeycomb tube type organic waste is prepared from sheep manure and corn straw, and specifically comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH. Adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with corn straw/sheep manure fertilizer to form a biological microbial agent which takes corn straw organic fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form B1 for later use.
And thirdly, preparing potassium calcium magnesium sulfate slurry, then placing the B1 obtained in the step two into the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the B1 to form a fertilizer C1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
After the bio-organic fertilizer obtained in the above example 1 and the common nitrogen-phosphorus-potassium compound fertilizer are prepared into a solution to act on the crop garlic, as shown in fig. 2, the root system and growth vigor of the garlic are observed. Compared with the common nitrogen-phosphorus-potassium compound fertilizer, the biological organic fertilizer obtained in the embodiment 1 has more developed, stronger and luxuriant root system (right in fig. 2), the root system is 1.5 times of that of the common nitrogen-phosphorus-potassium compound fertilizer (left in fig. 2), and the absorption capacity of plants is stronger, so that the biological organic fertilizer obtained in the embodiment 1 can effectively improve the root system of the plants and is beneficial to plant growth.
The growth characteristics of the plants were observed, as shown in fig. 2, and compared with the common nitrogen-phosphorus-potassium compound fertilizer (left of fig. 2), the garlic sprouts of the garlic cultivated by the bio-organic fertilizer obtained in example 1 have longer and more luxuriant growth period (right of fig. 2), and the growth period is one week longer than that of the common nitrogen-phosphorus-potassium compound fertilizer, which indicates that the bio-organic fertilizer obtained in example 1 has longer fertilizer efficiency.
After the bio-organic fertilizer obtained in the above example 1 and the common nitrogen-phosphorus-potassium compound fertilizer are applied to the corn of the crop, as shown in fig. 3, after the bio-organic fertilizer is applied, the soil of the bio-organic fertilizer obtained in the example 1 is loose, the root system of the crop is developed and happy (right in fig. 3), and the root system of the common nitrogen-phosphorus-potassium compound fertilizer is very thin and small (left in fig. 3), the bio-organic fertilizer obtained in the example 1 really improves the soil, increases the fertility and increases the growth of the crop.
After the bio-organic fertilizer obtained in example 1 and the common nitrogen-phosphorus-potassium compound fertilizer are applied to crop cucumbers, as shown in fig. 4, the bio-organic fertilizer obtained in example 1 is loose in soil, the root system of the crop is developed and grows out of the ground (right in fig. 4), the soil using the common nitrogen-phosphorus-potassium compound fertilizer is hardened, the root system is poor (left in fig. 4), and the bio-organic fertilizer obtained in example 1 really improves the soil, increases the fertility and increases the root system growth of the crop.
Example 2
An organic-inorganic compound fertilizer with a mesoporous core-shell type comprises a core layer and a shell layer, wherein the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts potassium sulfate calcium magnesium mineral fertilizer; the honeycomb tube type organic waste is prepared from cow dung and corn straw, and specifically comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH. Adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with corn straw/sheep manure fertilizer to form a biological microbial agent which takes corn straw organic fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form B1 for later use.
And thirdly, preparing potassium calcium magnesium sulfate slurry, then placing the B1 obtained in the step two into the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the B1 to form a fertilizer C1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
After the bio-organic fertilizer obtained in the example 1 and the common nitrogen-phosphorus-potassium compound fertilizer act on the strawberries of crops, as shown in fig. 5, after the bio-organic fertilizer is applied, the crop seedlings are quickly grown, the survival rate is higher, the agricultural loss is reduced (right in fig. 5), the seedlings are grown in 1 day, and the survival rate is 98%; the common NPK compound fertilizer is used for slow seedling growth (left part of figure 5), the seedling growth is carried out for 3-5 days, and the survival rate is only 87%. This example illustrates that the bio-organic fertilizer obtained in example 1 does not burn the seedlings and contributes to the survival of the plants, with a very fast rate of slow speed Miao Sulv.
The long-acting biological slow release fertilizer obtained in the previous step is acted on the initial field experiment, and the biological organic fertilizer obtained in the example 1 and the common nitrogen-phosphorus-potassium compound fertilizer are acted on the strawberries of crops, as shown in figure 6. After application, the period of the strawberry with the bio-organic fertilizer is longer, and under the same conditions, the strawberry with the bio-organic fertilizer is also produced in a large amount (as shown in the right part of fig. 6), while the strawberry with the common nitrogen-phosphorus-potassium compound fertilizer is close to not producing fruits (as shown in the left part of fig. 6). The result period of applying the bio-organic fertilizer obtained in the example 1 is 47 days, and the yield is improved by 20%; the result period of strawberry applying the common NPK compound fertilizer is 32 days, and the yield is lower. The bio-organic fertilizer obtained in example 1 is described as being beneficial to combat senescence and promote plant yield, which is critical for season-changing fruits.
Example 3
An organic-inorganic compound fertilizer with a mesoporous core-shell type comprises a core layer and a shell layer, wherein the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts potassium sulfate calcium magnesium mineral fertilizer; the honeycomb tube type organic waste is prepared from cow dung and corn straw, and specifically comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH. Adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with corn straw/sheep manure fertilizer to form a biological microbial agent which takes corn straw organic fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form B1 for later use.
And thirdly, preparing potassium calcium magnesium sulfate slurry, then placing the B1 obtained in the step two into the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the B1 to form a fertilizer C1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
After the bio-organic fertilizer obtained in the example 1 and the common nitrogen-phosphorus-potassium compound fertilizer are acted on the strawberries of crops, as shown in fig. 7, after the bio-organic fertilizer is applied, the crops grow faster, and plants are bigger, higher and stronger (right in fig. 7) by using the bio-organic fertilizer obtained in the example 1; the use of the common nitrogen-phosphorus-potassium compound fertilizer is slow in growth (left in fig. 7) which is only 0.75 times the height of the crops with the biological organic fertilizer in example 1, which shows that the biological organic fertilizer obtained in example 1 is better in growth vigor and faster in growth.
Example 4
An organic-inorganic compound fertilizer with a mesoporous core-shell type comprises a core layer and a shell layer, wherein the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts potassium sulfate calcium magnesium mineral fertilizer; the honeycomb tube type organic waste is prepared from cow dung and corn straw, and specifically comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH. Adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with corn straw/sheep manure fertilizer to form a biological microbial agent which takes corn straw organic fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form B1 for later use.
And thirdly, preparing potassium calcium magnesium sulfate slurry, then placing the B1 obtained in the step two into the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the B1 to form a fertilizer C1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
The long-acting biological slow release fertilizer is acted on a pot plant through a fertilizing mode of a hole fertilizer (8 a), a ditch fertilizer (8 b) and a water fertilizer (8 c), and after the long-acting biological slow release fertilizer is applied, as shown in fig. 8, the biological slow release fertilizer has high safety, does not burn seedlings, can plant the seedlings on the fertilizer directly, and saves the fertilizer and the cost. Meanwhile, by means of the water and fertilizer integrated fertilization mode, the plant growth effect is better, and the efficient utilization of the biological organic fertilizer is facilitated.
Example 5
An organic-inorganic compound fertilizer with a mesoporous core-shell type comprises a core layer and a shell layer, wherein the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts potassium sulfate calcium magnesium mineral fertilizer; the honeycomb tube type organic waste is prepared from cow dung and corn straw, and specifically comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH. Adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with corn straw/sheep manure fertilizer to form a biological microbial agent which takes corn straw organic fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form B1 for later use.
And thirdly, preparing potassium calcium magnesium sulfate slurry, then placing the B1 obtained in the step two into the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the B1 to form a fertilizer C1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
The effect of certain brands of bio-organic fertilizer, common nitrogen-phosphorus-potassium compound fertilizer, sheep manure, no fertilizer application and bio-organic fertilizer developed in our example 1 on plant yield and quality. After the bio-organic fertilizer obtained in the example 1 and the common nitrogen-phosphorus-potassium compound fertilizer and the bio-organic fertilizer of a certain product are acted on crop cucumbers, 50 cucumbers are respectively selected for comparison experiments. As can be seen from the experimental results shown in Table 1, the total application amount of the bio-organic fertilizer obtained in example 1 is 800 kg/mu, and compared with the conventional fertilizer for planting organic crops, the total application amount of the nitrogen-phosphorus-potassium compound fertilizer and sheep manure is 800 kg/mu+20m 3 The additional fertilizer dosage of the commercial organic fertilizer per mu is 1000 kg/mu. The amount of the common nitrogen, phosphorus and potassium fertilizer and the commercial organic fertilizer of a certain brand are higher than those of the biological organic fertilizer prepared in the embodiment 1.
As can be seen from the above experimental results Table 1, the bio-organic fertilizer obtained in example 1 has a price of 1600 yuan/mu, and compared with the conventional fertilizer for planting organic crops, the total price of nitrogen-phosphorus-potassium compound fertilizer and sheep manure is 3300 yuan/mu, and the additional fertilizer dosage of the commercial organic fertilizer is 2000 yuan/mu. Both the common nitrogen, phosphorus and potassium fertilizers and the commercial organic fertilizers of a certain brand are more expensive than the biological organic fertilizers prepared in the embodiment 1. Compared with the common nitrogen-phosphorus-potassium compound fertilizer, the application of the bio-organic fertilizer can save approximately 1300 yuan per mu of land under the same yield, the application amount of the bio-organic fertilizer researched and developed by people who apply per mu of land is less, the investment is further saved, and the high efficiency of the fertilizer is reflected.
As can be seen from the above experimental results Table 1, the yield of 50 cucumbers in the experiment of the bio-organic fertilizer obtained in example 1 was 47.5kg, which was 46.1% increased compared to the yield of cucumbers without any chemical fertilizer (total yield of 32.5 kg); compared with the traditional fertilizer for planting organic crops, the yield of 50 cucumbers in a nitrogen-phosphorus-potassium compound fertilizer and sheep manure experiment is 43.5kg, and the yield is increased by 33.8% compared with the yield of the cucumbers without applying any chemical fertilizer; the yield of 50 cucumbers tested by the commercial organic fertilizer is 46.5kg, and compared with the yield of the cucumbers without any chemical fertilizer, the yield is increased by 43.1%; both the common nitrogen, phosphorus and potassium fertilizers and the commercial organic fertilizers of a certain brand have lower yield increase than the biological organic fertilizer prepared in the embodiment 1. Meanwhile, the plant quality of the applied bio-organic fertilizer is better, and the content of vitamin C, protein and soluble sugar are improved, so that the yield and quality of the bio-organic fertilizer are truly improved; TABLE 1-1
In conclusion, the organic-inorganic mixed fertilizer is applied to agricultural products, so that the mouthfeel and the nutritive value of the agricultural products are improved, and the organic-inorganic mixed fertilizer is more favored by customers; and can improve soil, increase crop yield and quality, and increase crop disease resistance.
Example 6:
an organic-inorganic compound fertilizer with a mesoporous core-shell type comprises a core layer and a shell layer, wherein the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts potassium sulfate calcium magnesium mineral fertilizer; the honeycomb tube type organic waste is prepared from cow dung and corn straw, and specifically comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH. Adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with bean cake/cow dung fertilizer to form a biological microbial agent which takes bean cake/cow dung fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form D1 for later use.
And thirdly, preparing potassium calcium magnesium sulfate slurry, then placing the D1 obtained in the second step into the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the D1 to form a fertilizer E1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
Example 7
An organic-inorganic compound fertilizer with a mesoporous core-shell type comprises a core layer and a shell layer, wherein the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts potassium sulfate calcium magnesium mineral fertilizer; the honeycomb tube type organic waste is prepared from cow dung and corn straw, and specifically comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH. Adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with corn straw/chicken manure fertilizer to form a biological microbial agent which takes bean cakes/cow manure organic fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form F1 for later use.
And thirdly, preparing potassium calcium magnesium sulfate slurry, then placing F1 obtained in the second step into the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the F1 to form fertilizer G1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
Example 8
An organic-inorganic compound fertilizer with a mesoporous core-shell type comprises a core layer and a shell layer, wherein the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts potassium sulfate calcium magnesium mineral fertilizer; the honeycomb tube type organic waste is prepared from cow dung and corn straw, and specifically comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH. Adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with corn straw/pig manure fertilizer to form a biological microbial agent which takes corn straw/pig manure organic fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form H1 for later use.
Preparing potassium calcium magnesium sulfate slurry, placing the H1 obtained in the step II into the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the H1 to form a fertilizer I1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
Example 9
An organic-inorganic compound fertilizer with a mesoporous core-shell type comprises a core layer and a shell layer, wherein the core layer contains microbial agents, cellulose hydrogel and honeycomb tubular organic waste; the shell layer adopts potassium sulfate calcium magnesium mineral fertilizer; the honeycomb tube type organic waste is prepared from cow dung and corn straw, and specifically comprises the following steps:
step one, wrapping a microbial agent in cellulose hydrogel to form a core:
firstly, placing plant fiber chitosan dissolving pulp into a mixed solution composed of ethanol and water, continuously stirring, and then adding NaOH. Adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; the dispersion was rotary evaporated to a viscous state and was ready for use as A1.
And then blending the microbial agent with the A1, wrapping the microbial agent in cellulose hydrogel, and air-drying to obtain the A2 for later use.
Blending the material A2 obtained in the step one with dining-table waste/sheep manure fertilizer to form a biological microbial agent which takes dining-table waste/sheep manure organic fertilizer as a framework and is packed with cellulose hydrogel: firstly, fermenting organic fertilizer raw materials (animal manure, corn straw and EM bacteria), then feeding the fermented organic fertilizer raw materials into a semi-wet material pulverizer for pulverizing, and sieving the pulverized organic fertilizer raw materials with a 100-200-mesh sieve. Then adding cellulose hydrogel air-dried powder, grinding, sieving, blending, stirring by a stirrer, granulating by a granulating machine, and drying to form J1 for later use.
Preparing potassium calcium magnesium sulfate slurry, placing J1 obtained in the step II in the potassium calcium magnesium sulfate slurry, stirring to uniformly wrap the potassium calcium magnesium sulfate on the outer layer of the J1 to form fertilizer K1 wrapped by the potassium calcium magnesium sulfate on the outer layer, and drying to obtain the long-acting biological slow-release fertilizer.
Finally, it should be noted that: the foregoing description is only illustrative of the preferred embodiments of the present invention, and although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments described, or equivalents may be substituted for elements thereof, and any modifications, equivalents, improvements or changes may be made without departing from the spirit and principles of the present invention.
Claims (1)
1. The method for preparing the organic-inorganic compound fertilizer with the mesoporous core-shell is characterized by comprising the following steps of:
placing plant fiber chitosan dissolving pulp into a mixed solution consisting of ethanol and water, continuously stirring, and then adding NaOH; adding sodium acetate after the reaction, and reacting; forming a fiber aqueous solution, and dispersing the solution in a high-speed emulsifying machine; rotary evaporating the dispersion liquid to a viscous state to serve as A1 for standby; then blending the microbial agent with the A1, and air-drying to obtain a material A2; the microbial agent is selected from bacillus licheniformis XS2-450 strain with a preservation number of CGMCC NO.9430, and the viable count is more than or equal to 10 12 CFU/g；
Step two, fermenting animal manure, corn straw and EM bacteria, then feeding the fermented animal manure, corn straw and EM bacteria into a semi-wet material crusher for crushing, and sieving the crushed animal manure and the crushed corn straw and EM bacteria with a 100-200-mesh sieve; then adding the A2 material, grinding, sieving, carrying out blending doping, stirring by a stirrer, then granulating by a granulating machine, and drying after the mixture is discharged to form a material B1;
and thirdly, placing the material B1 obtained in the second step into potassium sulfate calcium magnesium slurry, and stirring to uniformly wrap the potassium sulfate calcium magnesium on the outer layer of the B1 to form a fertilizer C1 wrapped by the potassium sulfate calcium magnesium on the outer layer, thereby obtaining the long-acting biological slow-release fertilizer.
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| CN111732480A (en) * | 2020-07-08 | 2020-10-02 | 东北农业大学 | Special package fertilizer containing mineral and biological organic components for organic crops and preparation method thereof |
| CN112111412A (en) * | 2020-09-27 | 2020-12-22 | 江西华威科技有限公司 | Trichoderma harzianum microbial agent with double-network hydrogel shell multi-capsule core structure |
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| CN106148451A (en) * | 2015-03-27 | 2016-11-23 | 海南椰国食品有限公司 | Biological cellulose gel culture medium and the biological cellulose gel product prepared by it |
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| CN106084259A (en) * | 2016-07-29 | 2016-11-09 | 华南理工大学 | A kind of preparation method of cellulose aquagel |
| CN111732480A (en) * | 2020-07-08 | 2020-10-02 | 东北农业大学 | Special package fertilizer containing mineral and biological organic components for organic crops and preparation method thereof |
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Effective date of registration: 20240415 Address after: 010000 No. 2, building 1, gengyu fertilizer plant, Bayan Town, Saihan District, Hohhot City, Inner Mongolia Autonomous Region Patentee after: Inner Mongolia fengzhidao Ecological Engineering Co.,Ltd. Country or region after: China Address before: 067060 No. 2 Xueyuan Road, high tech Industrial Development Zone, Chengde City, Hebei Province Patentee before: Hebei Petroleum University of Technology Country or region before: China |