CN115094636A - 一种防起毛起球仿棉内衣面料的制备方法 - Google Patents
一种防起毛起球仿棉内衣面料的制备方法 Download PDFInfo
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Abstract
本发明涉及纺织品功能整理领域,具体关于一种防起毛起球仿棉内衣面料的制备方法;本方法还提供了一种防起毛起球剂的制备方法:聚醚多元醇,丙烯酸羟乙酯,二异氰酸酯在高温下扩链聚合生成带丙烯酸基团的预聚体;再与Α,Ω‑二氨基聚乙二醇盐酸盐、丙烯酸1,1,3,3‑四甲基胍盐发生加成反应,得到防起毛起球剂;本发明制备的防起毛起球剂,分子链中含有亲水性基团,与水具有很强的亲和性,它不仅具有溶剂型聚氨醋耐低温、柔韧性好、粘接强度大的优良吐能,还具有节约能源、不污染环境、成膜透气性好等优点。
Description
技术领域
本发明涉及纺织品功能整理领域,尤其是一种防起毛起球仿棉内衣面料的制备方法。
背景技术
随着针织产品的发展,广大消费者对针织产品质地、档次的要求在不断提高。近年来,消费者在选用针织服装方面追求舒适、自然、休闲,抗起毛起球的针织产品就越来越受广大消费者的青睐。因此,对织物进行抗起毛起球整理,提高织物的服用舒适性和品质,日益受到国内外染整工作者的重视。
CN201010595876.7:本发明为一种防起毛起球防紫外整理剂及制备方法与应用。所述的整理剂,由包括以下步骤制备而得:(1)将钛醇盐溶于有机溶剂中,再将所得的溶液加入酸性水溶液中,搅拌均匀,得到混合物;(2)将硅醇盐加入到步骤(1)中得到的混合物中,搅拌均匀,得到透明溶液;或者(1)将酸、硅醇盐依次溶于水中,搅拌均匀,得到混合物;(2)将钛醇盐溶于有机溶剂中,所得的溶液加入到步骤(1)中得到的混合物中,搅拌均匀,得到透明溶液。本发明的整理剂具有制备简单、整理流程短特点,符合节水节能、低碳环保的要求。
CN201711243330.3公开了一种防起毛起球保暖型针织布的制备方法,属于织物整理剂技术领域。将六亚甲基二异氰酸酯、聚乙二醇、一缩二乙二醇和叶酸混合后加热;向反应后的混合物中加入三乙胺和乙二胺,搅拌反应得到混合物料A;将羊毛纺织成的纱线浸入混合物料A,取出后于烘箱中烘干得到防起毛起球纱线;将太阳绒纤维和羊绒纤维混纺成保暖纱线;将防起毛起球纱线作为经纱,保暖纱线作为纬纱,经纱和纬纱交织成针织布。本发明制备的针织布处理温度低,能耗少,不会引起环境污染,属绿色技术。制备的产品有很好的抗菌效果,而且还能抗起球,力学强度无任何影响。本发明所述制备方法能够降低纤维表面的摩擦系数,减少针织布的定向摩擦效应,还可以增加针织布的强力。
CN201711238620.9:本发明公开了一种羊毛织物的防起毛起球整理方法,先将羊毛织物置于清洗液中进行超声波清洗,清洗时间为25-40min;将清洗后的羊毛织物放入低温等离子体处理仪进行氧气低温等离子处理,处理时间为2-4min,压强为30-40pa,功率为80-100w;然后将预处理后的羊毛织物放入浸轧防起毛起球整理液中通过轧车进行二浸二轧处理,防起毛起球整理液的温度25-35℃,pH为6.5-7.2,二浸二轧时轧车的转速为13-15r/min,轧余率75-85%,最后将经过处理的羊毛织物放入烘干机中进行烘干处理本发明提供了一种羊毛织物的防起毛起球整理方法,该方法整理的羊毛织物具有牢度好,织物柔软,比重大,悬垂好,吸湿性好,穿着吸湿透气、凉爽舒适、不起毛、不起皱和整齐美观的优点,制造成本低廉,操作简单。
发明内容
1、要解决的技术问题
现有技术虽然能增加纺织品的抗起球性能,但是存在以下缺陷:整理剂耐水洗牢度差,存在高分子物与纤维结合牢度的问题,随着服用水洗次数的增加,因高分子覆盖物的脱落,又会产生起毛起球现象;加工工艺复杂,耗水耗能,成本较高。
2、技术方案
为了解决上述问题,本发明提供了一种防起毛起球仿棉内衣面料的制备方法,属于纺织品功能整理领域,其操作步骤为:
按照质量份数,将3-15份仿棉内衣面料放入50-65份工作液,升温浸渍处理,两浸两轧,轧液率为60-70%,水洗,室温晾干,烘干,焙烘后得到防起毛起球仿棉内衣面料。
进一步的,所述升温至35-45℃浸渍处理30-75min。
进一步的,所述烘干温度为95-105℃,时间为60-180秒。
进一步的,所述焙烘温度为140-165℃,时间为60-90秒。
进一步的,所述一种工作液的制备方法为:
按照质量份数,在反应器中加入120-150份去离子水、17-25份防起毛起球剂,搅拌10-25min。
进一步的,所述一种防起毛起球剂的制备方法为:
S1:按照质量份数,在反应器中加入20-40份的聚醚多元醇,10-15份丙烯酸羟乙酯,进行高温真空脱水;
S2:向反应器中充入氮气,冷却至60-80℃,边搅拌边反应器中缓慢加入40-55份二异氰酸酯、2-7份扩链剂,反应2-4h;
S3:冷却至20-30℃加入50-75份Α,Ω-二氨基聚乙二醇盐酸盐、0.01-0.5份丙烯酸1,1,3,3-四甲基胍盐,加入12-18份三乙胺,调节PH值至4-7,继续反应1-3h;得到防起毛起球剂。
进一步的,所述聚醚多元醇为聚醚多元醇800或聚醚多元醇210或聚醚多元醇3050或聚醚多元醇220或聚醚多元醇4800。
进一步的,所述高温温度为100-120℃、真空度为0.08-0.1MPa、脱水1-2h。
进一步的,所述扩链剂为1,4-丁二醇或1,6-己二醇或甘油或山梨醇。
进一步的,所述一种丙烯酸1,1,3,3-四甲基胍盐,其制备方法为:
按照质量份数,准确称量1,1,3,3-四甲基胍10-15份,加入到带冷凝管和机械搅拌装置的反应釜中;准确称量丙烯酸5-9份,开始滴加丙烯酸溶液;15-60分钟内滴加完毕,室温下继续搅拌30-60分钟,得到丙烯酸1,1,3,3-四甲基胍盐。
3、技术创新点
所述聚醚多元醇,丙烯酸羟乙酯,二异氰酸酯在高温下扩链聚合生成带丙烯酸基团的预聚体;再与Α,Ω-二氨基聚乙二醇盐酸盐、丙烯酸1,1,3,3-四甲基胍盐发生加成反应,得到防起毛起球剂。
4、有益效果
相比于现有技术,经本发明制备的抗起毛起球剂整理后,织物表面起球现象大大降低,弹性好,毛感强,厚实丰满,柔软滑爽,耐磨,抗起毛起球等级由原来1-2级提高至4-4.5级。最后对处理后的针织物进行扫描电镜表征,发现纤维表面沉积着聚合物,有凝胶薄膜包覆现象,这使纤维间的相对滑动趋势降低,证明织物经处理后,表面形成强韧的薄膜。该薄膜耐磨擦、拉伸强度高、弹性好,并有一定的亲水性,可改善纤维间的粘结力,有利于抗起毛起球。同时抗起毛起球剂又具有一定的抗静电作用,使织物表面的毛羽不易纠缠在一起,也达到提高织物抗起球性能的效果。
具体实施方式
本发明所述的实施例是对本发明的说明而不能限制本发明,在与本发明相当的含义和范围内的任何改变和调整,都应认为是在本发明的范围内。
实施例1
一种防起毛起球仿棉内衣面料的制备方法,其操作步骤为:
将300g仿棉内衣面料放入5000g工作液,升温浸渍处理,两浸两轧,轧液率为60%,水洗,室温晾干,烘干,焙烘后得到防起毛起球仿棉内衣面料。
所述升温至35℃浸渍处理30min。
所述烘干温度为95℃,时间为60秒。
所述焙烘温度为140,时间为60秒。
所述一种工作液的制备方法为:
在反应器中加入12000g去离子水、1700g防起毛起球剂,搅拌10min。
所述一种防起毛起球剂的制备方法为:
S1:在反应器中加入2000g的聚醚多元醇,1000g丙烯酸羟乙酯,进行高温真空脱水;
S2:向反应器中充入氮气,冷却至60℃,边搅拌边反应器中缓慢加入4000g二异氰酸酯、200g扩链剂,反应2h;
S3:冷却至20℃加入5000gΑ,Ω-二氨基聚乙二醇盐酸盐、5g丙烯酸1,1,3,3-四甲基胍盐,加入1200g三乙胺,调节PH值至4,继续反应1h;得到防起毛起球剂。
所述聚醚多元醇为聚醚多元醇800。
所述高温温度为100℃、真空度为0.08MPa、脱水1h。
所述扩链剂为1,4-丁二醇。
所述一种丙烯酸1,1,3,3-四甲基胍盐,其制备方法为:
准确称量1,1,3,3-四甲基胍1000g,加入到带冷凝管和机械搅拌装置的反应釜中;准确称量丙烯酸500g,开始滴加丙烯酸溶液;15分钟内滴加完毕,室温下继续搅拌30分钟,得到丙烯酸1,1,3,3-四甲基胍盐。
实施例2
一种防起毛起球仿棉内衣面料的制备方法,其操作步骤为:
将600g仿棉内衣面料放入5500g工作液,升温浸渍处理,两浸两轧,轧液率为65%,水洗,室温晾干,烘干,焙烘后得到防起毛起球仿棉内衣面料。
所述升温至40℃浸渍处理45min。
所述烘干温度为100℃,时间为90秒。
所述焙烘温度为150℃,时间为70秒。
所述一种工作液的制备方法为:
在反应器中加入13000g去离子水、2000g防起毛起球剂,搅拌15min。
所述一种防起毛起球剂的制备方法为:
S1:在反应器中加入2500g的聚醚多元醇,1200g丙烯酸羟乙酯,进行高温真空脱水;
S2:向反应器中充入氮气,冷却至65℃,边搅拌边反应器中缓慢加入4500g二异氰酸酯、300g扩链剂,反应2.5h;
S3:冷却至25℃加入6000gΑ,Ω-二氨基聚乙二醇盐酸盐、10g丙烯酸1,1,3,3-四甲基胍盐,加入1400g三乙胺,调节PH值至5,继续反应1.5h;得到防起毛起球剂。
所述聚醚多元醇为聚醚多元醇210。
所述高温温度为105℃、真空度为0.09MPa、脱水1.5h。
所述扩链剂为1,6-己二醇。
所述一种丙烯酸1,1,3,3-四甲基胍盐,其制备方法为:
准确称量1,1,3,3-四甲基胍1200g,加入到带冷凝管和机械搅拌装置的反应釜中;准确称量丙烯酸600g,开始滴加丙烯酸溶液;30分钟内滴加完毕,室温下继续搅拌40分钟,得到丙烯酸1,1,3,3-四甲基胍盐。
实施例3
一种防起毛起球仿棉内衣面料的制备方法,其操作步骤为:
将1200g仿棉内衣面料放入6000g工作液,升温浸渍处理,两浸两轧,轧液率为65%,水洗,室温晾干,烘干,焙烘后得到防起毛起球仿棉内衣面料。
所述升温至40℃浸渍处理60min。
所述烘干温度为100℃,时间为120秒。
所述焙烘温度为160℃,时间为80秒。
所述一种工作液的制备方法为:
在反应器中加入14000g去离子水、2200g防起毛起球剂,搅拌20min。
所述一种防起毛起球剂的制备方法为:
S1:在反应器中加入3500g的聚醚多元醇,1400g丙烯酸羟乙酯,进行高温真空脱水;
S2:向反应器中充入氮气,冷却至75℃,边搅拌边反应器中缓慢加入5000g二异氰酸酯、600g扩链剂,反应3.5h;
S3:冷却至25℃加入7000gΑ,Ω-二氨基聚乙二醇盐酸盐、40g丙烯酸1,1,3,3-四甲基胍盐,加入1600g三乙胺,调节PH值至6,继续反应2.5h;得到防起毛起球剂。
所述聚醚多元醇为聚醚多元醇3050。
所述高温温度为115℃、真空度为0.09MPa、脱水1.5h。
所述扩链剂为甘油。
所述一种丙烯酸1,1,3,3-四甲基胍盐,其制备方法为:
准确称量1,1,3,3-四甲基胍1400g,加入到带冷凝管和机械搅拌装置的反应釜中;准确称量丙烯酸800g,开始滴加丙烯酸溶液;45分钟内滴加完毕,室温下继续搅拌45分钟,得到丙烯酸1,1,3,3-四甲基胍盐。
实施例4
一种防起毛起球仿棉内衣面料的制备方法,其操作步骤为:
将1200g仿棉内衣面料放入6500g工作液,升温浸渍处理,两浸两轧,轧液率为70%,水洗,室温晾干,烘干,焙烘后得到防起毛起球仿棉内衣面料。
所述升温至45℃浸渍处理5min。
所述烘干温度为105℃,时间为180秒。
所述焙烘温度为165℃,时间为80秒。
所述一种工作液的制备方法为:
在反应器中加入15000g去离子水、2500g防起毛起球剂,搅拌25min。
所述一种防起毛起球剂的制备方法为:
S1:在反应器中加入4000g的聚醚多元醇,1500g丙烯酸羟乙酯,进行高温真空脱水;
S2:向反应器中充入氮气,冷却至80℃,边搅拌边反应器中缓慢加入5500g二异氰酸酯、700g扩链剂,反应4h;
S3:冷却至30℃加入7500gΑ,Ω-二氨基聚乙二醇盐酸盐、50g丙烯酸1,1,3,3-四甲基胍盐,加入1800g三乙胺,调节PH值至7,继续反应3h;得到防起毛起球剂。
所述聚醚多元醇为聚醚多元醇220。
所述高温温度为120℃、真空度为0.1MPa、脱水2h。
所述扩链剂为山梨醇。
所述一种丙烯酸1,1,3,3-四甲基胍盐,其制备方法为:
准确称量1,1,3,3-四甲基胍1500g,加入到带冷凝管和机械搅拌装置的反应釜中;准确称量丙烯酸900g,开始滴加丙烯酸溶液;60分钟内滴加完毕,室温下继续搅拌60分钟,得到丙烯酸1,1,3,3-四甲基胍盐。
对比例1
操作步骤同实施例3,但配方中不加入防起毛起球剂,其它操作条件不变。
对比例2
操作步骤同实施例3,但配方中不加入丙烯酸1,1,3,3-四甲基胍盐,其它操作条件不变。
对比例3
操作步骤同实施例3,但配方中不加入Α,Ω-二氨基聚乙二醇盐酸盐,其它操作条件不变。
实施例评价
本发明的起毛起球等级按照GBT4802.3-1997《织物起球试验方法一起球箱法》测定,测定结果如下表所示:
抗起毛起球等级 | 手感 | |
实施例1 | 4 | 好 |
实施例2 | 4 | 好 |
实施例3 | 4.5 | 好 |
实施例4 | 4 | 好 |
对比例1 | 1 | 差 |
对比例2 | 2 | 较好 |
对比例3 | 2 | 较好 |
Claims (10)
1.一种防起毛起球仿棉内衣面料的制备方法,其操作步骤为:
按照质量份数,将3-15份仿棉内衣面料放入50-65份工作液,升温浸渍处理,两浸两轧,轧液率为60-70%,水洗,室温晾干,烘干,焙烘后得到防起毛起球仿棉内衣面料。
2.根据权利要求1所述的一种防起毛起球仿棉内衣面料的制备方法,其特征在于:所述升温至35-45℃浸渍处理30-75min。
3.根据权利要求1所述的一种防起毛起球仿棉内衣面料的制备方法,其特征在于:所述烘干温度为95-105℃,时间为60-180秒。
4.根据权利要求1所述的一种防起毛起球仿棉内衣面料的制备方法,其特征在于:所述焙烘温度为140-165℃,时间为60-90秒。
5.根据权利要求1所述的一种防起毛起球仿棉内衣面料的制备方法,其特征在于:所述一种工作液的制备方法为:
按照质量份数,在反应器中加入120-150份去离子水、17-25份防起毛起球剂,搅拌10-25min。
6.根据权利要求6所述的一种防起毛起球仿棉内衣面料的制备方法,其特征在于:所述一种防起毛起球剂的制备方法为:
S1:按照质量份数,在反应器中加入20-40份的聚醚多元醇,10-15份丙烯酸羟乙酯,进行高温真空脱水;
S2:向反应器中充入氮气,冷却至60-80℃,边搅拌边反应器中缓慢加入40-55份二异氰酸酯、2-7份扩链剂,反应2-4h;
S3:冷却至20-30℃加入50-75份Α,Ω-二氨基聚乙二醇盐酸盐、0.01-0.5份丙烯酸1,1,3,3-四甲基胍盐,加入12-18份三乙胺,调节PH值至4-7,继续反应1-3h;得到防起毛起球剂。
7.根据权利要求6所述的一种防起毛起球仿棉内衣面料的制备方法,其特征在于:所述聚醚多元醇为聚醚多元醇800或聚醚多元醇210或聚醚多元醇3050或聚醚多元醇220或聚醚多元醇4800。
8.根据权利要求6所述的一种防起毛起球仿棉内衣面料的制备方法,其特征在于:所述高温温度为100-120℃、真空度为0.08-0.1MPa、脱水1-2h。
9.根据权利要求6所述的一种防起毛起球仿棉内衣面料的制备方法,其特征在于:所述扩链剂为1,4-丁二醇或1,6-己二醇或甘油或山梨醇。
10.根据权利要求6所述的一种防起毛起球仿棉内衣面料的制备方法,其特征在于:所述一种丙烯酸1,1,3,3-四甲基胍盐,其制备方法为:
按照质量份数,准确称量1,1,3,3-四甲基胍10-15份,加入到带冷凝管和机械搅拌装置的反应釜中;准确称量丙烯酸5-9份,开始滴加丙烯酸溶液;15-60分钟内滴加完毕,室温下继续搅拌30-60分钟,得到丙烯酸1,1,3,3-四甲基胍盐。
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