CN114948844A

CN114948844A - Sulphur-light illusion eye shadow

Info

Publication number: CN114948844A
Application number: CN202210662050.0A
Authority: CN
Inventors: 侯贤碧; 宋凤蓉
Original assignee: Guangzhou Duoduo Cosmetics Co ltd
Current assignee: Guangzhou Duoduo Cosmetics Co ltd
Priority date: 2022-06-13
Filing date: 2022-06-13
Publication date: 2022-08-30

Abstract

The invention relates to the field of color cosmetics, and particularly discloses a sulfur-containing light illusion eye shadow. The sulfur-light illusion eye shadow specifically comprises the following components: silica; acrylic acid (ester) copolymers; hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymers; acrylic acid/C10-30 alkanol acrylate crosspolymer; CI 77491; CI 77891; oriental cherry flower extract; grape flower cell extract; a chlorella extract; flos Sophorae Immaturus extract; a flaxseed extract; a chelating agent; a preservative; a humectant; a skin conditioning agent; a solvent. The composition of the invention has the advantages of being easier to spread evenly and being less prone to make-up removal.

Description

Sulphur-light illusion eye shadow

Technical Field

The invention relates to the field of color cosmetics, in particular to a sulfur light illusion eye shadow.

Background

The eye shadow is a makeup cosmetic which is coated on eyelids (namely eyelids) and canthus to generate shadow and color contrast, show three-dimensional aesthetic feeling and strengthen the eye spirit to make eyes look beautiful and lively.

The existing eye shadow is mainly composed of powder components, and a finally prepared eye shadow product is also in a powder cake shape, so that the eye shadow is generally in a powder form during makeup, the problem that the eye shadow is dry and is not easy to uniformly spread during makeup is easily caused, and the condition of makeup removal or powder floating due to oil secretion of skin is easily caused after the eye shadow is made up for a period of time. Thus, there is still room for improvement.

Disclosure of Invention

In order to enable the eye shadow to be more easily and uniformly spread, make up is more difficult to remove, and the durability of the makeup is prolonged, the application provides the sulfur light illusion eye shadow.

The application provides a sulphur light illusion eye shadow adopts following technical scheme:

a sulfur light illusion eye shadow comprises the following components in percentage by mass:

10-13% of silica;

4-6% of acrylic acid (ester) copolymer;

0.5-1% of hydroxyethyl acrylate/acryloyl dimethyl sodium taurate copolymer;

acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer 0.1-0.5%;

CI 77491 2-3％；

CI 77891 0.1-0.2％；

oriental cherry extract 0.05-0.1%;

0.001-0.005% of grape flower cell extract;

chlorella extract 0.001-0.003%;

0.001-0.004% of flos Sophorae bud extract;

0.001-0.005% of linseed extract;

1-2% of a chelating agent;

0.1 to 0.3 percent of preservative;

0.3 to 0.4 percent of humectant;

skin conditioner 0.004-0.01%;

the balance being solvent.

The liquid eye shadow is prepared by adopting the components to cooperate and compound, so that the eye shadow product is in a liquid state, the eye shadow is easier to spread evenly, and the makeup effect of the eye shadow is better; meanwhile, silica, CI77491 and CI77891 are cooperatively compounded, so that the eye shadow can form rainbow color, a colorful effect is presented, different color effects can be presented when the eye shadow is observed from different angles, the eye makeup effect is more cool, and the eye makeup is more popular with consumers.

Through adopting the oriental cherry flower extract, the grape flower cell extract, the chlorella extract, the sophora flower bud extract and the linseed extract to cooperate and compound, the chlorella extract is favorable for better promoting the permeation of effective components, so that the effective components can penetrate through the horny layer and permeate into the true cortex, thereby being favorable for deep water replenishing of the skin, and the skin is more water-moist, thereby being favorable for keeping the water-moist state of the eye shadow part smeared by the eyes, so that the eye skin is more difficult to dry due to the influence of the eye shadow, and the eye shadow is also less easy to have the condition of floating powder and makeup removal due to over-drying.

Meanwhile, the cherry blossom extract, the grape blossom cell extract, the chlorella extract, the sophora flower bud extract and the linseed extract are cooperatively compounded, so that the activity of 5 alpha-reductase can be better inhibited, the testosterone in the male hormone can be better inhibited from being converted into dihydrotestosterone DHT, the sensitivity of sebaceous glands can be reduced, the command of the sebaceous glands for secreting oil can be blocked, the oil of the skin can be better reduced, the water-oil balance of the skin can be better regulated, and the skin is less prone to oil accumulation due to excessive water supplement and nutrition.

In conclusion, the cherry blossom extract, the grape flower cell extract, the chlorella extract, the sophora flower bud extract and the linseed extract are compounded in a synergistic manner, so that the deep water replenishing is facilitated, the oil secretion of the skin is reduced, the eye skin is maintained better, the eye skin is not influenced by the eye shadow easily, the makeup holding time of the eye shadow is prolonged well, and the eye shadow is not prone to the condition of floating powder or makeup removal due to over-drying or skin oil secretion.

Preferably, the humectant comprises one or more of 1, 2-hexanediol, glycerol, caprylyl glycol, and ethylhexyl glycerin.

Preferably, the humectant consists of 1, 2-hexanediol, glycerin, caprylyl glycol, and ethylhexylglycerin in a ratio of 10.4: 16: 13: 8 in a mass ratio.

1, 2-hexanediol, glycerol, caprylyl glycol and ethylhexylglycerin in a specific ratio are cooperatively compounded to serve as a humectant, so that the skin is favorably moisturized deeply, excessive oil and fat secretion of the skin is not easily caused, the water-oil balance of the skin is favorably adjusted, the eye skin is favorably maintained, and the makeup effect of the eye shadow is more durable. Meanwhile, the synergy of the substances in a specific proportion is also beneficial to better increasing the collagen content of the skin, so that the skin has higher compactness.

Preferably, the skin conditioning agent comprises one or more of hydrolyzed hyaluronic acid, sodium hyaluronate crosspolymer, acetylated sodium hyaluronate, hyaluronic acid and p-hydroxyacetophenone.

Preferably, the skin conditioning agent is prepared from hydrolyzed hyaluronic acid, a sodium hyaluronate crosspolymer, sodium acetylated hyaluronate and hyaluronic acid in a ratio of 1: 1: 1: 1 in a mass ratio.

The skin conditioner is prepared by adopting the synergistic compounding of the hydrolyzed hyaluronic acid, the sodium hyaluronate cross-linked polymer, the acetylated sodium hyaluronate, the hyaluronic acid and the hydroxyacetophenone in a specific ratio, so that the skin conditioner is favorable for better promoting the penetration of effective components, the deep water replenishing effect of the eye shadow is better, meanwhile, the phenomenon of excessive grease secretion is not easily caused, the water-oil balance of the skin is favorably adjusted, the skin nourishing effect of the eye shadow is better, and the durability of the makeup of the eye shadow is favorably prolonged. Meanwhile, the synergy of the substances in a specific proportion is also beneficial to better increasing the collagen content of the skin, so that the skin has higher compactness.

Preferably, the chelating agent is tetrahydroxypropyl ethylenediamine.

The tetrahydroxypropyl ethylenediamine is used as the chelating agent, so that the stability of the eye shadow is favorably improved, and the eye shadow is favorably cooperated with the preservative to play a role to a certain extent, so that the preservative property of the eye shadow is better.

Preferably, the preservative consists of phenoxyethanol and p-hydroxyacetophenone.

The phenoxyethanol and the p-hydroxyacetophenone are selected to be used as the preservative in a synergistic manner, so that the phenoxyethanol and the p-hydroxyacetophenone are beneficial to better synergy with the tetrahydroxypropyl ethylenediamine, better preservative effect is achieved, and meanwhile, stimulation to skin is not easy to cause, and the mildness of eye shadow is kept better.

Preferably, the solvent includes one or both of water and butanol.

Preferably, the solvent is prepared by mixing water and butanediol in a ratio of 14-15: 1.1 in mass ratio.

The water and the butanol in a specific proportion are used as the solvent in a synergistic manner, so that the compatibility of each component is promoted better, the components are mixed uniformly better, and the components are better cooperated with each other and play a role.

In summary, the present application has the following beneficial effects:

1. the liquid eye shadow is prepared by adopting the components to cooperate and compound, so that the eye shadow product is in a liquid state, the eye shadow is easier to spread evenly, and the makeup effect of the eye shadow is better.

2. By adopting the silica, CI77491 and CI77891 to cooperate and compound, the eye shadow can form rainbow color, presents a colorful effect, and presents different color effects when the eye shadow is observed from different angles, so that the eye makeup effect is more colorful and is more popular with consumers.

3. By adopting the mutual synergistic compounding of the oriental cherry flower extract, the grape flower cell extract, the chlorella extract, the sophora flower bud extract and the linseed extract, the eye mask is beneficial to reducing the oil secretion of the skin while better deeply moisturizing the skin, thereby being beneficial to better maintaining the eye skin, being beneficial to better prolonging the makeup holding time of the eye shadow while the eye skin is less susceptible to the influence of the eye shadow, and being less susceptible to the condition of floating powder or makeup removal due to over-drying or skin oil secretion.

Drawings

Fig. 1 is a makeup effect diagram after the sulfur light illusion eye shadow is made up.

Detailed Description

The present application will be described in further detail with reference to the following examples and accompanying drawings.

In the following examples and comparative examples, specifically used substances were commercially available. Specifically, the acrylic copolymer adopts acrylic copolymer with CAS number 25035-69-2; the hydroxyethyl acrylate/acryloyl dimethyl sodium taurate copolymer adopts a CAS number of 111286-86-3 hydroxyethyl acrylate/acryloyl dimethyl sodium taurate copolymer; acrylic/C10-30 Alkanolacrylate crosspolymer acrylic/C10-30 Alkanolacrylate crosspolymer, available from Kyowa McHeng trade company under the model number carbomer U20; the sodium hyaluronate cross-linked polymer adopts a sodium hyaluronate cross-linked polymer with CAS number of 105524-32-1; oriental cherry flower extract, chlorella extract, sophora flower bud extract, and linseed extract were obtained from knope, guangzhou biotechnology limited; grape flower cell extracts were purchased from guangzhou femtogetizer limited. The above extracts are all obtained by alcohol extraction.

Example 1

The embodiment of the application discloses a sulfur light illusion eye shadow, which consists of the following components in parts by mass:

10kg of silica; 4kg of acrylic acid (ester) copolymer; 0.5kg of hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer; 0.1kg of acrylic acid (ester)/C10-30 alkanol acrylate crosslinked polymer; CI 774912 kg; CI 778910.1 kg; oriental cherry extract 0.05 kg; 0.001kg of grape flower cell extract; 0.001kg of chlorella extract; 0.001kg of sophora flower bud extract; 0.001kg of linseed extract; 1kg of chelating agent; 0.1kg of preservative; 0.3kg of humectant; 0.004kg of skin conditioner; 81.842kg of solvent.

In this example, the chelating agent is tetrahydroxypropyl ethylenediamine; the preservative consists of phenoxyethanol and p-hydroxyacetophenone in a mass ratio of 230: 1; the humectant is prepared from 1, 2-hexanediol, glycerol, caprylyl glycol and ethylhexylglycerin in a weight ratio of 10.4: 16: 13: 8 in a mass ratio; the skin conditioning agent is prepared from hydrolyzed hyaluronic acid, sodium hyaluronate cross-linked polymer, acetylated sodium hyaluronate and hyaluronic acid in a weight ratio of 1: 1: 1: 1 in a mass ratio; the solvent consists of water and butanediol in a weight ratio of 14: 1.1 in mass ratio.

The embodiment of the application also discloses a preparation method of the sulfur light illusion eye shadow, which comprises the following steps:

step 1, cleaning and disinfecting production equipment, turning on a heating switch of a stirring kettle, and setting the heating temperature to be 80 ℃.

And 2, accurately weighing the components according to the mass, sequentially adding butanediol, hydroxyethyl acrylate/acryloyl dimethyl sodium taurate copolymer and acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer into a stirring kettle, stirring at the rotating speed of 1000r/min, and uniformly stirring and mixing to form a phase A mixture.

And 3, continuously adding water, 1/4 mass of 1, 2-hexanediol, a cherry flower extract, a grape flower cell extract, a chlorella extract, a sophora flower bud extract, a linseed extract, hydrolyzed hyaluronic acid, a sodium hyaluronate cross-linked polymer, acetylated sodium hyaluronate and sodium hyaluronate into the phase A mixture while stirring, raising the temperature to 85 ℃, and continuously stirring until all the components are completely and uniformly dispersed to form a phase B mixture.

And 4, adding tetrahydroxypropylethylenediamine and hydroxyacetophenone into the mixture of the phase B while continuing stirring, stirring and mixing, and uniformly dispersing to form a mixture of the phase C.

And 5, sequentially adding the acrylic acid (ester) copolymer, the rest 3/4 mass of 1, 2-hexanediol, phenoxyethanol, CI77891, caprylyl glycol and ethylhexyl glycerin into the C-phase mixture while continuing stirring, mixing and uniformly dispersing to form a D-phase mixture.

And step 6, adjusting the stirring speed to be 1500r/min, adding silica, CI77491 and glycerol into the D-phase mixture while continuously stirring, adjusting the color, stirring until all components are mixed and uniformly dispersed, and packaging to obtain the sulfur-containing light illusion eye shadow.

Example 2

The difference from example 1 is that:

the dosage proportions of the components of the sulfur light illusion eye shadow are different, and the dosage proportions are as follows:

13kg of silica; 6kg of an acrylic copolymer; 1kg of hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer; 0.5kg of acrylic acid (ester)/C10-30 alkanol acrylate crosspolymer; CI 774913 kg; CI 778910.2 kg; oriental cherry extract 0.1 kg; 0.005kg of grape flower cell extract; 0.003kg of chlorella extract; 0.004kg of flos sophorae bud extract; 0.005kg of linseed extract; 2kg of chelating agent; 0.3kg of preservative; 0.5kg of humectant; 0.01kg of skin conditioner; 73.373kg of solvent.

In this example, the solvent was prepared from water and butylene glycol in a ratio of 15: 1.1 in mass ratio.

Example 3

The difference from example 1 is that:

11.44kg of silica; 4.68kg of acrylic acid (ester) copolymer; 0.8kg of hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer; 0.2kg of acrylic acid (ester)/C10-30 alkanol acrylate crosspolymer; CI 774912.72 kg; CI 778910.14 kg; oriental cherry extract 0.007 kg; 0.002kg of grape flower cell extract; 0.002kg of chlorella extract; 0.002kg of sophora flower bud extract; 0.002kg of linseed extract; 1kg of chelating agent; 0.231kg of preservative; 0.474kg of humectant; 0.008kg of skin conditioner; 78.292kg of solvent.

In this example, the solvent was prepared from water and butanediol in a ratio of 14.6: 1.1 in mass ratio.

Example 4

The difference from example 1 is that:

the humectant is prepared from 1, 2-hexanediol, glycerol, caprylyl glycol and ethylhexylglycerin in a weight ratio of 10: 15: 15: 10 in mass ratio.

Example 5

The difference from example 1 is that:

the humectant is prepared from 1, 2-hexanediol, glycerol, caprylyl glycol and ethylhexylglycerin in a weight ratio of 12: 18: 12: 5 in a mass ratio.

Example 6

The difference from example 1 is that:

the humectant composition was such that the same amount of 1, 1-octanediol was used in place of the octanediol.

Example 7

The difference from example 1 is that:

the skin conditioning agent is prepared from hydrolyzed hyaluronic acid, sodium hyaluronate cross-linked polymer, acetylated sodium hyaluronate, hyaluronic acid and p-hydroxyacetophenone in a ratio of 1: 1: 3: 3: 2 in a mass ratio.

Example 8

The difference from example 1 is that:

the skin conditioning agent is prepared from hydrolyzed hyaluronic acid, sodium hyaluronate cross-linked polymer, acetylated sodium hyaluronate, hyaluronic acid and p-hydroxyacetophenone in a ratio of 3: 3: 1: 1: 0.1 in mass ratio.

Comparative example 1

Commercially available eye shadow discs in the form of a powder cake.

Comparative example 2

The difference from example 1 is that: equal amount of solvent is used to replace oriental cherry flower extract, grape flower cell extract, chlorella extract, sophora flower bud extract and linseed extract.

Comparative example 3

The difference from example 1 is that: equal amounts of solvent were substituted for the oriental cherry extract.

Comparative example 4

The difference from example 1 is that: equal amounts of solvent were substituted for the grape flower cell extract.

Comparative example 5

The difference from example 1 is that: equal amount of solvent is used to replace chlorella extract, sophora bud extract and linseed extract.

Experiment 1

Randomly selecting 130 female volunteers with the age range of 25-50 years and having a cosmetic habit, randomly dividing the volunteers into 13 groups, wherein each group comprises 10 persons, the eye shadow prepared by using the embodiment and the proportion is respectively and correspondingly applied to the eyelids on two sides, the using amount of each side of the eyelids is 2mg, the cosmetic holding time per day is 10 hours, the application is continuously carried out for 30 days, and the following detection is carried out on the volunteers using the eye shadows:

detection 1

Before the first use of the eye shadow by the volunteer, the moisture content of the skin of the eyelid part of the volunteer was measured by a Corneometer CM825, and after the first use of the eye shadow for making up for 3h and 8h, the moisture content of the skin of the eyelid part of the volunteer after making up for 3h and 8h was re-measured. The average of the test data of the same group of volunteers was calculated and recorded. The higher the detected moisture content is, the better the deep moisturizing effect of the eye shadow is.

Detection 2

When the volunteer uses the eye shadow for the first time, after the eye shadow is made up for 3h and 8h, the skin oil content of the eyelid of the volunteer is detected by a skin oil tester Sebumeter SM815 after the eyelid is made up for 3h and 8h respectively. The average of the test data of the same group of volunteers was calculated and recorded. The lower the content of the detected grease is, the better the oil control effect of the eye shadow is.

Detection 3

And observing and recording the uniform smearing degree of the eye shadow after makeup when the eye shadow is used by the volunteer.

Detection 4

The time when the eye shadow of the volunteer began to appear as floating powder and removed from the makeup after the eye shadow was applied every day was observed and recorded, and the average time (h) when the eye shadow began to appear as floating powder and removed from the makeup every day was calculated and recorded 30 days after the application.

Detection 5

Before the volunteers applied the eye shadow, the skin firmness of the eyelid portions of the volunteers was measured using a skin elasticity meter MPA580, and after the volunteers continuously applied the eye shadow for 30 days, the skin firmness of the eyelid portions of the volunteers was re-measured, and the rate (%) of change in skin firmness before and after the eye shadow was applied was calculated for each volunteer. The method for calculating the change rate of the skin tightness comprises the following steps:

the mean of the calculated data for the same group of volunteers was calculated and recorded. The smaller the skin firmness obtained by detection, the better the skin firmness is.

The data detected in the above experiment are shown in table 1 and table 2.

TABLE 1

TABLE 2

According to the data comparison between the example 1 and the comparative example 1 in tables 1 and 2, the conventional powder eye shadow is difficult to be applied and spread evenly, and the powder eye shadow also easily affects the skin of the eyelid part, which easily causes the skin to be dry.

According to the comparison of the data of the example 1 and the comparative examples 2-5 in the tables 1 and 2, the oriental cherry flower extract, the grape flower cell extract, the chlorella extract, the sophora flower bud extract and the linseed extract are compounded in a synergistic manner, so that the deep penetration of effective components into the dermis of the skin can be better promoted, and the deep water replenishing effect of the skin is better; meanwhile, the cosmetic is beneficial to better inhibiting the activity of 5 alpha-reductase, so that the sebaceous gland is more difficult to produce grease and accumulate the grease, and the water-oil balance of the skin is better regulated, so that the makeup removal condition caused by excessive grease secretion after the eye shadow is made up is more difficult, and the condition caused by excessive grease secretion caused by excessive moisture retention and nutrition of the skin of the eyelid part is also avoided.

According to the comparison of the data of the examples 1 and 4-6 in tables 1 and 2, only by adopting the synergistic combination of the 1, 2-hexanediol, the glycerin, the caprylyl glycol and the ethylhexyl glycerin in a specific mass ratio, the influence of the moisturizing ingredient on the oil secretion can be favorably relieved, so that the water-oil balance can be better regulated, the water-oil balance of the skin can be favorably maintained, the skin can be favorably firmed, the dosage ratio of the ingredients is changed or one of the ingredients is replaced, and the regulation of the water-oil balance of the skin and the effect of the firmed skin can be easily influenced.

According to the comparison of the data of the embodiment 1 and the embodiments 7 to 8 in tables 1 and 2, only by adopting the synergistic combination of the hydrolyzed hyaluronic acid, the sodium hyaluronate cross-linked polymer, the acetylated sodium hyaluronate and the hyaluronic acid in a specific mass ratio, the influence of the moisturizing ingredient on the secretion of the oil and fat can be favorably relieved, so that the water-oil balance can be better regulated and controlled, the water-oil balance of the skin can be favorably maintained, meanwhile, the skin can be favorably tightened better, the dosage ratio among the ingredients is changed, and the influence on the adjustment of the water-oil balance of the skin and the effect of tightening the skin can be caused.

The above embodiments are preferred embodiments of the present application, and the protection scope of the present application is not limited by the above embodiments, so: all equivalent changes made according to the structure, shape and principle of the present application shall be covered by the protection scope of the present application.

Claims

1. A sulfur-light illusion eye shadow, comprising: the paint comprises the following components in percentage by mass:

10-13% of silica;

4-6% of acrylic acid (ester) copolymer;

0.5-1% of hydroxyethyl acrylate/acryloyl dimethyl sodium taurate copolymer;

acrylic acid (ester)/C10-30 alkanol acrylate crosslinked polymer 0.1-0.5%;

CI 77491 2-3%；

CI 77891 0.1-0.2%；

oriental cherry extract 0.05-0.1%;

0.001-0.005% of grape flower cell extract;

chlorella extract 0.001-0.003%;

0.001-0.004% of flos Sophorae bud extract;

0.001-0.005% of linseed extract;

1-2% of a chelating agent;

0.1 to 0.3 percent of preservative;

0.3 to 0.5 percent of humectant;

skin conditioner 0.004-0.01%;

the balance being solvent.

2. A sulfur-light illusion eye shadow of claim 1, wherein: the humectant comprises one or more of 1, 2-hexanediol, glycerol, caprylyl glycol and ethylhexyl glycerol.

3. A sulfur-light illusion eye shadow of claim 2, wherein: the humectant is prepared from 1, 2-hexanediol, glycerol, caprylyl glycol and ethylhexylglycerin, wherein the ratio of (1, 2-hexanediol to glycerin) is 10.4: 16: 13: 8 in a mass ratio.

4. A sulfur-luminous eye shadow according to any one of claims 1 to 3, wherein: the skin conditioning agent comprises one or more of hydrolyzed hyaluronic acid, a sodium hyaluronate crosspolymer, acetylated sodium hyaluronate, and hyaluronic acid.

5. The sulfur-light illusion eye shadow of claim 4, wherein: the skin conditioner is prepared from hydrolyzed hyaluronic acid, a sodium hyaluronate cross-linked polymer, acetylated sodium hyaluronate and hyaluronic acid in a weight ratio of 1: 1: 1: 1 in a mass ratio.

6. A sulfur-luminous eye shadow according to any one of claims 1 to 3, wherein: the chelating agent is tetrahydroxypropyl ethylenediamine.

7. A sulfur-luminous eye shadow according to any one of claims 1 to 3, wherein: the preservative consists of phenoxyethanol and p-hydroxyacetophenone.

8. A sulfur-luminous eye shadow according to any one of claims 1 to 3, wherein: the solvent includes one or both of water and butanol.

9. A sulfur-light illusion eye shadow of claim 8, wherein: the solvent is prepared by mixing water and butanediol in a ratio of 14-15: 1.1 in mass ratio.