CN114673016A - 一种纺织品印花用纳米分散染料胶囊的制备方法 - Google Patents
一种纺织品印花用纳米分散染料胶囊的制备方法 Download PDFInfo
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- CN114673016A CN114673016A CN202210254541.1A CN202210254541A CN114673016A CN 114673016 A CN114673016 A CN 114673016A CN 202210254541 A CN202210254541 A CN 202210254541A CN 114673016 A CN114673016 A CN 114673016A
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- disperse
- disperse dye
- textile printing
- emulsifier
- nano
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Abstract
本发明公开了一种纺织品印花用纳米分散染料胶囊的制备方法,包括以下步骤:取一定量的乳化剂,完全溶解于水中得到乳化剂溶液作为水相,取一定量的分散染料加入到聚合单体、助乳化剂、交联单体和引发剂中。通过细乳液聚合法将分散染料与聚合物壳及交联单体复合成纳米胶囊,聚合物壳在印花时作为分散染料的发色场所,使印花织物具有鲜艳的颜色,并提供染料与织物的粘附作用,交联单体在高温焙烘固色时失水交联,提高聚合物壳间的作用力,增加牢度,减少粘合剂的大量使用。该纳米分散染料胶囊应用于纺织品的印花,具有高色牢度、良好手感、颜色鲜艳和适用性广的优点。
Description
技术领域
本发明涉及一种纺织品印花用纳米分散染料胶囊的制备方法,属于纺织印染领域。
背景技术
目前,纺织品的印花主要分为染料印花和涂料印花,染料印花由于专一性较高导致生产工艺复杂,而涂料印花则是利用粘合剂在纤维表面成膜的原理,将对织物没有亲和性和反应性的着色剂颗粒粘附在织物上,来获得所需颜色效果的印花技术,由于其对各类型纺织品的着色没有选择性,普遍适用性强,可有效提高印花加工产品时的正品率和加工效率,目前涂料印花织物已占印花织物的50%以上。
但在生产应用过程中,有机颜料颗粒尺寸较大、色彩鲜艳度较差,并且与粘合剂乳液配置共混成色浆后容易发生聚集现象,导致加工过程堵网以及印花颜色性能下降的问题。粘合剂和颜料印制到织物表面并烘焙成膜后,使得织物的手感发硬,并且最终胶膜中大量粘合剂分子往往只是以大规模聚集的形式低效地填充在颜料颗粒之间,对颜料颗粒的粘附针对性和靶向性不足,而单纯的减少粘合剂的用量又会造成印花织物的牢度较差,导致牢度和手感难以兼顾。
针对上述问题,目前的主要方法包括将颜料颗粒进行超细研磨,提高其颜色鲜艳度;添加柔软整理剂改善织物手感。但由于颜料颗粒研磨尺寸存在瓶颈,导致颜色性能提高有限、另外柔软剂与粘合剂乳液间的相互作用较弱,导致直接添加对印花手感提升幅度较小。因此开发一种印花着色剂,将其应用于常见纺织品的印花时,实现高色牢度、良好手感、颜色鲜艳和适用性广,具有重要意义。
发明内容
为了解决上述问题,本发明筛选含有芳基或酯基结构的共聚单体,利用细乳液聚合法制备纳米分散染料胶囊,通过对胶囊壳层结构设计,使分散染料能够直接在胶囊壳层中发色,将其作为新型着色剂,可用于多种织物的印花,聚合物壳层不仅为分散染料提供发色的场所,也能够提高染料的分散稳定性,改善分散染料与其他印花助剂的相容性,并与织物产生粘附作用,提高印花织物的色牢度。
本发明提供了一种纺织品印花用纳米分散染料胶囊的制备方法,S1:取一定量的乳化剂,完全溶解于水中得到乳化剂溶液作为水相;
S2:取一定量的分散染料加入到聚合单体、助乳化剂、交联单体和引发剂中,混合均匀得到油相,在搅拌条件下将油相缓慢加入到水相中进行预乳化;
S3:将预乳化后的乳液使用砂磨机、超声细胞粉碎机或乳化机进行细乳化制备细乳液;
S4:将细乳液在搅拌条件下升温到反应温度,引发聚合反应,反应结束后通过过滤去除杂质,得到纳米分散染料胶囊。
在本发明的一种实施方式中,所述的聚合单体含有芳基或酯基结构,包括苯乙烯、丙烯酸甲酯、甲基丙烯酸甲酯、甲基丙烯酸乙酯、甲基丙烯酸丁酯、丙烯酸异辛酯、丙烯酸乙酯、丙烯酸-2-乙基己酯、丙烯酸丁酯中的一种或几种,其比例为任意比例,具体总量为相对聚合反应体系的质量分数10-40%。
在本发明的一种实施方式中,所述的分散染料包括C.I.分散紫93、C.I.分散黄23、C.I.分散黄42、C.I.分散黄211、C.I.分散蓝60、C.I.分散蓝79、C.I.分散蓝291、C.I.分散蓝183、C.I.分散蓝56、C.I.分散蓝79、C.I.分散红73、C.I.分散红82、C.I.分散红153、C.I.分散红60、C.I.分散红74、C.I.分散红177、C.I.分散橙3、C.I.分散橙30、C.I.分散橙25、C.I.分散棕1、C.I.分散黑1、C.I.分散黑9 中的一种,具体用量为相对聚合单体的质量分数0.1-10%。
在本发明的一种实施方式中,所述的乳化剂为十二烷基硫酸钠、十二烷基苯磺酸钠、十二烷基磺酸钠、木质素磺酸钠、失水山梨醇脂肪酸酯、聚氧乙烯辛基酚醚-10、聚氧乙烯山梨糖醇酐单油酸酯、烷基酚聚氧乙烯醚-100、苯乙烯衍生物、马来酸衍生物中的一种或几种,具体用量为相对聚合单体的质量分数为 1-20%。
在本发明的一种实施方式中,所述的助乳化剂为十六烷、十六醇、正丁醇、乙二醇、乙醇、丙二醇、甘油、聚甘油酯中的一种或几种,具体用量为对聚合单体的质量分数为0.1-10%。
在本发明的一种实施方式中,所述的交联单体具体为乙烯基三甲氧基硅烷、乙烯基三乙氧基硅烷中的一种或几种,具体用量为对聚合单体的质量分数为 1-5%。
在本发明的一种实施方式中,所述的引发剂为油溶性引发剂,如偶氮二异丁腈、偶氮二异庚腈中的一种或几种,具体用量为相对聚合单体的质量分数0.1-5%。
在本发明的一种实施方式中,所述S4步骤中的反应温度为60-90℃。
在本发明的一种实施方式中,所述S4步骤中的反应时间为0.5-24h。
本发明提供了一种上述纳米分散染料胶囊在印花方面的应用。
在本发明的一种实施方式中,所述的纺织品包括棉织物、涤纶织物、涤棉织物、麻织物、粘胶织物、锦纶织物中的一种。
在本发明的一种实施方式中,采用制备的纳米分散染料胶囊与增稠剂调浆后,对纺织品进行直接印花,在30-80℃下烘干后,在130-220℃下焙烘1-6min,得到印花纺织品。
本发明的有益效果:
将分散染料与聚合物壳及交联单体复合成纳米胶囊,聚合物壳在印花时作为分散染料的发色场所,使印花织物具有鲜艳的颜色,并提供染料与织物的粘附作用,交联单体在高温焙烘固色时失水交联,提高聚合物壳间的作用力,减少粘合剂的大量使用。该纳米分散染料胶囊应用于纺织品的印花,具有高色牢度、良好手感、颜色鲜艳和适用性广的优点。
附图说明
图1为纳米分散染料胶囊的粒径分布图;
图2为纳米分散染料胶囊的Zeta电位分布图;
图3为纳米分散染料胶囊的透射电子显微镜图;
图4为纳米分散染料胶囊焙烘交联固色机理图。
具体实施方式
以下对本发明的实施例子进行说明,为进一步阐述和理解本发明的优点和特点,但不限制本发明。
粒径和Zeta电位:取0.05mL样品稀释1000倍后,利用Zeta电位及粒径分析仪测试粒子粒径分布及Zeta电位。
色牢度:按照国标GB/29865-2013《纺织品色牢度试验耐摩擦色牢度》测试,按照国标GB/T3921-2008《纺织品色牢度试验耐皂洗色牢度》实验方法A进行皂洗,使用灰色样卡评定摩擦牢度和水洗牢度。
断裂强力:用电子织物强力机测量25cm×5cm的织物的经向断裂强力,每样测试三次,取平均值。
柔软度:在织物上取直径为10cm的圆片,使用PhabrOmeter3仪器对织物进行手感测试。
表观色深值:在染色织物表面任取8个点,使用Datacolor650型台式分光光度测色仪测量染色织物的K/S值及ΔE(色差值)取平均值。
皂洗残液COD:取3mL样品与1mLCOD-1试剂(主要成分重铬酸钾),4mL COD-2(主要成分浓硫酸)试剂混匀后在165℃下,消解15min,冷却至室温后用MI-88S型水质测定仪测样品COD值。
实施例1:
取0.3g十二烷基硫酸钠和0.3g木质素磺酸钠完全溶解于25mL水中得到乳化剂溶液作为水相,取0.7gC.I.分散紫93染料加入5g甲基丙烯酸甲酯、5g丙烯酸丁酯、0.2g十六烷、0.18g乙烯基三甲氧基硅烷和0.15g偶氮二异丁腈中,混合均匀得到油相,在搅拌条件下将油相缓慢加入到水相中进行预乳化。将预乳化后的乳液使用砂磨机进行细乳化制备细乳液。将细乳液在搅拌条件下升温到 70℃,引发聚合反应,反应12h结束后通过过滤去除杂质,得到纳米分散染料胶囊。采用制备的纳米分散染料胶囊对涤棉混纺织物进行直接印花,工艺具体为:取制备所得的纳米分散染料胶囊,添加增稠剂(6%)搅拌均匀后作为印花糊料,采用丝网印花方式对涤棉织物印花,印花后织物在80℃烘干2min,180℃焙烘 5min。
图1为本发明的纳米分散染料胶囊的粒径分布图;
图1表明,纳米分散染料胶囊的平均粒径为309nm;
图2为本发明的C.I.分散紫93分散体和纳米包覆分散染料的Zeta电位分布图;
图2表明,纳米分散染料胶囊的Zeta电位为-55.0mV,说明其具有优秀的分散稳定性;
图3为本发明的纳米分散染料胶囊的透射电子显微镜照片;
图3表明,纳米分散染料胶囊具有明显的核壳结构,尺寸大小与粒径分布曲线相符合,证明纳米分散染料胶囊制备成功;
图4为纳米分散染料胶囊焙烘交联固色机理图;
图4表明,纳米分散染料胶囊的交联单体在焙烘过程中失水交联,提高聚合物间作用力,增加牢度。
本实施例采用实施例1所制备的纳米分散染料胶囊对涤棉混纺织物进行直接印花,工艺具体为:取制备所得的纳米分散染料胶囊,添加增稠剂(6%)搅拌均匀后作为印花糊料,采用丝网印花方式对涤棉织物印花,印花后织物在80℃烘干2min,180℃焙烘5min。
实施例2:
工艺步骤:取0.3g十二烷基苯磺酸钠和0.3g聚氧乙烯辛基酚醚-10完全溶解于25mL水中得到乳化剂溶液作为水相,取0.7gC.I.分散蓝60染料与3g苯乙烯、8g丙烯酸乙酯、0.2g十六醇、0.2g乙烯基三乙氧基硅烷和0.12g偶氮二异庚腈,混合均匀得到油相,在搅拌条件下将油相缓慢加入到水相中进行预乳化。将预乳化后的乳液使用超声细胞粉碎机进行细乳化制备细乳液。将细乳液在搅拌条件下升温到75℃,引发聚合反应,反应16h结束后通过过滤去除杂质,得到纳米分散染料胶囊。采用制备的纳米分散染料胶囊对涤棉混纺织物进行直接印花,工艺具体为:取制备所得的纳米分散染料胶囊,添加增稠剂(6%)搅拌均匀后作为印花糊料,采用丝网印花方式对涤棉织物印花,印花后织物在80℃烘干2 min,200℃焙烘5min。
实施例3:
工艺步骤:取0.3g十二烷基硫酸钠、0.3g木质素磺酸钠和0.1g烷基酚聚氧乙烯醚-100完全溶解于25mL水中得到乳化剂溶液作为水相,取1.0gC.I.分散橙30染料与4g苯乙烯、5g丙烯酸丁酯、5g丙烯酸乙酯、0.3g十六醇、0.12g 乙烯基三乙氧基硅烷、0.12g乙烯基三甲氧基硅烷和0.15g偶氮二异丁腈混合均匀得到油相,在搅拌条件下将油相缓慢加入到水相中进行预乳化。将预乳化后的乳液使用乳化机进行细乳化制备细乳液。将细乳液在搅拌条件下升温到75℃,引发聚合反应,反应24h结束后通过过滤去除杂质,得到纳米分散染料胶囊。采用制备的纳米分散染料胶囊对棉织物进行直接印花,工艺具体为:取制备所得的纳米分散染料胶囊,添加增稠剂(6%)搅拌均匀后作为印花糊料,采用丝网印花方式对棉织物印花,印花后织物在70℃烘干5min,190℃焙烘5min。
对比例1:
使用颜料红122(3%),水(58%)与增稠剂(7%)和粘合剂(30%)进行复配得到印花色浆,对涤棉混纺织物采用丝网印花方式对涤棉织物印花,印花后织物在120℃烘干10min。
对比例2:
使用颜料红122(4%)、水(42%)与增稠剂(8%)和粘合剂(40%)进行复配得到印花色浆,对涤棉混纺织物采用丝网印花方式对棉织物印花,印花后织物在120℃烘干10min。
表1
表1显示,相较于颜料印花,纳米分散染料胶囊印花涤棉织物在色深度相近的情况下,各项色牢度均达4-5级,强力有小幅度提高,表明交联单体有效在胶囊间形成交联,皂洗残液COD值可显著降低,并且柔软度有明显提高。说明制备的纳米分散染料胶囊利用其聚合物壳层及交联单体的作用牢固的附着在织物上,具有优异的色牢度,并且分散染料在聚合物内发色,具有良好的颜色性能。
表2
表2显示,相较于颜料印花,纳米分散染料胶囊印花棉织物在色深度相近的情况下,各项色牢度均达4级或4-5级,较其有小幅度提高,同时断裂强力提升约6.9%,皂洗残液COD值可降低24%,并且柔软度有明显提高。说明制备的纳米分散染料胶囊可以利用其聚合物壳层及交联单体的作用牢固的粘附固定在棉织物上,具有优异的色牢度,并且分散染料在聚合物内发色,具有良好的颜色性能。
Claims (9)
1.一种纺织品印花用纳米分散染料胶囊的制备方法,其特征在于,包括以下步骤:
S1:取一定量的乳化剂,完全溶解于水中得到乳化剂溶液作为水相;
S2:取一定量的分散染料加入到聚合单体、助乳化剂、交联单体和引发剂中,混合均匀得到油相,在搅拌条件下将油相缓慢加入到水相中进行预乳化;
S3:将预乳化后的乳液使用砂磨机、超声细胞粉碎机或乳化机进行细乳化制备细乳液;
S4:将细乳液在搅拌条件下升温到反应温度,引发聚合反应,反应结束后通过过滤去除杂质,得到纳米分散染料胶囊。
2.根据权利要求1所述的纺织品印花用纳米分散染料胶囊的制备方法,其特征在于:所述的聚合单体含有芳基或酯基结构,包括苯乙烯、丙烯酸甲酯、甲基丙烯酸甲酯、甲基丙烯酸乙酯、甲基丙烯酸丁酯、丙烯酸异辛酯、丙烯酸乙酯、丙烯酸-2-乙基己酯、丙烯酸丁酯中的一种或几种,其比例为任意比例,具体总量为相对聚合反应体系的质量分数10-40%。
3.根据权利要求1所述的纺织品印花用纳米分散染料胶囊的制备方法,其特征在于:所述的分散染料包括C.I.分散紫93、C.I.分散黄23、C.I.分散黄42、C.I.分散黄211、C.I.分散蓝60、C.I.分散蓝79、C.I.分散蓝291、C.I.分散蓝183、C.I.分散蓝56、C.I.分散蓝79、C.I.分散红73、C.I.分散红82、C.I.分散红153、C.I.分散红60、C.I.分散红74、C.I.分散红177、C.I.分散橙3、C.I.分散橙30、C.I.分散橙25、C.I.分散棕1、C.I.分散黑1、C.I.分散黑9中的一种,具体用量为相对聚合单体的质量分数0.1-10%。
4.根据权利要求1所述的纺织品印花用纳米分散染料胶囊的制备方法,其特征在于:所述的乳化剂为十二烷基硫酸钠、十二烷基苯磺酸钠、十二烷基磺酸钠、木质素磺酸钠、失水山梨醇脂肪酸酯、聚氧乙烯辛基酚醚-10、聚氧乙烯山梨糖醇酐单油酸酯、烷基酚聚氧乙烯醚-100、苯乙烯衍生物、马来酸衍生物中的一种或几种,具体用量为相对聚合单体的质量分数为1-20%。
5.根据权利要求1所述的纺织品印花用纳米分散染料胶囊的制备方法,其特征在于:所述的助乳化剂为十六烷、十六醇、正丁醇、乙二醇、乙醇、丙二醇、甘油、聚甘油酯中的一种或几种,具体用量为对聚合单体的质量分数为0.1-10%。
6.根据权利要求1所述的纺织品印花用纳米分散染料胶囊的制备方法,其特征在于:所述的交联单体具体为乙烯基三甲氧基硅烷、乙烯基三乙氧基硅烷中的一种或几种,具体用量为对聚合单体的质量分数为1-5%。
7.根据权利要求1所述的纺织品印花用纳米分散染料胶囊的制备方法,其特征在于:所述的引发剂为油溶性引发剂,如偶氮二异丁腈、偶氮二异庚腈中的一种或几种,具体用量为相对聚合单体的质量分数0.1-5%。
8.根据权利要求1所述的纺织品印花用纳米分散染料胶囊的制备方法,其特征在于:所述S4步骤中的反应温度为60-90℃。
9.根据权利要求1所述的纺织品印花用纳米分散染料胶囊的制备方法,其特征在于:所述S4步骤中的反应时间为0.5-24h。
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