CN114654839A - 一种敞篷车软顶复合材料及其制备方法 - Google Patents

一种敞篷车软顶复合材料及其制备方法 Download PDF

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CN114654839A
CN114654839A CN202210262874.9A CN202210262874A CN114654839A CN 114654839 A CN114654839 A CN 114654839A CN 202210262874 A CN202210262874 A CN 202210262874A CN 114654839 A CN114654839 A CN 114654839A
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白健洪
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    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B27/00Layered products comprising a layer of synthetic resin
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    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
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    • B32LAYERED PRODUCTS
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    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/043Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J7/00Non-fixed roofs; Roofs with movable panels, e.g. rotary sunroofs
    • B60J7/08Non-fixed roofs; Roofs with movable panels, e.g. rotary sunroofs of non-sliding type, i.e. movable or removable roofs or panels, e.g. let-down tops or roofs capable of being easily detached or of assuming a collapsed or inoperative position
    • B60J7/12Non-fixed roofs; Roofs with movable panels, e.g. rotary sunroofs of non-sliding type, i.e. movable or removable roofs or panels, e.g. let-down tops or roofs capable of being easily detached or of assuming a collapsed or inoperative position foldable; Tensioning mechanisms therefor, e.g. struts
    • B60J7/1226Soft tops for convertible vehicles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J7/00Non-fixed roofs; Roofs with movable panels, e.g. rotary sunroofs
    • B60J7/08Non-fixed roofs; Roofs with movable panels, e.g. rotary sunroofs of non-sliding type, i.e. movable or removable roofs or panels, e.g. let-down tops or roofs capable of being easily detached or of assuming a collapsed or inoperative position
    • B60J7/12Non-fixed roofs; Roofs with movable panels, e.g. rotary sunroofs of non-sliding type, i.e. movable or removable roofs or panels, e.g. let-down tops or roofs capable of being easily detached or of assuming a collapsed or inoperative position foldable; Tensioning mechanisms therefor, e.g. struts
    • B60J7/1226Soft tops for convertible vehicles
    • B60J7/126Soft tops for convertible vehicles for landaulet-type vehicles, i.e. using a collapsible upper structure of the vehicle body
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • B32B2262/0284Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
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    • B32LAYERED PRODUCTS
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Abstract

本发明公开了一种敞篷车软顶复合材料及其制备方法,涉及汽车软顶材料技术领域,所述的敞篷车软顶复合材料包括外饰面、中间层、内饰面;所述的外饰面为机织面料、仿皮材料、真皮材料中的一种;所述的中间层的原料组分为丁基橡胶或卤代丁基橡胶;所述的内饰面为机织面料、仿皮材料、真皮材料中的一种。本发明提供的敞篷车软顶复合材料具有优异的防水耐候性、粘结性能、气密性、隔音效果、抗光老化性、耐化学品性能,使用寿命10年以上。

Description

一种敞篷车软顶复合材料及其制备方法
技术领域
本发明涉及汽车软顶材料技术领域,具体涉及一种敞篷车软顶复合材料及其制备方法。
背景技术
敞篷车是一种常见车辆种类,按照车顶的结构可以分成硬顶车和软顶车。软顶车更为常见,通常采用帆布,乙烯或塑料为车顶材料,配以可折叠的支架。然而现有的敞篷车软顶材料的防水性能差、气密性差、隔音效果差、抗光老化的性能差、使用寿命较短。无法满足消费者对于敞篷车软顶材料的各项性能的需求。
发明内容
针对现有技术中的缺陷,本发明提供一种敞篷车软顶复合材料及其制备方法。本发明提供的敞篷车软顶复合材料具有优异的防水耐候性、粘结性能、气密性、隔音效果、抗光老化性、耐化学品性能,使用寿命10年以上。
本发明的一个目的在于保护一种敞篷车软顶复合材料。其中,所述的敞篷车软顶复合材料包括外饰面、中间层、内饰面;所述的外饰面为机织面料、仿皮材料、真皮材料中的一种;所述的中间层的原料组分为丁基橡胶或卤代丁基橡胶;所述的内饰面为机织面料、仿皮材料、真皮材料中的一种。
优选地,所述的机织面料为PET机织面料;所述的仿皮材料为PVC人造革、TPU蒙皮、TPO蒙皮中的一种;所述的真皮材料为牛皮或羊皮。
进一步优选地,所述的PET机织面料为PET色纺短纤纱机织面料NO:7008;或PET色纺短纤纱机织面料JM7053;所述的TPU蒙皮为BS3590-G;所述的TPO蒙皮为ARP2025/045。
优选地,所述的卤代丁基橡胶为氯化丁基橡胶或溴化丁基橡胶。
进一步优选地,所述的丁基橡胶为IIR 1751、IIR 1751F、IIR BK 1675N中的一种或多种;所述的卤代丁基橡胶为BIIR 2211、BIIR 2222、BIIR 2235、BIIR 2244、BIIR 2255、CIIR 1065、CIIR 1066、CIIR 1068中的一种或多种。
优选地,所述的敞篷车软顶复合材料的门幅为1-1.5m,厚度为0.8-2.5mm。
本发明的另一个目的在于保护上述的敞篷车软顶复合材料的制备方法,步骤如下:
S1.采用挤出机将丁基橡胶或卤代丁基橡胶进行挤出,制得橡胶卷材,加热硫化,制得中间层;
S2.从上到下将外饰面、中间层、内饰面进行复合,制得所述的敞篷车软顶复合材料。
优选地,步骤S1中,所述的加热硫化的温度为175-205℃,加热硫化的时间为60-180S。
优选地,步骤S2中,所述的复合的压力为0.1-1kg/cm2
本发明的有益效果体现在:
(1)本发明提供的敞篷车软顶复合材料的中间层的原料采用丁基橡胶或卤代丁基橡胶,具有良好的防水性和气密性,使用在寿命10年以上。
(2)本发明提供的敞篷车软顶复合材料的外饰面具有优异的抗光老化性能。
(3)本发明提供的敞篷车软顶复合材料具有较好的NVH声学属性,可以有效隔绝外界噪音。
(4)本发明提供的敞篷车软顶复合材料的制备方法操作简单、技术稳定、原料易得、制得的产品性优异、极具商业价值。
具体实施方式
下面将对本发明技术方案的实施例进行详细的描述。以下实施例仅用于更加清楚地说明本发明的技术方案,因此只作为示例,而不能以此来限制本发明的保护范围。
需要注意的是,除非另有说明,本申请使用的技术术语或者科学术语应当为本发明所属领域技术人员所理解的通常意义。
实施例中采用的原料的来源如下:
PET机织面料:嘉兴成晴纺织品有限公司;
CIIR、BIIR:埃克森EXXON;
TPU/TPO蒙皮:中山博锐斯新材料股份有限公司;
PVC人造革:中山博锐斯新材料股份有限公司。
实施例1
本实施例提供了一种敞篷车软顶复合材料,敞篷车软顶复合材料包括外饰面、中间层、内饰面;
外饰面为PET色纺短纤纱机织面料NO:7008;
中间层的原料组分为BIIR 2211;中间层的厚度为0.5mm。
内饰面为PET色纺短纤纱机织面料JM7053;
本实施例还提供了上述的敞篷车软顶复合材料的制备方法,步骤如下:
S1.采用挤出机将丁基橡胶或卤代丁基橡胶进行挤出,制得橡胶卷材,加热硫化,制得中间层;
S2.从上到下将外饰面、中间层、内饰面进行复合,制得所述的敞篷车软顶复合材料。
步骤S2中,加热硫化的温度为190℃,加热硫化的时间为120S。
步骤S2中,复合的压力为0.5kg/cm2
实施例2
本实施例提供了一种敞篷车软顶复合材料,敞篷车软顶复合材料包括外饰面、中间层、内饰面;
外饰面为PET色纺短纤纱机织面料NO:7008;
中间层的原料组分为BIIR 2222;中间层的厚度为0.5mm。
内饰面为PVC人造革;
本实施例还提供了上述的敞篷车软顶复合材料的制备方法,步骤如下:
S1.采用挤出机将丁基橡胶或卤代丁基橡胶进行挤出,制得橡胶卷材,加热硫化,制得中间层;
S2.从上到下将外饰面、中间层、内饰面进行复合,制得所述的敞篷车软顶复合材料。
步骤S2中,加热硫化的温度为190℃,加热硫化的时间为120S。
步骤S2中,复合的压力为0.5kg/cm2
实施例3
本实施例提供了一种敞篷车软顶复合材料,敞篷车软顶复合材料包括外饰面、中间层、内饰面;
外饰面为PET色纺短纤纱机织面料NO:7008;
中间层的原料组分为CIIR;中间层的厚度为0.5mm。
内饰面为TPO蒙皮;
本实施例还提供了上述的敞篷车软顶复合材料的制备方法,步骤如下:
S1.采用挤出机将丁基橡胶或卤代丁基橡胶进行挤出,制得橡胶卷材,加热硫化,制得中间层;
S2.从上到下将外饰面、中间层、内饰面进行复合,制得所述的敞篷车软顶复合材料。
步骤S2中,加热硫化的温度为190℃,加热硫化的时间为120S。
步骤S2中,复合的压力为0.5kg/cm2
实施例4
本实施例提供了一种敞篷车软顶复合材料,敞篷车软顶复合材料包括外饰面、中间层、内饰面;
外饰面为机织面料PET机织面料7008JM7053;
中间层的原料组分为CIIR 1065;中间层的厚度为0.5mm。
内饰面为TPU蒙皮BS3590-G;
本实施例还提供了上述的敞篷车软顶复合材料的制备方法,步骤如下:
S1.采用挤出机将丁基橡胶或卤代丁基橡胶进行挤出,制得橡胶卷材,加热硫化,制得中间层;
S2.从上到下将外饰面、中间层、内饰面进行复合,制得所述的敞篷车软顶复合材料。
步骤S2中,加热硫化的温度为190℃,加热硫化的时间为120S。
步骤S2中,复合的压力为0.5kg/cm2
实施例5
本实施例提供了一种敞篷车软顶复合材料,敞篷车软顶复合材料包括外饰面、中间层、内饰面;
外饰面为PET色纺短纤纱机织面料NO:7008;
中间层的原料组分为CIIR 1066;中间层的厚度为0.5mm。
内饰面为牛皮,厚度为0.5mm;
本实施例还提供了上述的敞篷车软顶复合材料的制备方法,步骤如下:
S1.采用挤出机将丁基橡胶或卤代丁基橡胶进行挤出,制得橡胶卷材,加热硫化,制得中间层;
S2.从上到下将外饰面、中间层、内饰面进行复合,制得所述的敞篷车软顶复合材料。
步骤S2中,加热硫化的温度为190℃,加热硫化的时间为120S。
步骤S2中,复合的压力为0.5kg/cm2
试验例
对实施例1-5制得的敞篷车软顶复合材料进行性能测试,结果见表1
表1
Figure BDA0003551318170000061
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围,其均应涵盖在本发明的权利要求和说明书的范围当中。

Claims (9)

1.一种敞篷车软顶复合材料,其特征在于:所述的敞篷车软顶复合材料包括外饰面、中间层、内饰面;所述的外饰面为机织面料、仿皮材料、真皮材料中的一种;所述的中间层的原料组分为丁基橡胶或卤代丁基橡胶;所述的内饰面为机织面料、仿皮材料、真皮材料中的一种。
2.根据权利要求1所述的敞篷车软顶复合材料,其特征在于:所述的机织面料为PET机织面料;所述的仿皮材料为PVC人造革、TPU蒙皮、TPO蒙皮中的一种;所述的真皮材料为牛皮或羊皮。
3.根据权利要求2所述的敞篷车软顶复合材料,其特征在于:所述的PET机织面料为PET色纺短纤纱机织面料NO:7008或PET色纺短纤纱机织面料JM7053;所述的TPU蒙皮为BS3590-G;所述的TPO蒙皮为ARP2025/045。
4.根据权利要求1所述的敞篷车软顶复合材料,其特征在于:所述的卤代丁基橡胶为氯化丁基橡胶或溴化丁基橡胶。
5.根据权利要求4所述的敞篷车软顶复合材料,其特征在于:所述的丁基橡胶为IIR1751、IIR 1751F、IIR BK 1675N中的一种或多种;所述的卤代丁基橡胶为BIIR 2211、BIIR2222、BIIR 2235、BIIR 2244、BIIR 2255、CIIR 1065、CIIR 1066、CIIR 1068中的一种或多种。
6.根据权利要求1所述的敞篷车软顶复合材料,其特征在于:所述的敞篷车软顶复合材料的门幅为1-1.5m,厚度为0.8-2.5mm。
7.权利要求1-6任一所述的敞篷车软顶复合材料的制备方法,其特征在于:所述的制备方法,步骤如下:
S1.采用挤出机将丁基橡胶或卤代丁基橡胶进行挤出,制得橡胶卷材,加热硫化,制得中间层;
S2.从上到下将外饰面、中间层、内饰面进行复合,制得所述的敞篷车软顶复合材料。
8.根据权利要求7所述的敞篷车软顶复合材料的制备方法,其特征在于:步骤S1中,所述的加热硫化的温度为175-205℃,加热硫化的时间为60-180S。
9.根据权利要求7所述的敞篷车软顶复合材料的制备方法,其特征在于:步骤S2中,所述的复合的压力为0.1-1kg/cm2
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