CN114617810A - Natural bamboo fiber wet tissue containing low-harm liquid medicine - Google Patents

Natural bamboo fiber wet tissue containing low-harm liquid medicine Download PDF

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Publication number
CN114617810A
CN114617810A CN202011531326.9A CN202011531326A CN114617810A CN 114617810 A CN114617810 A CN 114617810A CN 202011531326 A CN202011531326 A CN 202011531326A CN 114617810 A CN114617810 A CN 114617810A
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bamboo fiber
wet
natural
natural bamboo
liquid medicine
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李相镐
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Health Organization Co ltd
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Health Organization Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47KSANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00Body-drying implements; Toilet paper; Holders therefor
    • A47K10/16Paper towels; Toilet paper; Holders therefor
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47KSANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00Body-drying implements; Toilet paper; Holders therefor
    • A47K10/16Paper towels; Toilet paper; Holders therefor
    • A47K10/18Holders; Receptacles
    • A47K10/20Holders; Receptacles for piled sheets
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47KSANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K7/00Body washing or cleaning implements
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208Tissues; Wipes; Patches
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35Ketones, e.g. benzophenone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • A61K8/375Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/602Glycosides, e.g. rutin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06Paper forming aids
    • D21H21/10Retention agents or drainage improvers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002Tissue paper; Absorbent paper
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52Stabilizers
    • A61K2800/524Preservatives

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
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  • Mycology (AREA)
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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a natural bamboo fiber wet tissue which comprises 100% of pure natural bamboo fiber fabric and low-harm liquid medicine with low harm to human bodies and liquid medicine components only consisting of stability-certified EWG primary raw materials.

Description

Natural bamboo fiber wet tissue containing low-harm liquid medicine
Technical Field
The invention relates to a natural bamboo fiber wet tissue containing low-harm liquid medicine.
Background
The wet tissue is a tissue made of paper pulp and is used for various aspects of cleaning and sanitation, cleaning, dish washing, makeup removal and the like, such as skin cleaning and the like.
The wet tissue is a product with the fabric soaked with the liquid medicine, and has the condition that bacteria are easy to propagate because the wet tissue is always in a soaking state. Therefore, in addition to purified water, a preservative must be used for bacteriostasis.
Synthetic preservatives are widely used as preservatives, with the Paraben component being the most representative. However, there are some harmful problems, such as that Paraben causes skin diseases such as allergy or rash, erythema or skin inflammation.
For this reason, attempts are being made to find alternatives to various types of synthetic preservatives. For example, products using a part of natural extracts have been developed [ patent documents 1 and 2], but the natural extracts have not been commercialized because of problems such as poor color and stability.
Disclosure of Invention
Documents of the prior art
KR 10-1533195B (2015.07.02, notice)
KR 10-2013-0028196(2013.03.19, bulletin)
Problems to be solved
In the invention, in order to be more beneficial to commercialization, the wet tissue is prepared by soaking the fabric in the liquid medicine which is only composed of substances with low harm to human bodies and proved stability, so that the problems of allergy or skin in the past can be solved.
Therefore, the invention aims to provide a natural bamboo fiber wet tissue which comprises a low-harm liquid medicine obtained by soaking a bamboo fiber fabric in a liquid medicine only containing a primary substance of an Environmental Working Group (EWG).
Means for solving the problems
In order to achieve the purpose, the invention provides a natural bamboo fiber wet tissue with a natural bamboo fiber fabric soaked in a low-harm liquid medicine.
The low-hazard liquid medicine comprises purified water, a preservative, a skin conditioner, a natural surfactant, a humectant and additives, but only uses EWG primary raw materials.
Specifically, the preservatives are hydroxyacetophenone and 1, 2-hexanediol, the skin conditioner is centella asiatica extract, the natural surfactant is coco-glucoside, the moisturizer is methyl propylene glycol, and the additives are ethylhexyl glycerin and glyceryl caprylate.
The water content of each piece of the natural bamboo fiber fabric is more than 70 weight percent, and the water loss rate after 30 minutes is less than 5 weight percent compared with the initial water content.
In addition, the gram weight of the natural bamboo fiber fabric is 30-80 gsm, and the thickness of the natural bamboo fiber fabric is 0.3-0.8 mm.
Effects of the invention
The fabric used by the wet tissue is 100% natural bamboo fiber fabric and is prepared by only using liquid medicine of EWG primary raw material with low harm to human body and confirmed stability.
The natural bamboo fiber wet tissue has the advantages that due to the characteristics of bamboo, namely the deodorizing and antibacterial effects, the harm of low-harm liquid medicine components is low, and the stability is high, so that the skin irritation problems such as rash, erythema or skin inflammation and the like when the wet tissue is used can be reduced to the greatest extent. In addition, the components do not change even if the food is stored for a long time, and the food has good endurance and can effectively prevent the propagation of bacteria.
Detailed description of the invention
The wet tissue is prepared by soaking the fabric in the liquid medicine, and comprises disposable wet tissues such as cleaning wet tissues, face washing wet tissues, toilet wet tissues, infant wet tissues, multipurpose wet tissues, makeup removing wet tissues and female physiological wet tissues.
The fabric and the liquid medicine of the wet tissue are made of environment-friendly materials.
The fabric of the wet tissue is made of 100% pure natural bamboo fiber materials and does not contain other natural or synthetic fibers except the bamboo fibers.
The wet tissue liquid medicine only uses EWG first grade raw materials. The Environmental Working Group (EWG) rating is an assessment of the hazard and stability of ingredients, and the lower this figure, the less hazardous and safer.
The present invention will be specifically explained below.
The invention relates to a wet tissue which is prepared by soaking a natural bamboo fiber wet tissue fabric in a low-harm liquid medicine, wherein the low-harm liquid medicine comprises purified water; a preservative; a skin conditioner; a natural surfactant; a humectant; and additives, wherein except for purified water, only EWG primary raw material is used as other ingredients.
Low harm medicinal liquid component
The purified water of the low-harm liquid medicine is purified water filtered by a filtering device through 2 to 8 procedures. The filtering device is formed by combining and connecting various technologies such as precise filtering, reverse osmosis filtering, activated carbon filtering, ultraviolet sterilization and the like in series, is safe from bacteria or germs, and removes substances harmful to human bodies.
The preservative is used together with Hydroxyacetophenone (Hydroxyacetophenone) and 1, 2-Hexanediol (1, 2-Hexanediol). The hydroxyacetophenone and 1, 2-hexanediol are first-class materials of the EWG, and can replace the conventionally used parabens.
In addition to the preservative effect, hydroxyacetophenone is also excellent in stability at any temperature and pH. In addition, the 1, 2-hexanediol is used in a small amount, has a good antiseptic effect, has good moisture retention and antibacterial properties, and has a surfactant structure, so that the mixing degree with other components is high. However, if the amount of the surfactant is excessively added, the viscosity of the chemical solution needs to be greatly reduced and the content needs to be controlled.
The hydroxyacetophenone and the 1, 2-hexanediol are mixed for use in the invention, so that the preservative and the antibacterial power are improved compared with those of respective use, and compared with the conventional hydroxybenzoate preservative, the preservative has the advantages of obviously better preservative performance and less skin irritation. In particular, the hydroxyacetophenone and 1, 2-hexanediol may be included in a weight ratio of 1:10 to 10:1, preferably 1:1 to 5:1, most preferably 1:1 to 3: 1.
The preservative comprising hydroxyacetophenone and 1, 2-hexanediol is used in an amount of 0.1 to 10 parts by weight and 1 to 5 parts by weight per 100 parts by weight of purified water. If the content is less than the range, the degree of preservation sufficient to replace the conventionally used chemical preservative (i.e., hydroxybenzoate) is not attained, but even if it exceeds the range, the effect is improved to a very small extent and it is uneconomical.
The skin conditioner may be Centella Asiatica Extract (Centella Asiatica Extract) which is the primary substance of EWG. The centella asiatica extract comprises saponin (sapogenins) madecassoside (madecassoside), asiaticoside (asiaticoside) as an effective ingredient, and Asiatic acid (asiaticic acid) and madecassic acid (madecassic acid) as triterpenes (triterpenes) ingredients, and has skin regeneration, antibacterial, antiinflammatory, antioxidant, and skin color improving effects. The centella asiatica extract is obtained by extracting the stem, leaf, root, etc. of centella asiatica with an extraction solvent, i.e., water and/or an organic solvent (ethanol, methanol). The extract means a liquid or solid extract obtained by removing an extraction solvent by freeze drying, vacuum drying, hot air drying, spray drying or the like and then concentrating.
The centella asiatica extract is preferably used in an amount of 0.01 to 10 parts by weight, and 0.1 to 3 parts by weight, based on 100 parts by weight of purified water. Below this range, the desired skin conditioning effect is not achieved, whereas if it exceeds this range, skin problems may be caused.
The surfactant may be a natural surfactant, and well-known products may be used except those harmful to the human body and forbidden. Preferably, the natural surfactant is Decyl Glucoside (Decyl Glucoside), Coco-Glucoside (Coco-Glucoside), Lauryl sugar (Lauryl Glucoside), or apple amino acid foaming agent (apple wash), and Coco-Glucoside (Coco-Glucoside), which is an EWG grade, is used in the present invention. The coco-glucoside is a condensation reaction product of coconut alcohol and glucose, is derived from corn, coconut and palm kernel oils, and can be used for sensitive and fragile skin.
The natural surfactant is preferably used in an amount of 0.01 to 10 parts by weight, 0.5 to 5 parts by weight, relative to 100 parts by weight of purified water. If the amount is less than the above range, the mixing of the components of the liquid medicine cannot be smoothly achieved, whereas if the amount exceeds the above range, skin troubles may be caused or it is uneconomical.
The humectant is used for supplementing and maintaining water, and can be methyl propylene glycol, amyl glycol (amyl glycol), octyl glycol (caprylyl glycol) and the like, and the EWG primary substance methyl propylene glycol is used in the invention.
The humectant is preferably used in an amount of 0.01 to 10 parts by weight, 1 to 8 parts by weight, relative to 100 parts by weight of purified water. Below the range, the moisturizing effect is not obtained, whereas if it exceeds the range, the viscosity increases, thereby decreasing the stability of the components of the liquid medicine.
In addition to the components, conventionally used additives may be included.
Additives that may be used may be pH adjusters, modifiers, corrosion inhibitors, metal ion blocking agents, sweeteners, static electricity protectors, preservatives, meltable agents, antibacterial agents, deodorants, perfumes, and the like. The invention uses EWG primary substances of ethylhexyl glycerin (Ethylhexylglycerin) and Glyceryl Caprylate (Glyceryl caproate) as additives to achieve the skin conditioning effect and simultaneously supplement the preservative effect.
Ethylhexyl glycerin is a vegetable glycerin derived from nature, has a strong moisturizing power, and is used as the skin conditioner and the antiseptic auxiliary. Such ethylhexyl glycerin is preferably used in an amount of 0.01 to 5 parts by weight, 0.1 to 1 part by weight, relative to 100 parts by weight of purified water. The effect is not achieved below the range, whereas if the range is exceeded, the viscosity increases, thereby decreasing the stability of the components of the liquid medicine.
Caprylin is an auxiliary emulsifier, has strong antibacterial power and is known as a natural preservative. The glyceryl caprylate is preferably used in an amount of 0.01 to 5 parts by weight, 0.1 to 1 part by weight, relative to 100 parts by weight of purified water. The effect is not achieved below the range, whereas it is uneconomical because there is not much improvement in the effect beyond the range.
According to one embodiment of the present invention, the low-risk liquid medicine includes purified water, preservatives, skin conditioners, natural surfactants, moisturizers and additives, but only the EWG grade material is used for each ingredient.
Specifically, in the low-risk medicinal liquid composition, the preservatives are hydroxyacetophenone and 1, 2-hexanediol, the skin conditioner is centella asiatica extract, the natural surfactant is coco-glucoside, the moisturizer is methyl propylene glycol, and the additives are ethylhexyl glycerin and caprylic glyceride.
More specifically, the low-risk medical solution of the present invention is composed of, with respect to 100 parts by weight of purified water, 0.1 to 10 parts by weight of hydroxyacetophenone and 1, 2-hexanediol, 0.01 to 10 parts by weight of centella asiatica extract, 0.01 to 10 parts by weight of coco-glucoside, 0.01 to 10 parts by weight of methyl propylene glycol, 0.01 to 5 parts by weight of ethylhexyl glycerin, and 0.01 to 5 parts by weight of glyceryl caprylate.
Bamboo fiber fabric
On the other hand, the bamboo fiber wet tissue disclosed by the invention is made of a fabric made of 100% pure natural bamboo fibers.
The natural bamboo fiber fabric is a pure plant natural fiber material, also called breathable fiber, and is natural cellulose fiber extracted from pure bamboo pulp.
The gram weight (gram per square meter) of the natural bamboo fiber fabric is 30-80 gsm and 35-75 gsm, and the natural bamboo fiber fabric is moderate in thickness when in use, so that the natural bamboo fiber fabric is comfortable to use, and can keep certain strength for absorbing water, oil and other pollutants. In addition, the thickness is 0.3 to 0.8mm, 0.35 to 0.75 mm. The thickness of the natural bamboo fiber fabric can be prepared according to the application, can be thicker or thinner than the range, and can be prepared into a layered form with more than 2 layers if necessary.
The natural bamboo fiber fabric according to the present invention having these basic conditions has physical properties such as moisture content, moisture retention, strength, and elongation to be provided as a wet wipe, by parameter limitation of a dry state and a wet state.
The moisture content (moisture content) is a moisture content at which the moisture content of the sample reaches the moisture equilibrium from a relatively low moisture content in a standard state.
The water content means: the weight of the sample in a wet state is a, and the weight of the sample after drying is b, and the water content is calculated by the following equation 1.
[ mathematical formula 1]
Water content (%) - (a-b) ÷ a × 100
The sample size was 19.2 cm by 0.51 mm (length by width by height), and was a sheet of bamboo fiber fabric having a grammage of 65gsm, and the moisture content was taken as an average of 50 samples.
The weight a of the sample in the wet state is a value measured after a piece of bamboo fiber fabric is soaked in distilled water for 24 hours to naturally absorb moisture and the moisture is balanced. In order to realize the moisture balance, the bamboo fiber fabric before impregnation is placed at the temperature of a drying oven of 100 ℃ for 24 hours, and is used after moisture is completely removed.
The weight b of the sample in the dry state is a value measured after the bamboo fiber fabric is left at a temperature of 100 ℃ in a drying oven for 24 hours and the moisture is completely removed.
The water content of the natural bamboo fiber fabric measured according to the formula 1 is 70-85 wt% and 71-84 wt%. The range of water content is a value that can supplement unnecessary natural evaporation during use or storage. In addition, when the water content is too small or too large, inconvenience in use is caused, and therefore, the range is preferable.
Wet wipes having such a range of moisture content, even when in use, minimize moisture evaporation, and in view of a sufficient feeling of wetness during use, particularly when the wet wipes are used for a period of time, it is necessary to maintain a suitable level of moisture within 30 minutes. The moisture retention may be referred to as a moisturizing ability, and a change in moisture content within 30 minutes, that is, a moisture evaporation rate, may be confirmed by measurement.
The water evaporation rate is measured based on the wet state, and specifically, if the weight of the sample in the wet state is a 'and the weight of the sample after 30 minutes is b', the water evaporation rate after 30 minutes is calculated as shown in the following equation 2.
[ mathematical formula 2]
Water evaporation rate (%) after 30 minutes (a ' -b ')/(a ' x 100)
The sample size was 19.2 cm by 0.51 mm (length, width, height) and the water evaporation rate was an average of 50 samples, which is a piece of bamboo fiber fabric having a grammage of 65 gsm.
The weight a' of the sample in a wet state is a value measured after a piece of bamboo fiber fabric is soaked in distilled water for 24 hours to naturally absorb moisture and reach moisture balance. In order to realize the moisture balance, the bamboo fiber fabric before impregnation is placed at a drying oven temperature of 100 ℃ for 24 hours, and is used after moisture is completely removed.
The weight b' of the sample after 30 minutes is a value of the bamboo fiber fabric measured after the sample in a wet state is left at 25 ℃ and 40% relative humidity for 30 minutes.
The range of the moisture evaporation rate measured according to the above formula 2 of the bamboo fiber fabric according to the present invention is 5 wt% or less and 4.5 wt% or less. The moisture evaporation rate of the wet tissue after 30 minutes is related to the function and the economical efficiency of the wet tissue, and the new wet tissue is needed because the wet tissue is inconvenient to use when the moisture is easily volatilized. The moisture volatilization of the green natural bamboo fiber wet tissue related by the invention in the service life is reduced to the minimum, the moisture evaporation rate after 30 minutes is reduced to below 5 weight percent, and the wet state with high moisture content can be kept when in use.
On the other hand, the wet towel is used by repeated up-and-down or left-and-right movements, and friction is generated by the movements, so that the surface of the wet towel is worn or pilling, and the wet towel may be torn even when the wet towel is seriously worn. To prevent this, the wet wipe must have a tensile strength and elongation in the dry and wet states above a certain level.
The dry tensile strength, wet tensile strength, dry elongation and wet elongation were measured by KS K0521: 2017, the section method, at which time the sample was prepared into a 5cm by 15 cm rectangle, the gauge length was set to 100 mm on a static tensile testing machine, 3 preliminary experiments were performed, and after confirming the elongation at break, the gauge length, the tensile speed were set and the final experiments were performed. The test was conducted by stretching in the longitudinal direction and the transverse direction, respectively, and 5 sets of test pieces were prepared in each direction, and each set was measured 5 times, and the average values of the measured values were tensile strength (N) and elongation (%) in each direction.
And the dry tensile strength and the dry elongation are placed at the temperature of a drying oven of 100 ℃ for 24 hours, the moisture in the sample is completely removed, and then the test is carried out, and the wet tensile strength and the wet elongation are measured after the sample is soaked in distilled water for natural moisture absorption within 24 hours after the dry state, and the moisture is balanced.
The bamboo fiber fabric has longitudinal dry tensile strength of 30-50N/5 cm and 32-48N/5 cm, and transverse dry tensile strength of 15-30N/5 cm and 15-28N/5 cm. In addition, the longitudinal wet tensile strength is 8-15N/5 cm and 9-14N/5 cm, and the transverse wet tensile strength is 4-10N/5 cm and 4.5-9.5N/5 cm.
When the wet tissue has dry and wet tensile strength within the range, the wet tissue has good use comfort and can not be torn when in use. In this case, the wet towel feels soft when the transverse wet tensile strength is high, so that the transverse wet tensile strength is high to prevent damage during use.
In addition, the wet wipe is damaged in terms of wiping properties and tearing properties, and the wet tensile strength and the dry tensile strength are related to each other. Specifically, the ratio of the dry tensile strength in the machine direction/the dry tensile strength in the cross direction is preferably 1.5 to 3 and 1.8 to 2.5, and the difference between the dry tensile strength in the cross direction and the wet tensile strength in the cross direction is preferably 20N/5 or less and 18N/5cm or less. Satisfying this range maintains the balance between softness and firmness of the wet wipe.
In addition, the invention relates to a bamboo fiber fabric, wherein the longitudinal dry elongation is 5-25% and 6-20%, and the transverse dry elongation is 15-60% and 20-55%. In addition, the longitudinal wet elongation is 15-65% and 20-55%, and the transverse wet elongation is 30-75% and 40-70%. With the elongation in this range, the article can be cleaned and washed by wiping the article gently without being excessively elongated.
In addition, the natural bamboo fiber wet wipe according to the present invention has the wet tensile strength in the above-mentioned range even without using the wet paper strength enhancer.
Wet paper strength enhancer of green natural bamboo fiber wet tissue
The process for producing the green natural bamboo fiber wet wipe according to the present invention is not particularly limited, and can be produced by a known wet wipe production process.
The adding amount of the liquid medicine relative to the bamboo fiber fabric in the container needs to reach the degree that the pure water can completely wet the bamboo fiber fabric, and the liquid medicine content of 100 bamboo fiber fabrics is 10-50 parts by weight and 15-45 parts by weight. If the content of the chemical liquid is less than the above range, the cleaning effect is deteriorated due to insufficient moisture, whereas if the content is more than the above range, running water due to excessive moisture causes inconvenience in use, and thus the chemical liquid should be suitably used within the above range.
The green natural bamboo fiber wet tissue uses 100% of bamboo fiber fabric and EWG first-class substances, and does not have the problems of skin toxicity, skin irritation, skin allergy and the like. In addition, the composition is not changed even after long-term storage, has excellent endurance, and can effectively prevent bacterial propagation.
Further, the wet wipe has deodorant, antibacterial and antifungal effects of bamboo itself, physical properties such as controlled moisture content and strength, excellent tactile sensation in use, and soft touch feeling when contacting the skin.
[ examples ]
The following are preferred embodiments disclosed to aid in the understanding of the present invention. However, the following examples are provided only for easier understanding of the present invention and are not limited to the examples of the present invention.
Preparation example 1
(1) Preparation of bamboo fiber fabric
Adding water into bamboo pulp with the average length of 3 mm in a weight ratio of 1:9, and then turning the pulp to manufacture the film pulp. In order to remove moisture in the film pulp, the film pulp is put into a carding machine after being dehydrated, and then is prepared into pulp by a web former. At this time, the feeding speed on the apparatus was 200 m/min, and the web forming process was performed under a web forming tension of 5N. Next, a 100% bamboo fiber fabric (sponge-like nonwoven fabric) was prepared by performing a hydraulic punching process for 5 times at pressures of 30bar, 40bar, 50bar, and 50bar, respectively, on the bamboo pulp web in a wet state using a spray nozzle, and performing a heat treatment for 4 courses at temperatures of 105 ℃, 110 ℃, 120 ℃, and 130 ℃.
(2) Physical Property measurement and results
Physical properties of the bamboo fiber fabric prepared in manufacturing example 1 were measured, and the results are shown in table 1. In this case, the rayon/PET blended fabric widely used as the wet towel fabric was used in comparative example 1, and the product named "Mybidet" was used in comparative example 2.
The moisture content and the moisture reduction rate after 30 minutes were measured according to the above-mentioned numerical expressions 1 and 2, respectively, and the tensile strength and elongation were measured by a KS K0521: 2017 section method.
[ TABLE 1]
Figure BDA0002852188780000101
As shown in table 1 above, the bamboo fiber fabric according to the present invention has suitable values of tensile strength and elongation in dry and wet states.
In contrast, the rayon/PET blended fabric of comparative example 1 was improved in tensile strength, but the moisture content was low, and the moisture reduction rate was also greatly reduced after 30 minutes. The product of comparative example 2 is a product emphasizing softness, and has lower characteristics of tensile strength and elongation than other wet tissues, and is not suitable for general cleaning or washing purposes.
Example 1
The fabric is cut into pieces of 192 × 192(± 0.5) mm, and the pieces are put into a storage container with a cover, and then the liquid medicine components in the following table 2 are put into 50 g of the fabric per 290 g to prepare the wet tissue.
[ TABLE 2]
Figure BDA0002852188780000111
Experimental example 1
The results of the deodorizing test, the antibacterial test and the antifungal test were carried out for the wet tissues prepared in examples and comparative examples, and are shown in the table.
(1) Deodorization experiment
The fabrics (10 KHz 10 cm) of examples 1 to 3 and comparative examples 1 to 3 were sealed in a reactor at 22.9 ℃ under 42.5% R.H, ammonia gas was injected at an initial concentration of 52ppm, and the deodorizing power was measured after 2 hours.
Deodorizing rate (%) - (Cb-Cs)/Cb 100
Cb blank
Cs-concentration of residual Ammonia in the reactor after 2 hours
(2) Antibacterial experiments
Wet wipes (10 cm of KHz) in the wet state prepared in the examples and comparative examples were used, and Methicillin-Resistant Staphylococcus Aureus (MRSA, Methocillin-Resistant Staphylococcus Aureus ATCC 33591), Candida albicans (Candida albicans ATCC 10231), (Staphylococcus Aureus ATCC 6538P), and Klebsiella pneumoniae (Klebsiella pneumoniae ATCC 4352) were used as the test strains. Initial concentration (CFU/mL) was 2.2X 104The concentration (CFU/mL) was measured after 18 hours to obtain the sterilization rate (%).
(3) Water content and moisture retention
0.1 part by weight of red tar pigment was added to each wet wipe, and the number of the wiped squares was measured after wiping the squares having a length of 30 × 30 cm. In this case, the number of wiping areas means that when 1 wet wipe is used, the larger the number of wipes means the better the moisture content and the moisturizing ability.
(4) Human body patch test
The components of the drug solutions of example 1, comparative example 3 and comparative example 4 were subjected to patch tests for skin irritation and other side effects.
Selecting 20 healthy men and women, placing the medicinal liquid components on an aluminum plate or sticking the medicinal liquid components on a paper plate by using a Finn chamber (International Standard), processing by 40 μ l, fixing the medicinal liquid components on the skin by using a medical adhesive tape, taking down a patch after 24 hours, and judging the result after 4 hours.
[ TABLE 3 ]
Figure BDA0002852188780000121
Figure BDA0002852188780000131
According to the present invention, when the fabric made of 100% bamboo fiber is used, as shown in table 2 above, it can be seen that the deodorizing power is strong.
In addition, the bamboo fiber wet wipe of the present invention uses the combined preservative, and it can be seen that it has better antibacterial power than comparative examples 3 and 4. In addition, the values exhibited when the different fabrics of comparative example 5 were used were also lower than those of the wet wipes of example 1.
The test examples related to the water content and the moisturizing ability of the wet tissue also show that the wet tissue formed by the bamboo fiber fabric and the liquid medicine has good water content and storage performance, and can wipe a large number of squares.
In addition, the liquid medicine component of the invention does not generate red swelling and does not bring irritation to the skin from the aspect of skin stability, so the liquid medicine component can be applied to the wet tissue with low irritation.

Claims (5)

1. A natural bamboo fiber wet tissue is characterized in that a bamboo fiber fabric is soaked in a low-harm liquid medicine, the low-harm liquid medicine comprises purified water, a preservative, a skin conditioner, a natural surfactant, a humectant and an additive, and the components are all in the EWG level.
2. The natural bamboo fiber wet wipe as set forth in claim 1, wherein the preservatives are hydroxyacetophenone and 1, 2-hexanediol, and the skin conditioner is centella asiatica extract.
3. The natural bamboo fiber wet wipe of claim 1, wherein the natural surfactant is coco-glucoside, the humectant is methyl propylene glycol, and the additives are ethylhexyl glycerin and caprylic glyceride.
4. The natural bamboo fiber wet wipe as set forth in claim 1,
the water content of each piece of the natural bamboo fiber fabric is more than 70 weight percent, and the water loss rate after 30 minutes is less than 5 weight percent compared with the initial water content.
5. The natural bamboo fiber wet wipe as set forth in claim 1,
the basis weight of the natural bamboo fiber fabric is 30-80 gsm, and the thickness of the natural bamboo fiber fabric is 0.3-0.8 mm.
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