KR100749138B1 - Functional wet tissue - Google Patents
Functional wet tissue Download PDFInfo
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- KR100749138B1 KR100749138B1 KR1020050032955A KR20050032955A KR100749138B1 KR 100749138 B1 KR100749138 B1 KR 100749138B1 KR 1020050032955 A KR1020050032955 A KR 1020050032955A KR 20050032955 A KR20050032955 A KR 20050032955A KR 100749138 B1 KR100749138 B1 KR 100749138B1
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/16—Paper towels; Toilet paper; Holders therefor
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K7/00—Body washing or cleaning implements
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
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- Public Health (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Epidemiology (AREA)
- General Health & Medical Sciences (AREA)
- Artificial Filaments (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
본 발명은 천연펄프제인 스판레이스 등으로 구성된 물티슈에 은나노 처리하여 위생적이고 피부에 대한 안전성이 뛰어날 뿐만 아니라 피부에 상재하는 병원성 미생물에 대한 항균성 및 항진균성의 특성을 가지고 있는 기능성 물티슈에 관한 것으로,The present invention relates to a functional wet tissue having antimicrobial and antifungal properties against pathogenic microorganisms present in the skin as well as being hygienic and safe for skin by treating silver nano to wet wipes composed of spunlace, which is a natural pulp.
본 발명은 정제된 물 63~69 중량%에 은나노 파우더 1~2 중량%를 혼합한 수용액에 천연펄프제인 스판레이스 30~35 중량% 을 침지시킨 것을 특징으로 하는 기능성 물티슈에 의하여 달성될 수 있는 것이다.The present invention can be achieved by a functional wet tissue characterized in that 30 to 35% by weight of spunlace, a natural pulp agent, is immersed in an aqueous solution of 63 to 69% by weight of silver nanopowder mixed with 1 to 2% by weight of purified water. .
물티슈, 은나노, 항균 Wet tissue, silver nano, antibacterial
Description
본 발명은 기능성 물티슈에 관한 것으로서, 더욱 구체적으로는 천연펄프제인 스판레이스 등으로 구성된 물티슈에 은나노 처리하여 위생적이고 피부에 대한 안전성이 뛰어날 뿐만 아니라 피부에 상재하는 병원성 미생물에 대한 항균성 및 항진균성의 특성을 가지고 있는 기능성 물티슈에 관한 것이다.The present invention relates to functional wipes, and more specifically, silver nano treatment of wet wipes composed of spunlace, etc., which is a natural pulp, provides excellent hygiene and safety for the skin, as well as antibacterial and antifungal properties against pathogenic microorganisms on the skin. It is about functional wipes which I have.
일반적으로 물티슈는 여러 가지 위생적인 목적으로 사용되고 있는데, 주로 식당이나 공공장소에서 피부를 청결하게 유지하기 위해 사용되고, 유아들의 배변 후 피부를 닦는 데에도 쓰이며, 일회용 물수건 등의 형태로 사용된다.In general, wet wipes are used for various hygienic purposes, mainly used to keep the skin clean in restaurants or public places, used to clean the skin after the bowel movement of infants, and is used in the form of disposable wipes.
이러한 물티슈는 피부에 직접적으로 문질러서 사용하기 때문에 피부에 대한 안전성이 우수하고, 피부에 잔재하는 이물질 및 병원성 미생물에 대한 제거가 용이하며 항균성이 뛰어나야 한다.Since such wipes are used by rubbing directly on the skin, the safety of the skin should be excellent, the foreign substances and pathogenic microorganisms remaining on the skin should be easily removed and the antibacterial properties should be excellent.
한편, 물티슈는 펄프나 부직포에 정제수, 보습제, 살균소독제, 계면활성제, 화학 방부제, 알코올, 향료 등을 첨가하여 제조된다. 이러한 종래의 제조방법에 의해 생산된 물티슈는 피부자극성이 있는 것으로 알려진 살균소독제, 계면활성제, 화 학방부제 및 알코올 등을 첨가함으로써, 물티슈를 사용할 때 부작용의 발생되었을 뿐 아니라 피부보호에 문제점이 있었다.Meanwhile, wet wipes are prepared by adding purified water, a moisturizer, a disinfectant, a surfactant, a chemical preservative, an alcohol, a fragrance, or the like to the pulp or nonwoven fabric. The wet tissue produced by such a conventional manufacturing method has a problem in skin protection as well as the occurrence of side effects when using wet wipes by adding disinfectant disinfectants, surfactants, chemical preservatives and alcohol, which are known to be skin irritant.
또한, 살균소독제 및 알코올 등의 사용으로 인하여 좋지 않은 냄새가 발생하여 사용 시에 불쾌감을 주며, 계면활성제 및 알코올성분에 대한 단순한 세정작용만을 나타낼 뿐 피부의 보호, 미용, 세포활성화 및 노화방지 효과 등은 기대할 수 없었다.In addition, due to the use of disinfectant disinfectant and alcohol, bad odor occurs, causing discomfort during use, and only shows a simple cleaning action for surfactants and alcohol components, and protects skin, beauty, cell activation and anti-aging. Could not expect.
본 발명은 상기한 문제점을 감안하여 창안한 것으로서, 그 목적은 천연펄프제인 스판레이스에 은나노 물질을 함침시켜, 피부에 축적된 중금속 및 노폐물을 제거하고 세포를 활성화시켜 혈액순환을 원활하게 하며, 위생적이고 피부에 대한 안전성이 뛰어날 뿐만 아니라 피부에 상재하는 병원성 미생물에 대한 항균성 및 항진균성의 특성을 갖는 기능성 물티슈를 제공함에 있는 것이다.The present invention was devised in view of the above problems, and its purpose is to impregnate silver nanomaterials in a spunlace, a natural pulp, to remove heavy metals and wastes accumulated in the skin, and to activate cells to facilitate blood circulation, hygiene. In addition, the present invention provides a functional wet tissue having excellent antibacterial and antifungal properties against pathogenic microorganisms on the skin, as well as excellent and safe for the skin.
상기한 목적을 달성하기 위한 본 발명의 특징은, 정제된 물 63~69 중량%에 농도가 10~100ppm이고 입자의 크기가 1~10㎚ 또는 100~200㎚인 은나노 파우더 1~2 중량%를 혼합한 수용액에 천연펄프제인 스판레이스 30~35 중량%를 침지시킨 기능성 물티슈에 있어서, 상기 수용액에 폴리글루코사민(polyglucosamine) 0.2~0.4중량%와 세라믹액체(liquid ceramin) 0.6~0.8중량%를 혼합한 것을 특징으로 하는 기능성 물티슈에 의하여 달성될 수 있는 것이다.A feature of the present invention for achieving the above object is 1 to 2 wt% of silver nano powder having a concentration of 10 to 100 ppm and a particle size of 1 to 10 nm or 100 to 200 nm in 63 to 69 wt% of purified water. A functional wet tissue in which 30 to 35% by weight of spunlace, which is a natural pulp agent, is immersed in the mixed aqueous solution, and 0.2 to 0.4% by weight of polyglucosamine and 0.6 to 0.8% by weight of ceramic liquid are mixed with the aqueous solution. It can be achieved by a functional wet tissue characterized in that.
이하, 상기한 목적을 달성하기 위한 바람직한 실시예에 의하여 상세히 설명하면 다음과 같다.Hereinafter, described in detail by the preferred embodiment for achieving the above object is as follows.
실시예1Example 1
물을 깨끗하게 정화시킨 정제수를 준비하였다.Purified water was purified to clean the water.
농도가 10~100ppm 이고 입자의 크기가 1~10㎚인 은나노 파우더를 준비하였다.A silver nano powder having a concentration of 10 to 100 ppm and a particle size of 1 to 10 nm was prepared.
상기 정제수 280g에 상기 은나노 파우더 4g를 넣고 혼합하여 수용액을 완성하였다.4g of the silver nanopowder was added to 280g of the purified water and mixed to complete the aqueous solution.
상기 수용액에 천연펄프제인 스판레이스 140g를 침지시켜 기능성 물티슈를 완성하였다.A functional wipe was completed by immersing 140 g of spunlace, which is a natural pulp, in the aqueous solution.
본 발명에 사용되는 스판레이스는 주원료로 천연펄프를 사용한 것으로서, 스판레이스란 고속으로 물을 분사하여 한쪽의 원사가 다른 쪽의 원사를 쳐서 서로 웨브(web)조직을 형성하여 매듭되도록 하는 스판레이스(Spunlace)공법에 의해 만들어진 부직포를 말하는 것이다. 상기 스판레이스 제품은 현재 우리 생활과 밀접한 폭넓은 곳에서 사용되고 있으며, 그 예로 물티슈(Wet tissue) 등의 위생용품, 타월(Towel) 등의 주방용품, 화장솜 등의 화장용품, 거즈(Gauze)등의 의료용품 및 인공피혁용 기포(Base), 청소포, 인테리어용, 차량용, 건축용 자재에도 널리 사용되고 있는 것으로서 제조방법은 이미 널리 알려져 있는 방법이므로 자세한 설명은 생략하였다.The spanlace used in the present invention uses natural pulp as a main raw material, and the spanlace is a spunlace in which water is sprayed at high speed so that one yarn hits the other yarn to form a web structure with each other and is knotted. Spunlace) refers to the nonwoven fabric produced by the process. The spanlace products are currently used in a wide range close to our lives, such as sanitary products such as wet tissues, kitchen items such as towels, cosmetic items such as cotton, and gauze. It is widely used in medical supplies and artificial leather base (base), cleaning cloth, interior, vehicles, building materials as the manufacturing method is already well known method, detailed description thereof has been omitted.
본 발명에 사용되는 은나노 파우더는 은(銀) 화합물 형태인 질산은(AgNO3) 0.85g를 수용액에 넣고, 이소프로판올(isopropanol) 30ml, 폴리비닐피롤리돈(polyvinylprrolidone) 5g 그리고 단량체로서 아크릴로니트릴(acrylonitrile) 85g를 넣어 질소퍼징 한 후 방사선을 조사하여 10~100ppm의 농도와 1~10nm의 크기를 갖는 은나노 파우더를 제조하여 사용하였다.Silver nanopowder used in the present invention is a silver compound in the form of silver nitrate (AgNO 3 ) 0.85g in an aqueous solution, isopropanol 30ml, polyvinylpyrolidone 5g and acrylonitrile (acrylonitrile) as a monomer ) 85g was put in nitrogen purge and irradiated with radiation to prepare a silver nano powder having a concentration of 10 ~ 100ppm and a size of 1 ~ 10nm.
물론, 상기 은나노 파우더의 제조방법은 이미 알려져 있는 방법이므로 자세한 설명은 생략하였으며, 기타 전기적인 분해방법이나 화학적인 환원법 등을 사용하여 제조할 수 있는 것이므로 본 발명은 은나노 파우더의 제조방법에 국한되는 것은 아니다.Of course, the manufacturing method of the silver nanopowder is a known method, so a detailed description thereof has been omitted, and the present invention is limited to the manufacturing method of the silver nanopowder because it can be prepared using other electrical decomposition methods or chemical reduction methods. no.
은(銀) 성분은 예로부터 항균력과 살균력이 있는 것으로 밝혀져 있는 것으로, 은나노의 강한 살균력과 항균력에 의하여 유해세균(有害細菌) 및 곰팡이들의 번식을 억제하는 한편 살균처리 할 수 있는 것이므로 물티슈를 보다 청결하게 사용할 수 있을 뿐 아니라 물티슈가 세균에 감염되더라도 은나노의 살균력에 의하여 1시간 이내에 세균이 99％이상 살균되어 제거됨과 동시에 물티슈를 사용하는 곳에 기생하는 세균까지도 살균되는 것이므로 매우 위생적으로 사용할 수 있는 것으로서 향균력을 갖는 물티슈의 대외 경쟁력을 최대한 높여줄 수 있는 등의 이점이 있는 것이다.The silver component has been found to have antibacterial and bactericidal properties since ancient times, and the wet wipes are more clean because they are able to inhibit the growth of harmful bacteria and molds and to be sterilized by the strong bactericidal and antimicrobial properties of silver nano. In addition, even when wet tissues are infected with bacteria, they are sterilized by 99% or more within one hour by silver nanosterilization and at the same time, even the parasitic bacteria are sterilized where wet tissues are used. There is an advantage such as to increase the external competitiveness of the wet tissue having a maximum.
실시예2Example 2
물을 정제하여 정제수를 준비하였다.Purified water to prepare purified water.
농도가 10~100ppm 이고 입자의 크기가 100~200㎚인 은나노 코팅파우더(캡슐) 를 준비하였다.A silver nano coating powder (capsule) having a concentration of 10 to 100 ppm and a particle size of 100 to 200 nm was prepared.
상기 정제수 280g에 상기 은나노 코팅파우더 4g를 넣고 혼합하여 수용액을 완성하였다.4g of the silver nano-coated powder was added to 280g of purified water, and an aqueous solution was completed.
상기 수용액에 천연펄프제인 스판레이스 140g를 침지시켜 기능성 물티슈를 완성하였다.A functional wipe was completed by immersing 140 g of spunlace, which is a natural pulp, in the aqueous solution.
실시예3Example 3
상기 실시예 1,2 의 수용액에 폴리글루코사민(polyglucosamine) 1.2g와 세라믹액체(liquid ceramin) 2.8g를 투입하여 혼합액을 준비하였다.1.2 g of polyglucosamine and 2.8 g of ceramic liquid were added to the aqueous solution of Examples 1 and 2 to prepare a mixed solution.
상기 혼합액에 천연펄프제인 스판레이스 140g를 침지시켜 기능성 물티슈를 완성하였다.A functional wet tissue was completed by immersing 140 g of spunlace, a natural pulp, in the mixed solution.
상기 폴리글루코사민(polyglucosamine)은 천연 아미노당의 하나로서, 분자식 C6H13NO6. 탄소가 6개 있으므로 갈락토사민과 함께 헥소사민으로 총칭된다. 무색의 침상결정으로, 110℃에서 분해되며, 물에 녹는 강염기성 물질이다. 천연으로는 키틴을 비롯하여 세균의 세포벽, 동물의 연골이나 피부를 구성하는 뮤코다당 등 다당류의 성분으로 널리 분포한다. 또한, 사람의 혈액이나 점액 속에 이 당과 결합한 단백질이 다량 함유되어 있으며, 적혈구의 세포막에는 이 당을 결합한 당지질이 존재하고 키틴을 염산 분해하여 제조한다.The polyglucosamine (polyglucosamine) is one of the natural amino sugars, the molecular formula C 6 H 1 3NO 6 . Since it has six carbons, it is collectively referred to as hexamine with galactosamine. It is a colorless needle-like crystal that decomposes at 110 ° C and is a strong base that dissolves in water. Naturally, it is widely distributed as a component of polysaccharides such as chitin, bacterial cell walls, and mucopolysaccharides that make up the cartilage and skin of animals. In addition, the human blood or mucus contains a large amount of the protein bound to this sugar, the cell membrane of the red blood cells are present in the glycolipids bound to this sugar is prepared by hydrolysis of chitin.
한편, 폴리글루코사민은 게, 새우 등에서 추출한 카치온성 고분자 물질로서 정전기를 방지하며, 항균 및 악취제거 효과가 있는 것이다.On the other hand, polyglucosamine is a cationic polymer material extracted from crabs, shrimp, etc. to prevent static electricity and to have antibacterial and odor removing effects.
세라믹액체(liquid ceramin)는 세라믹을 액체화 한 것으로 원적외선이 방사되고, 항균작용을 하는 것이다.Ceramic liquid (liquid ceramin) is a liquid liquefied ceramic, far-infrared rays are radiated, antibacterial action.
실시예4Example 4
상기 실시예 1,2 의 수용액 또는 실시예 3의 혼합액에 로션, 알로에 및 비타민의 혼합물 4g를 투입하고 이 혼합물에 천연펄프제인 스판레이스 140g를 침지시켜 기능성 물티슈를 완성하였다.4 g of a mixture of lotion, aloe and vitamin were added to the aqueous solution of Examples 1 and 2 or the mixed solution of Example 3, and 140 g of spunlace, a natural pulp agent, was immersed in the mixture to complete a functional wet tissue.
여기서 상기 수용액 또는 혼합액에 로션, 알로에, 비타민 중에서 어느 하나를 1~2중량% 첨가하거나, 2이상의 혼합물을 1~2중량% 첨가하여 물티슈를 얻을 수 있는 것이다.Here, the wet tissue can be obtained by adding 1 to 2% by weight of any one of lotion, aloe and vitamin, or 1 to 2% by weight of a mixture of two or more to the aqueous solution or the mixed solution.
상기 로션은 피부의 각층(角層)에 수분을 주어 피부표면을 다듬는 작용을 하는 수용성 화장품으로서, 에탄올, 글리세롤, 글리콜, 붕산, 시트르산, 식물점액, 정제수(精製水) 등을 주원료로 한 피부전용 화장수로서, 피부에 윤기를 주고 피부 표면의 pH를 조절하거나 수렴(收斂:수축), 살균, 방취(防臭) 등의 효과가 있다.The lotion is a water-soluble cosmetics that moisturizes each layer of the skin to smooth the surface of the skin, and is exclusively for skin using ethanol, glycerol, glycol, boric acid, citric acid, plant mucus, purified water, etc. As a lotion, it gives moisture to the skin and adjusts the pH of the skin surface, or has an effect of convergence, disinfection, sterilization, deodorization, and the like.
상기 알로에는 노회, 또는 나무노회라고도 하고, 알로에속(Aloe)에 속하는 식물 전체를 가리키거나 그 한 종을 가리킨다. 아프리카가 원산지이고, 전 세계에 약 300종이 있다. 관엽식물로 온실에서 재배하거나 약으로 쓰려고 가정에서 기르기도 한다. 지금까지 밝혀진 효능에 의하면, 세균과 곰팡이에 대한 살균력이 있고 독소를 중화하는 알로에틴이 들어 있으며, 궤양에 효과가 있는 알로에우르신과 항암 효과가 있는 알로미틴이 들어 있다.The aloe, also called presbytery or tree presbyopia, refers to the whole plant belonging to the genus Aloe or one species thereof. It is native to Africa and has about 300 species worldwide. As a houseplant, it can be grown in a greenhouse or grown at home for use as a medicine. Efficacy has been found so far, it contains aloetin, which is bactericidal and fungal neutralizing for bacteria and fungi, aloeursin that is effective in ulcers, and aloemitin, which has anticancer effects.
상기 비타민에 대하여는 이미 널리 알려져 있는 것으로 그에 대한 설명은 생략하였다.The vitamin is already well known and a description thereof has been omitted.
이상에서는 본 발명의 바람직한 실시예에 대하여 도시하고 또한 설명하였으나, 본 발명은 상기한 실시예에 한정되지 아니하며, 청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 본 발명이 속하는 분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변형 실시가 가능한 것은 물론이고, 그와 같은 변경은 기재된 청구범위 내에 있게 된다.Although the preferred embodiments of the present invention have been illustrated and described above, the present invention is not limited to the above-described embodiments, and the present invention is not limited to the above-described embodiments without departing from the spirit of the present invention as claimed in the claims. Various modifications can be made by those skilled in the art, and such modifications are intended to fall within the scope of the appended claims.
이상에서 상술한 바와 같은 본 발명은, 천연펄프제인 스판레이스에 은나노 물질을 함침 시키고, 폴리글루코사민과 세라믹액체, 로션, 알로에 및 비타민 등을 첨가하여 물티슈 제작하므로, 물티슈를 사용하게 되면 피부에 축적된 중금속 및 노폐물을 제거하고 세포를 활성화시켜 혈액순환을 원활하게 하며, 위생적이고 피부에 대한 안전성이 뛰어날 뿐만 아니라 피부에 상재하는 병원성 미생물에 대한 항균성 및 항진균성을 갖는 등 여러 효과가 있는 유용한 발명이다.As described above, the present invention is impregnated with a silver nanomaterial in a spunlace, which is a natural pulp, and a wet tissue is prepared by adding polyglucosamine, ceramic liquid, lotion, aloe and vitamins. It is a useful invention that has various effects such as removing heavy metals and wastes and activating cells to facilitate blood circulation, hygienic and excellent skin safety, as well as antibacterial and antifungal activity against pathogenic microorganisms on the skin.
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| KR101034336B1 (en) * | 2008-11-26 | 2011-05-16 | (주) 그린페이퍼텍 | A disposable paper towel |
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| CN105362141B (en) * | 2015-11-26 | 2018-10-16 | 上海银京医用卫生材料有限公司 | A kind of antibacterial wiping hand wet tissue |
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