CN114574123A - 应用于折叠手机的oca胶带 - Google Patents

应用于折叠手机的oca胶带 Download PDF

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CN114574123A
CN114574123A CN202210404226.2A CN202210404226A CN114574123A CN 114574123 A CN114574123 A CN 114574123A CN 202210404226 A CN202210404226 A CN 202210404226A CN 114574123 A CN114574123 A CN 114574123A
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胡东超
郭啸风
郑章勤
周晓南
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Anhui Jinghua New Material Technology Co ltd
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Abstract

本发明公开了应用于折叠手机的OCA胶带,包括顺次设置的离型层、OCA胶层以及平面离型膜,OCA胶层的原料包括,以重量百分数计:25%~50%丙烯酸酯系共聚物、30%~55%乙酸乙酯、余量为甲苯。本发明通过对OCA胶带的组成和结构进行优化设计,有效地改善了产品的柔性和贴合性能,使其充分满足折叠屏长期使用的要求。

Description

应用于折叠手机的OCA胶带
技术领域
本发明是关于柔性材料技术,特别是关于一种应用于折叠手机的OCA胶带。
背景技术
随着科学技术发展及市场新需求,柔性可折叠智能手机于2019年世界移动通信大会面世,为了迎合当下消费者追求便携和功能多样统一的需求,各大手机厂商致力于研究可折叠智能手机。为满足折叠需求,手机内部零件链接胶带需匹配柔性可重复折叠,现有的OCA胶模量相对较大,折弯处应力集中区域易出现断裂或分层。
公开于该背景技术部分的信息仅仅旨在增加对本发明的总体背景的理解,而不应当被视为承认或以任何形式暗示该信息构成已为本领域一般技术人员所公知的现有技术。
发明内容
本发明的目的在于提供一种应用于折叠手机的OCA胶带,通过对OCA胶带的组成和结构进行优化设计,有效地改善了产品的柔性和贴合性能,使其充分满足折叠屏长期使用的要求。
为实现上述目的,本发明的实施例提供了应用于折叠手机的OCA胶带,包括顺次设置的离型层、OCA胶层以及平面离型膜,OCA胶层的原料包括,以重量百分数计:25%~50%丙烯酸酯系共聚物、30%~55%乙酸乙酯、余量为甲苯。
在本发明的一个或多个实施方式中,丙烯酸酯系共聚物的原料包括,以重量百分数计:20%~65%单体、0.1%~4%引发剂、余量为甲苯。优选的,引发剂选自过氧化苯甲酰、过氧化月桂酰、过氧化二异丙苯、过氧化甲乙酮、过氧化环己酮。
在本发明的一个或多个实施方式中,单体为丙烯酸丁酯、丙烯酸乙酯、甲基丙烯酸-2-乙基己酯,丙烯酸月桂酯,甲基丙烯酸一种或多种。
在本发明的一个或多个实施方式中,离型层为PET材质非离型面抗静电,阻抗为106~109Ω。
在本发明的一个或多个实施方式中,离型层满足:厚度75~100μm。
在本发明的一个或多个实施方式中,OCA胶层满足:厚度为25~75μm。
在本发明的一个或多个实施方式中,平面离型层为PET离型面抗静电,阻抗为106~109Ω。
在本发明的一个或多个实施方式中,平面离型层满足:厚度50~75μm。
与现有技术相比,根据本发明实施方式的应用于折叠手机的OCA胶带,通过采用特定的OCA胶层原料设计,采用特别组成的丙烯酸酯系共聚物为依托,改善树脂胶粘结构的结晶性,从而提升产品的柔性粘接性,从而极大地改善了产品的性能。优化后的OCA胶层具有低模量、低TG、蠕变恢复高等特性,满足常温/高温高湿/低温环境下折叠需求,从而降低折弯处普通OCA断裂或分层的风险。
附图说明
图1是根据本发明一实施方式的应用于折叠手机的OCA胶带的结构示意图。
具体实施方式
下面结合本发明的具体实施方式,对本发明技术方案进行示例性的详细描述,但应当理解本发明的保护范围并不受具体实施方式的限制。
除非另有其它明确表示,否则在整个说明书和权利要求书中,术语“包括”或其变换如“包含”或“包括有”等等将被理解为包括所陈述的元件或组成部分,而并未排除其它元件或其它组成部分。
如图1所示,根据本发明优选实施方式的应用于折叠手机的OCA胶带中离型层1为厚度75~100μm离型膜,优选的离型层1的厚度可以为75μm、85μm、95μm、90μm、100μm以及75~100μm范围内的其它任意值;OCA胶层2为厚度25~75μm,优选的OCA胶层2的厚度可以为25μm、35μm、45μm、55μm、65μm、75μm以及25~75μm范围内的其它任意值;平面离型膜3为厚度50~75nm,优选的平面离型膜3的厚度可以为50μm、65μm、75μm、60μm、55μm、70μm以及50~75μm范围内的其它任意值。
实施例1
合成OCA胶水
将20wt%单体(质量比1:2:3:4的丙烯酸丁酯、丙烯酸乙酯、甲基丙烯酸-2-乙基己酯、丙烯酸月桂酯)、0.1wt%引发剂过氧化苯甲酰、余量的甲苯加入反应釜,70℃聚合6h,得到丙烯酸酯系共聚物。以此丙烯酸酯系共聚物为基础计量为占OCA胶层的原料的25wt%,再加入稀释溶剂55wt%乙酸乙酯、余量的甲苯,调整至合理5000~6000cps粘度,即得到OCA胶水制备OCA胶带
选择合适离型力(15~100g)的75μm离型层,通过狭缝或刮刀涂布,直涂75μm制备的OCA胶水(干胶厚度),经烘箱热固化后,复合工位复合合适离型力(3~50g)的50μm平面离型膜,产出成品无基材OCA胶带。
实施例2
合成OCA胶水
将30wt%单体(质量比1:1:1的甲基丙烯酸-2-乙基己酯、丙烯酸月桂酯、甲基丙烯酸)、1t%引发剂过氧化苯甲酰、余量的甲苯加入反应釜,72℃聚合6h,得到丙烯酸酯系共聚物。以此丙烯酸酯系共聚物为基础计量为占OCA胶层的原料的35wt%,再加入稀释溶剂30~55wt%乙酸乙酯、余量的甲苯,调整至合理5000~6000cps粘度,即得到OCA胶水
制备OCA胶带
选择合适离型力(15~100g)的100μm离型层,通过狭缝或刮刀涂布,直涂65μm制备的OCA胶水(干胶厚度),经烘箱热固化后,复合工位复合合适离型力(3~50g)的55μm平面离型膜,产出成品无基材OCA胶带。
实施例3
合成OCA胶水
将40wt%单体甲基丙烯酸-2-乙基己酯、2wt%引发剂过氧化二异丙苯、余量的甲苯加入反应釜,74℃聚合6h,得到丙烯酸酯系共聚物。以此丙烯酸酯系共聚物为基础计量为占OCA胶层的原料的45wt%,再加入稀释溶剂40wt%乙酸乙酯、余量的甲苯,调整至合理5000~6000cps粘度,即得到OCA胶水制备OCA胶带
选择合适离型力(15~100g)的85m离型层,通过狭缝或刮刀涂布,直涂33μm制备的OCA胶水(干胶厚度),经烘箱热固化后,复合工位复合合适离型力(3~50g)的65μm平面离型膜,产出成品无基材OCA胶带。
实施例4
合成OCA胶水
将50wt%单体丙烯酸乙酯、3wt%引发剂过氧化环己酮、余量的甲苯加入反应釜,76℃聚合7h,得到丙烯酸酯系共聚物。以此丙烯酸酯系共聚物为基础计量为占OCA胶层的原料的50wt%,再加入稀释溶剂45wt%乙酸乙酯、余量的甲苯,调整至合理5000~6000cps粘度,即得到OCA胶水
制备OCA胶带
选择合适离型力(15~100g)的95μm离型层,通过狭缝或刮刀涂布,直涂30μm制备的OCA胶水(干胶厚度),经烘箱热固化后,复合工位复合合适离型力(3~50g)的70μm平面离型膜,产出成品无基材OCA胶带。
实施例5
合成OCA胶水
将65wt%单体丙烯酸丁酯、4wt%引发剂过过氧化月桂酰、余量的甲苯加入反应釜,80℃聚合8h,得到丙烯酸酯系共聚物。以此丙烯酸酯系共聚物为基础计量为占OCA胶层的原料的40wt%,再加入稀释溶剂30wt%乙酸乙酯、余量的甲苯,调整至合理5000~6000cps粘度,即得到OCA胶水制备OCA胶带
选择合适离型力(15~100g)的100μm离型层,通过狭缝或刮刀涂布,直涂25μm制备的OCA胶水(干胶厚度),经烘箱热固化后,复合工位复合合适离型力(3~50g)的75μm平面离型膜,产出成品无基材OCA胶带。
实施例测试结果:
Figure BDA0003601622900000051
Figure BDA0003601622900000061
包括而不限于上述实施例的本发明方案,其测试性能均满足:
OCA胶水:模量25℃30~50kpa、60℃>15kpa、-20℃<300kpa;蠕变回复率>90%,500%应力松弛>90%,TG<-30℃,降低RA环境下(常温/高温高湿/低温)动态/静态折弯OCA断裂或分层风险。
前述对本发明的具体示例性实施方案的描述是为了说明和例证的目的。这些描述并非想将本发明限定为所公开的精确形式,并且很显然,根据上述教导,可以进行很多改变和变化。对示例性实施例进行选择和描述的目的在于解释本发明的特定原理及其实际应用,从而使得本领域的技术人员能够实现并利用本发明的各种不同的示例性实施方案以及各种不同的选择和改变。本发明的范围意在由权利要求书及其等同形式所限定。

Claims (9)

1.一种应用于折叠手机的OCA胶带,包括顺次设置的离型层、OCA胶层以及平面离型膜,其特征在于,所述OCA胶层的原料包括,以重量百分数计:25%~50%丙烯酸酯系共聚物、30%~55%乙酸乙酯、余量为甲苯。
2.如权利要求1所述的应用于折叠手机的OCA胶带,其特征在于,所述丙烯酸酯系共聚物的原料包括,以重量百分数计:20%~65%单体、0.1%~4%引发剂、余量为甲苯。
3.如权利要求2所述的应用于折叠手机的OCA胶带,其特征在于,所述单体为丙烯酸丁酯、丙烯酸乙酯、甲基丙烯酸-2-乙基己酯,丙烯酸月桂酯,甲基丙烯酸一种或多种。
4.如权利要求2所述的应用于折叠手机的OCA胶带,其特征在于,所述引发剂为过氧化苯甲酰。
5.如权利要求1所述的应用于折叠手机的OCA胶带,其特征在于,所述离型层为PET材质非离型面抗静电,阻抗为106~109Ω。
6.如权利要求1或5所述的应用于折叠手机的OCA胶带,其特征在于,所述离型层满足:厚度75~100μm。
7.如权利要求1所述的应用于折叠手机的OCA胶带,其特征在于,所述OCA胶层满足:厚度为25~75μm。
8.如权利要求1所述的应用于折叠手机的OCA胶带,其特征在于,所述平面离型层为PET材质离型面抗静电,阻抗为106~109Ω。
9.如权利要求1或8所述的应用于折叠手机的OCA胶带,其特征在于,所述平面离型层满足:厚度50~75μm。
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Publication number Priority date Publication date Assignee Title
CN103773260A (zh) * 2013-12-24 2014-05-07 四川东材科技集团股份有限公司 一种光学透明双面胶带的制备方法
JP2020139038A (ja) * 2019-02-27 2020-09-03 リンテック株式会社 繰り返し屈曲デバイス用粘着剤、粘着シート、繰り返し屈曲積層部材および繰り返し屈曲デバイス

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103773260A (zh) * 2013-12-24 2014-05-07 四川东材科技集团股份有限公司 一种光学透明双面胶带的制备方法
JP2020139038A (ja) * 2019-02-27 2020-09-03 リンテック株式会社 繰り返し屈曲デバイス用粘着剤、粘着シート、繰り返し屈曲積層部材および繰り返し屈曲デバイス

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