CN114532349A - Compound pesticide containing spinosad and hexythiazox and application thereof - Google Patents
Compound pesticide containing spinosad and hexythiazox and application thereof Download PDFInfo
- Publication number
- CN114532349A CN114532349A CN202210276870.6A CN202210276870A CN114532349A CN 114532349 A CN114532349 A CN 114532349A CN 202210276870 A CN202210276870 A CN 202210276870A CN 114532349 A CN114532349 A CN 114532349A
- Authority
- CN
- China
- Prior art keywords
- hexythiazox
- spinosad
- toxicity
- composition
- mass ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a compound insecticide containing spinosad and hexythiazox and application thereof, wherein the active ingredients of the composition comprise spinosad and hexythiazox, and the mass ratio of the spinosad to the hexythiazox is (0.1-10): 1. After the spinosad and the hexythiazox are compounded, the insecticidal composition has certain synergism on spider mites and activity for expanding an insecticidal spectrum, can obviously improve the control effect, reduce the using amount of pesticides, reduce the use cost and reduce the pollution to the environment.
Description
Technical Field
The invention belongs to the technical field of pest control, and particularly relates to a compound pesticide with synergistic activity and an expanded insecticidal spectrum for controlling tetranychus urticae and application thereof.
Background
Tetranychus cinnabarinus, also called red spider, belongs to the Tetranychus urticae of Acarina of Aranea, is widely distributed in various regions of China, and harms various solanaceous and flowering crops, such as eggplant, capsicum, tomato, cucumber, Chinese rose and the like. Generally, the heavy oil is generated in summer, and can be generated in a large area in a short time to cause serious harm. The control difficulty of tetranychus cinnabarinus is high, chemical control is a main control method of tetranychus cinnabarinus, but after long-term use of a chemical insecticide, tetranychus cinnabarinus is easy to generate drug resistance, so that the control effect is reduced, and frequent use of chemical pesticides can destroy the ecological environment and threaten the health of human beings, so that the control of harmful insects and mites is more and more concerned by people. One pesticide is usually effective only for one or a few insect pests, and has the defect of narrow insecticidal spectrum, so that different pesticide varieties or mixed synergy between biological pesticide varieties and chemical pesticide varieties and expansion of the insecticidal spectrum are mostly adopted in order to delay the drug resistance of the pests, expand the insecticidal spectrum and improve the pesticide effect in the actual production. Whether the two medicaments are synergized, antagonized or added or not can be judged by taking a certain pest or pest mite as a test object, measuring the toxicity of the two medicaments indoors, screening the optimal mixture ratio and calculating the co-toxicity coefficient, if the co-toxicity coefficient is more than 100 after compounding, the synergism is realized, and the pesticide effect of the compounded and synergized mixture can be further verified by pot culture and field pesticide effect. The synergistic compound agent improves the actual control effect, reduces the using amount of pesticides, delays the generation of the drug resistance of pests and expands the insecticidal spectrum, and is an important means for comprehensively controlling the pests.
Spinosad is a macrolide nuisance-free high-efficiency biopesticide extracted from a Saccharopolyspora spinosa fermentation broth, has quick contact poisoning and stomach poisoning effects on pests, has strong infiltration effect on leaves, can kill pests below the epidermis, has long residual effect period, and has a certain ovicidal effect on some pests. Has no systemic effect, and can effectively control lepidoptera, diptera and thysanoptera pests.
The hexythiazox is called Nixoron, and has the acaricidal characteristics that: has strong contact poisoning and stomach poisoning effects on pest mites; the pesticide has strong infiltration effect on the crop epidermis, can penetrate into the leaf and penetrate to the leaf back to kill harmful mites on the leaf back, but has no systemic effect; the mite egg, nymph and young mites are all effective, the toxicity to adult mites is low, however, the egg laying rate of female adult mites contacting with the medicament is low; the drug effect is slow, the peak of the drug effect is reached in 7-10 days after the application, and the lasting period is 40-50 days; the effect of the composition used at high temperature or low temperature is not obviously different; when the pesticide is used at a common concentration, the pesticide has little influence on crops, natural enemies, bees and predatory mites. The hexythiazox can control tetranychus on various crops such as fruit, forest, tea, cotton, vegetables, beans, flowers and the like, but has poor control effect on rust mites.
The research and the report of the biological activity of the spinosad and the hexythiazox on spider mites are many, but the spinosad is mainly used for preventing and controlling adult mites and has quick response and good effect, while the hexythiazox has good effect on young mites and young mites, has low toxicity on adult mites and slow drug effect, but the report of the compounded synergistic action and the compounded proportion between the spinosad and the hexythiazox is not available, so that the mixed insecticide which can give consideration to both the adult mites and the plectriazox and has the synergistic activity is designed in order to solve the problems that the single use of the spinosad and the hexythiazox can not give consideration to both the adult mites and the hexythiazox, and the drug effect is unstable.
Disclosure of Invention
The purpose of the invention is as follows: the technical problem to be solved by the invention is to provide a composition aiming at the defects of the prior art.
The invention also provides a pesticide containing the composition.
The invention also aims to solve the technical problem of providing the application of the composition in preparing pesticides.
In order to solve the first technical problem, the invention discloses a composition, and the effective components of the composition comprise spinosad and hexythiazox.
Wherein the mass ratio of the spinosad to the hexythiazox is (0.1-10) to 1; in some embodiments, the mass ratio of the spinosad to the hexythiazox is (3.7-6.1): 1; in some embodiments, the mass ratio of the spinosad to the hexythiazox is (4.2-5.6): 1; in some embodiments, the spinosyn and hexythiazox are in a mass ratio of 4.2:1 or 5.6: 1.
In order to solve the second technical problem, the invention discloses a pesticide.
Wherein the pesticide comprises spinosad and hexythiazox; in some embodiments, the mass ratio of the spinosad to the hexythiazox is (0.1-10): 1; in some embodiments, the mass ratio of the spinosad to the hexythiazox is (3.7-6.1): 1; in some embodiments, the mass ratio of the spinosad to the hexythiazox is (4.2-5.6): 1; in some embodiments, the spinosyn and hexythiazox are in a mass ratio of 4.2:1 or 5.6: 1.
In some embodiments, the tetranychus control is tetranychus in vegetables and/or flowers.
In order to solve the third technical problem, the invention discloses an application of a composition in preparing an insecticide.
Wherein the effective components of the composition comprise spinosad and hexythiazox; in some embodiments, the mass ratio of the spinosad to the hexythiazox is (0.1-10): 1; in some embodiments, the mass ratio of the spinosad to the hexythiazox is (3.7-6.1): 1; in some embodiments, the mass ratio of the spinosad to the hexythiazox is (4.2-5.6): 1; in some embodiments, the spinosyn and hexythiazox are in a mass ratio of 4.2:1 or 5.6: 1.
Wherein the pesticide is used for preventing and controlling spider mites.
In some embodiments, the tetranychus control is tetranychus in vegetables and/or flowers.
The spinosad and the hexythiazox used in the invention can be purchased directly from the market, and at present, a plurality of companies produce the spinosad and hexythiazox on the market, and the spinosad and hexythiazox have wide sources as long as the ratio range and the application condition of the spinosad and hexythiazox are met.
Has the advantages that: compared with the prior art, the invention has the following advantages:
after the spinosad and the hexythiazox are compounded, the insecticidal composition has certain synergism on spider mites and activity for expanding an insecticidal spectrum in a certain compounding proportion, can obviously improve the control effect, reduce the using amount of pesticides, reduce the use cost and reduce the pollution to the environment.
Detailed Description
The experimental methods described in the following examples are all conventional methods unless otherwise specified; the reagents and materials are commercially available, unless otherwise specified.
The following is a detailed description of the synergistic combination of spinosad and hexythiazox, which is provided for illustration only and is not meant to limit the scope of the present invention, wherein the active ingredients are calculated as effective ingredients.
Experimental example 1: screening of compounding ratio of spinosad and hexythiazox to tetranychus cinnabarinus and determination of co-toxicity coefficient
1.1 test pests and test methods
Testing insects: tetranychus cinnabarinus bred by eggplant seedlings at gardening and school stations.
1.2 test Agents
30% spinosyn suspension (dow Yinong, usa); 5% hexythiazox emulsifiable concentrate (Jiangsu Longdeng chemical Co., Ltd.); a spinosad and hexythiazox mixed agent: is prepared from single agents according to the proportion requirement.
1.3 Experimental methods
1.3.1 determination of toxicity of Spinosad and hexythiazox on Tetranychus cinnabarinus
The leaf dipping method is adopted in the experiment. According to the test results of the pretreatment, the agents (multi-fungicide and hexythiazox single agents) were prepared and diluted in sequence to 5 series of concentration gradients (200ppm, 100ppm, 50ppm, 25ppm, 12.5 ppm). Soaking the collected eggplant leaves with 20-25 heads of tetranychus urticae on the back into the liquid medicine, standing the leaves in the liquid medicine for 40s, taking out the leaves by using tweezers, placing the leaves in a clean culture dish, airing the leaves at normal temperature, and wrapping absorbent cotton at petioles of the leaves for moisturizing. Storing in a culture dish added with water-absorbing filter paper, sealing with a sealing film, testing under the environmental conditions of 20-25 ℃ of temperature, 10-14 h of light and dark cycle and 75-85% of relative humidity, checking the number of dead (living) insects (judging whether the insects survive or not by lightly touching the insects body with a brush pen tip under a dissecting mirror) at 48h, 72h and 120h respectively, and recording, sorting, calculating the insect population death rate of the spider mites and correcting the death rate. And (3) summarizing and collating data on Excel software, and calculating toxicity baseline, correlation coefficient, lethal medium dose and the like of each medicament on tetranychus cinnabarinus.
1.3.2 screening of different combinations of spinosad and hexythiazox
According to the toxicity baseline of 2 acaricides on tetranychus cinnabarinus measured in the test 1.3.1, LC of the acaricides is respectively calculated50Value according to LC50Preparing 70mg/L spinosad aqueous solution and 50mg/L hexythiazox aqueous solution, preparing the 70mg/L spinosad aqueous solution and the 50mg/L hexythiazox aqueous solution into 7 mixed solutions with different volume ratios according to the mixture ratio of 1:1, 2:1, 3:1, 4:1, 1:2, 1:3 and 1:4, testing the insecticidal activity of the mixed preparation on leaf mites by adopting a leaf soaking method, recording the number of insect mouths before and after the preparation and calculating the insect mouth death rate 24 hours after the preparation, wherein the death rate of the mixture is higher than 50 percent and the highest death rate is the best mixture, and comparing and analyzing the mixture ratio of the toxic factors.
The compound synergy degree of the 3 combinations is judged by adopting a co-toxicity factor (CTF) method, and the synergy is realized when the co-toxicity factor ratio is obviously more than 20; when the content is obviously less than-20, the antagonism is obtained, and when the content is between-20 and 20, the additivity is obtained.
Co-toxicity factor (CTF) ═ (actual mortality-expected mortality)/expected mortality × 100.
1.3.3 determination of co-toxicity coefficient of spinosad and hexythiazox mixed agent with different proportions to tetranychus cinnabarinus
The toxicity of the spinosad and hexythiazox mixture on tetranychus cinnabarinus is measured by the method 1.3.1.
The co-toxicity coefficient is calculated as follows
From the results of the bioassay, by using a method of Finney (1952) probability value analysis, a regression equation and LC of toxicity of the spinosad, the hexythiazox and the mixture of the spinosad and the hexythiazox to tetranychus cinnabarinus are respectively obtained50Values and relative virulence indices. Finally, the Co-Toxicity Coefficient (Co-Toxicity Coefficient, C.T.C for short) of the mixture is calculated according to the method published by Sunpiping in 1960 and the following formula. A and B respectively represent two single agents to be mixed, and the co-toxicity coefficient of the mixed agents is finally calculated.
Theoretical (A + B) mixture virulence index ═ ASheetThe virulence index of the agent multiplied by the percentage of A in the mixture and the virulence index of the agent multiplied by the percentage of B in the mixture.
C.T.C is less than or equal to 80, and the two single agents have antagonistic action after being mixed
80< C.T.C <120 means that the two single agents have additive effect after being mixed
The C.T.C. is not less than 120, which shows that the two single agents have synergistic effect after being mixed.
1.4 results and analysis
1.4.1 toxicity of Agents such as spinosad on Tetranychus cinnabarinus
As can be seen from Table 1, spinosad and hexythiazox have virulence of 67.39ppm and 46.24ppm respectively after 72 hours of medicament treatment.
TABLE 1 toxicity of spinosad and hexythiazox insecticides against Tetranychus cinnabarinus
1.4.2 comparison of acaricidal activity of mixed agents with different proportions
Respectively approaching spinosad and hexythiazox to LC50The mass concentrations of the values 70mg/L and 50mg/L were compounded in pairs at different volume ratios, and the results are shown in Table 2, respectively. The mortality rate of the treated test insects of spinosad and hexythiazox in each ratio is higher than the expected mortality rate, the co-toxicity factors are between 11.36 and 48, and the co-toxicity factors are additive and synergistic, wherein the co-toxicity factors are higher in the ratio of the volume ratio of spinosad to hexythiazox of 3:1 and the volume ratio of hexythiazox to 4:1, are respectively 44 and 48, and are respectively used in the two concentrationsThe mixed ratio of the two concentrations is used for measuring the toxicity of the mixed agent to tetranychus cinnabarinus, and the co-toxicity coefficient is calculated so as to further determine whether the ratio of the two concentrations has a synergistic effect.
TABLE 2 comparison of the indoor biological activity of the combined insecticides of spinosad and hexythiazox in different ratios on tetranychus cinnabarinus
1.4.3 determination of toxicity and co-toxicity coefficient of different combined mixed agents on tetranychus cinnabarinus adults
The combined action of the 4:1 and 3:1 mixture ratio combination of spinosad and hexythiazox on tetranychus cinnabarinus is determined by adopting a co-toxicity coefficient method. The results show that: the co-toxicity coefficient of the 2 compound combinations is more than 120, and the composition has obvious synergistic effect, wherein the co-toxicity coefficient of the spinosad and the hexythiazox in a ratio (4:1) reaches 531.20, the synergistic effect is most obvious, the insecticidal activity is highest, and the control effect is better.
TABLE 3 toxicity and co-toxicity coefficient of different combinations of mixed agents against Tetranychus cinnabarinus
Example 2 field efficacy of spinosad and hexythiazox and other compound insecticides on Tetranychus cinnabarinus
The field test sets 3 small areas for treatment, each small area is divided into certain limits, and the mixed agent with different concentrations and the drug effect of the single agent with corresponding concentrations are respectively measured. The clear water is used as a reference (CK), and isolation rows are arranged among all the cells. And (3) fixing 3 points for each 5 treated seedlings in the cells of different mixed agents and corresponding single agents, picking 3 leaves from each point every 24h, 48h and 72h after the application, returning the leaves to the laboratory for counting the total population and dead population, calculating the population mortality rate after different treatment times, and calculating the corrected control effect.
As can be seen from table 4: the field control effects of the 4 treatment agents are not obviously different, the spinosad and hexythiazox compound agent has the control effect on spider mites of 52 percent under the condition that the mixture ratio is 3:1 and the concentration is 30ppm, the control effect on the spider mites of 60 percent under the conditions that the mixture ratio is 4:1 and the concentration is 30ppm is higher than the control effects of a single spinosad agent of 60ppm and hexythiazox of 50ppm, and the control effects of the spinosad agent and the single spinosad agent are obviously different, which shows that the two mixed agents can effectively reduce the field application concentration of the agents and obtain the control effect higher than that of the single agent.
TABLE 4 field test results of Spinosad, hexythiazox and other compound insecticides on Tetranychus cinnabarinus
Note: different lower case after the same column of data indicate significant difference (P < 0.05).
The invention provides a compound pesticide containing spinosad and hexythiazox and an application thought and a method thereof, and a plurality of methods and ways for realizing the technical scheme are provided. All the components not specified in the present embodiment can be realized by the prior art.
Claims (10)
1. A composition characterized in that the active ingredients of the composition comprise spinosad and hexythiazox.
2. The composition according to claim 1, wherein the mass ratio of the spinosad to the hexythiazox is (0.1-10): 1.
3. The composition according to claim 1, wherein the mass ratio of the spinosad to the hexythiazox is (3.7-6.1): 1.
4. The composition according to claim 1, wherein the mass ratio of the spinosad to the hexythiazox is (4.2-5.6): 1.
5. The composition of claim 1, wherein the spinosyn and hexythiazox are present in a mass ratio of 4.2:1 or 5.6: 1.
6. An insecticide comprising the composition of any one of claims 1 to 5.
7. The insecticide according to claim 6, wherein the insecticide is a pesticide for controlling spider mites.
8. Use of a composition according to any one of claims 1 to 5 in the preparation of a pesticide.
9. The use as claimed in claim 8, wherein the insecticide is a tetranychid control insecticide.
10. The insecticide according to claim 7, or the use according to claim 9, wherein said tetranychus is tetranychus in vegetables and/or flowers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210276870.6A CN114532349B (en) | 2022-03-21 | 2022-03-21 | Compound pesticide containing spinosad and hexythiazox and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210276870.6A CN114532349B (en) | 2022-03-21 | 2022-03-21 | Compound pesticide containing spinosad and hexythiazox and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114532349A true CN114532349A (en) | 2022-05-27 |
| CN114532349B CN114532349B (en) | 2023-05-09 |
Family
ID=81665892
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210276870.6A Active CN114532349B (en) | 2022-03-21 | 2022-03-21 | Compound pesticide containing spinosad and hexythiazox and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114532349B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101808522A (en) * | 2007-09-26 | 2010-08-18 | 拜尔农作物科学股份公司 | Active agent combinations having insecticidal and acaricidal properties |
| CN106572658A (en) * | 2014-08-26 | 2017-04-19 | 美国陶氏益农公司 | Molecules having certain pesticidal utilities, and intermediates, compositions, and processes related thereto |
| CN108330071A (en) * | 2017-01-19 | 2018-07-27 | 中国科学院上海生命科学研究院 | Have Strain of Beauveria bassiana and its control of insect application of insect gut infection effect |
-
2022
- 2022-03-21 CN CN202210276870.6A patent/CN114532349B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101808522A (en) * | 2007-09-26 | 2010-08-18 | 拜尔农作物科学股份公司 | Active agent combinations having insecticidal and acaricidal properties |
| CN106572658A (en) * | 2014-08-26 | 2017-04-19 | 美国陶氏益农公司 | Molecules having certain pesticidal utilities, and intermediates, compositions, and processes related thereto |
| CN108330071A (en) * | 2017-01-19 | 2018-07-27 | 中国科学院上海生命科学研究院 | Have Strain of Beauveria bassiana and its control of insect application of insect gut infection effect |
Non-Patent Citations (1)
| Title |
|---|
| 苏莉珊: "蔬菜叶螨的综合防治" * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114532349B (en) | 2023-05-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101803605B (en) | Insecticidal composition of butene-fipronil and spinosad | |
| CN116897948A (en) | Pesticide for preventing and treating tea-stick thrips | |
| CN103947647A (en) | Insecticidal composition | |
| CN114532349B (en) | Compound pesticide containing spinosad and hexythiazox and application thereof | |
| CN114847293B (en) | Pesticide composition and application thereof | |
| CN112400903A (en) | Beauveria bassiana and cyenopyrafen compound insecticidal composition | |
| CN110973136A (en) | Pesticide composition containing flonicamid and sincalide and application thereof | |
| CN109907051B (en) | Insecticidal composition containing fluazinam and propargite | |
| CN107372554B (en) | Formula of novel high-efficiency cockroach killing bait | |
| CN115251079B (en) | Composition for preventing and controlling taro field aphids | |
| CN116172006B (en) | Pesticide composition for preventing and controlling balsam pear melon fruit fly | |
| CN109122692B (en) | Insecticidal and acaricidal pesticide composition with synergistic effect | |
| CN109006857A (en) | It is a kind of to kill thrips composition containing emamectin benzoate and thiacloprid | |
| CN103004842A (en) | Pesticide compound composition comprising acetamiprid and flonicamid | |
| CN115968892B (en) | Insecticidal composition for preventing and controlling taro field red spiders | |
| CN114651826B (en) | Insecticidal composition for preventing and controlling taro Tian Xiewen noctuid | |
| CN111248210A (en) | Compound insecticide | |
| CN116548452A (en) | Application of chlorantraniliprole-containing composition in control of plutella xylostella | |
| CN116548453A (en) | Application of suspension composition containing cyromazine in preventing and controlling chive spot fly | |
| CN116548460A (en) | Application of dinotefuran-containing composition in preventing and controlling cauliflower cabbage caterpillars | |
| CN117652521A (en) | Combined synergistic insecticidal composition for preventing and treating tea wing stinkbug | |
| CN116210713A (en) | Insecticidal composition containing bromarol diamide | |
| CN113115780A (en) | Insecticidal composition containing spinosad and thiocyclam | |
| CN116420732A (en) | Insecticidal composition containing bromarol diamide | |
| CN115005226A (en) | Insecticidal composition for preventing and treating corn armyworm |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |