CN114456003A - Flower-promoting and fruit-promoting type microelement liquid fertilizer and preparation method thereof - Google Patents

Flower-promoting and fruit-promoting type microelement liquid fertilizer and preparation method thereof Download PDF

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Publication number
CN114456003A
CN114456003A CN202210152694.5A CN202210152694A CN114456003A CN 114456003 A CN114456003 A CN 114456003A CN 202210152694 A CN202210152694 A CN 202210152694A CN 114456003 A CN114456003 A CN 114456003A
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parts
seaweed
liquid fertilizer
sugar alcohol
proline
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CN202210152694.5A
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Chinese (zh)
Inventor
张斌
刘颖
安卓
张帆
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Shaanxi Max Agricultural Technology Co ltd
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Shaanxi Max Agricultural Technology Co ltd
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Priority to CN202210152694.5A priority Critical patent/CN114456003A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C11/00Other nitrogenous fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/20Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation using specific microorganisms or substances, e.g. enzymes, for activating or stimulating the treatment
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Health & Medical Sciences (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Fertilizers (AREA)

Abstract

The invention relates to a flower promoting and fruit promoting type microelement liquid fertilizer, which comprises the following components in parts by weight: 50-150 parts of gulfweed, 750 parts of softened water, 25-75 parts of cellulase, 20-40 parts of citric acid, 1-5 parts of pectinase, 1-4 parts of alkaline protease, 50-150 parts of mannitol, 450 parts of cosolvent triethanolamine 350-. The invention also discloses a preparation method of the liquid fertilizer. The invention has strong functionality and can be widely applied to the technical field of agricultural production.

Description

Flower-promoting and fruit-promoting type microelement liquid fertilizer and preparation method thereof
Technical Field
The invention relates to the technical field of agricultural production, in particular to a flower-promoting and fruit-promoting type microelement liquid fertilizer and a preparation method thereof.
Background
The liquid fertilizer in the prior art has the defects of poor stability, low absorption rate and slow transportation speed; in addition, the liquid fertilizer in the prior art has the defects of less flowering, low fruit setting rate, serious flower and fruit dropping phenomenon and incapability of realizing the functions of promoting flower and promoting fruit, and the liquid fertilizer also has the defect of incapability of ensuring that the survival capability of flowers and fruits can be improved in adverse circumstances in the specific implementation process.
Disclosure of Invention
Aiming at the problems, the invention provides a liquid fertilizer capable of solving the problems of flower and fruit dropping, low fruit setting rate and the like, and provides a preparation method of the liquid fertilizer.
The technical scheme provided by the invention is as follows:
a flower and fruit promoting type microelement liquid fertilizer comprises the following components in parts by weight:
50-150 parts of gulfweed, 750 parts of softened water, 25-75 parts of cellulase, 20-40 parts of citric acid, 1-5 parts of pectinase, 1-4 parts of alkaline protease, 50-150 parts of mannitol, 450 parts of cosolvent triethanolamine 350, 20-40 parts of proline, 450 parts of boric acid 353-containing material, 267-300 parts of EDTA-Zn and 4-6 parts of preservative Kathon.
Further, the feed comprises the following components in parts by weight:
50 parts of gulfweed, 250 parts of softened water, 25 parts of cellulase, 20 parts of citric acid, 1 part of pectinase, 1 part of alkaline protease, 50 parts of mannitol, 350 parts of cosolvent triethanolamine, 20 parts of proline, 353 parts of boric acid, 267 parts of EDTA-Zn and 4 parts of preservative Kathon.
Further, the feed comprises the following components in parts by weight:
150 parts of gulfweed, 750 parts of softened water, 75 parts of cellulase, 40 parts of citric acid, 5 parts of pectinase, 4 parts of alkaline protease, 150 parts of mannitol, 450 parts of cosolvent triethanolamine, 40 parts of proline, 450 parts of boric acid, 300 parts of EDTA-Zn and 6 parts of preservative kasong.
Further, the feed comprises the following components in parts by weight:
100 parts of gulfweed, 500 parts of softened water, 50 parts of cellulase, 30 parts of citric acid, 3 parts of pectinase, 2.5 parts of alkaline protease, 100 parts of mannitol, 400 parts of cosolvent triethanolamine, 30 parts of proline, 400 parts of boric acid, 260 parts of EDTA-Zn and 5 parts of preservative Kathon.
The invention also provides a technical scheme that:
the preparation method of the liquid fertilizer at least comprises the following implementation processes:
(1) pretreatment: cleaning Sargassum with clear water, air drying, and pulverizing;
preparing a seaweed stock solution: adding the pretreated dry sargassum powder and softened water into a reaction kettle A according to the proportion of 1:5, adding 1 million u/g of cellulase according to the weight of 0.5 percent of the dry sargassum powder, adjusting the pH to 5.0 by using citric acid, controlling the temperature to be 45-50 ℃, and carrying out enzymolysis for 3 hours; adding 1 million u/g of pectinase according to the weight of 0.5 percent of the dry sargassum powder, adjusting the pH to 4.0, controlling the temperature at 45-50 ℃, and carrying out enzymolysis for 3 hours; then adding 1 ten thousand u/g of alkaline protease according to the weight of 0.5 percent of the dry sargassum powder, adjusting the pH to 6.0, controlling the temperature to be 50-55 ℃, and carrying out enzymolysis for 4 hours;
(2) enzyme deactivation and sterilization: heating to 95 deg.C for half an hour, and cooling to room temperature;
(3) centrifuging: centrifugally separating the reactant, and reserving the supernatant for later use;
(4) adding softened water, the seaweed stock solution and mannitol into a reaction kettle in sequence, and stirring for 30min until the materials are completely dissolved to obtain sugar alcohol seaweed liquid;
(5) adding cosolvents triethanolamine and proline into the sugar alcohol seaweed liquid, and stirring until the cosolvents triethanolamine and proline are completely dissolved to obtain a sugar alcohol seaweed amino acid liquid;
(6) adding boric acid into the sugar alcohol seaweed amino acid liquid, and continuously stirring for reaction for 120min to obtain boron liquid containing the sugar alcohol seaweed amino acid;
(7) and adding EDTA-Zn and a preservative kasong into the boron liquid containing the sugar alcohol, the seaweed amino acid, continuously stirring, standing and filtering to obtain the liquid fertilizer.
Furthermore, in the liquid fertilizer, proline is more than or equal to 20g/L, sugar alcohol is more than or equal to 50g/L, seaweed extract is more than or equal to 100g/L, B is more than or equal to 60g/L, and Zn is more than or equal to 40 g/L.
Compared with the prior art, the invention has the advantages that:
the liquid fertilizer is rich in organic nutrients such as chelated boron and zinc, seaweed extracts and the like, can effectively promote crops to bloom and strengthen flowers, improve fruit setting rate, prevent flower and fruit dropping, and has the effects of promoting flower and fruit;
the seaweed extract and the proline can improve the stress resistance of crops, particularly the lodging-resistant spring cold resistance of flowers and fruits, and enhance the survival ability of the flowers and fruits in the stress; the foliar fertilizer is rich in zinc and organic nutrition, can prevent the occurrence of lobular disease, can promote the thickening and the glossy leaf color of the leaves, enhances the photosynthesis, accumulates more carbohydrates and enables the crops to grow more robustly;
this liquid fertilizer adopts two chelation techniques, utilizes sugar alcohol and amino acid to carry out the chelation with zinc boron simultaneously, compares single material chelation, and stability is higher, and the transport speed is faster, absorbs more high-efficiently.
Detailed Description
The present invention will be described in further detail with reference to examples.
The flower and fruit promoting type microelement liquid fertilizer provided by the invention comprises the following components in parts by weight:
50-150 parts of gulfweed, 750 parts of softened water, 25-75 parts of cellulase, 20-40 parts of citric acid, 1-5 parts of pectinase, 1-4 parts of alkaline protease, 50-150 parts of mannitol, 450 parts of cosolvent triethanolamine 350, 20-40 parts of proline, 450 parts of boric acid 353-containing material, 267-300 parts of EDTA-Zn and 4-6 parts of preservative Kathon.
The preparation process of the liquid fertilizer by using the components provided by the invention comprises the following implementation processes:
(1) pretreatment: cleaning Sargassum with clear water, air drying, and pulverizing;
preparing a seaweed stock solution: adding the pretreated dry sargassum powder and softened water into a reaction kettle A according to the proportion of 1:5, adding 1 million u/g of cellulase according to the weight of 0.5 percent of the dry sargassum powder, adjusting the pH to 5.0 by using citric acid, controlling the temperature to be 45-50 ℃, and carrying out enzymolysis for 3 hours; adding 1 million u/g of pectinase according to the weight of 0.5 percent of the dry sargassum powder, adjusting the pH to 4.0, controlling the temperature at 45-50 ℃, and carrying out enzymolysis for 3 hours; then adding 1 ten thousand u/g of alkaline protease according to the weight of 0.5 percent of the dry sargassum powder, adjusting the pH to 6.0, controlling the temperature to be 50-55 ℃, and carrying out enzymolysis for 4 hours;
(2) enzyme deactivation and sterilization: heating to 95 deg.C for half an hour, and cooling to room temperature;
(3) centrifuging: centrifugally separating the reactant, and reserving the supernatant for later use;
(4) adding softened water, the seaweed stock solution and mannitol into a reaction kettle in sequence, and stirring for 30min until the materials are completely dissolved to obtain sugar alcohol seaweed liquid;
(5) adding cosolvents triethanolamine and proline into the sugar alcohol seaweed liquid, and stirring until the cosolvents triethanolamine and proline are completely dissolved to obtain a sugar alcohol seaweed amino acid liquid;
(6) adding boric acid into the sugar alcohol seaweed amino acid liquid, and continuously stirring for reaction for 120min to obtain boron liquid containing the sugar alcohol seaweed amino acid;
(7) and adding EDTA-Zn and a preservative kasong into the boron liquid containing the sugar alcohol, the seaweed amino acid, continuously stirring, standing and filtering to obtain the liquid fertilizer.
In the liquid fertilizer obtained by the preparation method, proline is more than or equal to 20g/L, sugar alcohol is more than or equal to 50g/L, seaweed extract is more than or equal to 100g/L, B is more than or equal to 60g/L, and Zn is more than or equal to 40 g/L.
The present invention will be specifically described below with reference to specific examples.
A preparation method of a flower-promoting and fruit-promoting type microelement liquid fertilizer comprises the following steps:
(1) adding 180 parts of softened water, 100 parts of seaweed stock solution and 50 parts of mannitol into a reaction kettle in sequence by mass fraction, and stirring for 30min until the materials are completely dissolved to obtain sugar alcohol seaweed liquid;
(2) according to mass fraction, 350 parts of cosolvent triethanolamine and 20 parts of proline are stirred in the sugar alcohol seaweed liquid until the cosolvents triethanolamine and 20 parts of proline are completely dissolved to obtain a sugar alcohol seaweed amino acid liquid;
(3) adding 353 parts of boric acid into the sugar alcohol seaweed amino acid liquid by mass fraction, and continuously stirring for reaction for 120min to obtain boron liquid containing the sugar alcohol seaweed amino acid;
(4) 267 parts of EDTA-Zn and 5 parts of preservative kasong are added into boron liquid containing sugar alcohol, seaweed amino acid and continuously stirred for 120min, the mixture is kept stand and filtered to obtain the flower-promoting and fruit-promoting type microelement liquid fertilizer, proline is more than or equal to 20g/L, sugar alcohol is more than or equal to 50g/L, seaweed extract is more than or equal to 100g/L, B is more than or equal to 60g/L, and Zn is more than or equal to 40 g/L.
This is further illustrated by its application to a particular test field.
The test is arranged in a modern agriculture demonstration park in east Town of Jing county, Jing, Shanxi province, and the soil type is sandy moisture soil, organic matters are 18.4g/kg, alkaline hydrolysis nitrogen is 102mg/kg, quick-acting phosphorus is 22.7mg/kg, quick-acting potassium is 175mg/kg, and the pH value is 8.0. The tested land has even fertility, flat topography and convenient irrigation and drainage. The tomato variety is local main cultivated variety Provence, and the previous crop of the test field is Chinese cabbage. Before tomato transplantation, 2500 kg of decomposed chicken manure and 50 kg of compound fertilizer are applied to each mu in a combined soil preparation mode. Three treatment tests are designed, 3 treatments are set, the treatment is repeated for 3 times, 9 cells are formed, and the area of each cell is 20 square meters. The length multiplied by the width is 10 meters multiplied by 2 meters, and the furrows are isolated among cells.
Treatment (1): and (5) applying 2500 kg of mature rotten chicken manure and 50 kg of nitrogen-phosphorus-potassium (20-10-15) ternary compound fertilizer per mu of conventional fertilizer and applying 30 kg of urea.
Treatment (2): conventional fertilizer + clear water Control (CK). Respectively, the first cluster walnut and the test are performed at the same period.
Treatment (3): the conventional fertilizer and the flower-promoting and fruit-promoting type microelement liquid fertilizer provided by the invention are sprayed on leaf surfaces, the dilution concentration is 600 times, the fertilizer is sprayed on the first cluster of walnut trees at a large start, the spraying is carried out for three times, each time is separated by 15 days, and the using amount is carried out according to the product specification.
Results and analysis
Influence on tomato production factors
According to the investigation of each test cell in different growth periods of the tomatoes, the plant height, the number of fruits per plant and the average weight of the fruits are obviously different among 3 treatments, and the fruits are uniform and bright in color in the treatment (3) compared with the fruits in the treatment (1) and the treatment (2) in the appearance of the fruits.
Effect on tomato yield
The test results show that the treatment (3) is carried out every 667m2The tomato yield is 6453.2kg, and the net yield is increased by 10.6 percent compared with the yield increased by 620.3kg in the treatment (1); compared with the treatment (2), the yield of the product is increased by 550.2kg, and the yield is increased by 9.3%.
On the basis of conventional fertilization, 50ml of fertilizer to be tested is added with 30 kg of water, the fertilizer is sprayed once every 15 days from the fruiting period of the tomatoes and is sprayed for 3 times totally, compared with the conventional fertilization in the same period, the number of fruits per plant and the weight of each fruit are increased, the yield is improved, and the average yield is increased every 667m2The yield is increased by 620.3kg, the yield is increased by 10.6 percent, and the yield difference reaches an extremely obvious level.
The present invention and the embodiments thereof have been described above, but the description is not limited thereto, and the embodiments shown in the examples are only one of the embodiments of the present invention, and the actual content is not limited thereto. In summary, those skilled in the art should appreciate that embodiments and examples similar to those of the present invention can be devised without departing from the spirit and scope of the invention.

Claims (6)

1. The flower and fruit promoting type microelement liquid fertilizer is characterized by comprising the following components in parts by weight:
50-150 parts of gulfweed, 750 parts of softened water, 25-75 parts of cellulase, 20-40 parts of citric acid, 1-5 parts of pectinase, 1-4 parts of alkaline protease, 50-150 parts of mannitol, 450 parts of cosolvent triethanolamine 350, 20-40 parts of proline, 450 parts of boric acid 353-containing material, 267-300 parts of EDTA-Zn and 4-6 parts of preservative Kathon.
2. The flower and fruit promoting type microelement liquid fertilizer according to claim 1, which is characterized by comprising the following components in parts by weight:
50 parts of gulfweed, 250 parts of softened water, 25 parts of cellulase, 20 parts of citric acid, 1 part of pectinase, 1 part of alkaline protease, 50 parts of mannitol, 350 parts of cosolvent triethanolamine, 20 parts of proline, 353 parts of boric acid, 267 parts of EDTA-Zn and 4 parts of preservative Kathon.
3. The flower and fruit promoting type microelement liquid fertilizer according to claim 1, which is characterized by comprising the following components in parts by weight:
150 parts of gulfweed, 750 parts of softened water, 75 parts of cellulase, 40 parts of citric acid, 5 parts of pectinase, 4 parts of alkaline protease, 150 parts of mannitol, 450 parts of cosolvent triethanolamine, 40 parts of proline, 450 parts of boric acid, 300 parts of EDTA-Zn and 6 parts of preservative kasong.
4. The flower and fruit promoting type microelement liquid fertilizer according to claim 1, which is characterized by comprising the following components in parts by weight:
100 parts of gulfweed, 500 parts of softened water, 50 parts of cellulase, 30 parts of citric acid, 3 parts of pectinase, 2.5 parts of alkaline protease, 100 parts of mannitol, 400 parts of cosolvent triethanolamine, 30 parts of proline, 400 parts of boric acid, 260 parts of EDTA-Zn and 5 parts of preservative Kathon.
5. A method for preparing a liquid fertilizer according to any one of claims 1 to 4, characterized by comprising at least the following implementation processes:
(1) pretreatment: cleaning Sargassum with clear water, air drying, and pulverizing;
preparing a seaweed stock solution: adding the pretreated dry sargassum powder and softened water into a reaction kettle A according to the proportion of 1:5, adding 1 million u/g of cellulase according to the weight of 0.5 percent of the dry sargassum powder, adjusting the pH to 5.0 by using citric acid, controlling the temperature to be 45-50 ℃, and carrying out enzymolysis for 3 hours; adding 1 million u/g of pectinase according to the weight of 0.5 percent of the dry sargassum powder, adjusting the pH to 4.0, controlling the temperature at 45-50 ℃, and carrying out enzymolysis for 3 hours; then adding 1 ten thousand u/g of alkaline protease according to the weight of 0.5 percent of the dry sargassum powder, adjusting the pH to 6.0, controlling the temperature to be 50-55 ℃, and carrying out enzymolysis for 4 hours;
(2) enzyme deactivation and sterilization: heating to 95 deg.C for half an hour, and cooling to room temperature;
(3) centrifuging: centrifugally separating the reactant, and reserving the supernatant for later use;
(4) adding softened water, the seaweed stock solution and mannitol into a reaction kettle in sequence, and stirring for 30min until the materials are completely dissolved to obtain sugar alcohol seaweed liquid;
(5) adding cosolvents triethanolamine and proline into the sugar alcohol seaweed liquid, and stirring until the cosolvents triethanolamine and proline are completely dissolved to obtain a sugar alcohol seaweed amino acid liquid;
(6) adding boric acid into the sugar alcohol seaweed amino acid liquid, and continuously stirring for reaction for 120min to obtain boron liquid containing the sugar alcohol seaweed amino acid;
(7) and adding EDTA-Zn and a preservative kasong into the boron liquid containing the sugar alcohol, the seaweed amino acid, continuously stirring, standing and filtering to obtain the liquid fertilizer.
6. The preparation method of the liquid fertilizer as claimed in claim 5, wherein proline is more than or equal to 20g/L, sugar alcohol is more than or equal to 50g/L, seaweed extract is more than or equal to 100g/L, B is more than or equal to 60g/L, and Zn is more than or equal to 40 g/L.
CN202210152694.5A 2022-02-18 2022-02-18 Flower-promoting and fruit-promoting type microelement liquid fertilizer and preparation method thereof Pending CN114456003A (en)

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CN202210152694.5A CN114456003A (en) 2022-02-18 2022-02-18 Flower-promoting and fruit-promoting type microelement liquid fertilizer and preparation method thereof

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103058750A (en) * 2012-12-19 2013-04-24 华南农业大学 Seaweed amino acid composite liquid manure and preparation method and application thereof
CN105859445A (en) * 2016-06-08 2016-08-17 国乃胜 Environment-friendly algae amino acid compound fertilizer
CN106866268A (en) * 2017-03-24 2017-06-20 上海芳甸生物科技有限公司 Water-soluble fertilizer that a kind of Accelerate bloom is beared fruit and preparation method thereof
CN112047780A (en) * 2020-08-18 2020-12-08 陕西麦克斯农业科技股份有限公司 Compound liquid fertilizer containing algin amino acid and calcium, boron, zinc, iron, copper and manganese
CN113321563A (en) * 2021-06-18 2021-08-31 创想未来生物工程(北京)有限公司 Seaweed organic water-soluble fertilizer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103058750A (en) * 2012-12-19 2013-04-24 华南农业大学 Seaweed amino acid composite liquid manure and preparation method and application thereof
CN105859445A (en) * 2016-06-08 2016-08-17 国乃胜 Environment-friendly algae amino acid compound fertilizer
CN106866268A (en) * 2017-03-24 2017-06-20 上海芳甸生物科技有限公司 Water-soluble fertilizer that a kind of Accelerate bloom is beared fruit and preparation method thereof
CN112047780A (en) * 2020-08-18 2020-12-08 陕西麦克斯农业科技股份有限公司 Compound liquid fertilizer containing algin amino acid and calcium, boron, zinc, iron, copper and manganese
CN113321563A (en) * 2021-06-18 2021-08-31 创想未来生物工程(北京)有限公司 Seaweed organic water-soluble fertilizer

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