CN114437298A - 抗菌耐磨鞋用3d打印树脂 - Google Patents
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Abstract
本发明提供了一种抗菌耐磨鞋用3D打印树脂,运用于3D打印领域包括:原料重量组份如下:端羧基丁二烯改性丙烯酸酯20~40份、氟代烷烃改性丙烯酸酯类单体10~30份、活性稀释剂10~15份,阻聚剂1~2份、光引发剂2~3份、颜料3~5份、填料10~15份,抗菌整理剂0.5~2份,硅烷偶联剂5~10份;本发明得到的抗菌耐磨鞋用3D打印树脂,树脂复合鞋类材料要求的高弹性,耐摩性,同时具备抗菌性的要求,可以用在3D打印鞋类领域。
Description
技术领域
本发明涉及3D打印技术领域,特别涉及为一种抗菌耐磨鞋用3D打印树脂。
背景技术
近年来,随着技术的不断成熟,3D打印除了应用于工艺品设计、医疗器械制造等领域之外,也开始应用于服装鞋帽领域,3D打印跑鞋、3D打印旗袍等也开始出现在各大秀场上。
采用3D打印技术可以有效缩短产品的研发周期,并进一步验证设计师的创意是否可行。按照传统方式进行鞋类产品设计时,鞋模样品通常采用钻头、车床、制模机等工具,制作过程耗时费力。采用3D打印技术后,可以利用计算机将鞋样设计图纸转换为模型,这样做就克服了传统工艺的局限性,并更好的体现不同群体个性化要求。采用3D打印技术制鞋效率高,灵活性强。采用3D打印技术可以不受结构限制,让设计师自由地释放自己的创意。与此同时,3D打印技术为设计师及时修改设计方案提供了便利,并减少了因模具重制产生的前期成本。采用3D打印技术有望实现不同消费者个性化定制鞋子的需求。通常来说,由于工序、原料、研发等成本因素,定制鞋的价格比普通鞋高出不少。3D打印技术通过缩短研发周期、降低模具成本、提高材料利用率等,能最大限度缩减制鞋企业的生产成本。但是由于工艺与材料的限制,目前的3D打印材料比较脆,同时耐磨和耐污能力较弱,打印运动鞋舒适度不太好,不能满足人们对其的需求,因此研究一种弹性耐磨抗菌材料用于3D打印鞋类意义重大。
发明内容
本发明旨在解决3D打印材料比较脆,同时耐磨和耐污能力较弱,不能适用3D打印鞋类的技术问题,提供一种抗菌耐磨鞋用3D打印树脂。
本发明提供一种抗菌耐磨鞋用3D打印树脂,原料重量组份包括:端羧基丁二烯改性丙烯酸酯20~40份、氟代烷烃改性丙烯酸酯类单体10~30份、活性稀释剂10~15份、阻聚剂1~2份、光引发剂2~3份、颜料3~5份、填料10~15份、抗菌整理剂0.5~2份和硅烷偶联剂5~10份。
进一步的,所述的抗菌耐磨鞋用3D打印树脂,所述端羧基丁二烯改性丙烯酸酯为端羧基丁二烯改性聚氨酯丙烯酸酯或者丁二烯改性聚酯丙烯酸酯。
进一步的,所述的抗菌耐磨鞋用3D打印树脂,所述活性稀释剂包括TMPTA或/和TPGDA。
进一步的,所述的抗菌耐磨鞋用3D打印树脂,所述阻聚剂包括对笨酚、对甲氧基酚以及对苯醌中的一种或多种。
进一步的,所述的抗菌耐磨鞋用3D打印树脂,所述光引发剂包括TPO或/和184。
进一步的,所述的抗菌耐磨鞋用3D打印树脂,所述颜料包括钛白粉、立德粉以及色浆中的一种或多种。
进一步的,所述的抗菌耐磨鞋用3D打印树脂,所述的填料选自碳酸钙、硫酸钡、氢氧化铝、二氧化硅以及滑石粉中的一种或多种。
进一步的,所述的抗菌耐磨鞋用3D打印树脂,所述抗菌整理剂包括ATB9800、SCJ-963、SCJ-2000以及SCJ-891中的一种或多种。
一种抗菌耐磨鞋用3D打印树脂的制备方法,包括以下步骤:
S1:将端羧基丁二烯改性丙烯酸酯20-30份、氟代烷烃改性丙烯酸酯类单体10份~30份、活性稀释剂10-15份、阻聚剂1~2份、光引发剂2份~3份、颜料3份~5份、填料10份~15份和抗菌整理剂0.5-2份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
本发明提供了抗菌耐磨鞋用3D打印树脂,具有以下有益效果:本发明的端羧基丁二烯改性聚氨酯丙烯酸酯20-30份是一种弹性树脂单体,氟碳树脂具有优异的低摩擦系数、憎水憎油、耐沾污等性能,JLSUN®抗菌剂具有明显的抗菌、消炎、防臭、防霉、止痒、收敛作用,抑菌率高达99%以上,高度耐干洗和水洗;对皮肤无刺激性、无过敏反应,无毒,无致畸性,无致突变性,无潜在致癌性,不含甲醛和重金属离子等有害物质,符合环保要求,满足Oeko-Tex stand 100的标准;能有效地预防疾病通过织物传染,对防治脚癣、股癣、湿疹、疖痈、汗臭、脚臭、皮肤骚痒有显著效果。
附图说明
图1是本发明抗菌耐磨鞋用3D打印树脂的方法流程图;
图2是本发明抗菌耐磨鞋用3D打印树脂的实验结果图。
本发明为目的的实现、功能特点及优点将结合实施例,参照附图做进一步说明。
具体实施方式
应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。
下面将结合本发明的实施例中的附图,对本发明的实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
参考附图1-2,为本发明一种抗菌耐磨鞋用3D打印树脂的制备方法的流程图;
一种抗菌耐磨鞋用3D打印树脂,原料重量组份包括:端羧基丁二烯改性丙烯酸酯20~40份、氟代烷烃改性丙烯酸酯类单体10~30份、活性稀释剂10~15份、阻聚剂1~2份、光引发剂2~3份、颜料3~5份、填料10~15份、抗菌整理剂0.5~2份和硅烷偶联剂5~10份。
所述端羧基丁二烯改性丙烯酸酯为端羧基丁二烯改性聚氨酯丙烯酸酯或者丁二烯改性聚酯丙烯酸酯。
所述活性稀释剂包括TMPTA或/和TPGDA。
所述阻聚剂包括对笨酚、对甲氧基酚以及对苯醌中的一种或多种。
所述光引发剂包括TPO或/和184。
所述颜料包括钛白粉、立德粉以及色浆中的一种或多种。
所述的填料选自碳酸钙、硫酸钡、氢氧化铝、二氧化硅以及滑石粉中的一种或多种。
所述抗菌整理剂包括ATB9800、SCJ-963、SCJ-2000以及SCJ-891中的一种或多种。
一种抗菌耐磨鞋用3D打印树脂的制备方法,包括以下步骤:
S1:将端羧基丁二烯改性丙烯酸酯20-30份、氟代烷烃改性丙烯酸酯类单体10份~30份、活性稀释剂10-15份、阻聚剂1~2份、光引发剂2份~3份、颜料3份~5份、填料10份~15份和抗菌整理剂0.5-2份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
对比例1:
S1:将端羧基丁二烯改性聚氨酯丙烯酸酯20份、氟代烷烃改性丙烯酸酯类单体30份、活性稀释剂TMPTA为15份、阻聚剂对笨酚2份、光引发剂TPO为3份、颜料立德粉5份、填料二氧化硅15份和硅烷偶联剂10份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
对比例2:
S1:将聚氨酯丙烯酸酯40份、氟代烷烃改性丙烯酸酯类单体25份、活性稀释剂TMPTA为15份,阻聚剂对笨酚2份、光引发剂TPO为3份、颜料立德粉5份、硅烷偶联剂10份、抗菌剂SCJ-963为1份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
实施例1:
S1:将端羧基丁二烯改性聚酯丙烯酸酯40份、氟代烷烃改性丙烯酸酯类单体10份、活性稀释剂TMPTA为15份、阻聚剂对笨酚1份、光引发剂TPO为 3份、颜料立德粉5份、填料二氧化硅15份、抗菌剂SCJ-963为1份和硅烷偶联剂10份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
实施例2:
S1:将端羧基丁二烯改性聚氨酯丙烯酸酯35份、氟代烷烃改性丙烯酸酯类单体15份、活性稀释剂TMPTA为15份、阻聚剂对苯醌2份、光引发剂TPO为3份、颜料立德粉5份、填料碳酸钙15份,抗菌剂SCJ-963为2份和硅烷偶联剂8份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
实施例3:
S1;将端羧基丁二烯改性聚氨酯丙烯酸酯25份、氟代烷烃改性丙烯酸酯类单体30份、活性稀释剂TPGDA为12份,阻聚剂对甲氧基酚1.5份、光引发剂TPO2份、颜料钛白粉5份、填料滑石粉15份,抗菌剂SCJ-963为0.5份和硅烷偶联剂9份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
实施例4:
S1;将端羧基丁二烯改性聚氨酯丙烯酸酯35份、氟代烷烃改性丙烯酸酯类单体20份、活性稀释剂TMPTA为15份,阻聚剂笨酚2份、光引发剂TPO为2份、颜料立德粉5份、填料二氧化硅15份、抗菌剂SCJ-963为1份和硅烷偶联剂5份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
实施例5:
S1;将端羧基丁二烯改性聚氨酯丙烯酸酯40份、氟代烷烃改性丙烯酸酯类单体20份、活性稀释剂TMPTA为15份、阻聚剂笨酚1份、光引发剂184为3份、颜料立德粉3份、填料氢氧化铝10份、抗菌剂SCJ-963为2份和硅烷偶联剂6份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
实施例6:
S1;将端羧基丁二烯改性聚氨酯丙烯酸酯30份、氟代烷烃改性丙烯酸酯类单体30份、活性稀释剂TMPTA为15份、阻聚剂笨酚1份、光引发剂TPO为2份、颜料立德粉3份、填料硫酸钡12份、抗菌剂ATB9800为2份和硅烷偶联剂5份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。
Claims (9)
1.一种抗菌耐磨鞋用3D打印树脂,其特征在于,原料重量组份包括:端羧基丁二烯改性丙烯酸酯20~40份、氟代烷烃改性丙烯酸酯类单体10~30份、活性稀释剂10~15份、阻聚剂1~2份、光引发剂2~3份、颜料3~5份、填料10~15份、抗菌整理剂0.5~2份和硅烷偶联剂5~10份。
2.根据权利要求1所述的抗菌耐磨鞋用3D打印树脂,其特征在于,所述端羧基丁二烯改性丙烯酸酯为端羧基丁二烯改性聚氨酯丙烯酸酯或者丁二烯改性聚酯丙烯酸酯。
3.根据权利要求1所述的抗菌耐磨鞋用3D打印树脂,其特征在于,所述活性稀释剂包括TMPTA或/和TPGDA。
4.根据权利要求1所述的抗菌耐磨鞋用3D打印树脂,其特征在于,所述阻聚剂包括对笨酚、对甲氧基酚以及对苯醌中的一种或多种。
5.根据权利要求1所述的抗菌耐磨鞋用3D打印树脂,其特征在于,所述光引发剂包括TPO或/和184。
6.根据权利要求1所述的抗菌耐磨鞋用3D打印树脂,其特征在于,所述颜料包括钛白粉、立德粉以及色浆中的一种或多种。
7.根据权利要求1所述的抗菌耐磨鞋用3D打印树脂,其特征在于,所述的填料选自碳酸钙、硫酸钡、氢氧化铝、二氧化硅以及滑石粉中的一种或多种。
8.根据权利要求1所述的抗菌耐磨鞋用3D打印树脂,其特征在于,所述抗菌整理剂包括ATB9800、SCJ-963、SCJ-2000以及SCJ-891中的一种或多种。
9.一种抗菌耐磨鞋用3D打印树脂的制备方法,根据权利要求1-8任一所述的抗菌耐磨鞋用3D打印树脂,其特征在于,包括以下步骤: S1:将端羧基丁二烯改性丙烯酸酯20-30份、氟代烷烃改性丙烯酸酯类单体10份~30份、活性稀释剂10-15份、阻聚剂1~2份、光引发剂2份~3份、颜料3份~5份、填料10份~15份和抗菌整理剂0.5-2份混合;
S2:将S1所述的混合物放入搅拌机中高速搅拌,使混合物分散均匀;
S3:将S2所得物放入超声波清洗机中超声震荡,得到所述的光固化树脂组合物。
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