CN114316727A - Wall wear-resistant material and preparation method thereof - Google Patents
Wall wear-resistant material and preparation method thereof Download PDFInfo
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- CN114316727A CN114316727A CN202011039605.3A CN202011039605A CN114316727A CN 114316727 A CN114316727 A CN 114316727A CN 202011039605 A CN202011039605 A CN 202011039605A CN 114316727 A CN114316727 A CN 114316727A
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Abstract
The invention discloses a wall surface wear-resistant material and a preparation method thereof, wherein the wall surface wear-resistant material comprises the following components in parts by mass: 30-45 parts of epoxy resin, 20-30 parts of modified graphene oxide, 2-5 parts of silica gel powder, 5-12 parts of carborundum, 3-8 parts of alumina powder, 5-12 parts of alcohol ester, 5-12 parts of anti-cracking fiber, 3-8 parts of xylene, 0.1-0.5 part of wetting agent, 0.2-0.4 part of defoaming agent, 0.5-1.5 parts of organic bentonite, 1-1.5 parts of preservative and 10-15 parts of color paste. Compared with the related technology, the wall wear-resistant material has the advantages of cost saving, no efflorescence and cracking, long service life and environmental protection.
Description
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a wall surface wear-resistant material and a preparation method thereof.
Background
The wear-resistant wall material is a decorative setting material for leveling the surface of a wall body, is thick paste paint and is an essential product before painting. Is applied on the primer or directly applied on the object to remove the defects of high and low unevenness on the surface of the object to be coated. It is made up by using a small quantity of paint base, a large quantity of filling material and a proper quantity of colouring pigment, and the used pigment mainly is iron red, carbon black and chrome yellow, etc., and the filling material mainly is heavy calcium carbonate and talcum powder, etc.. The wall wear-resistant material can fill a working surface with a local recess, can also be scraped off on the whole surface, is usually applied to the surface of a primer after the primer is dried completely, and has the requirements of good adhesion and no crack in the baking process. At present, traditional wear-resistant wall material powder is generally used for decorating building walls, the wear-resistant wall material powder is made of white latex, 107 glue, titanium dioxide and the like, the material has the defects of poor adhesion, poor water resistance, short service life and the like, and the surface of the wall is easy to roll skin, drop slag, crack, shed powder and the like.
However, with the development and progress of society, people have higher and higher requirements for the field of home decoration. The traditional wall decoration adopts the mode that more than three times of brushing is needed in the construction process, the construction process is complicated, the construction period is long, the efflorescence and the cracking are easy, and the environmental impact is great.
Therefore, in order to avoid the above technical problems, it is necessary to provide a novel wall wear-resistant material and a manufacturing method thereof, so as to overcome the above-mentioned drawbacks in the prior art.
Disclosure of Invention
The invention aims to provide a wear-resistant wall material which is cost-saving, free from efflorescence and cracking, long in service life and environment-friendly.
The technical solution of the invention is as follows:
the wall wear-resistant material comprises the following components in parts by mass: 30-45 parts of epoxy resin, 20-30 parts of modified graphene oxide, 2-5 parts of silica gel powder, 5-12 parts of carborundum, 3-8 parts of alumina powder, 5-12 parts of alcohol ester, 5-12 parts of anti-cracking fiber, 3-8 parts of xylene, 0.1-0.5 part of wetting agent, 0.2-0.4 part of defoaming agent, 0.5-1.5 parts of organic bentonite, 1-1.5 parts of preservative and 10-15 parts of color paste.
Further, the wall wear-resistant material comprises the following components in parts by mass: 30 parts of epoxy resin, 20 parts of modified graphene oxide, 2 parts of silica gel powder, 5 parts of carborundum, 3 parts of alumina powder, 5 parts of alcohol ester, 5 parts of anti-cracking fiber, 3 parts of dimethylbenzene, 0.1 part of wetting agent, 0.2 part of defoaming agent, 0.5 part of organic bentonite, 1 part of preservative and 10 parts of color paste.
Further, the wall wear-resistant material comprises the following components in parts by mass: 45 parts of epoxy resin, 30 parts of modified graphene oxide, 5 parts of silica gel powder, 12 parts of carborundum, 8 parts of alumina powder, 12 parts of alcohol ester, 12 parts of anti-cracking fiber, 8 parts of dimethylbenzene, 0.5 part of wetting agent, 0.4 part of defoaming agent, 1.5 parts of organic bentonite, 1.5 parts of preservative and 15 parts of color paste.
Further, the wall wear-resistant material comprises the following components in parts by mass: 40 parts of epoxy resin, 25 parts of modified graphene oxide, 4 parts of silica gel powder, 8 parts of carborundum, 5 parts of alumina powder, 10 parts of alcohol ester, 7 parts of anti-cracking fiber, 5 parts of dimethylbenzene, 0.3 part of wetting agent, 0.3 part of defoaming agent, 1.2 parts of organic bentonite, 1 part of preservative and 12 parts of color paste.
Further, the wetting agent adopts alkyl polyoxyethylene ether.
Further, tributyl phosphate is adopted as the defoaming agent.
The invention also provides a preparation method of the wall surface wear-resistant material, which comprises the following steps:
step 1, adding epoxy resin, a wetting agent, a defoaming agent and xylene into a production dispersion kettle according to a proportion, and stirring and mixing uniformly;
step 2, adding organic bentonite, anti-crack fibers, silica gel powder, alumina powder and carborundum into the production dispersion kettle in proportion, and dispersing to the requirement of the inspection standard;
step 3, adding the modified graphene oxide and the alcohol ester twelve into the production dispersion kettle in proportion, and mixing until the requirements of inspection standards are met;
and 4, adding color paste and a preservative into the production dispersion kettle in proportion, and mixing until the mixture meets the requirement of inspection standards to prepare the novel wall wear-resistant material.
Has the advantages that:
the wall wear-resistant material disclosed by the invention has super-strong adhesive force and good permeability by adopting the modified graphene oxide, does not contain silicate components, is not easy to crack due to efflorescence, is waterproof and breathable, can be widely applied to walls in various places, is wide in application range, simplifies construction procedures, saves cost, is longer in practical life, and is more environment-friendly.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Example 1:
the wall wear-resistant material comprises the following components in parts by mass: 30-45 parts of epoxy resin, 20-30 parts of modified graphene oxide, 2-5 parts of silica gel powder, 5-12 parts of carborundum, 3-8 parts of alumina powder, 5-12 parts of alcohol ester, 5-12 parts of anti-cracking fiber, 3-8 parts of xylene, 0.1-0.5 part of wetting agent, 0.2-0.4 part of defoaming agent, 0.5-1.5 parts of organic bentonite, 1-1.5 parts of preservative and 10-15 parts of color paste.
The invention also provides a preparation method of the wall wear-resistant material, which comprises the following steps:
step 1, adding epoxy resin, a wetting agent, a defoaming agent and xylene into a production dispersion kettle according to a proportion, and stirring and mixing uniformly;
step 2, adding organic bentonite, anti-crack fibers, silica gel powder, alumina powder and carborundum into the production dispersion kettle in proportion, and dispersing to the requirement of the inspection standard;
step 3, adding the modified graphene oxide and the alcohol ester twelve into the production dispersion kettle in proportion, and mixing until the requirements of inspection standards are met;
and 4, adding color paste and a preservative into the production dispersion kettle in proportion, and mixing until the mixture meets the requirement of inspection standards to prepare the novel wall wear-resistant material.
Example 2:
the wall wear-resistant material comprises the following components in parts by mass: 30 parts of epoxy resin, 20 parts of modified graphene oxide, 2 parts of silica gel powder, 5 parts of carborundum, 3 parts of alumina powder, 5 parts of alcohol ester, 5 parts of anti-cracking fiber, 3 parts of dimethylbenzene, 0.1 part of wetting agent, 0.2 part of defoaming agent, 0.5 part of organic bentonite, 1 part of preservative and 10 parts of color paste.
The invention also provides a preparation method of the wall wear-resistant material, which comprises the following steps:
step 1, adding epoxy resin, a wetting agent, a defoaming agent and xylene into a production dispersion kettle according to a proportion, and stirring and mixing uniformly;
step 2, adding organic bentonite, anti-crack fibers, silica gel powder, alumina powder and carborundum into the production dispersion kettle in proportion, and dispersing to the requirement of the inspection standard;
step 3, adding the modified graphene oxide and the alcohol ester twelve into the production dispersion kettle in proportion, and mixing until the requirements of inspection standards are met;
and 4, adding color paste and a preservative into the production dispersion kettle in proportion, and mixing until the mixture meets the requirement of inspection standards to prepare the novel wall wear-resistant material.
Example 3:
the wall wear-resistant material comprises the following components in parts by mass: 45 parts of epoxy resin, 30 parts of modified graphene oxide, 5 parts of silica gel powder, 12 parts of carborundum, 8 parts of alumina powder, 12 parts of alcohol ester, 12 parts of anti-cracking fiber, 8 parts of dimethylbenzene, 0.5 part of wetting agent, 0.4 part of defoaming agent, 1.5 parts of organic bentonite, 1.5 parts of preservative and 15 parts of color paste.
The invention also provides a preparation method of the wall wear-resistant material, which comprises the following steps:
step 1, adding epoxy resin, a wetting agent, a defoaming agent and xylene into a production dispersion kettle according to a proportion, and stirring and mixing uniformly;
step 2, adding organic bentonite, anti-crack fibers, silica gel powder, alumina powder and carborundum into the production dispersion kettle in proportion, and dispersing to the requirement of the inspection standard;
step 3, adding the modified graphene oxide and the alcohol ester twelve into the production dispersion kettle in proportion, and mixing until the requirements of inspection standards are met;
and 4, adding color paste and a preservative into the production dispersion kettle in proportion, and mixing until the mixture meets the requirement of inspection standards to prepare the novel wall wear-resistant material.
Example 4:
the wall wear-resistant material comprises the following components in parts by mass: 40 parts of epoxy resin, 25 parts of modified graphene oxide, 4 parts of silica gel powder, 8 parts of carborundum, 5 parts of alumina powder, 10 parts of alcohol ester, 7 parts of anti-cracking fiber, 5 parts of dimethylbenzene, 0.3 part of wetting agent, 0.3 part of defoaming agent, 1.2 parts of organic bentonite, 1 part of preservative and 12 parts of color paste.
The invention also provides a preparation method of the wall wear-resistant material, which comprises the following steps:
step 1, adding epoxy resin, a wetting agent, a defoaming agent and xylene into a production dispersion kettle according to a proportion, and stirring and mixing uniformly;
step 2, adding organic bentonite, anti-crack fibers, silica gel powder, alumina powder and carborundum into the production dispersion kettle in proportion, and dispersing to the requirement of the inspection standard;
step 3, adding the modified graphene oxide and the alcohol ester twelve into the production dispersion kettle in proportion, and mixing until the requirements of inspection standards are met;
and 4, adding color paste and a preservative into the production dispersion kettle in proportion, and mixing until the mixture meets the requirement of inspection standards to prepare the novel wall wear-resistant material.
Example 5:
the wall wear-resistant material comprises the following components in parts by mass: 32 parts of epoxy resin, 22 parts of modified graphene oxide, 3 parts of silica gel powder, 10 parts of carborundum, 6 parts of alumina powder, 7 parts of alcohol ester, 6 parts of anti-cracking fiber, 6 parts of dimethylbenzene, 0.2 part of wetting agent, 0.35 part of defoaming agent, 1 part of organic bentonite, 1.2 parts of preservative and 13 parts of color paste.
The invention also provides a preparation method of the wall wear-resistant material, which comprises the following steps:
step 1, adding epoxy resin, a wetting agent, a defoaming agent and xylene into a production dispersion kettle according to a proportion, and stirring and mixing uniformly;
step 2, adding organic bentonite, anti-crack fibers, silica gel powder, alumina powder and carborundum into the production dispersion kettle in proportion, and dispersing to the requirement of the inspection standard;
step 3, adding the modified graphene oxide and the alcohol ester twelve into the production dispersion kettle in proportion, and mixing until the requirements of inspection standards are met;
and 4, adding color paste and a preservative into the production dispersion kettle in proportion, and mixing until the mixture meets the requirement of inspection standards to prepare the novel wall wear-resistant material.
In the invention, the epoxy resin serves as a film forming base material and provides the bonding strength of the wear-resistant wall material, the epoxy resin has the advantages of good weather resistance, environmental protection, high glossiness, small emulsion particle size, easy cleaning of the coating surface and high stability, is an environment-friendly coating base resin, can be compounded with various organic resins according to a certain proportion for use, eliminates the risks of flammability and explosiveness in the production process, reduces environmental pollution, and simultaneously reduces the production cost and the use cost.
The modified graphene oxide is used as an important derivative of a graphene-based material, and the introduction of the oxygen-containing group not only enables the graphene oxide to have chemical stability, but also provides a surface modification active site and a larger specific surface area for synthesizing the graphene-based/graphene oxide-based material; the graphene oxide is used as a precursor and a support carrier for synthesizing the graphene-based composite material, is easy to functionalize and high in controllability, is an excellent reinforcing material, can inhibit permeation and infiltration of water and corrosive ions to a finish coat, and has super-strong adhesive force, good permeability, water seepage resistance, water resistance and air permeability.
In the invention, the defoaming agent is used as an auxiliary agent for further improving the performance of the wall surface wear-resistant material, preferably, the defoaming agent in the embodiment can be tributyl phosphate, and can be used for improving the workability of the wall surface wear-resistant material; the alcohol ester is an effective film-forming assistant, can reduce the minimum film-forming temperature, and does not influence other materials.
In the invention, the organic bentonite can be used for toughening and modifying the novel special wall surface wear-resistant material. The organic bentonite is an organic ammonium compound, takes bentonite as a raw material, utilizes the lamellar structure of montmorillonite in the bentonite and the characteristic that the montmorillonite can be swelled and dispersed into colloidal clay particles in water or an organic solvent, and is prepared by inserting an organic covering agent through an ion exchange technology. The organic bentonite can form gel in various organic solvents, oils and liquid resins, and has good thickening property, thixotropy, suspension stability, high-temperature stability, lubricity, film-forming property, water resistance and chemical stability.
The crack-resistant fiber is added to effectively solve the cracking problem of the wear-resistant wall material, and can effectively prevent the generation and development of cracks and improve the stability, strength, compactness and uniformity of the wear-resistant wall material by virtue of the unique properties of tensile strength, dispersity, melting point, ignition point, acid and alkali resistance and the like.
In the invention, the pigment and filler has the functions of ensuring that the wall surface wear-resistant material has certain covering power and various required colors, filling the wall surface wear-resistant material coating, increasing the coating thickness, reducing coating cracks, atmospheric erosion and the like, and preferably, the functional pigment and filler can comprise titanium dioxide, calcium carbonate powder and quartz sand.
According to the invention, the color paste is used for finally determining the color of the wear-resistant wall material, so that the molding color effect is more attractive.
The wall wear-resistant material disclosed by the invention has super-strong adhesive force and good permeability by adopting the modified graphene oxide, does not contain silicate components, is not easy to crack due to efflorescence, is waterproof and breathable, can be widely applied to walls in various places, is wide in application range, simplifies construction procedures, saves cost, is longer in practical life, and is more environment-friendly.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (7)
1. The wall wear-resistant material is characterized by comprising the following components in parts by mass: 30-45 parts of epoxy resin, 20-30 parts of modified graphene oxide, 2-5 parts of silica gel powder, 5-12 parts of carborundum, 3-8 parts of alumina powder, 5-12 parts of alcohol ester, 5-12 parts of anti-cracking fiber, 3-8 parts of xylene, 0.1-0.5 part of wetting agent, 0.2-0.4 part of defoaming agent, 0.5-1.5 parts of organic bentonite, 1-1.5 parts of preservative and 10-15 parts of color paste.
2. The wall wear-resistant material according to claim 1, which is composed of the following components in parts by mass: 30 parts of epoxy resin, 20 parts of modified graphene oxide, 2 parts of silica gel powder, 5 parts of carborundum, 3 parts of alumina powder, 5 parts of alcohol ester, 5 parts of anti-cracking fiber, 3 parts of dimethylbenzene, 0.1 part of wetting agent, 0.2 part of defoaming agent, 0.5 part of organic bentonite, 1 part of preservative and 10 parts of color paste.
3. The wall wear-resistant material according to claim 1, which is composed of the following components in parts by mass: 45 parts of epoxy resin, 30 parts of modified graphene oxide, 5 parts of silica gel powder, 12 parts of carborundum, 8 parts of alumina powder, 12 parts of alcohol ester, 12 parts of anti-cracking fiber, 8 parts of dimethylbenzene, 0.5 part of wetting agent, 0.4 part of defoaming agent, 1.5 parts of organic bentonite, 1.5 parts of preservative and 15 parts of color paste.
4. The wall wear-resistant material according to claim 1, which is composed of the following components in parts by mass: 40 parts of epoxy resin, 25 parts of modified graphene oxide, 4 parts of silica gel powder, 8 parts of carborundum, 5 parts of alumina powder, 10 parts of alcohol ester, 7 parts of anti-cracking fiber, 5 parts of dimethylbenzene, 0.3 part of wetting agent, 0.3 part of defoaming agent, 1.2 parts of organic bentonite, 1 part of preservative and 12 parts of color paste.
5. The wall lining as claimed in claim 1, wherein said wetting agent is alkyl polyoxyethylene ether.
6. The wall wear-resistant material of claim 1, wherein the defoaming agent is tributyl phosphate.
7. The method for preparing the wall surface wear-resistant material according to claim 1, wherein the method for preparing the wall surface wear-resistant material comprises the following steps:
step 1, adding epoxy resin, a wetting agent, a defoaming agent and xylene into a production dispersion kettle according to a proportion, and stirring and mixing uniformly;
step 2, adding organic bentonite, anti-crack fibers, silica gel powder, alumina powder and carborundum into the production dispersion kettle in proportion, and dispersing to the requirement of the inspection standard;
step 3, adding the modified graphene oxide and the alcohol ester twelve into the production dispersion kettle in proportion, and mixing until the requirements of inspection standards are met;
and 4, adding color paste and a preservative into the production dispersion kettle in proportion, and mixing until the mixture meets the requirement of inspection standards to prepare the novel wall wear-resistant material.
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CN109593440A (en) * | 2018-12-17 | 2019-04-09 | 浙江润奥环保科技有限公司 | A kind of environment-friendly type nano graphene floor material and preparation method thereof |
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CN109593440A (en) * | 2018-12-17 | 2019-04-09 | 浙江润奥环保科技有限公司 | A kind of environment-friendly type nano graphene floor material and preparation method thereof |
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