CN114311874A - Antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric and production method thereof - Google Patents

Antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric and production method thereof Download PDF

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CN114311874A
CN114311874A CN202111386225.1A CN202111386225A CN114311874A CN 114311874 A CN114311874 A CN 114311874A CN 202111386225 A CN202111386225 A CN 202111386225A CN 114311874 A CN114311874 A CN 114311874A
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moisture
antibacterial
warm
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dyeing
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CN114311874B (en
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吴敏
王江波
沈萍
刁春娟
陈志华
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Jiangsu Zhongfanglian Knitting Co ltd
Nantong Textile Vocational Technology College
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Jiangsu Zhongfanglian Knitting Co ltd
Nantong Textile Vocational Technology College
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Abstract

The invention discloses an antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric and a production method thereof, wherein the fabric comprises an inner layer with antibacterial warm-keeping moisture-conducting composite function, an outer layer with antibacterial warm-keeping moisture-absorbing composite function and a connecting layer with antibacterial moisture-conducting composite function; the inner layer adopts core-spun yarn of antibacterial modified polyester wrapped waterproof wool; the outer layer adopts a core-spun yarn of which the wool is prevented from shrinking by using isatis root fiber; the connecting layer adopts antibacterial modified terylene; the production method of the fabric comprises weaving and dyeing and finishing. The fabric conducts moisture through the inner layer and the connecting layer, moisture absorption and diffusion are carried out by combining the outer layer, moisture absorption gradient is formed, and particularly, the shrink-proof wool on the outer layer becomes thin after moisture absorption, so that gaps are formed inside the face yarn, heat and moisture are favorably dissipated, wetting gradient and differential capillary effect from inside to outside are formed, sweat is effectively promoted to migrate to the outer side of the skin, and the fabric has good moisture conducting and sweat releasing effects.

Description

Antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric and production method thereof
Technical Field
The invention belongs to the technical field of moisture-absorbing and quick-drying knitted fabrics, and particularly relates to an antibacterial, warm-keeping, moisture-absorbing and quick-drying knitted sportswear fabric and a production method thereof.
Background
Body-building activities are now a part of people's lives. The excellent sports fabric is good in elasticity, close to the skin and free of restriction during sports; to enable thermal and moisture control, it is the second skin of the human body; heat and moisture are dissipated during movement; the warm-keeping function can be achieved under the wet state after the exercise; the heat and moisture performance of the fabric is determined by the characteristics and the geometric shape of the fiber raw material, the structure of yarn, the density and the texture structure of the fabric and after finishing; other properties such as softness, light weight, uv resistance, ease of care, etc.
Wool is a high-grade natural textile fiber that has many excellent wearing qualities. For a long time, the application of wool in knitted products mainly highlights the heat retention and elasticity of the wool, and the wool is mostly used for medium-thickness autumn and winter clothing materials. With the continuous and deep research on the wearability of wool, people gradually realize the characteristics of high hygroscopicity, moisture absorption, non-sticky body, cool feeling and the like of wool fabrics, and even under the humid condition, wool also has excellent heat retention property and new ultraviolet resistance, so that the wool yarn is suitable for the development of sportswear products in spring and autumn.
At present, the application of wool to moisture-absorbing and quick-drying knitted fabrics is mainly in the following two ways:
first, wool is blended with other natural and/or functional fibers, such as documents CN102587020A, CN104947302A, CN108049008A, etc.
The disadvantages of this approach are: (1) the blending mode is difficult to fully exert the excellent performance of each fiber, and (2) the fibers in the blending mode are in disordered arrangement, and the moisture absorption and quick drying effects are not good usually.
Secondly, the wool is respectively subjected to hydrophilic processing and hydrophobic processing, and then blended and woven to obtain the fabric (for example, the document CN 103194908A), or the fabric is directly woven (see the document CN 104178875A).
The disadvantages of this approach are: (1) the fabric is single in functionality; (2) the blending mode is difficult to form wetting gradient on the inner layer and the outer layer of the fabric, and the moisture-conducting and sweat-releasing effects are poor; (3) the pure wool fabric has a high shrinkage rate, and after the pure wool fabric is washed for several times, gaps of the pure wool fabric are reduced, so that the cooling performance of the pure wool fabric is seriously influenced.
Disclosure of Invention
The invention aims to solve the problems and provides the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric with good moisture-conducting and sweat-releasing effects and the production method thereof.
The technical scheme for realizing the purpose of the invention is as follows: an antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric comprises an inner layer (1) with antibacterial warm-keeping moisture-conducting composite function, an outer layer (2) with antibacterial warm-keeping moisture-absorbing composite function and a connecting layer (3) with antibacterial moisture-conducting composite function.
The yarn adopted by the inner layer (1) is core-spun yarn; the yarn core of the core-spun yarn is waterproof wool (11), and the yarn sheath of the core-spun yarn is antibacterial modified terylene (12).
The yarn adopted by the outer layer (2) is core-spun yarn; the yarn core of the core-spun yarn is shrink-proof wool (21), and the yarn sheath of the core-spun yarn is isatis root fiber (22).
The yarn adopted by the connecting layer (3) is antibacterial modified terylene.
The gram weight of the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric is 200-250 g/m2
The thickness of the antibacterial warm-keeping moisture-absorption quick-drying knitted sportswear fabric is 0.5-0.8 mm.
The waterproof treatment process adopted by the waterproof wool is as follows: the treatment liquid is an aqueous solution containing 3-5% of a waterproof agent TF-5503, the pH value is adjusted to 4-5.5 by glacial acetic acid, the bath ratio is 1: 8-1: 20, the treatment time is 20-30 min, and the treatment liquid is completely dried at 110-125 ℃ after waterproof treatment.
The shrink-proof wool is chloridized mercerized wool which is treated by plasma and is also called hygroscopic wool. The chlorinated mercerized wool has the scales removed, and the plasma treatment can form a large amount of micro-protrusions on the surface of the wool, so that the wool obtains excellent hygroscopicity and softness, and the good warmth retention property of the wool under the humid condition is reserved. In addition, the wool without scales has the water-driven shape memory characteristic, and can become thin and long when absorbing water; the wool can be recovered to a thicker and shorter state after dehydration; the shape memory response is more obvious and faster not only in water but also in artificial sweat (slightly acidic) environment, and the characteristic is bidirectional and can be repeated for multiple times.
The specific conditions of the plasma treatment are selected according to different wool fineness as follows:
ultra-fine wool (diameter of 14-15.5 μm): the output power is 100W, and the processing time is 80-100 s.
Thin wool (diameter 15.5-16.5 μm): the output power is 150W, and the processing time is 80-100 s.
Coarse wool (diameter 16.5-17.5 μm): the output power is 200W, and the processing time is 80-100 s.
The radix Isatidis fiber is prepared by extracting effective components (such as alkaloids, organic acids or multiple amino acids) from radix Isatidis, and blending with viscose spinning solution for spinning. The isatis root fiber not only has excellent hygroscopicity and drapability of viscose fiber, but also has excellent antibacterial property and water washing resistance.
The antibacterial modified polyester is prepared by preparing organic micromolecules such as toluene, sodium phenyl formate, methyl salicylate and the like into microcapsules, adding the microcapsules and silver ions into a polyester spinning stock solution, and preparing the fibers with the moisture-conducting and antibacterial functions through melt spinning by utilizing a cross-shaped spray hole. The antibacterial modified polyester fiber not only keeps the inherent comfortable hydrophilicity of the polyester fiber, but also has the characteristic of low-temperature dyeing. When the dyeing temperature reaches 80 ℃, the organic small molecules begin to be scattered out of the microcapsules, so that fiber gaps are increased, and the dye is favorably fed in. Therefore, the antibacterial modified polyester fiber is different from common polyester fiber which needs to be dyed under the conditions of high temperature and high pressure of 125-130 ℃, can be dyed under the conditions of 95-100 ℃ and normal pressure, and greatly reduces the damage of high-temperature dyeing to wool.
The production method of the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric comprises weaving and dyeing and finishing.
The dyeing and finishing comprises: presetting → pretreatment → acid neutralization → dyeing → shaping of finished product.
The dyeing can be carried out in one of two ways:
mode A: dyeing antibacterial modified terylene → reduction washing → acid neutralization → dyeing wool and isatis root fiber in one bath → fixation.
Mode B: and (3) dyeing the antibacterial modified polyester and wool in one bath → dyeing the isatis root fiber → fixing color.
The invention has the following positive effects:
(1) the antibacterial warm-keeping moisture-absorption quick-drying knitted sportswear fabric disclosed by the invention has the advantages that the inner layer adopts antibacterial modified polyester and waterproof wool with good moisture conductivity, the connecting layer adopts antibacterial modified polyester with good moisture conductivity, the outer layer adopts isatis root fiber and shrink-proof wool with good moisture absorption, moisture conductivity is realized through the inner layer and the connecting layer, moisture absorption and diffusion are carried out by combining the outer layer, a moisture absorption gradient is formed, sweat can be diffused from inside to outside, and moisture absorption and quick drying are realized.
(2) The inner layer and the outer layer of the antibacterial warm-keeping moisture-absorption quick-drying knitted sportswear fabric both adopt the core-spun yarn structure, on one hand, compared with blended yarn, the functionality of each fiber can be displayed to the maximum, on the other hand, the core-spun yarn structure can well keep the excellent warm-keeping performance of wool, and particularly, the shrink-proof wool on the outer layer becomes thin after moisture absorption, so that gaps are formed inside the surface yarn, heat and moisture are more favorably dissipated, and therefore, a wetting gradient and a differential capillary effect from inside to outside are formed, sweat is effectively promoted to migrate to the outer side of skin, and the moisture-conduction sweat-discharging effect is better.
(3) The inner layer and the outer layer of the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric disclosed by the invention both contain wool, so that the excellent warm-keeping performance is still maintained under the condition of massive sweating during outdoor sports in spring and autumn, and the 'after-cold' effect after severe sports is prevented.
(4) The antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric disclosed by the invention adopts the isatis root fiber and the antibacterial modified terylene, so that a better antibacterial effect can be obtained, the antibacterial modified terylene can realize low-temperature (95-100 ℃) dyeing, the damage to wool is greatly reduced, the alkali solubility of the wool can be reduced to 10.5% at 98 ℃ from 15% at 130 ℃, and various dyeing fastness of the fabric meets requirements.
Drawings
Fig. 1 is a schematic structural view of the antibacterial, warm-keeping, moisture-absorbing and quick-drying knitted sportswear fabric of example 1.
Fig. 2 is a weaving view of the antibacterial, warm-keeping, moisture-absorbing and quick-drying knitted sportswear fabric of example 1.
Fig. 3 is a dyeing process of the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric of example 1.
Fig. 4 is a dyeing process of the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric of example 2.
Detailed Description
(example 1)
Referring to fig. 1, the antibacterial, warm-keeping, moisture-absorbing and quick-drying knitted sportswear fabric of the present embodiment comprises an inner layer 1, an outer layer 2 and a connecting layer 3 connecting the inner layer 1 and the outer layer 2.
The inner layer 1 has the composite functions of antibiosis, warm keeping and moisture conduction, and adopts the core-spun yarn; wherein: the yarn core is waterproof wool 11, and the yarn skin is antibacterial modified terylene 12.
The outer layer 2 has the composite functions of antibiosis, warm keeping and moisture absorption, and the adopted yarn is core-spun yarn; wherein: the yarn core is shrink-proof wool 21, and the yarn skin is isatis root fiber 22.
The connecting layer 3 has the composite functions of antibiosis and moisture conduction, and the adopted yarn is antibacterial modified terylene.
The gram weight of the antibacterial warm-keeping moisture-absorption quick-drying knitted sportswear fabric is 220g/m2
The thickness of the antibacterial warm-keeping moisture-absorption quick-drying knitted sportswear fabric of the embodiment is 0.7 mm.
The production method of the antibacterial warm-keeping moisture-absorption quick-drying knitted sportswear fabric comprises the following steps:
s1: and (5) weaving.
A weft knitting double-sided machine is adopted, the machine number is 24 needles/25.4 mm, the tube diameter is 864mm (34'), the path number is 72F, and the total number of needles is 2496.
The loop length and yarn ratio were as follows: face yarn (outer layer): 14.76tex shrinkproof wool yarn core isatis root fiber yarn sheath core-spun yarn, 29cm/100 loops, yarn accounts for 27%; connecting yarn (connecting layer): 8.33tex/34F antibacterial modified terylene, 26cm/100 coils, 15 percent of yarn; ground yarn (inner layer): 16.67tex waterproof wool yarn core antibacterial modified polyester yarn sheath core-spun yarn, 26cm/100 coils, and 58% of yarn.
The knitting needle arrangement and the cam arrangement are as follows: designing a double-sided tissue structure, configuring cotton wool, arranging upper dial knitting needles according to A, B sequence, and forming a cycle by two sections; the lower needle cylinder needles are arranged according to the A, B sequence, and two sections are a cycle; each section forms a cycle by 6 paths and weaves a complete tissue; wherein the 1 st, 4F penetrate the face yarn, the 3 rd, 6F penetrate the connecting yarn, and the 2 nd, 5F penetrate the ground yarn.
The specific weaving diagram is shown in fig. 2, and the triangular configuration diagram is shown in table 1.
TABLE 1
Figure DEST_PATH_IMAGE002
Wherein, V-shaped represents a needle plate needle looping triangle, and inverted V represents a needle cylinder needle looping triangle; "n" represents a cylinder needle tucking triangle; "-" indicates a float triangle (i.e., not woven).
S2: and (6) dyeing and finishing.
S21: and (4) pre-setting, namely pre-setting by adopting small overfeeding at 160 ℃.
S22: and (4) pre-treating at 90-95 ℃ for 25 +/-5 min.
The formula of the pretreatment liquid is as follows: 3g/L of sodium carbonate, 2g/L of hydrogen peroxide, 2g/L of penetrating agent 2A, 3g/L of emulsifier SEM-35N and the balance of water.
S23: neutralizing with acid, adding glacial acetic acid 0.8g/L and Ono. 0.1g/L, and running for 20 min.
S24: dyeing in a mode A, specifically comprising the following steps:
s241: adding water into a dye vat, adding 2g/L of glacial acetic acid, running for 10min, and controlling the pH to be 4-4.5; then adding 1g/L leveling agent RDT-27, and running for 10 min; then adding 1 percent of disperse blue CRE and 0.8 percent of disperse blue SR, heating to 98 ℃, and dyeing the antibacterial modified terylene for 30 min.
S242: cooling to 85 ℃, adding 5g/L of soda ash and 3g/L of sodium hydrosulfite, carrying out reduction washing for 20min, and discharging liquid.
S243: adding water into the dye vat, adding 2g/L glacial acetic acid, performing acid neutralization for 20min, and discharging liquid.
S244: adding water into a dye vat, adding 5g/L of soda ash, 50g/L of anhydrous sodium sulphate, 1.5% of reactive brilliant blue WB for wool and 3% of reactive blue KN-R, heating to 60 ℃, and dyeing wool and isatis root fibers in one bath for 40 min.
S245: and (5) fixing color, discharging liquid and discharging from a vat.
The specific dyeing process is shown in figure 3.
S25: and (5) shaping the finished product, namely shaping the finished product by adopting a 180-DEG C large overfeed to obtain the knitted sportswear fabric.
(example 2)
The antibacterial, warm-keeping, moisture-absorbing and quick-drying knitted sportswear fabric of the embodiment is the same as that of embodiment 1, and the production method is basically the same as that of embodiment 1, except that the dyeing of step S24 adopts a mode B as follows:
s241': adding water into a dye vat, adding 2g/L of precipitation inhibitor HT-33N, and running for 10min to prevent precipitation of acid dye; then adding 2g/L glacial acetic acid and 1g/L leveling agent CA250, running for 10min, and controlling the pH to be 4-4.5; then adding 1.1% of dispersed navy blue R, 0.5% of dispersed ruby 4B, 1.5% of acid blue NFS and 0.65% of acid red NFS, heating to 98 ℃, dyeing and modifying the terylene and the wool in one bath for 30min, and discharging liquid.
S242': adding water into a dye vat, adding 5g/L of soda ash, 50g/L of anhydrous sodium sulphate, 2.1% of active blue CA and 0.9% of active purple BN, heating to 60 ℃, and dyeing the isatis root fiber for 40 min.
S243': finally, color fixation and liquid discharge are carried out.
The specific dyeing process is shown in figure 4.
(test example 1)
The moisture absorption and quick drying properties of the knitted sportswear fabrics of examples 1 and 2 were tested, and the results are shown in table 2.
The test method is GB/T21655.1-2008' evaluation of moisture absorption and quick drying of textiles part 1: single combinatorial testing approach.
TABLE 2
Test itemEyes of a user Index requirement Example 1 Example 2
Water absorption (before washing)/%) ≥200 242 238
Water absorption (after 5 washes)/%) ≥200 237 247
Drip spread time (before washing)/s ≤3 1.1 1.2
Drip diffusion time (after 5 times of water washing)/s ≤3 0.8 0.6
Wicking height (before washing)/mm ≥100 171.5 169.3
Wicking height (after 5 washes)/mm ≥100 188.8 189.7
Evaporation Rate (before washing)/(g/h) ≥0.18 0.21 0.19
Evaporation Rate (after 5 washes)/(g/h) ≥0.18 0.22 0.22
Moisture permeability (before washing)/[ g/m ]2·d] ≥10000 11200 10300
Moisture permeability (after washing 5 times)/[ g/m2·d] ≥10000 10900 10300
As can be seen from table 2: the indexes of the knitted sportswear fabrics of the embodiments 1 and 2 before and after washing all meet the technical requirements, and the knitted sportswear fabrics belong to moisture absorption and quick drying fabrics.
(test example 2)
The knitted sportswear fabrics of examples 1, 2 were tested for various colorfastness, and the results are shown in table 3, wherein:
the method for testing the color fastness to rubbing is GB/T3920-.
The method for testing the color fastness to water is GB/T5713 and 2013 ' color fastness to water ' of textile color fastness test '.
The test method of the color fastness to perspiration is GB/T3922-.
TABLE 3
Test items Index requirement Example 1 Example 2
Colour fastness to rubbing (Dry) Grade not less than 3 4-5 stages 4-5 stages
Colour fastness to water/discolouration Not less than 3-4 grade 4-5 stages 4-5 stages
Colour fastness to water/staining Not less than 3-4 grade 4-5 stages 4-5 stages
Color fastness to perspiration (acid)/discoloration Not less than 3-4 grade 4-5 stages 4-5 stages
Colour fastness to perspiration (acid)/staining Not less than 3-4 grade 4-5 stages 4-5 stages
Color fastness to perspiration (alkali)/discoloration Not less than 3-4 grade 4-5 stages 4-5 stages
Color fastness to perspiration (alkali)/staining Not less than 3-4 grade 4-5 stages 4-5 stages
As can be seen from table 3: the knitted sportswear fabrics of examples 1 and 2 have high color fastness.
(test example 3)
The knitted sportswear fabrics of examples 1 and 2 were tested for antibacterial properties, and the results are shown in table 4.
The test method is GB/T20944.3-2008 < evaluation of antibacterial performance of textiles part 3: oscillation method.
Wherein: and (3) washing with water according to an industry standard FZ/T73023 and 2006 antibacterial knitwear, and testing the bacteriostasis rate of the antibacterial agent to staphylococcus aureus, escherichia coli and candida albicans after 50 times of washing.
TABLE 4
Example 1 Example 2
Staphylococcus aureus >99% >99%
Escherichia coli >99% >99%
Candida albicans >99% >99%
As can be seen from table 4: the knitted sports fabric of the embodiments 1 and 2 has the bacteriostasis rate of over 99% on staphylococcus aureus, escherichia coli and candida albicans, and has good antibacterial performance.
(test example 4)
The knitted sportswear fabrics of examples 1 and 2 were tested for heat retention performance by GB/T11048-: thermal resistance values of 0.060m, respectively2K/W and 0.054m2·K/W。
Therefore, the knitted sportswear fabrics of the embodiments 1 and 2 have better heat preservation performance.

Claims (10)

1. The utility model provides an antibiotic cold-proof moisture absorption rapid-curing cutback knitting motion surface fabric which characterized in that: comprises an inner layer (1) with the composite functions of antibiosis, warm keeping and moisture conduction, an outer layer (2) with the composite functions of antibiosis, warm keeping and moisture absorption and a connecting layer (3) with the composite functions of antibiosis, warm keeping and moisture conduction.
2. The antibacterial, warm-keeping, moisture-absorbing and quick-drying knitted sportswear fabric according to claim 1, characterized in that: the yarn adopted by the inner layer (1) is core-spun yarn; the yarn core of the core-spun yarn is waterproof wool (11), and the yarn sheath of the core-spun yarn is antibacterial modified terylene (12).
3. The antibacterial, warm-keeping, moisture-absorbing and quick-drying knitted sportswear fabric according to claim 2, characterized in that: the yarn adopted by the outer layer (2) is core-spun yarn; the yarn core of the core-spun yarn is shrink-proof wool (21), and the yarn sheath of the core-spun yarn is isatis root fiber (22).
4. The antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric according to claim 3, characterized in that: the yarn adopted by the connecting layer (3) is antibacterial modified terylene.
5. The antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric according to claim 4, characterized in that: the antibacterial modified polyester is prepared by firstly preparing toluene, sodium phenyl formate or methyl salicylate into microcapsules, then adding the microcapsules and silver ions into a polyester spinning solution together, and performing melt spinning by using a cross-shaped spray orifice.
6. A method for producing the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric according to any one of claims 1 to 5, characterized in that: weaving and dyeing and finishing; the dyeing and finishing comprises: presetting → pretreatment → acid neutralization → dyeing → shaping of finished product.
7. The production method of the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric according to claim 6, characterized by comprising the following steps: the dyeing is carried out by dyeing antibacterial modified terylene → reduction washing → acid neutralization → one-bath dyeing of wool and isatis root fiber → fixation.
8. The production method of the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric according to claim 7, characterized in that: the temperature for dyeing the antibacterial modified polyester is 95-100 ℃, and the adopted dye is a disperse dye; the temperature of the wool and the isatis root fiber dyed in one bath is 50-70 ℃, and the adopted dye is a reactive dye.
9. The production method of the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric according to claim 6, characterized by comprising the following steps: the dyeing is one-bath dyeing antibacterial modified terylene and wool → dyeing of isatis root fiber → fixation.
10. The production method of the antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric according to claim 9, characterized by comprising the following steps: the temperature of the co-bath dyeing antibacterial modified polyester and wool is 95-100 ℃, and the adopted dyes are disperse dyes and acid dyes; the temperature for dyeing the isatis root fiber is 50-70 ℃, and the adopted dye is a reactive dye.
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