CN114261168B - 防水透湿功能面料 - Google Patents

防水透湿功能面料 Download PDF

Info

Publication number
CN114261168B
CN114261168B CN202111628497.8A CN202111628497A CN114261168B CN 114261168 B CN114261168 B CN 114261168B CN 202111628497 A CN202111628497 A CN 202111628497A CN 114261168 B CN114261168 B CN 114261168B
Authority
CN
China
Prior art keywords
waterproof
fabric
film
body fabric
permeable functional
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202111628497.8A
Other languages
English (en)
Other versions
CN114261168A (zh
Inventor
谢国炎
陈明贤
金世豪
孙立新
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Dongjin New Material Co ltd
Original Assignee
Zhejiang Dongjin New Material Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Dongjin New Material Co ltd filed Critical Zhejiang Dongjin New Material Co ltd
Priority to CN202111628497.8A priority Critical patent/CN114261168B/zh
Publication of CN114261168A publication Critical patent/CN114261168A/zh
Priority to DE102022116534.5A priority patent/DE102022116534A1/de
Application granted granted Critical
Publication of CN114261168B publication Critical patent/CN114261168B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • C09D183/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/527Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads waterproof or water-repellent
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3568Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing silicon
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34Material containing ester groups
    • D06P3/52Polyesters
    • D06P3/54Polyesters using dispersed dyestuffs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0292Polyurethane fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14Mixture of at least two fibres made of different materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/732Dimensional properties
    • B32B2307/737Dimensions, e.g. volume or area
    • B32B2307/7375Linear, e.g. length, distance or width
    • B32B2307/7376Thickness
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/20Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/22Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38Polyurethanes
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/061Load-responsive characteristics elastic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/04Outerwear; Protective garments

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明公开了一种防水透湿功能面料,属于功能面料领域。所述的面料包括:本体面料、本体面料表面设置的防水层、薄膜、粘合本体面料与薄膜的粘结层;所述的本体面料为涤氨弹力面料;所述的防水透湿功能面料,由以下步骤制成:a、按工艺处方配置防水整理液;b、将本体面料浸渍于防水整理液中,轧液;c、预烘、焙烘;d、在本体面料、薄膜表面设置粘合层,平整地叠加在一起,再移至压烫机中进行压烫,完成热压复膜,制成防水透湿功能面料;所述的防水整理液由交联剂与纳米二氧化硅改性聚硅氧烷乳液混合成。本发明防水透湿功能面料,先将本体面料浸轧防水整理液形成防水表层,再与功能薄膜复合制成,具有良好的防水、透湿、透气性能。

Description

防水透湿功能面料
技术领域
本发明属于功能面料领域,具体涉及一种防水透湿功能面料。
背景技术
户外运动越来越受人们的喜爱,户外运动发热量大、汗液蒸发多,服装的散热性和透气应良好,而防水透湿类面料服装则是最佳的选择。防水透湿服装的面料通常包括三种类型:高密织物、涂层织物和层压复合面料。其中,高密织物的耐水渗透性能较差但透湿性能优异,涂层织物的耐水渗透性能优异但透湿性能较差,只有层压复合面料可以同时表现出优异的耐水渗透性能和透湿性能。因而层压复合面料成为目前市场中防水透湿服装使用的主流面料。所谓面料的防水透湿性能,是指面料在一定压力的水的作用下,未被水渗透,而人体散发的汗液蒸气却能通过面料扩散或传递到外界,不在体表和织物之间积聚冷凝。
发明内容
本发明目的是提供一种防水透湿功能面料。
为实现上述目的,本发明采用了以下技术方案。
一种防水透湿功能面料,包括:本体面料、本体面料表面设置的防水层、薄膜、粘合本体面料与薄膜的粘结层;所述的本体面料为涤氨弹力面料;
所述的防水透湿功能面料,由以下步骤制成:
步骤a、按工艺处方配置防水整理液;
步骤b、将本体面料浸渍于防水整理液中,轧液;
步骤c、预烘、焙烘;
步骤d、在本体面料、薄膜表面设置粘合层,平整地叠加在一起,再移至压烫机中进行压烫,完成热压复膜,制成防水透湿功能面料;
所述的防水整理液由交联剂与纳米二氧化硅改性聚硅氧烷乳液混合成。
所述的本体面料为:经丝:甲FDY70D/48F+40DSP;纬丝组合:甲FDY70D/48F+40DSP、乙FDY160D/136F;织物组织:平纹1/1;坯布经纬密:34×30.5根/cm。
所述的粘结层为聚氨酯热熔胶。
所述的薄膜为PU膜,厚度为10-20微米。
所述的本体面料还经过精练、预定型、碱减量、染色工序加工。
所述的精练,具体为面料在处理浴中于100℃保温30min;处理浴处方为氢氧化钠10g/L、精练剂2g/L、螯合分散剂2g/L;处理浴的浴比为1:10。
所述的预定型,温度为180-210℃、时间25-45s。
所述的碱减量,NaOH质量浓度20g/L,浴比1:10,处理时间40min,处理温度110℃。
所述的染色,工艺流程为:室温时加入浴中柔软剂、匀染剂、螯合分散剂、醋酸、运转15min,再加入预先溶解好的分散染料,运转15min,以1.5℃/min的升温速率将染浴升温到85℃,保温运转30min,然后以0.5℃/min的升温速率将染浴升温到130℃,保温染色45min;最后以1.5℃/min速度冷却,染浴降温至50℃以下,排液。
本发明防水透湿功能面料,先将本体面料浸轧防水整理液形成防水表层,再与功能薄膜复合制成。面料具有良好的防水、透湿、透气性能。
防水整理液由交联剂与纳米二氧化硅改性聚硅氧烷乳液混合成,在涤纶纤维表面形成的防水层具有类似荷叶表面的微/纳米乳突结构,与低表面张力的有机硅协同,使面料具有超强的疏水性能。
涤纶面料通过碱减量,在涤纶纤维表面水解形成刻蚀效果,在纤维表面产生凹凸不平的坑穴,使涤纶纤维表面形成微纳粗糙结构,纳米二氧化硅改性聚硅氧烷则在涤纶纤维微纳粗糙结构的表面形成疏水层,使面料具有优异的疏水性能。
纳米二氧化硅改性聚硅氧烷存在着与纺织品附着力低、机械强度较低的不足,涤纶纤维经碱减量后,纤维表面生成了羟基,封端型聚氨酯交联剂可同时与涤纶纤维表面的羟基及聚硅氧烷分子中的氨基反应,从而通过化学键将纳米二氧化硅改性聚硅氧烷固定在面料表面,进而增强面料疏水性能的耐久性。
具体实施方式
本发明公开了一种防水透湿功能面料,包括:本体面料、本体面料表面设置的防水层、薄膜、粘合本体面料与薄膜的粘结层;所述的本体面料为涤氨弹力面料;
所述的防水透湿功能面料,由以下步骤制成:
步骤a、按工艺处方配置防水整理液;
步骤b、将本体面料浸渍于防水整理液中,轧液;
步骤c、预烘、焙烘,形成防水层;
步骤d、在本体面料、薄膜表面设置粘合层,平整地叠加在一起,再移至压烫机中,设定热压时间30s和热压温度110℃,待温度达到后,进行压烫,完成热压复膜,制成防水透湿功能面料;
所述的本体面料为:经丝:甲FDY70D/48F+40DSP;纬丝组合:甲FDY70D/48F+40DSP、乙FDY160D/136F;织物组织:平纹1/1;坯布经纬密:34×30.5根/cm。甲纬:乙纬=2:1。含氨纶的涤纶面料耐氯、耐光等性能稍差,如果面料要求耐氯、耐光等性能,则可采用纯涤纶面料。
所述的粘结层为聚氨酯热熔胶,市售产品。
所述的薄膜为PU膜,厚度为10-20微米,市售产品。
涤纶面料通过碱减量,可在涤纶纤维表面水解刻蚀产生凹凸不平的坑穴,在涤纶纤维表面形成微纳粗糙结构,而微纳粗糙结构与低表面能的聚有机硅氧烷结合可形成疏水表面。因此,在对本体面料进行防水、复膜加工前,可通过精练、预定型、碱减量、染色工序加工,来实现涤纶纤维表面的这种微纳粗糙结构。
所述的精练,具体为面料在处理浴中于100℃保温30min;处理浴处方为氢氧化钠10g/L、精练剂2g/L、螯合分散剂2g/L;处理浴的浴比为1:10。
所述的预定型,温度为180-210℃、时间25-45s。
所述的碱减量,NaOH质量浓度20g/L,浴比1:10,处理时间40min,处理温度110℃。
所述的染色,工艺流程为:室温时加入浴中柔软剂、匀染剂、螯合分散剂、醋酸、运转15min,再加入预先溶解好的分散染料,运转15min,以1.5℃/min的升温速率将染浴升温到85℃,保温运转30min,然后以0.5℃/min的升温速率将染浴升温到130℃,保温染色45min;最后以1.5℃/min速度冷却,染浴降温至50℃以下,排液。
染色工艺处方:
精练剂、匀染剂、螯合分散剂、浴中柔软剂、分散染料等染整过程中涉及的染料助剂均为市售产品。
所述的防水整理液由交联剂与纳米二氧化硅改性聚硅氧烷乳液按质量比1:20组成,使用时将交联剂缓慢加入纳米二氧化硅改性聚硅氧烷乳液中,搅拌使两者混合均匀。
交联剂为水性封端型聚氨酯,市售产品,如德国科思创的水性封闭型异氰酸酯固化剂BL5335。
纳米二氧化硅改性聚硅氧烷乳液由端氨基乙烯基聚硅氧烷在侧链以巯基与“C=C”反应成,使纳米二氧化硅分散于聚硅氧烷分子链上,不会在后续使用时团聚。
所述的纳米二氧化硅改性聚硅氧烷乳液,通过以下步骤制得:
①向反应器中依次加入端氨基乙烯基聚硅氧烷,表面改性纳米二氧化硅,光催化剂DMPA(安息香双甲醚)及新蒸的THF(四氢呋喃),待反应物溶解后,保持搅拌状态在紫外灯下照射反应30min,反应完毕后真空除去THF,将反应产物在无水甲醇中沉淀三次除去未反应的原料和催化剂,真空干燥至恒重后即得到纳米二氧化硅改性聚硅氧烷;端氨基乙烯基聚硅氧烷中的“-C=C”基团与表面改性纳米二氧化硅中的“-SH”基团摩尔比为1:1.05;
②将纳米二氧化硅改性聚硅氧烷与乳化剂按质量比10:1混合,搅拌过程中添加水和乙酸的混合物,乙酸与纳米二氧化硅改性聚硅氧烷质量比为1:30,搅拌至溶液呈透明状,得纳米二氧化硅改性聚硅氧烷乳液。乳液质量百分浓度约10%,乙酸调节乳液呈弱酸性。乳化剂由异构十三醇聚氧乙烯醚1307、1309按质量比1:2组成。反应过程如下式(1)所示。
其中,端氨基乙烯基聚硅氧烷制备方法为:
在装有温度计、搅拌器的干燥四口烧瓶中,加入摩尔比为1:40:2的1,3-双(3-氨基丙基)-1,1,3,3-四甲基二硅氧烷、八甲基环四硅氧烷、四甲基四乙烯基环四硅氧烷,边搅拌边升温至反应温度,并加入一定量的三氟甲基磺酸,保温反应一定时间;反应结束后加入无水Na2CO3搅拌中和至pH为6-7,过滤并将产物进行减压蒸馏(90℃,真空度-0.1Mpa以下),脱除未反应单体,得无色透明的液体产物,为端氨基乙烯基聚硅氧烷。转化率91.5%,Mn(g/mol):12776,C=C键含量0.626mmol/g;反应过程如反应式(2)所示。
所述的纳米二氧化硅表面改性,制备方法为:
称取适量纳米SiO2加入到无水乙醇中,磁力搅拌使纳米SiO2分散均匀,以HCl溶液调节pH值至4,再向体系中滴加硅烷偶联剂KH590(γ-巯丙基三甲氧基硅烷),混合均匀后将溶液转移至三口烧瓶中,控制体系温度为80℃,搅拌反应10h,冷却,将混合液抽滤、洗涤、干燥,即得到KH590改性纳米Si02。纳米SiO2、硅烷偶联剂KH590、无水乙醇的质量比为10:1.5:100。硅烷偶联剂在纳米SiO2表面的相对接枝率约为10%。·:代表纳米二氧化硅。反应过程如反应式(3)所示。
实施例1:
一种防水透湿功能面料,包括:本体面料、本体面料表面设置的防水层、薄膜、粘合本体面料与薄膜的粘结层;所述的本体面料涤氨弹力面料,经丝:甲FDY70D/48F+40DSP;纬丝组合:甲FDY70D/48F+40DSP、乙FDY160D/136F;织物组织:平纹1/1;坯布经纬密:34×30.5根/cm。甲纬:乙纬=2:1。
所述的防水透湿功能面料,由以下步骤制成:
步骤a、按质量比1:20,将水性封闭型异氰酸酯固化剂BL5335缓慢加入纳米二氧化硅改性聚硅氧烷乳液中,搅拌使两者混合均匀,配置成防水整理液。;
步骤b、将本体面料浸渍于防水整理液中,两浸两轧,轧液率80%;
步骤c、90℃预烘2min、130℃焙烘30-60s,形成防水层;
步骤d、在本体面料、PU薄膜表面涂覆聚氨酯热熔胶,将面料与薄膜平整地叠加在一起,再移至压烫机中,设定热压时间30s和热压温度110℃,待温度达到后,进行压烫,完成热压复膜,制成防水透湿功能面料。
对所得的防水透湿功能面料的防水、透湿性能进行了测试,结果为:防泼水洗前5级,5次水洗后4级;耐静水压19000mmH2O;透湿性能
≥10000g/m2/24h。
实施例2:
一种防水透湿功能面料,包括:本体面料、本体面料表面设置的防水层、薄膜、粘合本体面料与薄膜的粘结层;所述的本体面料涤氨弹力面料,经丝:甲FDY70D/48F+40DSP;纬丝组合:甲FDY70D/48F+40DSP、乙FDY160D/136F;织物组织:平纹1/1;坯布经纬密:34×30.5根/cm。甲纬:乙纬=2:1。
所述的防水透湿功能面料,由以下步骤制成:
步骤a、按质量比1:20,将水性封闭型异氰酸酯固化剂BL5335缓慢加入纳米二氧化硅改性聚硅氧烷乳液中,搅拌使两者混合均匀,配置成防水整理液。;
步骤b、将经过精练、预定型、碱减量、染色工序加工的本体面料浸渍于防水整理液中,两浸两轧,轧液率80%;
步骤c、90℃预烘2min、130℃焙烘30-60s;
步骤d、在本体面料、PU薄膜表面涂覆聚氨酯热熔胶,将面料与薄膜平整地叠加在一起,再移至压烫机中,设定热压时间30s和热压温度110℃,待温度达到后,进行压烫,完成热压复膜,制成防水透湿功能面料。
所述本体面料的精练、预定型、碱减量、染色工序加工,具体为:
1)精练,室温时本体面料浸入浴比为1:10的精练浴中,1.5℃/min升温至100℃保温30min,降温至50℃后排液水洗;精练浴处方为氢氧化钠10g/L、精练剂2g/L、螯合分散剂2g/L;
2)预定型,温度为180-210℃、时间25-45s,车速25-40m/min。
3)碱减量,室温时本体面料浸入质量浓度20g/L的NaOH水溶液中,浴比1:10,1.5℃/min升温至110℃处理时间40min,降温至50℃后排液、水洗至pH值中性;
4)染色,室温时加入浴中柔软剂、匀染剂、螯合分散剂、醋酸、运转15min,再加入预先溶解好的分散染料,运转15min,以1.5℃/min的升温速率将染浴升温到85℃,保温运转30min,然后以0.5℃/min的升温速率将染浴升温到130℃,保温染色45min;最后以1.5℃/min速度冷却,染浴降温至50℃以下,排液。
染色处方:
对所得的防水透湿功能面料的防水、透湿性能进行了测试,结果为:防泼水洗前5级,5次水洗后4级;耐静水压17000mmH2O;透湿性能≥10000g/m2/24h。
防泼水性能测试测试参照GB/T 4745-2012《纺织品防水性能的检测和评价沾水法》;耐静水压测试参照JIS L 1092-1998纺织物抗水性的测试方法;透湿性能测试参照JISL 1099-2006纺织品透湿度试验方法。

Claims (9)

1.一种防水透湿功能面料,包括:本体面料、本体面料表面设置的防水层、薄膜、粘合本体面料与薄膜的粘结层;所述的本体面料为涤氨弹力面料;
所述的防水透湿功能面料,由以下步骤制成:
步骤a、按工艺处方配置防水整理液;
步骤b、将本体面料浸渍于防水整理液中,轧液;
步骤c、预烘、焙烘;
步骤d、在本体面料、薄膜表面设置粘合层,平整地叠加在一起,再移至压烫机中进行压烫,完成热压复膜,制成防水透湿功能面料;
所述的防水整理液由交联剂与纳米二氧化硅改性聚硅氧烷乳液混合成;
所述的纳米二氧化硅改性聚硅氧烷乳液,通过以下步骤制得:
①向反应器中依次加入端氨基乙烯基聚硅氧烷,表面改性纳米二氧化硅,光催化剂安息香双甲醚及新蒸的四氢呋喃,待反应物溶解后,保持搅拌状态在紫外灯下照射反应30min,反应完毕后真空除去THF,将反应产物在无水甲醇中沉淀三次除去未反应的原料和催化剂,真空干燥至恒重后即得到纳米二氧化硅改性聚硅氧烷;端氨基乙烯基聚硅氧烷中的“-C=C”基团与表面改性纳米二氧化硅中的“-SH”基团摩尔比为1:1.05;
②将纳米二氧化硅改性聚硅氧烷与乳化剂按质量比10:1混合,搅拌过程中添加水和乙酸的混合物,乙酸与纳米二氧化硅改性聚硅氧烷质量比为1:30,搅拌至溶液呈透明状,得纳米二氧化硅改性聚硅氧烷乳液。
2.根据权利要求1所述的一种防水透湿功能面料,其特征在于:所述的本体面料为:经丝:甲FDY70D/48F+40DSP;纬丝组合:甲FDY70D/48F+40DSP、乙FDY160D/136F;织物组织:平纹1/1;坯布经纬密:34×30.5根/cm。
3.根据权利要求1所述的一种防水透湿功能面料,其特征在于:所述的粘结层为聚氨酯热熔胶。
4.根据权利要求1所述的一种防水透湿功能面料,其特征在于:所述的薄膜为PU膜,厚度为10-20微米。
5.根据权利要求1所述的一种防水透湿功能面料,其特征在于:所述的本体面料还经过精练、预定型、碱减量、染色工序加工。
6.根据权利要求5所述的一种防水透湿功能面料,其特征在于:所述的精练,具体为面料在处理浴中于100℃保温30min;处理浴处方为氢氧化钠10g/L、精练剂2 g/L、螯合分散剂2 g/L;处理浴的浴比为1:10。
7.根据权利要求5所述的一种防水透湿功能面料,其特征在于:所述的预定型,温度为180-210℃、时间25-45s。
8.根据权利要求5所述的一种防水透湿功能面料,其特征在于:所述的碱减量,NaOH质量浓度20g/L,浴比1:10,处理时间40min,处理温度110℃。
9.根据权利要求5所述的一种防水透湿功能面料,其特征在于:所述的染色,工艺流程为:室温时加入浴中柔软剂、匀染剂、螯合分散剂、醋酸,运转15min,再加入预先溶解好的分散染料,运转15min,以1.5℃/min的升温速率将染浴升温到85℃,保温运转30min,然后以0.5℃/min的升温速率将染浴升温到130℃,保温染色45min;最后以1.5℃/min速度冷却,染浴降温至50℃以下,排液。
CN202111628497.8A 2021-12-28 2021-12-28 防水透湿功能面料 Active CN114261168B (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202111628497.8A CN114261168B (zh) 2021-12-28 2021-12-28 防水透湿功能面料
DE102022116534.5A DE102022116534A1 (de) 2021-12-28 2022-07-01 Wasserdichtes, feuchtigkeitsdurchlässiges funktionsgewebe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111628497.8A CN114261168B (zh) 2021-12-28 2021-12-28 防水透湿功能面料

Publications (2)

Publication Number Publication Date
CN114261168A CN114261168A (zh) 2022-04-01
CN114261168B true CN114261168B (zh) 2024-08-23

Family

ID=80830940

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111628497.8A Active CN114261168B (zh) 2021-12-28 2021-12-28 防水透湿功能面料

Country Status (2)

Country Link
CN (1) CN114261168B (zh)
DE (1) DE102022116534A1 (zh)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102587129A (zh) * 2012-02-29 2012-07-18 绍兴文理学院 一种仿生超疏水防污涤纶织物的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100334291C (zh) * 2005-04-20 2007-08-29 中科波司登纳米服饰(苏州)有限公司 具有纳米自清洁功能的羽绒服面料或成衣制品的制备方法
CN102220694B (zh) * 2010-04-16 2012-11-07 香港纺织及成衣研发中心 用于织物多功能整理的组合物及使用其的织物多功能整理方法
CN102965910B (zh) * 2012-09-11 2014-12-24 陕西科技大学 一种超疏水涤纶纺织品的制备方法
CN103074768A (zh) * 2012-12-17 2013-05-01 陕西科技大学 一种超耐用超疏水纺织品及其制备方法
CN105037679B (zh) * 2015-09-23 2018-01-16 苏州依司特新材料科技有限公司 阳离子型聚氨酯改性有机硅拒水剂及其制备方法与应用
CN111172748B (zh) * 2020-01-20 2022-08-30 宁波萌恒线业有限公司 一种纺织品用无氟防水剂及其制备方法
CN111636211A (zh) * 2020-06-24 2020-09-08 京准化工技术(上海)有限公司 一种耐久型阻燃抗菌防水整理剂及其制备方法和应用
CN112477352B (zh) * 2020-10-15 2022-02-15 浙江东进新材料有限公司 一种石墨烯导电面料
CN112376281B (zh) * 2020-11-05 2022-12-30 广州市新志能服装有限公司 一种防污抗油纺织面料及其制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102587129A (zh) * 2012-02-29 2012-07-18 绍兴文理学院 一种仿生超疏水防污涤纶织物的制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘志强.《中国优秀硕士学位论文全文数据库(电子期刊)》工程科技Ⅰ辑/聚酰亚胺多孔薄膜及块体制备与性能研究.2020,B014-476. *

Also Published As

Publication number Publication date
CN114261168A (zh) 2022-04-01
DE102022116534A1 (de) 2023-06-29

Similar Documents

Publication Publication Date Title
CN109706746B (zh) 一种拒水聚烯烃弹性面料
CN105884999A (zh) 含亲水及疏水侧长链的改性阳离子水性聚氨酯乳液的制备方法及其产品
WO2018099150A1 (zh) 一种水性双面绒面超纤pu合成革及其制备方法
CN101418518A (zh) 耐久亲水性聚醚改性氨基聚硅氧烷柔软剂的制备方法
CN110627828B (zh) 用于改善抗菌性能的有机硅季铵盐及其制备方法和应用
CN113293618B (zh) 一种阻燃防水整理剂的制备方法
CN109750503B (zh) 一种含硅拒水整理剂
CN109760397B (zh) 一种防水面料
CN111421920A (zh) 防水遮光复合面料
CN110983801A (zh) 一种防水透湿棉织物的制备方法
CN114261168B (zh) 防水透湿功能面料
CN102924734A (zh) 一种氟硅树脂、制备方法及其应用
CN110904687B (zh) 一种纯棉缎纹面料仿真丝整理剂及制备方法
CN116084162A (zh) 一种生物基抗起毛球整理剂及其制备方法和应用
CN113291039B (zh) 一种阻燃防水透湿复合面料的加工方法
CN109703076B (zh) 一种空气枕面料的制备方法
CN116675826A (zh) 一种面料用聚氨酯防水剂及其制备工艺
CN115717335A (zh) 一种棉用吸湿排汗整理剂及其制备方法
CN215321128U (zh) 一种环保真皮复合内饰材料
CN109267355A (zh) 一种硅油柔软剂的制备方法
CN113276533B (zh) 一种低湿阻防水复合面料的制备方法
CN110818875A (zh) 一种有机硅改性聚氨酯及其应用与其涂层织物制备方法
CN111607969B (zh) 一种用于棉织物的亲水有机硅整理剂及其制备方法
CN114635290A (zh) 异形复合丝仿麂皮绒防水面料的制备方法
CN114230797B (zh) 一种阳离子有机硅聚合物、微乳液及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant