CN1142067C - Water-transferring patterned paper for ceramics, its making method and its application - Google Patents
Water-transferring patterned paper for ceramics, its making method and its application Download PDFInfo
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- CN1142067C CN1142067C CNB011301015A CN01130101A CN1142067C CN 1142067 C CN1142067 C CN 1142067C CN B011301015 A CNB011301015 A CN B011301015A CN 01130101 A CN01130101 A CN 01130101A CN 1142067 C CN1142067 C CN 1142067C
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Abstract
The present invention relates to water-transferring patterned paper for ceramics, and a making method and application thereof. The making method comprises the following steps of preparing printing ink, printing and coating a glue film, wherein the printing ink is prepared from inorganic pigments and printing ink oil which is mainly prepared from ethane-vinyl acetate copolymer, dibutyl phthalate and a solvent; the step of coating a glue film comprises the step of printing a base film and the step of printing a web film. Base film glue solution is mainly prepared from ethylene-vinylacetate copolymer, dibutyl phthalate and xylene; web film glue solution is mainly prepared from polymethylmethacrylate, dibutyl phthalate, xylene and butyl acetate. Using the patterned paper can realize one time glaze firing technology. Compared with the prior art, the present invention can calcine a finished product one time, and therefore, the present invention has the advantages of simple technology, low production cost, low energy consumption, less investment, no color difference generation on the finished product, high productive efficiency and stable production quality when producing printing ceramics.
Description
Technical field
The present invention relates to the using method that a kind of ceramic water shifts marble paper and manufacture method and this marble paper.
Background technology
Existing stringcourse, the water transfering printing process on the flower sheet that is widely used in ceramic decoration mainly is made of following processing step:------------decal paper---dries---decoration firing---product to the raw glaze base to the table burning to moulded pottery not yet put in a kiln to bake in glaze firing.Marble paper used in the production process mainly is made of paper substrate, patterned layer, face glued membrane, the production technology of marble paper is with silk screen porcelain to be formed pattern with ink printing on the paper substrate face earlier, dry back is coated with one deck glue with the silk screen seal on pattern, treat promptly to form the face glued membrane after the glue drying, pattern just is attached to becomes the marble paper finished product on the face glued membrane.The using method of paper substrate is to be soaked in water earlier marble paper 2-3 minute, treat with the face glued membrane of pattern with after paper substrate separates, with the paving of face glued membrane on ceramic plane, the bubble that venting comprises dries moisture, carries out decoration firing in the kiln below 900 ℃, in the decoration firing process, the face glued membrane volatilizees through pyrolytic, the pottery on the pattern with pigment then fusion stick in ceramic surface, form decorative pattern.There is following shortcoming in above-mentioned technology:
1, process links is many in the production process, and complex process causes breakage easily.
2, will carry out earlier after the glaze firing vitreous could decal paper for porcelain, and energy consumption is big, the production cost height.
3, because the independence of each operation is strong, discontinuous, be difficult to form streamline production, therefore, production efficiency is low.
4, because the restriction of material that marble paper adopts, drain moisture more than wanting dry half a day after marble paper moves and is attached on the porcelain could decoration firing, otherwise the steam that meeting is produced during the high temperature decoration firing because moisture is not drained fully breaks through the face glued membrane.Cause snuff and destroy pattern.
5, the stringcourse of traditional decal paper production and flower sheet, all to burn till through secondary or three glazes, compare through the glaze that repeatedly burns till and the glaze of once-firing, its color developing effect is inconsistent, particularly contain the darker glaze of colorant, can produce tangible aberration, this is two, three insurmountable at all a great problems of Low fire ceramic marble paper of tradition, also is the shortcoming and defect part of traditional marble paper maximum.In order to solve the above problems, general stringcourse factory adopts the method for saw brick more, stringcourse is sawn into strip and end brick separately, to reduce the aberration of stringcourse, but for the aberration that exists in the flower sheet is insurmountable at all, and general glazed tile manufacturer as forming a complete production network stringcourse and flower sheet, then wants other configuration device, increased production cost, so stringcourse factory and ceramics factory are difficult to organically combine.
Summary of the invention
Goal of the invention of the present invention be to provide a kind of when producing the stamp pottery with marble paper technology simple, production cost is low, less energy consumption, small investment, can not produce aberration, the production efficiency height, the ceramic water of constant product quality shifts the using method of marble paper and manufacture method and this marble paper.
It is to realize like this that ceramic water of the present invention shifts marble paper, comprise and be coated with the paper substrate that is covered with the hydrosol, be printed on stamp on the hydrosol face, be printed on the face glued membrane on the stamp, the printing ink that constitutes decalcomania mainly is made of inorganic pigment, binding agent, the face glued membrane is by counterdie and be coated with the nethike embrane that is laid on above the counterdie and constitute, it is that a kind of fusing point is higher but be lower than 100 ℃ organic compound than room temperature that its special feature is to link agent, and counterdie is that a kind of fusing point is higher but be lower than 100 ℃ organic compound binder than room temperature.
Here the binding agent of being adopted is ethene-acetate ethylene copolymer, also can be ethlyene dichloride-acetate ethylene copolymer.Also contain dibutyl phthalate in the printing ink, and solvent.The effect of dibutyl phthalate is a plasticization, can increase the pliability and the stability of marble paper pattern.
Counterdie mainly by ethene-acetate ethylene copolymer.Dibutyl phthalate, solvent constitute.
Also be coated with shop one deck nethike embrane on the counterdie surface.The effect of nethike embrane is the effect of playing balladeur train, makes counterdie not yielding, guarantees that the pattern on the counterdie is stable.Because base film material is ethene-acetate ethylene copolymer, this kind physical property is softer, to responsive to temperature, the size temperature influence changes greatly, so do the time spent separately, cause pattern above it to be subjected to surrounding environment influence easily easily and be out of shape, destroyed pattern integrity.Therefore, need be coated with shop one deck nethike embrane on counterdie, the effect of skeleton had both been played in the effect of nethike embrane, simultaneously can overslaugh glaze firing process yet in gas purging, the gas that is produced in the glaze firing process can be drained along the mesh on the nethike embrane.
The chemical composition of nethike embrane mainly is polymethyl methacrylate, dibutyl phthalate, dimethylbenzene, butyl acetate.Polymethyl methacrylate is a kind of thermoplastic resin, its hardness height, and good toughness, not yielding, be coated with the effect that can play skeleton and carrier on the counterdie that is layered on.
The manufacture process of marble paper is to realize like this, comprise the preparation of printing ink, stamp, be coated with the face glued membrane, it is characterized in that printing ink is by inorganic pigment, ink oil is formulated, ethene in the ink oil-acetate ethylene copolymer content accounts for 5-20%, dibutyl phthalate content is 1-5%, solvent is 65-94%, vinyl acetate is more than 10% in ethene-acetate ethylene copolymer, ethene-acetate ethylene copolymer MI (melt index (MI)) is more than the 120g/10min, be coated with face glued membrane operation successively by the seal counterdie, seal nethike embrane operation constitutes, the counterdie glue is mainly accounted for ethene-acetate ethylene copolymer of 15-30% by content, content accounts for the dibutyl phthalate of 1-5%, the dimethylbenzene that content accounts for 65-84% constitutes, and the nethike embrane glue is mainly accounted for the polymethyl methacrylate of 20-30% by content, content accounts for the dibutyl phthalate of 2-8%, the solvent that content accounts for 60-75% constitutes.Printing technology is pattern to be printed on the hydrosol face of paper substrate with shining the silk screen that makes pattern with printing-ink, and carry out drying, drawing glued membrane operation is after treating the abundant drying of pattern printing ink, with silk screen the counterdie glue is printed on the pattern, carry out drying then, drawing glued membrane operation is after treating the abundant drying of pattern printing ink, with silk screen the counterdie glue is printed on the pattern, carry out drying then, treat with the silk screen that is shaped on net-like pattern the nethike embrane glue to be printed on the counterdie face again after the counterdie glue is dried to counterdie, become marble paper after the drying.
The using method of marble paper is to realize like this, comprise moulded pottery not yet put in a kiln to bake operation, biscuiting operation, raw glaze blank process, revenue stamp process, it is characterized in that revenue stamp process mainly is made of decal paper operation, glaze firing, before the applique, earlier marble paper is soaked in water a period of time, treat with the film of pattern to the raw glaze base, can to carry out klining to the film transfer of having pattern to ceramics with after paper substrate separates.Because stamp and face glued membrane on the marble paper have adopted low-melting binding agent and low-melting film glue respectively, make the incipient stage of glaze firing link agent thawing already before the gas generation in the glaze firing process, water and organic matter can be drained the pattern that does not destroy ceramic tile surface swimmingly because of high-temperature evaporation or gas that decomposition produced in the glaze firing process, thereby realize the purpose of once-firing.
Marble paper of the present invention also can use on the glaze after the glaze firing, if the intensity of moulded pottery not yet put in a kiln to bake is enough, also can directly use after the moulded pottery not yet put in a kiln to bake glazing, and using method is consistent with above-mentioned using method.
Compared with the prior art the present invention can realize the once-firing finished product when producing the stamp pottery with the present invention, and it is simple to have technology when therefore producing the stamp pottery with the present invention, production cost is low, less energy consumption, small investment, manufactured goods can not produce aberration, production efficiency height, the advantage of constant product quality.
Description of drawings:
Fig. 1 is the structural representation of marble paper of the present invention.
The specific embodiment:
Now in conjunction with the embodiments the present invention is done and describes in further detail:
As shown in the figure, marble paper of the present invention comprises and is coated with the paper substrate 2 that is covered with the hydrosol 1, is printed on stamp 3 on 1 of the hydrosol, is printed on the counterdie 4 on the stamp 3, the printing ink that constitutes stamp 3 patterns mainly is made of inorganic pigment, binding agent, it is that a kind of fusing point is higher but be lower than 100 ℃ organic compound than room temperature that its special feature is to link agent, and counterdie 4 is that a kind of fusing point is higher but be lower than that 100 ℃ organic compound is glutinous to contain agent than room temperature.
Here, the binding agent of being adopted is ethene-acetate ethylene copolymer.Also contain dibutyl phthalate, xylene solvent in the printing ink.
Counterdie 4 mainly is made of ethene-acetate ethylene copolymer, dibutyl phthalate, xylene solvent.
Also be coated with shop one deck nethike embrane 5 on counterdie 4 surfaces.
The manufacture method of marble paper of the present invention is to realize like this, comprise the preparation of printing ink, stamp, be coated with the face glued membrane, wherein printing ink is by inorganic pigment, ink oil is formulated, ethene in the ink oil-acetate ethylene copolymer content accounts for 5-20%, dibutyl phthalate content is 1-5%, solvent xylene is 65-89%, vinyl acetate is more than 50% in ethene-acetate ethylene copolymer, ethene-acetate ethylene copolymer MI (melt index (MI)) is more than the 200g/10min, be coated with face glued membrane operation successively by the seal counterdie, seal nethike embrane operation constitutes, the counterdie glue is mainly accounted for ethene-acetate ethylene copolymer of 24-30% by content, content accounts for the dibutyl phthalate of 1-5%, the dimethylbenzene that content accounts for 65-84% constitutes, and the nethike embrane glue is mainly accounted for the polymethyl methacrylate of 20-30% by content, content accounts for the dibutyl phthalate of 2-8%, content accounts for the dimethylbenzene of 15-25%, the butyl acetate that content accounts for 35-60% constitutes.Printing technology is pattern to be printed on the hydrosol face of paper substrate with shining the silk screen that makes pattern with printing-ink, and carry out drying, drawing glued membrane operation is after treating the abundant drying of pattern printing ink, with silk screen the counterdie glue is printed on the pattern, carry out drying then, treat with the silk screen that is shaped on net-like pattern the nethike embrane glue to be printed on the counterdie face again after the counterdie glue is dried to counterdie, become marble paper after the drying.
The using method of marble paper of the present invention is to realize like this, comprise moulded pottery not yet put in a kiln to bake operation, biscuiting operation, raw glaze blank process, revenue stamp process, its special feature is that revenue stamp process mainly is made of decal paper operation, glaze firing, before the applique, earlier marble paper is soaked in water a period of time, treat with the film of pattern to the raw glaze base, can to carry out klining to the film transfer of having pattern to ceramics with after paper substrate separates.
Here, in order to make the applique can be along must finishing, spraying one deck water-soluble glue on the glaze of applique be Cai treat applique behind its drying and forming-film.
Claims (7)
1, a kind of ceramic water shifts marble paper, comprise and be coated with the paper substrate that is covered with the hydrosol, be printed on the stamp on the hydrosol face, be printed on the face glued membrane on the stamp, the printing ink that constitutes decalcomania is mainly by inorganic pigment, linking agent constitutes, the face glued membrane is by counterdie and be coated with the nethike embrane that is laid on above the counterdie and constitute, it is higher but be lower than 100 ℃ hot melt organic compound than room temperature to it is characterized in that linking agent and be a kind of fusing point, this hot melt organic compound can be ethene-acetate ethylene copolymer, it also can be ethlyene dichloride-acetate ethylene copolymer, counterdie is that a kind of fusing point is higher but be lower than 100 ℃ hot melt than room temperature, film forming organic compound binder, this hot melt, film forming organic compound binder can be ethene-acetate ethylene copolymer.
2, ceramic water according to claim 1 shifts marble paper, and the chemical composition that it is characterized in that nethike embrane mainly is a polymethyl methacrylate.
3, the manufacture process of ceramic water transfer marble paper is to realize like this, comprise printing ink preparation, stamp, be coated with the face glued membrane, it is characterized in that printing ink is formulated by inorganic pigment, ink oil, ethene in the ink oil-acetate ethylene copolymer content accounts for 5-20%, dibutyl phthalate content is 1-5%, solvent xylene is 65-94%, and vinyl acetate is more than 10% in ethene-acetate ethylene copolymer, and ethene-acetate ethylene copolymer MI (melt index (MI)) is more than the 120g/10min.
4, ceramic water according to claim 3 shifts the manufacture process of marble paper, it is characterized in that being coated with face glued membrane operation successively is made of seal counterdie, seal nethike embrane operation, the counterdie glue mainly accounts for ethene-acetate ethylene copolymer of 15-30%, the dibutyl phthalate that content accounts for 1-5%, the xylene solvent formation that content accounts for 65-84% by content, the nethike embrane glue mainly accounts for the polymethyl methacrylate of 20-30%, the dibutyl phthalate that content accounts for 2-8%, the solvent that content accounts for 60-75% by content and constitutes, and the composition of solvent is dimethylbenzene and butyl acetate.
5, ceramic water according to claim 3 shifts the manufacture process of marble paper, it is characterized in that printing technology is pattern to be printed on the hydrosol face of paper substrate with shining the silk screen that makes pattern with printing-ink, and carry out drying, drawing glued membrane operation is after treating the abundant drying of pattern printing ink, with silk screen the counterdie glue is printed on the pattern, carry out drying then, treat with the silk screen that is shaped on net-like pattern the nethike embrane glue to be printed on the counterdie face again after the counterdie glue is dried to counterdie, become marble paper after the drying.
6, ceramic water shifts the using method of marble paper, comprise moulded pottery not yet put in a kiln to bake operation, biscuiting operation, raw glaze blank process, revenue stamp process, it is characterized in that revenue stamp process mainly is made of decal paper operation, glaze firing, before the applique, earlier marble paper is soaked in water a period of time, treat with the film of pattern to the raw glaze base, can to carry out klining to the film transfer of having pattern to ceramics with after paper substrate separates.
7, ceramic water according to claim 6 shifts the using method of marble paper, it is characterized in that applique before, the water-soluble glue of spraying one deck on the glaze of raw glaze base earlier.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011301015A CN1142067C (en) | 2001-12-14 | 2001-12-14 | Water-transferring patterned paper for ceramics, its making method and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011301015A CN1142067C (en) | 2001-12-14 | 2001-12-14 | Water-transferring patterned paper for ceramics, its making method and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1356214A CN1356214A (en) | 2002-07-03 |
| CN1142067C true CN1142067C (en) | 2004-03-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011301015A Expired - Fee Related CN1142067C (en) | 2001-12-14 | 2001-12-14 | Water-transferring patterned paper for ceramics, its making method and its application |
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| Country | Link |
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| CN (1) | CN1142067C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102774160A (en) * | 2012-08-13 | 2012-11-14 | 宁波长青家居用品有限公司 | Method for printing water-absorption cup mat |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1318695C (en) * | 2005-10-13 | 2007-05-30 | 中国制浆造纸研究院<Del/> | Production method of coated water transferal base paper for water transfer ceramic applique bottom paper |
| CN102174788A (en) * | 2011-01-01 | 2011-09-07 | 蔡锋盛 | Decal suitable for resin coating and production method and use method thereof |
| CN102153904B (en) * | 2011-01-12 | 2013-06-19 | 郑州鸿盛数码科技股份有限公司 | Ceramic transfer digital printing ink-jet ink and using method thereof |
| CN102555564A (en) * | 2012-01-12 | 2012-07-11 | 宗海燕 | Ceramic decal paper printing method by directly unrolling roll paper on multicolor synchronous overprinting line |
| CN103465662A (en) * | 2013-08-09 | 2013-12-25 | 上海高诚艺术包装有限公司 | Preparation method of burn-free stained paper |
| DE102017104658B4 (en) | 2017-03-06 | 2022-06-23 | Leonhard Kurz Stiftung & Co. Kg | Method for producing a decal and a decal and method for decorating surfaces of objects |
| CN109094278A (en) * | 2018-10-29 | 2018-12-28 | 广东非凡实业有限公司 | The preparation method of ancient painted pottery porcelain utensil is printed under a kind of glaze |
| CN110154611A (en) * | 2019-05-28 | 2019-08-23 | 江苏拜富科技有限公司 | A kind of low-temperature nano ceramic water transfer paste marble paper |
-
2001
- 2001-12-14 CN CNB011301015A patent/CN1142067C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102774160A (en) * | 2012-08-13 | 2012-11-14 | 宁波长青家居用品有限公司 | Method for printing water-absorption cup mat |
| CN102774160B (en) * | 2012-08-13 | 2015-04-22 | 宁波长青家居用品有限公司 | Method for printing water-absorption cup mat |
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| Publication number | Publication date |
|---|---|
| CN1356214A (en) | 2002-07-03 |
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