CN102153904B - Ceramic transfer digital printing ink-jet ink and using method thereof - Google Patents
Ceramic transfer digital printing ink-jet ink and using method thereof Download PDFInfo
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- CN102153904B CN102153904B CN 201110006128 CN201110006128A CN102153904B CN 102153904 B CN102153904 B CN 102153904B CN 201110006128 CN201110006128 CN 201110006128 CN 201110006128 A CN201110006128 A CN 201110006128A CN 102153904 B CN102153904 B CN 102153904B
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Abstract
The invention discloses a ceramic transfer digital printing ink-jet ink, which comprises the following components in percentage by weight: 1.0 to 16 percent of nano inorganic pigment, 0.5 to 20 percent of dispersant, 0.2 to 2 percent of surface tension regulator, 0.1 to 1.0 percent of bacteriacide, 2 to 30 percent of viscosity regulator, 0.1 to 2 percent of pH regulator and the balance of deionized water. The invention also discloses the method for using the ceramic transfer digital printing ink-jet ink for printing on a ceramic surface, which comprises transferring patterns formed by using the ceramic transfer digital printing ink-jet ink onto the blank, inglaze or glaze of the ceramic through water transfer printing paper, and calcining the ceramic in a furnace at 600 to 1,200 DEG C to form digital transfer printed patterns on the ceramic. The ink has the advantages of high quality stability and long storage time and can reach high technical requirements on color strength, color fastness and print clarity.
Description
Technical field
The present invention relates to a kind of pottery and shift digit printing ink-jet writing ink and using method thereof.
Background technology
The production process of printing screen has been saved in ink-jet printed application in the ceramic industry stamp, thereby can save a large amount of time and cost, especially for changeable pattern modelling situation, can reach significantly desired variation within the shorter time.The printing ink that is applied at present pottery coordinates traditional method for printing screen, can't realize high trace sharpness because being subject to silk screen hole purpose restriction, and simultaneously owing to containing a large amount of organic solvents in printing ink, in use after the volatilization, environmental pollution is serious.
Ink for ink-jet print is applied in ceramic industry, and the stability of ink, colour fastness, look dynamics, granularity, trace sharpness all need to satisfy higher requirement.
United States Patent (USP) 5407474 discloses a kind of mineral dye printing ink, this printing ink can utilize ink-jet printer to be applied on high temp objects, but, because the density difference between ceramic idiosome and mineral dye printing ink is large, so this solid that is suspended in mineral dye printing ink is unsettled, and the excessive easy obstruction ink jet printing head of the solid particulate in this mineral dye printing ink has shortened the working life of print head.
Summary of the invention
The objective of the invention is to solve problems of the prior art, provide a kind of pottery with high stability, look dynamics and colour fastness to shift digital digit printing ink-jet writing ink and using method thereof.
Technical scheme of the present invention is: a kind of pottery shifts digit printing ink-jet writing ink, and it is composed of the following components by weight percentage:
Nano grade inorganic pigment 1.0～16%;
Dispersion agent 0.5～20%;
Surface tension modifier 0.2～2%;
Sterilant 0.1～1.0%;
Viscosity modifier 2～30%;
PH value conditioning agent 0.1～2%;
Its surplus of deionized water.
Described nano grade inorganic pigment is one or more the mixture in the black Fe-Cr-Mn of mineral dye, the gorgeous black Co-Cr-Fe-Cu of mineral dye, the goth black Co-Cr-Fe of mineral dye, the pink Sn-Cr-Ca-Si of mineral dye, mineral dye praseodymium yellow Pr-Zr-Si, mineral dye vanadium zirconium blue Zr-Si-V, the sapphire blue Co-Si of mineral dye, the bright red Cd-Se-Si-Zr of mineral dye, the green Cr-Si of mineral dye, and the median size of described nano grade inorganic pigment is 50～150nm.
Described dispersion agent is that the multipolymer of vinylformic acid and acrylate is or/and vinylformic acid and cinnamic multipolymer.
Described surface tension modifier is the affixture of oxyethane and 2,4,7,9-tetramethyl--decine-4,7 glycol.
Described sterilant is CMIT.
Described viscosity modifier is acrylic resin, ethanol, Virahol, n-propyl alcohol, propyl carbinol, triethylene glycol methyl ether, methoxypolyethylene glycol, Diethylene Glycol, N, the mixture of one or more in N-dimethyl meta-aminotoluene, ethylene glycol benzyl oxide, furfuryl alcohol, tetrahydrofurfuryl alcohol, morpholine.
Described pH value conditioning agent is one or more the mixture in Monoethanolamine MEA BASF, trolamine, lactic acid, ammonium hydroxide, sodium hydroxide, citric acid.
the present invention also provides a kind of above-mentioned pottery to shift the using method that digit printing ink-jet writing ink is used for the ceramic surface printing, the pottery that makes is shifted digit printing ink-jet writing ink to be printed on water-transfer printing paper by design configuration, be coated on ceramic marble paper front cover oil the one side of printing decorative pattern is arranged on water-transfer printing paper, being placed in room temperature environment 20～40min dries naturally, water-transfer printing paper after drying is immersed in water, the basic paper for the treatment of water-transfer printing paper separates with transfer film, the transfer film that will be printed on figure is attached to the idiosome of pottery, in glaze or on glaze, subsequently pottery is calcined in the stove of 600～1200 ℃, can form the digital figure that shifts seal on pottery.
The invention has the beneficial effects as follows: quality stability can store by force for a long time, and look dynamics and colour fastness all can reach higher technical requirements.
Embodiment
Embodiment 1
Pottery shifts digit printing ink-jet writing ink, and it is composed of the following components according to weight percent: the goth black Co-Cr-Fe 10% of mineral dye, the black Fe-Cr-Mn 6% of mineral dye,
UDN dispersion agent 20%, Surfynol-465 surface tension modifier 2%, CMIT 1%, acrylic resin 2%, Monoethanolamine MEA BASF 0.1%, all the other are deionized water; Above component is mixed in proportion by 0.45 micron membrane filtration, can make product, Lay anthracene company of the present embodiment preferred section produces
The UDN dispersion agent, the Surfynol-465 surface tension modifier that U.S. aerochemistry company produces.
Embodiment 2
Pottery shifts digit printing ink-jet writing ink, and it is composed of the following components according to weight percent: the blue Zr-Si-V 10% of mineral dye vanadium zirconium,
UDN dispersion agent 12%, Surfynol-465 surface tension modifier 1.2%, CMIT 0.5%, triethylene glycol methyl ether 15%, trolamine 1%, lactic acid 1%, all the other are deionized water; Above component is mixed in proportion by 0.45 micron membrane filtration, can make product, Lay anthracene company of the present embodiment preferred section produces
The UDN dispersion agent, the Surfynol-465 surface tension modifier that U.S. aerochemistry company produces.
Embodiment 3
Pottery shifts digit printing ink-jet writing ink, and it is composed of the following components according to weight percent: the pink Sn-Cr-Ca-Si 12% of mineral dye,
UDN dispersion agent 15%, Surfynol-465 surface tension modifier 0.8%, CMIT 0.5%, ethylene glycol benzyl oxide 10%, furfuryl alcohol 5%, Monoethanolamine MEA BASF 0.1%, all the other are deionized water; Above component is mixed in proportion by 0.45 micron membrane filtration, can make product, Lay anthracene company of the present embodiment preferred section produces
The UDN dispersion agent, the Surfynol-465 surface tension modifier that U.S. aerochemistry company produces.
Embodiment 4
Pottery shifts digit printing ink-jet writing ink, and it is composed of the following components according to weight percent: mineral dye praseodymium yellow Pr-Zr-Si 11%,
UDN dispersion agent 12%, Surfynol-465 surface tension modifier 0.8%, CMIT 0.6%, ethanol 5%, Diethylene Glycol 10%, Monoethanolamine MEA BASF 0.1%, all the other are deionized water; Above component is mixed in proportion by 0.45 micron membrane filtration, can make product, Lay anthracene company of the present embodiment preferred section produces
The UDN dispersion agent, the Surfynol-465 surface tension modifier that U.S. aerochemistry company produces.
Embodiment 5
Pottery shifts digit printing ink-jet writing ink, and it is composed of the following components according to weight percent: the gorgeous black Fe-Cr-Mn 1.0% of mineral dye,
Dispersion agent 0.5%, Surfynol-465 surface tension modifier 0.2%, CMIT 0.1%, methoxypolyethylene glycol 15%, tetrahydrofurfuryl alcohol 15%, ammonium hydroxide 1.0%, all the other are deionized water; Above component is mixed in proportion by 0.45 micron membrane filtration, can make product, Lay anthracene company of the present embodiment preferred section produces
Dispersion agent, the Surfynol-465 surface tension modifier that U.S. aerochemistry company produces.
Embodiment 6
Pottery shifts digit printing ink-jet writing ink, and it is composed of the following components according to weight percent: the bright red Cd-Se-Si-Zr 8% of mineral dye, section's Lay anthracene
Dispersion agent 9%, Surfynol-465 surface tension modifier 1.0%, CMIT 0.5%, triethylene glycol methyl ether 10%, ethylene glycol benzyl oxide 5%, ammonium hydroxide 1.0%, trolamine 0.2%, all the other are deionized water; Above component is mixed in proportion by 0.45 micron membrane filtration, can make product, Lay anthracene company of the present embodiment preferred section produces
Dispersion agent, the Surfynol-465 surface tension modifier that U.S. aerochemistry company produces.
Embodiment 7
Pottery shifts digit printing ink-jet writing ink, and it is composed of the following components according to weight percent: the green Cr-Si9% of mineral dye,
Dispersion agent 9%, Surfynol-465 surface tension modifier 0.8%, CMIT 0.5%, N, N-dimethyl meta-aminotoluene 5%, polyoxyethylene glycol 10%, ammonium hydroxide 1%, trolamine 0.1%, all the other are deionized water; Above component is mixed in proportion by 0.45 micron membrane filtration, can make product, Lay anthracene company of the present embodiment preferred section produces
Dispersion agent, the Surfynol-465 surface tension modifier that U.S. aerochemistry company produces.
Embodiment 8
Pottery shifts digit printing ink-jet writing ink, and it is composed of the following components according to weight percent: the sapphire blue Co-Si 7% of mineral dye,
Dispersion agent 8%, Surfynol-465 surface tension modifier 0.8%, CMIT 0.4%, Diethylene Glycol 10%, n-propyl alcohol 5%, ammonium hydroxide 0.8%, trolamine 0.2%, all the other are deionized water; Above component is mixed in proportion by 0.45 micron membrane filtration, can make product, Lay anthracene company of the present embodiment preferred section produces
Dispersion agent, the Surfynol-465 surface tension modifier that U.S. aerochemistry company produces.
The product evaluation of the embodiment of the present invention 1～8 preparation the results are shown in table 1.
Table 1
The trace resolving power test:
Sample 1: mix with mineral dye with stand linseed oil, scrape the monochromatic color lump of standard of 20mm * 30mm on water-transfer printing paper in the silk screen mode, re-using ceramic marble paper front cover oil is coated with in the one side that the screen printing decorative pattern is arranged, being placed in room temperature environment 30min dries naturally, water-transfer printing paper after drying soaks in water, treats that basic paper separates with transfer film, will have the transfer film of decalcomania to be affixed on ceramic glaze, calcine in the stove of 900 ℃ at last, obtain the pottery after screen printing.
Sample 2: the pottery that the embodiment of the present invention 1～embodiment 8 makes shifts digit printing ink-jet writing ink and directly is printed on respectively the monochromatic color lump of the standard of printing 20mm * 30mm on ceramic glaze, being placed in room temperature environment 30min dries naturally, calcine in the stove of 900 ℃ at last, obtain the pottery after directly ink-jet printed.
sample 3: the pottery that the embodiment of the present invention 1～embodiment 8 makes shifts digit printing ink-jet writing ink and shifts respectively the using method of digit printing ink-jet writing ink according to the present invention's pottery, print the monochromatic color lump of standard of 20mm * 30mm on water-transfer printing paper, use ceramic marble paper front cover oil having the one side of printing decorative pattern to be coated with, being placed in room temperature environment 30min dries naturally, water-transfer printing paper after drying soaks in water, treat that basic paper separates with transfer film, to there be the transfer film of decalcomania to be affixed on ceramic glaze, calcine in the stove of 900 ℃ at last, obtain the pottery after digital transfer printing.
Trace resolving power test result sees also table 2.
| Test item | Sample 1 | Sample 2 | Sample 3 |
| The trace sharpness | △ | □ | ● |
Table 2
Annotate:
Symbol in table 2 " △ " expression: the ceramic decorative pattern after stamp has the site, soft edge.
Symbol in table 2 " " expression: after stamp the decorative pattern of fabric without the site, but soft edge.
Symbol "●" in table 2 represents: after stamp the decorative pattern of fabric without the site, clear-cut, sharp keen, edge-smoothing.Print adaptive testing:
Print on Epson 7910 printers respectively making the ink for ink-jet print that ink for ink-jet print and comparative example 1 (United States Patent (USP) 5407474 embodiment 1), comparative example 2 (United States Patent (USP) 5407474 embodiment 2) make in the embodiment of the present invention 6～embodiment 8, use Mengtai software, the 720dpi printing model is printed respectively monochromatic color lump 10m
2, printing nozzle detects page, observes the broken string radical, and adaptability is printed in evaluation and test, and test result is referring to table 3:
| Test item | Embodiment 6 | Embodiment 7 | Embodiment 8 | Comparative example 1 | Comparative example 2 |
| The broken string radical | 1 | 0 | 1 | 26 | 31 |
| Print adaptability | √ | √ | √ | × | × |
Table 3
Annotate: " √ " expression in table 3: broken string 0-3 root is evaluated as printing adaptability qualified; " * " expression in table 3: broken string is evaluated as printing adaptability defective more than 3.
Claims (7)
1. a pottery shifts digit printing ink-jet writing ink, and it is characterized in that: it is composed of the following components by weight percentage:
Nano grade inorganic pigment 1.0 ~ 16%;
Dispersion agent 0.5 ~ 20%;
Surface tension modifier 0.2 ~ 2%;
Sterilant 0.1 ~ 1.0%;
Viscosity modifier 2 ~ 30%;
PH value conditioning agent 0.1 ~ 2%;
Its surplus of deionized water;
Wherein: described nano grade inorganic pigment is one or more the mixture in the black Fe-Cr-Mn of mineral dye, the gorgeous black Co-Cr-Fe-Cu of mineral dye, the goth black Co-Cr-Fe of mineral dye, the pink Sn-Cr-Ca-Si of mineral dye, mineral dye praseodymium yellow Pr-Zr-Si, mineral dye vanadium zirconium blue Zr-Si-V, the sapphire blue Co-Si of mineral dye, the bright red Cd-Se-Si-Zr of mineral dye, the green Cr-Si of mineral dye, and the median size of described nano grade inorganic pigment is 50 ~ 150nm.
2. pottery according to claim 1 shifts digit printing ink-jet writing ink, it is characterized in that: described dispersion agent is that the multipolymer of vinylformic acid and acrylate is or/and vinylformic acid and cinnamic multipolymer.
3. pottery according to claim 1 shifts digit printing ink-jet writing ink, and it is characterized in that: described surface tension modifier is the affixture of oxyethane and 2,4,7,9-tetramethyl--decine-4,7 glycol.
4. pottery according to claim 1 shifts digit printing ink-jet writing ink, and it is characterized in that: described sterilant is CMIT.
5. pottery according to claim 1 shifts digit printing ink-jet writing ink, it is characterized in that: described viscosity modifier is acrylic resin, ethanol, Virahol, n-propyl alcohol, propyl carbinol, triethylene glycol methyl ether, methoxypolyethylene glycol, Diethylene Glycol, N, the mixture of one or more in N-dimethyl meta-aminotoluene, ethylene glycol benzyl oxide, furfuryl alcohol, tetrahydrofurfuryl alcohol, morpholine.
6. pottery according to claim 1 shifts digit printing ink-jet writing ink, it is characterized in that: described pH value conditioning agent is one or more the mixture in Monoethanolamine MEA BASF, trolamine, lactic acid, ammonium hydroxide, sodium hydroxide, citric acid.
7. a pottery claimed in claim 1 shifts the using method that digit printing ink-jet writing ink is used for the ceramic surface printing, the pottery that makes is shifted digit printing ink-jet writing ink to be printed on water-transfer printing paper by design configuration, be coated on ceramic marble paper front cover oil the one side of printing decorative pattern is arranged on water-transfer printing paper, being placed in room temperature environment 20 ~ 40min dries naturally, water-transfer printing paper after drying is immersed in water, the basic paper for the treatment of water-transfer printing paper separates with transfer film, the transfer film that will be printed on figure is attached to the idiosome of pottery, in glaze or on glaze, subsequently pottery is calcined in the stove of 600 ~ 1200 ℃, can form the digital figure that shifts seal on pottery.
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| CN 201110006128 CN102153904B (en) | 2011-01-12 | 2011-01-12 | Ceramic transfer digital printing ink-jet ink and using method thereof |
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| CN 201110006128 CN102153904B (en) | 2011-01-12 | 2011-01-12 | Ceramic transfer digital printing ink-jet ink and using method thereof |
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| CN102358086A (en) * | 2011-09-13 | 2012-02-22 | 唐昌富 | Heat transfer process for digital product shell |
| CN102433044A (en) * | 2011-11-02 | 2012-05-02 | 广东新中源陶瓷有限公司 | Ink for 3D digital ink-jet ceramic tile |
| CN102382518B (en) * | 2011-11-23 | 2015-03-04 | 佛山市明朝科技开发有限公司 | Ceramic ink-jet ink with low viscosity and preparation method thereof |
| CN102516842A (en) * | 2011-12-06 | 2012-06-27 | 广东道氏技术股份有限公司 | Roller printing oil for ceramic printing and preparation method thereof |
| CN102512256B (en) * | 2011-12-26 | 2014-05-21 | 辽宁爱尔创生物材料有限公司 | Method for dyeing all-zirconium tooth by using film |
| CN102675967B (en) * | 2012-05-08 | 2014-01-15 | 中山大学 | Water-based ceramic three-dimensional pattern printing ink and preparation method thereof |
| CN103342917B (en) * | 2013-07-04 | 2015-07-15 | 西安电子科技大学 | Yellow ceramic ink for ink-jet printing |
| CN103614003B (en) * | 2013-11-20 | 2015-03-18 | 佛山市东鹏陶瓷有限公司 | Anti-static colored glaze mixed ink for ceramic ink-jet printing and preparation method thereof |
| CN106400538A (en) * | 2016-08-30 | 2017-02-15 | 苏州市恒信针织印染有限责任公司 | Printing color paste composition for pigment printing of linen-cotton fiber fabric |
| CN106567265A (en) * | 2016-11-04 | 2017-04-19 | 苏州吉谷新材料有限公司 | Heat sublimation printed tile and preparation technology thereof |
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| EP0886000A2 (en) * | 1997-06-17 | 1998-12-23 | Ciba SC Holding AG | Process for ink jet printing textile materials |
| CN1356214A (en) * | 2001-12-14 | 2002-07-03 | 姚少锋 | Water-transferring patterned paper for ceramics, its making method and its application |
| CN101709177A (en) * | 2009-12-03 | 2010-05-19 | 上海英威喷墨科技有限公司 | Waterborne digital ink-jet printing sublimation ink and preparation method thereof |
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- 2011-01-12 CN CN 201110006128 patent/CN102153904B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0886000A2 (en) * | 1997-06-17 | 1998-12-23 | Ciba SC Holding AG | Process for ink jet printing textile materials |
| CN1356214A (en) * | 2001-12-14 | 2002-07-03 | 姚少锋 | Water-transferring patterned paper for ceramics, its making method and its application |
| CN101709177A (en) * | 2009-12-03 | 2010-05-19 | 上海英威喷墨科技有限公司 | Waterborne digital ink-jet printing sublimation ink and preparation method thereof |
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Denomination of invention: An ink-jet ink for ceramic transfer digital printing and its use method Effective date of registration: 20221230 Granted publication date: 20130619 Pledgee: Bank of Zhengzhou Co.,Ltd. Zhongyuan Science and Technology City Sub branch Pledgor: HONGSAM DIGITAL SCIENCE & TECHNOLOGY Co.,Ltd. Registration number: Y2022980029740 |
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