CN106567265A - Heat sublimation printed tile and preparation technology thereof - Google Patents

Heat sublimation printed tile and preparation technology thereof Download PDF

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Publication number
CN106567265A
CN106567265A CN201610962844.3A CN201610962844A CN106567265A CN 106567265 A CN106567265 A CN 106567265A CN 201610962844 A CN201610962844 A CN 201610962844A CN 106567265 A CN106567265 A CN 106567265A
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CN
China
Prior art keywords
parts
layer
tile
afterwards
printed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610962844.3A
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Chinese (zh)
Inventor
戚裕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Jigu New Material Co Ltd
Original Assignee
Suzhou Jigu New Material Co Ltd
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Filing date
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Priority to CN201610962844.3A priority Critical patent/CN106567265A/en
Publication of CN106567265A publication Critical patent/CN106567265A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003Transfer printing
    • D06P5/004Transfer printing using subliming dyes
    • D06P5/006Transfer printing using subliming dyes using specified dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/32Inkjet printing inks characterised by colouring agents
    • C09D11/328Inkjet printing inks characterised by colouring agents characterised by dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • D06P1/50Derivatives of cellulose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5228Polyalkenyl alcohols, e.g. PVA
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257(Meth)acrylic acid

Abstract

The invention discloses a heat sublimation printed tile and a preparation technology thereof. The printed tile comprises a tile body. A paint layer is painted on the surface of the tile body. A printed transfer film, which has been printed, is covered on the surface of the paint layer. A hydrophilic material layer is painted on the surface of the printed transfer film. A layer of heat transfer printing ink is printed on the surface of the hydrophilic material layer. The heat transfer printing ink comprises the following components in parts by weight: 20 to 40 parts of dispersed dye, 6 to 15 parts of viscosity regulator, 4 to 12 parts of surfactant, 6 to 15 parts of sodium lignin sulfonate, 2 to 8 parts of antiseptic, 6 to 13 parts of carboxymethyl cellulose, 2 to 6 parts of corrosion inhibitor, 4 to 10 parts of styrene acrylic resin, and 4 to 10 parts of polyvinyl alcohol. The preparation technology is simple. The patterns of produced printed tile are clear and beautiful, moreover, the patterns are firmly attached and the adhesive force is strong.

Description

A kind of heat sublimation imprinted tile and its preparation technology
Technical field
The present invention relates to printed articles preparing technical field, specially a kind of heat sublimation imprinted tile and its preparation technology.
Background technology
With the improvement of people's living standards, ceramic tile is the common used material of people's decoration, and especially ceramic tile is people's decoration book The indispensable material such as room, bedroom, toilet, bathroom, the ceramic tile of prior art are only processed by common ceramic material, Appearance color is single, and with the improvement of people's living standards, people not only meet the decoration function of former ceramic tile, to its external beauty Sight degree is put forward higher requirement, and although the ceramic tile surface of prior art is printed on pattern, but this pattern exposes for a long time, easily falls Color, the definition and verity of multicolour pattern are poor.
The content of the invention
It is an object of the invention to provide a kind of heat sublimation imprinted tile and its preparation technology, to solve above-mentioned background technology The problem of middle proposition.
For achieving the above object, the present invention provides following technical scheme:A kind of heat sublimation imprinted tile, including ceramic tile sheet Body, the ceramic tile body surface coat a coating layer, and coating layer surface covers one layer of printed decal transfer film, and stamp turns One layer of hydrophilic material of die surface-coated, one layer of thermal transfer ink of hydrophilic material printout surface, thermal transfer ink component are pressed Parts by weight include disperse dyes 20-40 parts, viscosity-controlling agent 6-15 parts, surfactant 4-12 parts, sodium lignin sulfonate 6- 15 parts, preservative 2-8 parts, carboxymethyl cellulose 6-13 parts, corrosion inhibiter 2-6 parts, styrene acrylic resin 4-10 parts, polyethylene Alcohol 4-10 parts.
Preferably, thermal transfer ink preferred component proportioning includes 30 parts of disperse dyes, 10 parts of viscosity-controlling agent, surface activity 8 parts of agent, 11 parts of sodium lignin sulfonate, 5 parts of preservative, 10 parts of carboxymethyl cellulose, 4 parts of corrosion inhibiter, styrene acrylic resin 7 Part, 7 parts of polyvinyl alcohol.
Preferably, the hydrophilic material by 40% polyvinyl alcohol, 40% polyacrylic acid, 10% polyalkylene oxide system resin with And 10% SiO 2 powder composition.
Preferably, the thickness of the decal transfer film is 4 microns -10 microns.
Preferably, its preparation technology is comprised the following steps:
A, ceramic tile body surface is cleaned after decontamination, 30min is dried in being put into 100 DEG C of drying baker, is cooled to often after taking-up Temperature;
B, by step A clean after ceramic tile surface sanding and polishing, afterwards again after clean surface be dried;
C, the ceramic tile surface after the process of step B coat a coating layer, are dried in being put into drying baker afterwards;
D, the outer surface that printed decal transfer film is covered in step C dope layer, afterwards in decal transfer film appearance Face coats one layer of hydrophilic material, afterwards in one layer of thermal transfer ink of hydrophilic material printout surface;
E, be put into afterwards the transfer of thermal transfer machine print, thermal transfer temperature be 130 DEG C -160 DEG C, transfer time 40s-80s, it After be cooled to room temperature, finally decal transfer film is torn, that is, obtains heat sublimation imprinted tile.
Compared with prior art, the invention has the beneficial effects as follows:
(1) preparation process is simple of the present invention, obtained paint glass pattern texture are clear, and aesthetics is good, and pattern is difficult Come off, adhesive force is good.
(2) the thermal transfer ink drying rate that the present invention is adopted is fast, while having sterilization, antisepsises, improves transfer Quality.
Specific embodiment
Below the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment Only it is a part of embodiment of the invention, rather than the embodiment of whole.Based on the embodiment in the present invention, ordinary skill The every other embodiment obtained under the premise of creative work is not made by personnel, belongs to the scope of protection of the invention.
The present invention provides a kind of technical scheme:A kind of heat sublimation imprinted tile, including ceramic tile body, ceramic tile body surface are applied A coating layer is covered, coating layer surface covers one layer of printed decal transfer film, and one layer of decal transfer film surface-coated is hydrophilic Material layer, one layer of thermal transfer ink of hydrophilic material printout surface, thermal transfer ink component include disperse dyes by weight 20-40 parts, viscosity-controlling agent 6-15 parts, surfactant 4-12 parts, sodium lignin sulfonate 6-15 parts, preservative 2-8 parts, carboxylic first Base cellulose 6-13 parts, corrosion inhibiter 2-6 parts, styrene acrylic resin 4-10 parts, polyvinyl alcohol 4-10 parts;Wherein, hydrophilic material The bed of material is made up of 40% polyvinyl alcohol, 40% polyacrylic acid, 10% polyalkylene oxide system resin and 10% SiO 2 powder.
Embodiment one:
In the present embodiment, thermal transfer ink component includes 20 parts of disperse dyes, 6 parts of viscosity-controlling agent, table by weight 4 parts of face activating agent, 6 parts of sodium lignin sulfonate, 2 parts of preservative, 6 parts of carboxymethyl cellulose, 2 parts of corrosion inhibiter, styrene acrylic 4 parts of resin, 4 parts of polyvinyl alcohol.
In the present embodiment, the thickness of decal transfer film is 4 microns.
The preparation technology of the present embodiment is comprised the following steps:
A, ceramic tile body surface is cleaned after decontamination, 30min is dried in being put into 100 DEG C of drying baker, is cooled to often after taking-up Temperature;
B, by step A clean after ceramic tile surface sanding and polishing, afterwards again after clean surface be dried;
C, the ceramic tile surface after the process of step B coat a coating layer, are dried in being put into drying baker afterwards;
D, the outer surface that printed decal transfer film is covered in step C dope layer, afterwards in decal transfer film appearance Face coats one layer of hydrophilic material, afterwards in one layer of thermal transfer ink of hydrophilic material printout surface;
E, thermal transfer machine transfer print is put into afterwards, thermal transfer temperature is 130 DEG C, and transfer time 40s is cooled to often afterwards Decal transfer film is finally torn by temperature, that is, obtain heat sublimation imprinted tile.
Embodiment two:
In the present embodiment, thermal transfer ink component includes 40 parts of disperse dyes, 15 parts of viscosity-controlling agent, table by weight 12 parts of face activating agent, 15 parts of sodium lignin sulfonate, 8 parts of preservative, 13 parts of carboxymethyl cellulose, 6 parts of corrosion inhibiter, styrene-acrylonitrile copolymer 10 parts of acid resin, 10 parts of polyvinyl alcohol.
In the present embodiment, the thickness of decal transfer film is 10 microns.
The preparation technology of the present embodiment is comprised the following steps:
A, ceramic tile body surface is cleaned after decontamination, 30min is dried in being put into 100 DEG C of drying baker, is cooled to often after taking-up Temperature;
B, by step A clean after ceramic tile surface sanding and polishing, afterwards again after clean surface be dried;
C, the ceramic tile surface after the process of step B coat a coating layer, are dried in being put into drying baker afterwards;
D, the outer surface that printed decal transfer film is covered in step C dope layer, afterwards in decal transfer film appearance Face coats one layer of hydrophilic material, afterwards in one layer of thermal transfer ink of hydrophilic material printout surface;
E, thermal transfer machine transfer print is put into afterwards, thermal transfer temperature is 160 DEG C, and transfer time 80s is cooled to often afterwards Decal transfer film is finally torn by temperature, that is, obtain heat sublimation imprinted tile.
Embodiment three:
In the present embodiment, thermal transfer ink component includes 25 parts of disperse dyes, 7 parts of viscosity-controlling agent, table by weight 5 parts of face activating agent, 7 parts of sodium lignin sulfonate, 3 parts of preservative, 7 parts of carboxymethyl cellulose, 3 parts of corrosion inhibiter, styrene acrylic 5 parts of resin, 5 parts of polyvinyl alcohol.
In the present embodiment, the thickness of decal transfer film is 5 microns.
The preparation technology of the present embodiment is comprised the following steps:
A, ceramic tile body surface is cleaned after decontamination, 30min is dried in being put into 100 DEG C of drying baker, is cooled to often after taking-up Temperature;
B, by step A clean after ceramic tile surface sanding and polishing, afterwards again after clean surface be dried;
C, the ceramic tile surface after the process of step B coat a coating layer, are dried in being put into drying baker afterwards;
D, the outer surface that printed decal transfer film is covered in step C dope layer, afterwards in decal transfer film appearance Face coats one layer of hydrophilic material, afterwards in one layer of thermal transfer ink of hydrophilic material printout surface;
E, thermal transfer machine transfer print is put into afterwards, thermal transfer temperature is 140 DEG C, and transfer time 50s is cooled to often afterwards Decal transfer film is finally torn by temperature, that is, obtain heat sublimation imprinted tile.
Example IV:
In the present embodiment, thermal transfer ink component includes 35 parts of disperse dyes, 13 parts of viscosity-controlling agent, table by weight 10 parts of face activating agent, 12 parts of sodium lignin sulfonate, 7 parts of preservative, 12 parts of carboxymethyl cellulose, 5 parts of corrosion inhibiter, styrene-acrylonitrile copolymer 8 parts of acid resin, 8 parts of polyvinyl alcohol.
In the present embodiment, the thickness of decal transfer film is 8 microns.
The preparation technology of the present embodiment is comprised the following steps:
A, ceramic tile body surface is cleaned after decontamination, 30min is dried in being put into 100 DEG C of drying baker, is cooled to often after taking-up Temperature;
B, by step A clean after ceramic tile surface sanding and polishing, afterwards again after clean surface be dried;
C, the ceramic tile surface after the process of step B coat a coating layer, are dried in being put into drying baker afterwards;
D, the outer surface that printed decal transfer film is covered in step C dope layer, afterwards in decal transfer film appearance Face coats one layer of hydrophilic material, afterwards in one layer of thermal transfer ink of hydrophilic material printout surface;
E, thermal transfer machine transfer print is put into afterwards, thermal transfer temperature is 150 DEG C, and transfer time 70s is cooled to often afterwards Decal transfer film is finally torn by temperature, that is, obtain heat sublimation imprinted tile.
Embodiment five:
In the present embodiment, thermal transfer ink component includes 30 parts of disperse dyes, 10 parts of viscosity-controlling agent, table by weight 8 parts of face activating agent, 11 parts of sodium lignin sulfonate, 5 parts of preservative, 10 parts of carboxymethyl cellulose, 4 parts of corrosion inhibiter, styrene-acrylonitrile copolymer 7 parts of acid resin, 7 parts of polyvinyl alcohol.
In the present embodiment, the thickness of decal transfer film is 7 microns.
The preparation technology of the present embodiment is comprised the following steps:
A, ceramic tile body surface is cleaned after decontamination, 30min is dried in being put into 100 DEG C of drying baker, is cooled to often after taking-up Temperature;
B, by step A clean after ceramic tile surface sanding and polishing, afterwards again after clean surface be dried;
C, the ceramic tile surface after the process of step B coat a coating layer, are dried in being put into drying baker afterwards;
D, the outer surface that printed decal transfer film is covered in step C dope layer, afterwards in decal transfer film appearance Face coats one layer of hydrophilic material, afterwards in one layer of thermal transfer ink of hydrophilic material printout surface;
E, thermal transfer machine transfer print is put into afterwards, thermal transfer temperature is 145 DEG C, and transfer time 60s is cooled to often afterwards Decal transfer film is finally torn by temperature, that is, obtain heat sublimation imprinted tile.
Preparation process is simple of the present invention, obtained paint glass pattern texture are clear, and aesthetics is good, and pattern is difficult to take off Fall, adhesive force is good;The thermal transfer ink drying rate that the present invention is adopted is fast, while having sterilization, antisepsises, improves transfer Quality.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention And modification, the scope of the present invention be defined by the appended.

Claims (5)

1. a kind of heat sublimation imprinted tile, including ceramic tile body, it is characterised in that:The ceramic tile body surface coats a coating Layer, coating layer surface cover one layer of printed decal transfer film, and one layer of hydrophilic material of decal transfer film surface-coated is hydrophilic Material surface prints one layer of thermal transfer ink, and thermal transfer ink component includes disperse dyes 20-40 parts, viscosity by weight Regulator 6-15 parts, surfactant 4-12 parts, sodium lignin sulfonate 6-15 parts, preservative 2-8 parts, carboxymethyl cellulose 6-13 Part, corrosion inhibiter 2-6 parts, styrene acrylic resin 4-10 parts, polyvinyl alcohol 4-10 parts.
2. a kind of heat sublimation imprinted tile according to claim 1, it is characterised in that:Thermal transfer ink preferred component proportioning Including 30 parts of disperse dyes, 10 parts of viscosity-controlling agent, 8 parts of surfactant, 11 parts of sodium lignin sulfonate, 5 parts of preservative, carboxylic first 10 parts of base cellulose, 4 parts of corrosion inhibiter, 7 parts of styrene acrylic resin, 7 parts of polyvinyl alcohol.
3. a kind of heat sublimation imprinted tile according to claim 1, it is characterised in that:The hydrophilic material is gathered by 40% Vinyl alcohol, 40% polyacrylic acid, 10% polyalkylene oxide system resin and 10% SiO 2 powder composition.
4. a kind of heat sublimation imprinted tile according to claim 1, it is characterised in that:The thickness of the decal transfer film is 4 microns -10 microns.
5. a kind of preparation technology of the heat sublimation imprinted tile described in claim 1 is realized, it is characterised in that:Its preparation technology bag Include following steps:
A, by ceramic tile body surface clean decontamination after, be dried 30min in being put into 100 DEG C of drying baker, after taking-up, be cooled to room temperature;
B, by step A clean after ceramic tile surface sanding and polishing, afterwards again after clean surface be dried;
C, the ceramic tile surface after the process of step B coat a coating layer, are dried in being put into drying baker afterwards;
D, the outer surface that printed decal transfer film is covered in step C dope layer, are applied in decal transfer film outer surface afterwards One layer of hydrophilic material is covered, afterwards in one layer of thermal transfer ink of hydrophilic material printout surface;
E, be put into afterwards the transfer of thermal transfer machine print, thermal transfer temperature be 130 DEG C -160 DEG C, transfer time 40s-80s, Zhi Houleng But to room temperature, finally decal transfer film is torn, that is, obtains heat sublimation imprinted tile.
CN201610962844.3A 2016-11-04 2016-11-04 Heat sublimation printed tile and preparation technology thereof Pending CN106567265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610962844.3A CN106567265A (en) 2016-11-04 2016-11-04 Heat sublimation printed tile and preparation technology thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610962844.3A CN106567265A (en) 2016-11-04 2016-11-04 Heat sublimation printed tile and preparation technology thereof

Publications (1)

Publication Number Publication Date
CN106567265A true CN106567265A (en) 2017-04-19

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Country Link
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CN110893560A (en) * 2018-09-13 2020-03-20 肖克有限公司 Method for manufacturing a component with a polymer adhesive matrix

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110893560A (en) * 2018-09-13 2020-03-20 肖克有限公司 Method for manufacturing a component with a polymer adhesive matrix

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Application publication date: 20170419