CN114173905A - 减少汞蒸气排放 - Google Patents

减少汞蒸气排放 Download PDF

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Publication number
CN114173905A
CN114173905A CN202080050818.8A CN202080050818A CN114173905A CN 114173905 A CN114173905 A CN 114173905A CN 202080050818 A CN202080050818 A CN 202080050818A CN 114173905 A CN114173905 A CN 114173905A
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CN
China
Prior art keywords
polymer composite
sorbent polymer
mercury
treated
halogen source
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Pending
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CN202080050818.8A
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English (en)
Chinese (zh)
Inventor
S·J·哈德维克
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WL Gore and Associates Inc
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WL Gore and Associates Inc
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Publication of CN114173905A publication Critical patent/CN114173905A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/82—Solid phase processes with stationary reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/264—Synthetic macromolecular compounds derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3014—Kneading
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/10—Oxidants
    • B01D2251/108—Halogens or halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/202—Polymeric adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/46—Materials comprising a mixture of inorganic and organic materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/60—Heavy metals; Compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
CN202080050818.8A 2019-05-13 2020-05-12 减少汞蒸气排放 Pending CN114173905A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962846985P 2019-05-13 2019-05-13
US62/846,985 2019-05-13
PCT/US2020/032454 WO2020231982A1 (en) 2019-05-13 2020-05-12 Mitigation of mercury vapor emissions

Publications (1)

Publication Number Publication Date
CN114173905A true CN114173905A (zh) 2022-03-11

Family

ID=70857297

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202080050818.8A Pending CN114173905A (zh) 2019-05-13 2020-05-12 减少汞蒸气排放

Country Status (5)

Country Link
US (1) US11865496B2 (https=)
EP (1) EP3969153A1 (https=)
JP (2) JP7650824B2 (https=)
CN (1) CN114173905A (https=)
WO (1) WO2020231982A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20240367091A1 (en) * 2021-07-30 2024-11-07 Albemarle Corporation Processes For Suppressing Emission of Mercury Vapor

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04247237A (ja) * 1991-01-31 1992-09-03 Hitachi Zosen Corp 水銀吸着剤の再生方法
DE4422661A1 (de) * 1994-06-28 1996-01-04 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Verfahren und Anordnung zur kontinuierlichen Abtrennung von Quecksilber aus strömenden Gasen
WO2004094024A2 (en) * 2003-04-23 2004-11-04 Energy & Environmental Research Center Foundation, Inc. Process for regenerating a spent sorbent
EP2033702A1 (de) * 2007-09-04 2009-03-11 Evonik Energy Services Gmbh Verfahren zum Entfernen von Quecksilber aus Verbrennungsabgasen
CA2757309A1 (en) * 2009-04-23 2010-10-28 Energy & Environmental Research Center Foundation Sorbents for the oxidation and removal of mercury
US20110048231A1 (en) * 2009-08-28 2011-03-03 Sinha Rabindra K Composition and Method for Reducing Mercury Emitted into the Atmosphere
US20140260976A1 (en) * 2013-03-15 2014-09-18 W. L. Gore & Associates, Inc. Mist Elimination and Pollutant Removal Device and Method
WO2016138193A1 (en) * 2015-02-27 2016-09-01 W.L. Gore & Associates, Inc. A flue gas purification system and process using a sorbent polymer composite material
US20170100692A1 (en) * 2003-04-23 2017-04-13 Edwin S. Olson Promoted ammonium salt-protected activated carbon sorbent particles for removal of mercury from gas streams
US20170173557A1 (en) * 2013-03-06 2017-06-22 Energy & Environmental Research Foundation Sorbent comprising carbon and nitrogen and methods of using the same

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1285659B (de) 1965-09-16 1968-12-19 Bergwerksverband Gmbh Verfahren zur Adsorption von Schwefeldioxid aus schwefeldioxidhaltigen Abgasen
SE392582B (sv) 1970-05-21 1977-04-04 Gore & Ass Forfarande vid framstellning av ett porost material, genom expandering och streckning av en tetrafluoretenpolymer framstelld i ett pastabildande strengsprutningsforfarande
US4419107A (en) 1980-11-10 1983-12-06 Roydhouse Richard H Mercury filtering apparatus and method
US5202301A (en) 1989-11-22 1993-04-13 Calgon Carbon Corporation Product/process/application for removal of mercury from liquid hydrocarbon
WO1995019828A1 (en) 1994-01-25 1995-07-27 Extraction Systems, Inc. Air filtering
EP0969922B1 (en) * 1997-02-07 2004-10-20 Battelle Memorial Institute A surface functionalized mesoporous material and method of making same
US20040074391A1 (en) 2002-10-16 2004-04-22 Vincent Durante Filter system
US7442352B2 (en) * 2003-06-20 2008-10-28 Gore Enterprise Holdings, Inc. Flue gas purification process using a sorbent polymer composite material
US7352558B2 (en) 2003-07-09 2008-04-01 Maxwell Technologies, Inc. Dry particle based capacitor and methods of making same
US10343114B2 (en) * 2004-08-30 2019-07-09 Midwest Energy Emissions Corp Sorbents for the oxidation and removal of mercury
KR100760236B1 (ko) 2006-02-28 2007-10-04 한국과학기술연구원 할로겐화 화합물 첨착 활성탄을 이용한 연소 설비 배출가스 중 수은의 저감 방법
JP5553966B2 (ja) 2008-03-19 2014-07-23 千代田化工建設株式会社 水銀吸着材およびその吸着材を用いた排煙処理方法
JP4889621B2 (ja) 2006-12-15 2012-03-07 日揮株式会社 水銀吸着剤、水銀吸着剤の製造方法及び水銀吸着除去方法
JP5094468B2 (ja) 2007-03-01 2012-12-12 日本エンバイロケミカルズ株式会社 ガス中の水銀蒸気除去法
US8372362B2 (en) 2010-02-04 2013-02-12 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
EP2539044A4 (en) * 2010-02-22 2013-11-06 Central Michigan University NETWORKED POLYMER CARBON SORBON FOR THE REMOVAL OF HEAVY METALS, TOXIC MATERIALS AND CARBON DIOXIDE
TWI549737B (zh) 2010-08-26 2016-09-21 片片堅俄亥俄州工業公司 過濾介質及其應用
US8883099B2 (en) * 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US8974578B2 (en) 2012-05-07 2015-03-10 Northwestern University Porous polymer networks and ion-exchange media and metal-polymer composites made therefrom
DE112013005490T5 (de) * 2012-10-16 2015-08-13 Novinda Corporation Oxidation und Auffangen von gasförmigem Quecksilber
US9138684B2 (en) 2013-01-03 2015-09-22 Milliken & Company Filter for removal of heavy metals
WO2015077746A2 (en) 2013-11-25 2015-05-28 Milliken & Company Filtration medium and process for filtering a fluid stream
CN105214601A (zh) 2015-09-24 2016-01-06 华中科技大学 单质汞矿物吸附剂及其制备方法
US10099072B2 (en) 2015-12-15 2018-10-16 Vanderbilt University Adsorbent materials and methods of making and use thereof
WO2019046882A1 (en) * 2017-09-08 2019-03-14 Macquarie University CAPTURE OF MERCURY GASEOUS
CN109224829A (zh) * 2018-09-28 2019-01-18 安徽元琛环保科技股份有限公司 一种多功能型聚四氟乙烯纤维的制备方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04247237A (ja) * 1991-01-31 1992-09-03 Hitachi Zosen Corp 水銀吸着剤の再生方法
DE4422661A1 (de) * 1994-06-28 1996-01-04 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Verfahren und Anordnung zur kontinuierlichen Abtrennung von Quecksilber aus strömenden Gasen
WO2004094024A2 (en) * 2003-04-23 2004-11-04 Energy & Environmental Research Center Foundation, Inc. Process for regenerating a spent sorbent
US20170100692A1 (en) * 2003-04-23 2017-04-13 Edwin S. Olson Promoted ammonium salt-protected activated carbon sorbent particles for removal of mercury from gas streams
EP2033702A1 (de) * 2007-09-04 2009-03-11 Evonik Energy Services Gmbh Verfahren zum Entfernen von Quecksilber aus Verbrennungsabgasen
CA2757309A1 (en) * 2009-04-23 2010-10-28 Energy & Environmental Research Center Foundation Sorbents for the oxidation and removal of mercury
US20110048231A1 (en) * 2009-08-28 2011-03-03 Sinha Rabindra K Composition and Method for Reducing Mercury Emitted into the Atmosphere
US20170173557A1 (en) * 2013-03-06 2017-06-22 Energy & Environmental Research Foundation Sorbent comprising carbon and nitrogen and methods of using the same
US20140260976A1 (en) * 2013-03-15 2014-09-18 W. L. Gore & Associates, Inc. Mist Elimination and Pollutant Removal Device and Method
WO2016138193A1 (en) * 2015-02-27 2016-09-01 W.L. Gore & Associates, Inc. A flue gas purification system and process using a sorbent polymer composite material

Also Published As

Publication number Publication date
WO2020231982A1 (en) 2020-11-19
JP7650824B2 (ja) 2025-03-25
US11865496B2 (en) 2024-01-09
EP3969153A1 (en) 2022-03-23
US20220314164A1 (en) 2022-10-06
JP2022533951A (ja) 2022-07-27
JP2023179523A (ja) 2023-12-19

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